CN109065897A - 磷掺杂孔状碳包覆四氧化三钴氧还原催化剂及其制备方法和应用 - Google Patents
磷掺杂孔状碳包覆四氧化三钴氧还原催化剂及其制备方法和应用 Download PDFInfo
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- CN109065897A CN109065897A CN201810922115.4A CN201810922115A CN109065897A CN 109065897 A CN109065897 A CN 109065897A CN 201810922115 A CN201810922115 A CN 201810922115A CN 109065897 A CN109065897 A CN 109065897A
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- catalyst
- oxygen reduction
- zif
- phosphorus
- cobaltosic oxide
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- 239000003054 catalyst Substances 0.000 title claims abstract description 90
- UBEWDCMIDFGDOO-UHFFFAOYSA-N cobalt(2+);cobalt(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Co+2].[Co+3].[Co+3] UBEWDCMIDFGDOO-UHFFFAOYSA-N 0.000 title claims abstract description 82
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 43
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 43
- 239000001301 oxygen Substances 0.000 title claims abstract description 43
- 238000002360 preparation method Methods 0.000 title claims abstract description 42
- 230000009467 reduction Effects 0.000 title claims abstract description 39
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 27
- FENRSEGZMITUEF-ATTCVCFYSA-E [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].OP(=O)([O-])O[C@@H]1[C@@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H]1OP(=O)([O-])[O-] Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].OP(=O)([O-])O[C@@H]1[C@@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H]1OP(=O)([O-])[O-] FENRSEGZMITUEF-ATTCVCFYSA-E 0.000 claims abstract description 35
- 229940083982 sodium phytate Drugs 0.000 claims abstract description 35
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 27
- 239000011574 phosphorus Substances 0.000 claims abstract description 27
- 229910052751 metal Inorganic materials 0.000 claims abstract description 8
- 239000002184 metal Substances 0.000 claims abstract description 8
- 239000012298 atmosphere Substances 0.000 claims abstract description 5
- 238000003837 high-temperature calcination Methods 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- 239000008367 deionised water Substances 0.000 claims description 22
- 229910021641 deionized water Inorganic materials 0.000 claims description 22
- 150000001875 compounds Chemical class 0.000 claims description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
- 239000011248 coating agent Substances 0.000 claims description 16
- 238000000576 coating method Methods 0.000 claims description 16
- 229910052573 porcelain Inorganic materials 0.000 claims description 16
- 238000001354 calcination Methods 0.000 claims description 10
- 239000000446 fuel Substances 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 9
- 239000006185 dispersion Substances 0.000 claims description 8
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 8
- 238000001291 vacuum drying Methods 0.000 claims description 8
- 238000010792 warming Methods 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 8
- 238000004090 dissolution Methods 0.000 claims description 5
- 238000005303 weighing Methods 0.000 claims description 5
- 239000013078 crystal Substances 0.000 claims description 4
- 239000011541 reaction mixture Substances 0.000 claims description 3
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 238000006722 reduction reaction Methods 0.000 abstract description 34
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract description 18
- 238000006243 chemical reaction Methods 0.000 abstract description 13
- 239000003575 carbonaceous material Substances 0.000 abstract description 12
- 238000006555 catalytic reaction Methods 0.000 abstract description 8
- 239000010411 electrocatalyst Substances 0.000 abstract description 3
- 239000002243 precursor Substances 0.000 abstract description 2
