RU2019101612A - Способ получения пенопластовых частиц из термопластичных эластомеров с полиамидными сегментами - Google Patents

Способ получения пенопластовых частиц из термопластичных эластомеров с полиамидными сегментами Download PDF

Info

Publication number
RU2019101612A
RU2019101612A RU2019101612A RU2019101612A RU2019101612A RU 2019101612 A RU2019101612 A RU 2019101612A RU 2019101612 A RU2019101612 A RU 2019101612A RU 2019101612 A RU2019101612 A RU 2019101612A RU 2019101612 A RU2019101612 A RU 2019101612A
Authority
RU
Russia
Prior art keywords
impregnation
range
suspension
temperature
imt
Prior art date
Application number
RU2019101612A
Other languages
English (en)
Other versions
RU2745267C2 (ru
RU2019101612A3 (ru
Inventor
Уве КЕППЕЛЕР
Юрген БАРТЛЬ
Юрген АЛЕРС
Кристиан ДЕШЛАЙН
Петер Гутманн
Франк ПРИССОК
Original Assignee
Басф Се
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Басф Се filed Critical Басф Се
Publication of RU2019101612A publication Critical patent/RU2019101612A/ru
Publication of RU2019101612A3 publication Critical patent/RU2019101612A3/ru
Application granted granted Critical
Publication of RU2745267C2 publication Critical patent/RU2745267C2/ru

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00—Making granules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00—Making granules
    • B29B9/12—Making granules characterised by structure or composition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00—Making granules
    • B29B9/16—Auxiliary treatment of granules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34—Auxiliary operations
    • B29C44/3461—Making or treating expandable particles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/40—Polyamides containing oxygen in the form of ether groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/122—Hydrogen, oxygen, CO2, nitrogen or noble gases
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/141—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/16—Making expandable particles
    • C08J9/18—Making expandable particles by impregnating polymer particles with the blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/22—After-treatment of expandable particles; Forming foamed products
    • C08J9/228—Forming foamed products
    • C08J9/232—Forming foamed products by sintering expandable particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34—Auxiliary operations
    • B29C44/3442—Mixing, kneading or conveying the foamable material
    • B29C44/3446—Feeding the blowing agent
    • B29C44/3453—Feeding the blowing agent to solid plastic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2077/00—Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2101/00—Use of unspecified macromolecular compounds as moulding material
    • B29K2101/12—Thermoplastic materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0037—Other properties
    • B29K2995/0063—Density
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00—Foams characterised by the foaming process
    • C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
    • C08J2201/032—Impregnation of a formed object with a gas
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00—Foams characterised by the foaming process
    • C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
    • C08J2201/034—Post-expanding of foam beads or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/06—CO2, N2 or noble gases
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2300/00—Characterised by the use of unspecified polymers
    • C08J2300/22—Thermoplastic resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2300/00—Characterised by the use of unspecified polymers
    • C08J2300/26—Elastomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2371/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
    • C08J2371/02—Polyalkylene oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • C08J2377/06—Polyamides derived from polyamines and polycarboxylic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Claims (20)

1. Способ получения пенопластовых частиц из термопластичных эластомеров с полиамидными сегментами, который включает следующие стадии:
(a) получение суспензии гранулятов термопластичного эластомера в суспензионной среде,
(b) добавление вспенивающего агента,
(c) пропитку гранулятов вспенивающим агентом посредством нагревания суспензии в резервуаре высокого давления до температуры пропитки (IMT) при давлении пропитки (IMP),
(d) декомпрессию суспензии посредством опорожнения резервуара высокого давления посредством расширительного устройства и обработку полученных пенопластовых частиц.
2. Способ по п. 1, отличающийся тем, что в качестве термопластичных эластомеров используют полиэфирблокамиды (РЕВА).
3. Способ по п. 1, отличающийся тем, что содержание азота в термопластичном эластомере составляет от 0,5 до 7,5% масс.
4. Способ по п. 1, отличающийся тем, что температура размягчения по Вика термопластичного эластомера согласно стандарту DIN EN ISO 306 при испытательном усилии 10 Н, составляет от 40 до 170°С.
5. Способ по п. 1, отличающийся тем, что грануляты обладают средней массой в диапазоне от 1 до 50 мг.
6. Способ по п. 1, отличающийся тем, что в качестве суспензионной среды используют воду.
7. Способ по п. 1, отличающийся тем, что в качестве вспенивающего агента используют углеводород с 3-6 атомами углерода, диоксид углерода, азот или их смеси.
8. Способ по п. 1, отличающийся тем, что пропитку на стадии (с) осуществляют при температуре пропитки (IMT) в интервале от 80 до 180°С.
9. Способ по п. 1, отличающийся тем, что для пропитки на стадии (с) суспензию нагревают до температуры пропитки (IMT) со скоростью 2°С/мин или более и выдерживают в температурном интервале от температуры, которая на 2°С выше IMT, до температуры, которая до 5°С ниже IMT, в течение промежутка времени от 2 до 100 минут.
10. Способ по п. 1, отличающийся тем, что пропитку на стадии (с) осуществляют при абсолютных значениях давления пропитки (IMP) в диапазоне от 150 до 5500 кПа.
11. Способ по п. 1, отличающийся тем, что на стадии (с) при температуре суспензии в диапазоне от 30 до 75°С в резервуар высокого давления подают азот, вследствие чего давление пропитки (IMP) устанавливается в диапазоне от 500 до 4000 кПа.
12. Способ по п. 1, отличающийся тем, что декомпрессию суспензии на стадии (d) осуществляют посредством опорожнения резервуара высокого давления в расширительный резервуар через шариковый кран.
13. Способ по одному из пп. 1-12, отличающийся тем, что на стадии (d) суспензию после расширительного устройства приводят в контакт с жидким охлаждающим агентом.
14. Пенопластовые частицы из термопластичных эластомеров с полиамидными сегментами и насыпной плотностью в диапазоне от 20 до 250 кг/м3, получаемые способом по одному из пп. 1-13.
15. Пенопластовые формованные изделия, получаемые свариванием пенопластовых частиц по п. 14 посредством водяного пара.
Пенопластовые формованные изделия по п. 15 с эластичностью по отскоку шарика по меньшей мере 55%, измеренной согласно стандарту DIN EN ISO 8307.
RU2019101612A 2016-06-23 2017-06-21 Способ получения пенопластовых частиц из термопластичных эластомеров с полиамидными сегментами RU2745267C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP16175980.8 2016-06-23
EP16175980 2016-06-23
PCT/EP2017/065275 WO2017220671A1 (de) 2016-06-23 2017-06-21 Verfahren zur herstellung von schaumstoffpartikeln aus thermoplastischen elastomeren mit polyamidsegmenten

