CN109627419B - 用于塑料光学镜片的多硫醇组合物 - Google Patents

用于塑料光学镜片的多硫醇组合物 Download PDF

Info

Publication number
CN109627419B
CN109627419B CN201811625363.9A CN201811625363A CN109627419B CN 109627419 B CN109627419 B CN 109627419B CN 201811625363 A CN201811625363 A CN 201811625363A CN 109627419 B CN109627419 B CN 109627419B
Authority
CN
China
Prior art keywords
polythiol
compound
polythiol compound
hydrogen
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201811625363.9A
Other languages
English (en)
Chinese (zh)
Other versions
CN109627419A (zh
Inventor
沈钟珉
明正焕
洪承模
韩赫熙
慎政焕
徐贤明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Aisikai Core Polyurethane Co ltd
Original Assignee
SKC Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SKC Co Ltd filed Critical SKC Co Ltd
Publication of CN109627419A publication Critical patent/CN109627419A/zh
Application granted granted Critical
Publication of CN109627419B publication Critical patent/CN109627419B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3855—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur
    • C08G18/3876—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing mercapto groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02—Polythioethers
    • C08G75/04—Polythioethers from mercapto compounds or metallic derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C321/00—Thiols, sulfides, hydropolysulfides or polysulfides
    • C07C321/12—Sulfides, hydropolysulfides, or polysulfides having thio groups bound to acyclic carbon atoms
    • C07C321/14—Sulfides, hydropolysulfides, or polysulfides having thio groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/24—Catalysts containing metal compounds of tin
    • C08G18/242—Catalysts containing metal compounds of tin organometallic compounds containing tin-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
    • C08G18/7628—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring containing at least one isocyanate or isothiocyanate group linked to the aromatic ring by means of an aliphatic group
    • C08G18/7642—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring containing at least one isocyanate or isothiocyanate group linked to the aromatic ring by means of an aliphatic group containing at least two isocyanate or isothiocyanate groups linked to the aromatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate groups, e.g. xylylene diisocyanate or homologues substituted on the aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/37—Thiols
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • G02B1/041—Lenses
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/24—Catalysts containing metal compounds of tin
    • C08G18/248—Catalysts containing metal compounds of tin inorganic compounds of tin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
    • C08G18/7621—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring being toluene diisocyanate including isomer mixtures
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/005—Stabilisers against oxidation, heat, light, ozone

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Inorganic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Eyeglasses (AREA)
CN201811625363.9A 2018-01-19 2018-12-28 用于塑料光学镜片的多硫醇组合物 Active CN109627419B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020180007050A KR101894921B1 (ko) 2018-01-19 2018-01-19 플라스틱 광학 렌즈용 폴리티올 조성물
KR10-2018-0007050 2018-01-19

Publications (2)

Publication Number Publication Date
CN109627419A CN109627419A (zh) 2019-04-16
CN109627419B true CN109627419B (zh) 2020-04-14

Family

ID=63598262

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811625363.9A Active CN109627419B (zh) 2018-01-19 2018-12-28 用于塑料光学镜片的多硫醇组合物

Country Status (6)

Country Link
US (1) US10435512B2 (https=)
EP (1) EP3514187B1 (https=)
JP (1) JP6700444B2 (https=)
KR (1) KR101894921B1 (https=)
CN (1) CN109627419B (https=)
TW (1) TWI675821B (https=)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101935031B1 (ko) * 2017-12-28 2019-01-03 에스케이씨 주식회사 플라스틱 광학 렌즈용 폴리티올 조성물
KR102564990B1 (ko) * 2020-12-01 2023-08-07 에스케이씨 주식회사 폴리티올 조성물 및 이를 포함하는 중합성 조성물
WO2022050662A1 (ko) * 2020-09-01 2022-03-10 에스케이씨 주식회사 폴리티올 조성물, 광학 조성물 및 광학 제품
GB2615966B (en) * 2020-11-27 2024-09-11 Sk Pucore Co Ltd Polythiol composition, optical composition, and optical product
EP4253444A4 (en) * 2020-11-27 2024-10-23 SK pucore co., ltd. POLYTHIOL COMPOSITION, OPTICAL COMPOSITION AND OPTICAL PRODUCT
KR102707088B1 (ko) * 2020-11-27 2024-09-19 에스케이피유코어 주식회사 폴리티올 조성물, 광학 조성물 및 광학 제품
CN116601200A (zh) * 2020-11-27 2023-08-15 Skc株式会社 多硫醇组合物、光学组合物和光学产品
CN114605605B (zh) * 2022-03-08 2023-03-24 益丰新材料股份有限公司 一种含有多硫醇组合物的光学材料组合物

