CN109415529B - 制备由具有聚酰胺链段的热塑性弹性体制成的泡沫颗粒的方法 - Google Patents
制备由具有聚酰胺链段的热塑性弹性体制成的泡沫颗粒的方法 Download PDFInfo
- Publication number
- CN109415529B CN109415529B CN201780038957.7A CN201780038957A CN109415529B CN 109415529 B CN109415529 B CN 109415529B CN 201780038957 A CN201780038957 A CN 201780038957A CN 109415529 B CN109415529 B CN 109415529B
- Authority
- CN
- China
- Prior art keywords
- suspension
- impregnation
- thermoplastic elastomer
- temperature
- blowing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/16—Making expandable particles
- C08J9/18—Making expandable particles by impregnating polymer particles with the blowing agent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/12—Making granules characterised by structure or composition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/16—Auxiliary treatment of granules
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/3461—Making or treating expandable particles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/40—Polyamides containing oxygen in the form of ether groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/122—Hydrogen, oxygen, CO2, nitrogen or noble gases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/141—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
- C08J9/228—Forming foamed products
- C08J9/232—Forming foamed products by sintering expandable particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/3442—Mixing, kneading or conveying the foamable material
- B29C44/3446—Feeding the blowing agent
- B29C44/3453—Feeding the blowing agent to solid plastic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2077/00—Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2101/00—Use of unspecified macromolecular compounds as moulding material
- B29K2101/12—Thermoplastic materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0037—Other properties
- B29K2995/0063—Density
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
- C08J2201/032—Impregnation of a formed object with a gas
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
- C08J2201/034—Post-expanding of foam beads or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/06—CO2, N2 or noble gases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/22—Thermoplastic resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/26—Elastomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2371/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
- C08J2371/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
- C08J2377/06—Polyamides derived from polyamines and polycarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP16175980.8 | 2016-06-23 | ||
| EP16175980 | 2016-06-23 | ||
| PCT/EP2017/065275 WO2017220671A1 (de) | 2016-06-23 | 2017-06-21 | Verfahren zur herstellung von schaumstoffpartikeln aus thermoplastischen elastomeren mit polyamidsegmenten |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109415529A CN109415529A (zh) | 2019-03-01 |
| CN109415529B true CN109415529B (zh) | 2022-08-30 |
Family
ID=56235670
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201780038957.7A Active CN109415529B (zh) | 2016-06-23 | 2017-06-21 | 制备由具有聚酰胺链段的热塑性弹性体制成的泡沫颗粒的方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US12234338B2 (https=) |