- 238000003860 storage Methods 0.000 abstract description 2
- 230000002195 synergetic effect Effects 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 20
- 238000000034 method Methods 0.000 description 19
- 230000003197 catalytic effect Effects 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 13
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 10
- 230000008569 process Effects 0.000 description 8
- 230000008901 benefit Effects 0.000 description 7
- 239000000463 material Substances 0.000 description 6
- 230000004048 modification Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 230000007246 mechanism Effects 0.000 description 4
- 229910000510 noble metal Inorganic materials 0.000 description 4
- 230000027756 respiratory electron transport chain Effects 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000011017 operating method Methods 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 230000004044 response Effects 0.000 description 3
- 229910000314 transition metal oxide Inorganic materials 0.000 description 3
- 239000010953 base metal Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000002242 deionisation method Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 150000002460 imidazoles Chemical class 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- 239000013110 organic ligand Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 description 1
- 229920000557 Nafion® Polymers 0.000 description 1
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- CODVACFVSVNQPY-UHFFFAOYSA-N [Co].[C] Chemical compound [Co].[C] CODVACFVSVNQPY-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910003481 amorphous carbon Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 229910021389 graphene Inorganic materials 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000003863 metallic catalyst Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229940068041 phytic acid Drugs 0.000 description 1
- 235000002949 phytic acid Nutrition 0.000 description 1
- 239000000467 phytic acid Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000001338 self-assembly Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000010408 sweeping Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8825—Methods for deposition of the catalytic active composition
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9075—Catalytic material supported on carriers, e.g. powder carriers
- H01M4/9083—Catalytic material supported on carriers, e.g. powder carriers on carbon or graphite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Catalysts (AREA)
Abstract
Description
Claims (3)
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CN201810922115.4A CN109065897B (zh) | 2018-08-14 | 2018-08-14 | 磷掺杂孔状碳包覆四氧化三钴氧还原催化剂及其制备方法和应用 |
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CN201810922115.4A CN109065897B (zh) | 2018-08-14 | 2018-08-14 | 磷掺杂孔状碳包覆四氧化三钴氧还原催化剂及其制备方法和应用 |
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CN109065897A true CN109065897A (zh) | 2018-12-21 |
CN109065897B CN109065897B (zh) | 2021-05-04 |
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Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109809498A (zh) * | 2019-02-03 | 2019-05-28 | 复旦大学 | 一种三维多级孔四氧化三钴材料及其制备方法和应用 |
CN110436430A (zh) * | 2019-08-21 | 2019-11-12 | 河南师范大学 | 具有独特分级结构的双功能电催化剂的制备方法及其应用 |
CN110635144A (zh) * | 2019-10-23 | 2019-12-31 | 湖南科技大学 | 氮-钴-磷共掺杂的碳空心球复合材料的制备及产品和应用 |
CN111362254A (zh) * | 2020-03-17 | 2020-07-03 | 广西师范大学 | 一种氮掺杂碳纳米管负载磷掺杂四氧化三钴复合材料的制备方法及应用 |
CN111740083A (zh) * | 2020-06-12 | 2020-10-02 | 新昌县华发机械股份有限公司 | 一种碳包覆多孔Co3O4微球的锂离子电池负极材料及其制法 |
CN111785971A (zh) * | 2020-07-17 | 2020-10-16 | 扬州大学 | 一种MWCNT/PCN/Co3O4复合纳米材料的制备方法及锂硫电池正极材料 |
CN111952604A (zh) * | 2020-07-29 | 2020-11-17 | 天津大学 | 一种一体式氧还原催化电极及其用途 |
CN113042087A (zh) * | 2021-03-29 | 2021-06-29 | 陕西科技大学 | 一种电催化双功能氮掺杂碳负载碳包覆磷化钴核壳纳米材料的制备方法 |