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0351073B1 (en) * 1988-07-14 1994-09-21 MITSUI TOATSU CHEMICALS, Inc. Lens comprising a resin having a large refractive index and process for preparing the lens
FR2649711B1 (fr) * 1989-07-13 1993-01-22 Essilor Int Compositions de polymeres a base de polythiourethanes pour la fabrication de verres organiques
JPH0768326B2 (ja) * 1989-10-09 1995-07-26 三井東圧化学株式会社 ウレタン系レンズ用樹脂の製造方法
KR920007246B1 (ko) 1990-11-10 1992-08-28 현대자동차 주식회사 직접분사식 디이젤기관의 연소실
JP2695599B2 (ja) * 1993-09-29 1997-12-24 ホーヤ株式会社 ポリウレタンレンズの製造方法
US5608115A (en) 1994-01-26 1997-03-04 Mitsui Toatsu Chemicals, Inc. Polythiol useful for preparing sulfur-containing urethane-based resin and process for producing the same
JPH09194558A (ja) 1996-01-23 1997-07-29 Mitsui Toatsu Chem Inc 含硫ウレタン系プラスチックレンズ
US5942158A (en) * 1998-03-09 1999-08-24 Ppg Industries Ohio, Inc. One-component optical resin composition
JP3974404B2 (ja) * 2002-01-15 2007-09-12 三井化学株式会社 ポリチオール、その製造方法、これを含有する重合性組成物、並びに樹脂及びレンズ
JP4758987B2 (ja) * 2005-04-11 2011-08-31 三井化学株式会社 ポリチオウレタン系重合性組成物およびそれを用いた光学用樹脂の製造方法
CN101421232A (zh) * 2006-04-19 2009-04-29 三井化学株式会社 光学材料用（多）硫醇化合物的制造方法及含有该化合物的聚合性组合物
KR101029908B1 (ko) * 2006-05-05 2011-04-18 피피지 인더스트리즈 오하이오 인코포레이티드 싸이오에터 작용성 올리고머성 폴리싸이올로부터 제조된 조성물 및 제품
KR101400358B1 (ko) * 2012-05-23 2014-05-27 주식회사 케이오씨솔루션 신규한 폴리티올 화합물의 제조방법 및 이를 포함하는 광학재료용 중합성 조성물
JP5373226B1 (ja) * 2012-08-14 2013-12-18 三井化学株式会社 ポリチオール組成物、光学材料用重合性組成物およびその用途
TW201506083A (zh) * 2013-06-18 2015-02-16 Mitsubishi Gas Chemical Co 光學材料用組成物
WO2015190809A1 (ko) * 2014-06-09 2015-12-17 주식회사 케이오씨솔루션 새로운 티올화합물과 이를 포함하는 중합성 조성물
JP6438976B2 (ja) * 2015-02-02 2018-12-19 三井化学株式会社 光学材料用重合性組成物、光学材料およびその用途
BR112017016612A2 (pt) * 2015-02-05 2018-04-03 Sekisui Chemical Co., Ltd película de intercamada para vidro laminado, e vidro laminado
KR102512167B1 (ko) * 2015-03-10 2023-03-21 가부시끼가이샤 도꾸야마 포토크로믹 경화체의 제조 방법
KR101990237B1 (ko) * 2015-06-24 2019-06-17 미쯔이가가꾸가부시끼가이샤 펜타에리트리톨머캅토카르복실산에스테르의 제조 방법, 중합성 조성물, 수지, 광학 재료 및 렌즈
KR101831892B1 (ko) * 2016-06-30 2018-02-26 에스케이씨 주식회사 폴리티오우레탄계 광학 재료용 중합성 조성물
WO2018012803A1 (ko) * 2016-07-14 2018-01-18 에스케이씨 주식회사 광학 재료용 방향족 폴리티올 화합물
JP6632493B2 (ja) * 2016-08-05 2020-01-22 ホヤ レンズ タイランド リミテッドＨＯＹＡ Ｌｅｎｓ Ｔｈａｉｌａｎｄ Ｌｔｄ ポリチオール化合物の製造方法、硬化性組成物の製造方法、および硬化物の製造方法
JP6633990B2 (ja) * 2016-08-08 2020-01-22 ホヤ レンズ タイランド リミテッドＨＯＹＡ Ｌｅｎｓ Ｔｈａｉｌａｎｄ Ｌｔｄ ポリチオール化合物の製造方法、硬化性組成物の製造方法、および硬化物の製造方法