| EP (1) | EP3475352B1 (https=) |
| JP (1) | JP7080833B2 (https=) |
| KR (1) | KR20190022727A (https=) |
| CN (1) | CN109415529B (https=) |
| BR (1) | BR112018076228A2 (https=) |
| RU (1) | RU2745267C2 (https=) |
| WO (1) | WO2017220671A1 (https=) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11499028B2 (en) | 2017-08-04 | 2022-11-15 | Basf Se | Expandable, expanding-agent-containing granules based on high-temperature thermoplastics |
| WO2019050032A1 (ja) | 2017-09-11 | 2019-03-14 | 積水化成品工業株式会社 | 熱可塑性エラストマー組成物、発泡粒子及び発泡成形体 |
| WO2019086144A1 (en) * | 2017-10-31 | 2019-05-09 | Linde Aktiengesellschaft | Method for impregnation a polymeric granulate with a physical blowing agent |
| CN108864557B (zh) * | 2018-05-29 | 2021-04-20 | 福建师范大学 | 一种运动鞋底用超轻注射离子/共价交联闭孔式发泡聚合物材料及其制备方法 |
| CN108587137B (zh) * | 2018-05-29 | 2020-11-17 | 福建师范大学 | 聚醚嵌段酰胺为基体的离子/共价交联发泡高弹耐磨超轻运动鞋底材料及其制备方法 |
| JPWO2020049802A1 (ja) * | 2018-09-04 | 2021-08-12 | 株式会社ジェイエスピー | ポリアミド系樹脂発泡粒子及びその製造方法 |
| EP3639997A1 (de) * | 2018-10-15 | 2020-04-22 | Linde Aktiengesellschaft | Verfahren zum imprägnieren von polymergranulat |
| CN109385097B (zh) * | 2018-10-23 | 2021-12-24 | 安踏(中国)有限公司 | 一种鞋用泡沫材料、其制备方法及其应用 |
| FR3093726B1 (fr) * | 2019-03-15 | 2021-10-01 | Arkema France | Procédé de fabrication d’une mousse de copolymère à blocs polyamides et à blocs polyéthers |
| CN109971025B (zh) * | 2019-03-18 | 2021-08-03 | 军事科学院系统工程研究院军需工程技术研究所 | 一种化学发泡型聚酰胺弹性体发泡材料及其制备方法 |
| WO2020196020A1 (ja) | 2019-03-28 | 2020-10-01 | 積水化成品工業株式会社 | 植物由来ポリアミド系エラストマー発泡成形体、その製造方法、及びその発泡粒子 |
| EP4079796A4 (en) * | 2019-12-18 | 2023-04-19 | Asahi Kasei Kabushiki Kaisha | PROCESS FOR PRODUCTION OF EXPANDED POLYAMIDE RESIN PARTICLES |
| JP7398294B2 (ja) * | 2020-02-18 | 2023-12-14 | 株式会社ジェイエスピー | ポリアミド系樹脂発泡粒子、ポリアミド系樹脂発泡粒子成形体およびポリアミド系樹脂発泡粒子の製造方法 |
| FR3119396B1 (fr) * | 2021-02-01 | 2024-04-19 | Arkema France | Copolymère à blocs polyamides et à blocs polyéthers pour la fabrication d’un article moussé |
| EP4293059A1 (en) | 2022-06-17 | 2023-12-20 | Basf Se | Debondable compact pu materials |
| CN119948092A (zh) * | 2022-09-29 | 2025-05-06 | 积水化成品工业株式会社 | 酰胺系弹性体发泡颗粒、酰胺系弹性体发泡成型体和该发泡成型体的制造方法 |
| EP4608902A1 (en) | 2022-10-28 | 2025-09-03 | Basf Se | Particle foam molding with different layers |
| WO2024200432A1 (en) | 2023-03-31 | 2024-10-03 | Basf Se | Preparation of storage-stable particles of a moldable thermoplastic particle foam and shaped bodies and preparation products and uses thereof |
| CN121195020A (zh) | 2023-03-31 | 2025-12-23 | 巴斯夫欧洲公司 | 制备具有涂覆颗粒的泡沫模塑部件的方法 |
| KR20260015283A (ko) | 2023-05-24 | 2026-02-02 | 바스프 에스이 | 폴리아미드 폼 입자 및 폴리아미드 폼 입자의 제조 방법 |
| WO2025002949A1 (en) | 2023-06-28 | 2025-01-02 | Basf Se | Storage-stable coated particles and their preparation |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4409400A1 (de) * | 1994-03-18 | 1995-09-21 | Basf Ag | Verfahren zur kontinuierlichen Herstellung von expandierten Polymer-Partikeln |
| CN1665866A (zh) * | 2002-07-05 | 2005-09-07 | 巴斯福股份公司 | 开孔聚丙烯泡沫颗粒 |
| WO2015052265A1 (de) * | 2013-10-11 | 2015-04-16 | Basf Se | Verfahren zur herstellung von expandierten thermoplastischen elastomerpartikeln |