Publications (3)

Publication Number Publication Date
RU2019101612A true RU2019101612A (ru) 2020-07-23
RU2019101612A3 RU2019101612A3 (ru) 2020-10-09
RU2745267C2 RU2745267C2 (ru) 2021-03-22

Family

ID=56235670

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2019101612A RU2745267C2 (ru) 2016-06-23 2017-06-21 Способ получения пенопластовых частиц из термопластичных эластомеров с полиамидными сегментами

Country Status (8)

Country Link
US (1) US20190203009A1 (ru)
EP (1) EP3475352A1 (ru)
JP (1) JP7080833B2 (ru)
KR (1) KR20190022727A (ru)
CN (1) CN109415529B (ru)
BR (1) BR112018076228A2 (ru)
RU (1) RU2745267C2 (ru)
WO (1) WO2017220671A1 (ru)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11499028B2 (en) 2017-08-04 2022-11-15 Basf Se Expandable, expanding-agent-containing granules based on high-temperature thermoplastics
US11643538B2 (en) 2017-09-11 2023-05-09 Sekisui Plastics Co., Ltd. Thermoplastic elastomer composition, foam particle, and foam molded body
US11780118B2 (en) * 2017-10-31 2023-10-10 Messer Industries Usa, Inc. Method for impregnation a polymeric granulate with a physical blowing agent
CN108587137B (zh) * 2018-05-29 2020-11-17 福建师范大学 聚醚嵌段酰胺为基体的离子/共价交联发泡高弹耐磨超轻运动鞋底材料及其制备方法
CN108864557B (zh) * 2018-05-29 2021-04-20 福建师范大学 一种运动鞋底用超轻注射离子/共价交联闭孔式发泡聚合物材料及其制备方法
WO2020049802A1 (ja) * 2018-09-04 2020-03-12 株式会社ジェイエスピー ポリアミド系樹脂発泡粒子及びその製造方法
EP3639997A1 (de) * 2018-10-15 2020-04-22 Linde Aktiengesellschaft Verfahren zum imprägnieren von polymergranulat
CN113755017B (zh) * 2018-10-23 2023-04-07 安踏（中国）有限公司 一种鞋用泡沫材料、其制备方法及其应用
FR3093726B1 (fr) * 2019-03-15 2021-10-01 Arkema France Procédé de fabrication d’une mousse de copolymère à blocs polyamides et à blocs polyéthers
CN109971025B (zh) * 2019-03-18 2021-08-03 军事科学院系统工程研究院军需工程技术研究所 一种化学发泡型聚酰胺弹性体发泡材料及其制备方法
US20220153949A1 (en) * 2019-03-28 2022-05-19 Sekisui Plastics Co., Ltd. Plant-derived polyamide-based elastomer foam molded body, method for manufacturing same, and foam particles thereof
EP4079796A4 (en) * 2019-12-18 2023-04-19 Asahi Kasei Kabushiki Kaisha PROCESS FOR PRODUCTION OF EXPANDED POLYAMIDE RESIN PARTICLES
FR3119396B1 (fr) * 2021-02-01 2024-04-19 Arkema France Copolymère à blocs polyamides et à blocs polyéthers pour la fabrication d’un article moussé
EP4293059A1 (en) 2022-06-17 2023-12-20 Basf Se Debondable compact pu materials
WO2024070887A1 (ja) * 2022-09-29 2024-04-04 積水化成品工業株式会社 アミド系エラストマー発泡粒子、アミド系エラストマー発泡成形体、及び当該発泡成形体の製造方法
WO2024089016A1 (en) 2022-10-28 2024-05-02 Basf Se Particle foam molding with different layers