Also Published As

Publication number Publication date
TW201932449A (zh) 2019-08-16
JP2019128596A (ja) 2019-08-01
TWI675821B (zh) 2019-11-01
CN109627419A (zh) 2019-04-16
EP3514187B1 (en) 2020-07-29
JP6700444B2 (ja) 2020-05-27
EP3514187A1 (en) 2019-07-24
KR101894921B1 (ko) 2018-09-04
US10435512B2 (en) 2019-10-08
US20190225755A1 (en) 2019-07-25

Similar Documents

Publication Publication Date Title
CN109627419B (zh) 用于塑料光学镜片的多硫醇组合物
JP2018193370A (ja) 向上した安定性および反応性を有するキシリレンジイソシアネート組成物およびそれを用いた光学レンズ
TWI646073B (zh) 使用於光學材料製造的多元硫醇組成物及其製備方法
TWI653220B (zh) 用於製備使用於光學材料製造之多元硫醇化合物的方法
KR20170046763A (ko) 중합성 조성물, 투명 수지, 광학 재료, 플라스틱 렌즈 및 투명 수지의 제조 방법
TWI698420B (zh) 用於塑膠光學透鏡之多元硫醇組成物
KR101988494B1 (ko) 안정성 및 반응성이 개선된 자이릴렌디이소시아네이트 조성물, 및 이를 이용한 광학 렌즈
JPH03281312A (ja) ポリウレタンレンズの製造方法
JP6957445B2 (ja) 光学材料用重合性組成物
KR102743168B1 (ko) 폴리티올 화합물 및 그의 제조 방법
KR20220078316A (ko) 자일릴렌디이소시아네이트 조성물 및 이를 포함하는 중합성 조성물
JP6891155B2 (ja) プラスチックレンズ用重合性組成物
KR101813258B1 (ko) 광학 재료용 실록산 티올 올리고머
CN115403737B (zh) 聚合性组合物及使用其的光学材料
KR102878238B1 (ko) 폴리티올 조성물 및 이를 포함하는 광학용 중합성 조성물
KR102448166B1 (ko) 폴리티올 조성물 및 이를 포함하는 광학용 중합성 조성물
TWI896904B (zh) 苯二亞甲基二異氰酸酯組成物及包含其的光學可聚合組成物
KR102853547B1 (ko) 중합성 조성물 및 이를 이용한 광학 재료
KR101870380B1 (ko) 광학 재료용 방향족 폴리티올 화합물
KR101791221B1 (ko) 광학 재료용 방향족 폴리티올 화합물
KR101883814B1 (ko) 광학 재료용 방향족 폴리티올 화합물
JP2026513765A (ja) ポリチオウレタン系基材をプレポリマーから硬化させる方法
CN119998348A (zh) 用盐催化剂固化基于聚硫氨酯的基材的方法
CN116601200A (zh) 多硫醇组合物、光学组合物和光学产品

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20240206

Address after: 255 Longyan Road, Ulsan South District, South Korea

Patentee after: Aisikai Core Polyurethane Co.,Ltd.

Country or region after: Republic of Korea

Address before: Chang'an Road 309 Pan Street 84, Chang'an District, Shuiyuan City, Gyeonggi Road, Korea

Patentee before: SKC Co.,Ltd.

Country or region before: Republic of Korea

TR01 Transfer of patent right