| WO2015052019A1 (de) * | 2013-10-09 | 2015-04-16 | Basf Se | Verfahren zur herstellung von expandierten polyester-schaumstoffpartikeln |
| WO2016052387A1 (ja) * | 2014-09-30 | 2016-04-07 | 積水化成品工業株式会社 | アミド系エラストマー発泡粒子、その製造方法、発泡成形体及びその製造方法 |
| CN105601980A (zh) * | 2006-01-18 | 2016-05-25 | 巴斯夫欧洲公司 | 基于热塑性聚氨酯的泡沫 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6042432A (ja) | 1983-08-18 | 1985-03-06 | Japan Styrene Paper Co Ltd | 発泡粒子 |
| US4704239A (en) * | 1984-04-28 | 1987-11-03 | Japan Styrene Paper Corp. | Process for the production of expanded particles of a polymeric material |
| DE10358786A1 (de) | 2003-12-12 | 2005-07-14 | Basf Ag | Partikelschaumformteile aus expandierbaren, Füllstoff enthaltenden Polymergranulaten |
| EP1650255A1 (en) | 2004-10-19 | 2006-04-26 | Arkema | Polyether block amide foam |
| PL2336225T3 (pl) | 2009-12-17 | 2017-01-31 | Basf Se | Sposób wytwarzania cząstek poliolefinowego tworzywa piankowego |
| WO2011134996A1 (de) | 2010-04-27 | 2011-11-03 | Basf Se | Expandierbares polyamidgranulat |
| US10279516B2 (en) | 2013-06-13 | 2019-05-07 | Basf Se | Method for producing expanded granulate |
| DE102014216992A1 (de) * | 2014-08-26 | 2016-03-03 | Adidas Ag | Expandierte Polymerpellets |
-
2017
- 2017-06-21 KR KR1020197002298A patent/KR20190022727A/ko not_active Ceased
- 2017-06-21 CN CN201780038957.7A patent/CN109415529B/zh active Active
- 2017-06-21 WO PCT/EP2017/065275 patent/WO2017220671A1/de not_active Ceased
- 2017-06-21 RU RU2019101612A patent/RU2745267C2/ru active
- 2017-06-21 US US16/311,888 patent/US12234338B2/en active Active
- 2017-06-21 EP EP17731582.7A patent/EP3475352B1/de active Active
- 2017-06-21 JP JP2018567678A patent/JP7080833B2/ja active Active
- 2017-06-21 BR BR112018076228-8A patent/BR112018076228A2/pt not_active Application Discontinuation
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4409400A1 (de) * | 1994-03-18 | 1995-09-21 | Basf Ag | Verfahren zur kontinuierlichen Herstellung von expandierten Polymer-Partikeln |
| CN1665866A (zh) * | 2002-07-05 | 2005-09-07 | 巴斯福股份公司 | 开孔聚丙烯泡沫颗粒 |
| CN105601980A (zh) * | 2006-01-18 | 2016-05-25 | 巴斯夫欧洲公司 | 基于热塑性聚氨酯的泡沫 |
| WO2015052019A1 (de) * | 2013-10-09 | 2015-04-16 | Basf Se | Verfahren zur herstellung von expandierten polyester-schaumstoffpartikeln |
| WO2015052265A1 (de) * | 2013-10-11 | 2015-04-16 | Basf Se | Verfahren zur herstellung von expandierten thermoplastischen elastomerpartikeln |
| WO2016052387A1 (ja) * | 2014-09-30 | 2016-04-07 | 積水化成品工業株式会社 | アミド系エラストマー発泡粒子、その製造方法、発泡成形体及びその製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| RU2019101612A (ru) | 2020-07-23 |
| JP2019518859A (ja) | 2019-07-04 |
| EP3475352B1 (de) | 2026-04-29 |
| JP7080833B2 (ja) | 2022-06-06 |
| EP3475352A1 (de) | 2019-05-01 |
| US12234338B2 (en) | 2025-02-25 |
| CN109415529A (zh) | 2019-03-01 |
| WO2017220671A1 (de) | 2017-12-28 |
| US20190203009A1 (en) | 2019-07-04 |
| RU2745267C2 (ru) | 2021-03-22 |
| BR112018076228A2 (pt) | 2019-03-26 |
| KR20190022727A (ko) | 2019-03-06 |
| RU2019101612A3 (https=) | 2020-10-09 |
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