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6042432A (ja) * 1983-08-18 1985-03-06 Japan Styrene Paper Co Ltd 発泡粒子
DE4409400A1 (de) * 1994-03-18 1995-09-21 Basf Ag Verfahren zur kontinuierlichen Herstellung von expandierten Polymer-Partikeln
DE10230583A1 (de) * 2002-07-05 2004-01-15 Basf Ag Offenzellige Polypropylen-Partikelschäume
DE10358786A1 (de) * 2003-12-12 2005-07-14 Basf Ag Partikelschaumformteile aus expandierbaren, Füllstoff enthaltenden Polymergranulaten
EP1650255A1 (en) 2004-10-19 2006-04-26 Arkema Polyether block amide foam
WO2007082838A1 (de) * 2006-01-18 2007-07-26 Basf Se Schaumstoffe auf basis thermoplastischer polyurethane
PL2336225T3 (pl) 2009-12-17 2017-01-31 Basf Se Sposób wytwarzania cząstek poliolefinowego tworzywa piankowego
HUE028448T2 (en) 2010-04-27 2016-12-28 Basf Se Expandable polyamide granulate
JP6386543B2 (ja) 2013-06-13 2018-09-05 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 膨張ペレットの製造
EP3055351B1 (de) 2013-10-09 2017-09-13 Basf Se Verfahren zur herstellung von expandierten polyester-schaumstoffpartikeln
TWI656153B (zh) * 2013-10-11 2019-04-11 巴斯夫歐洲公司 膨脹熱塑性彈性體珠粒之製造
DE102014216992A1 (de) 2014-08-26 2016-03-03 Adidas Ag Expandierte Polymerpellets
JP6081674B2 (ja) * 2014-09-30 2017-02-15 積水化成品工業株式会社 アミド系エラストマー発泡粒子、その製造方法、発泡成形体及びその製造方法

Also Published As

Publication number Publication date
CN109415529B (zh) 2022-08-30
JP7080833B2 (ja) 2022-06-06
EP3475352A1 (de) 2019-05-01
US20190203009A1 (en) 2019-07-04
KR20190022727A (ko) 2019-03-06
RU2745267C2 (ru) 2021-03-22
CN109415529A (zh) 2019-03-01
BR112018076228A2 (pt) 2019-03-26
JP2019518859A (ja) 2019-07-04
RU2019101612A3 (ru) 2020-10-09
WO2017220671A1 (de) 2017-12-28

Similar Documents

Publication Publication Date Title
RU2019101612A (ru) Способ получения пенопластовых частиц из термопластичных эластомеров с полиамидными сегментами
JP2019518859A5 (ru)
CN104194030B (zh) 一种热塑性聚氨酯弹性体发泡珠粒及其制备方法
ATE544806T1 (de) Verfahren zur herstellung von flexiblem, elastischem polyurethanschaum und damit erhaltener schaum
Liao et al. The effects of viscoelastic properties on the cellular morphology of silicone rubber foams generated by supercritical carbon dioxide
Ge et al. Preparation of microcellular thermoplastic polyurethane (TPU) foam and its tensile property
CN104130439A (zh) 一种热塑性聚氨酯弹性体发泡珠粒及其制备方法
CN107177051A (zh) 制备热塑性弹性体发泡珠粒的方法
JP2019521231A (ja) 高倍率の熱可塑性ポリウレタン微細孔発泡シート及びその生産方法
RU2017133125A (ru) Пенопласт на основе фенольной смолы и способ его получения
CN107614583A (zh) 热塑性聚氨酯发泡粒子以及热塑性聚氨酯发泡粒子成形体
JP2008056927A5 (ru)
JP2014062213A (ja) 熱可塑性ポリウレタン樹脂発泡粒子とその製造方法及び熱可塑性ポリウレタン樹脂発泡成形体
WO2019014959A1 (zh) 一种低密度发泡热塑性聚氨酯弹性体及其制备方法
Haugen et al. Water as foaming agent for open cell polyurethane structures
MX2011009198A (es) Material de espuma de particula elastica a base de mezclas de poliolefina/polimero de estireno.
CN114729148A (zh) 聚酰胺树脂发泡颗粒的制造方法
KR102516853B1 (ko) 발포 입자 성형체
CN111511788A (zh) 用于舒适应用的聚氨基甲酸酯泡沫
US20230031181A1 (en) Physical foaming process using foaming press
RU2019120988A (ru) Способ производства экспандированных термопластичных полимеров
SU470967A3 (ru) Способ получени изделий из пенопластов
KR101181377B1 (ko) 폴리스틸렌 발포립 제조방법 및 이에 의해 제조되는 폴리스틸렌 발포립, 그리고 폴리스틸렌 발포립을 이용한 유연성 충진제품
CN109354707A (zh) 一种发泡尼龙复合材料及其制备方法
JP7449791B2 (ja) ビーズ複合材及びその製造方法