CN113437314A (zh) * | 2021-06-29 | 2021-09-24 | 青岛科技大学 | 氮掺杂碳负载低含量钌和Co2P纳米粒子的三功能电催化剂及其制备方法和应用 |
CN114171747A (zh) * | 2021-10-12 | 2022-03-11 | 南京林业大学 | 一种镂空多面体四氧化三钴/碳基复合载体锚定钯纳米材料及其制备方法和应用 |
CN114592210A (zh) * | 2022-01-22 | 2022-06-07 | 温州大学新材料与产业技术研究院 | 一种Co3O4-RuO2复合材料的制备方法及应用 |
CN114892201A (zh) * | 2022-05-12 | 2022-08-12 | 华南师范大学 | 磷掺杂多孔碳包覆石墨毡材料及其制备方法和应用 |
CN115050977A (zh) * | 2022-06-20 | 2022-09-13 | 江苏展鸣新能源有限公司 | 一种应用于锌-空气电池的多孔碳负载Co3O4电催化剂及制法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2236578A1 (en) * | 2008-01-04 | 2010-10-06 | Guang Yang | A new lumber adhesive and the preparation thereof |
US8961768B2 (en) * | 2008-12-29 | 2015-02-24 | Basf Corporation | Metal containing integrated electrocoat for better corrosion resistance |
CN106111171A (zh) * | 2016-06-29 | 2016-11-16 | 武汉大学苏州研究院 | 一种碳层包裹的磷化钴的制备方法 |
CN106449179A (zh) * | 2016-11-26 | 2017-02-22 | 桂林理工大学 | 一种mof/氮掺杂活性炭非对称超级电容器器件的组装方法 |
CN107199044A (zh) * | 2017-06-13 | 2017-09-26 | 兰州理工大学 | 一种氮掺杂碳负载四氧化三钴催化剂的制备方法 |
-
2018
- 2018-08-14 CN CN201810922115.4A patent/CN109065897B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2236578A1 (en) * | 2008-01-04 | 2010-10-06 | Guang Yang | A new lumber adhesive and the preparation thereof |
US8961768B2 (en) * | 2008-12-29 | 2015-02-24 | Basf Corporation | Metal containing integrated electrocoat for better corrosion resistance |
CN106111171A (zh) * | 2016-06-29 | 2016-11-16 | 武汉大学苏州研究院 | 一种碳层包裹的磷化钴的制备方法 |
CN106449179A (zh) * | 2016-11-26 | 2017-02-22 | 桂林理工大学 | 一种mof/氮掺杂活性炭非对称超级电容器器件的组装方法 |
CN107199044A (zh) * | 2017-06-13 | 2017-09-26 | 兰州理工大学 | 一种氮掺杂碳负载四氧化三钴催化剂的制备方法 |
Non-Patent Citations (3)
Title |
---|
SHANPENG LI: "Polycrystalline CoP/CoP2 structures for efficient full water splitting", 《CHEMELECTROCHEM》 * |
TIANRONG ZHAN: "Alginate derived Co3O4/Co nanoparticles decorated in N-doped porous carbon as an efficient bifunctional catalyst for oxygen evolution and reductoin reactions", 《ELCTROCHIMICA ACTA》 * |
YINGBIN HUANG: "Co3O4 supported on N,P-doped carbon as a bifunctional electrocatalyst for oxygen reduction and evolution reactions", 《CHINESE JOURNAL OF CATALYSIS》 * |
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109809498A (zh) * | 2019-02-03 | 2019-05-28 | 复旦大学 | 一种三维多级孔四氧化三钴材料及其制备方法和应用 |
CN110436430A (zh) * | 2019-08-21 | 2019-11-12 | 河南师范大学 | 具有独特分级结构的双功能电催化剂的制备方法及其应用 |
CN110436430B (zh) * | 2019-08-21 | 2022-07-19 | 河南师范大学 | 双功能电催化剂的制备方法及其应用 |
CN110635144B (zh) * | 2019-10-23 | 2022-03-18 | 湖南科技大学 | 氮-钴-磷共掺杂的碳空心球复合材料的制备及产品和应用 |
CN110635144A (zh) * | 2019-10-23 | 2019-12-31 | 湖南科技大学 | 氮-钴-磷共掺杂的碳空心球复合材料的制备及产品和应用 |
CN111362254A (zh) * | 2020-03-17 | 2020-07-03 | 广西师范大学 | 一种氮掺杂碳纳米管负载磷掺杂四氧化三钴复合材料的制备方法及应用 |
CN111362254B (zh) * | 2020-03-17 | 2022-07-05 | 广西师范大学 | 一种氮掺杂碳纳米管负载磷掺杂四氧化三钴复合材料的制备方法及应用 |
CN111740083A (zh) * | 2020-06-12 | 2020-10-02 | 新昌县华发机械股份有限公司 | 一种碳包覆多孔Co3O4微球的锂离子电池负极材料及其制法 |
CN111785971A (zh) * | 2020-07-17 | 2020-10-16 | 扬州大学 | 一种MWCNT/PCN/Co3O4复合纳米材料的制备方法及锂硫电池正极材料 |
CN111952604A (zh) * | 2020-07-29 | 2020-11-17 | 天津大学 | 一种一体式氧还原催化电极及其用途 |
CN113042087A (zh) * | 2021-03-29 | 2021-06-29 | 陕西科技大学 | 一种电催化双功能氮掺杂碳负载碳包覆磷化钴核壳纳米材料的制备方法 |
CN113437314A (zh) * | 2021-06-29 | 2021-09-24 | 青岛科技大学 | 氮掺杂碳负载低含量钌和Co2P纳米粒子的三功能电催化剂及其制备方法和应用 |
CN114171747A (zh) * | 2021-10-12 | 2022-03-11 | 南京林业大学 | 一种镂空多面体四氧化三钴/碳基复合载体锚定钯纳米材料及其制备方法和应用 |
CN114592210A (zh) * | 2022-01-22 | 2022-06-07 | 温州大学新材料与产业技术研究院 | 一种Co3O4-RuO2复合材料的制备方法及应用 |
CN114592210B (zh) * | 2022-01-22 | 2024-05-14 | 温州大学新材料与产业技术研究院 | 一种Co3O4-RuO2复合材料的制备方法及应用 |
CN114892201A (zh) * | 2022-05-12 | 2022-08-12 | 华南师范大学 | 磷掺杂多孔碳包覆石墨毡材料及其制备方法和应用 |
CN114892201B (zh) * | 2022-05-12 | 2024-04-30 | 华南师范大学 | 磷掺杂多孔碳包覆石墨毡材料及其制备方法和应用 |
CN115050977A (zh) * | 2022-06-20 | 2022-09-13 | 江苏展鸣新能源有限公司 | 一种应用于锌-空气电池的多孔碳负载Co3O4电催化剂及制法 |
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