CN108914574A - 一种抗皱防缩丝织面料的制备方法 - Google Patents

一种抗皱防缩丝织面料的制备方法 Download PDF

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CN108914574A
CN108914574A CN201810824514.7A CN201810824514A CN108914574A CN 108914574 A CN108914574 A CN 108914574A CN 201810824514 A CN201810824514 A CN 201810824514A CN 108914574 A CN108914574 A CN 108914574A
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CN108914574B (zh
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李德喜
陈宗明
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Suzhou Zhisheng Silk Technology Center
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Suzhou City Tianao Special Embroidery Co Ltd
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Abstract

本发明提供了一种抗皱防缩丝织面料的制备方法，首先将面料用氢氧化钠溶液进行处理，浸入三羟甲基丙烷三丙烯酸酯的DMF溶液中，在面料表面接枝二甲基二羟基乙烯脲和八甲基环四硅氧烷，再将接枝的面料用含琥珀酸苷改性的纳米二氧化硅、二氯异氰尿酸钠、氟基烷基聚醚改性聚硅氧烷、壳聚糖、丝素蛋白、海藻酸钠的乙醇溶液进行处理，制得抗皱防缩面料。通过测试结果得出，经处理的面料的折皱回复角高达298°，与未处理的面料相比，其折皱回复角提高一倍以上，具有良好的折皱回复性能。面料的断裂强度降为857N，强力保留率达到91.4%，因此，本发明制得面料与未处理的面料相比在抗皱性能方面具有更大的优势。

Description

一种抗皱防缩丝织面料的制备方法
技术领域
本发明属于纺织技术领域，具体涉及一种抗皱防缩丝织面料的制备方法。
背景技术
丝织面料手感柔软，吸湿透气性好，穿着舒适，但存在易起皱和收缩的缺陷，影响了丝织面料的服用性能。因此，长期以来人们一直致力于提高丝织面料的防皱性。进入90年代，随着人们对穿着卫生的日益重视，开发新一代抗皱防缩面料的需求越来越大。
目前开发出了多种抗皱防缩丝织面料，但是面料的抗皱性能较差，并且面料经处理后的强力保留率较低，因此对面料的整体处理效果较差，影响面料的质量、抗皱效果、以及抗皱性能的周期。因此，有必要对抗皱防缩面料进行进一步开发，使得整理后的丝织面料具有更好的防缩抗皱性和良好的机械强度，从而实现耐洗牢度、吸湿透气性好，并且保持丝织面料原有的品质。
发明内容
为了解决以上现有技术存在的技术问题，本发明的目的在于提供一种抗皱防缩丝织面料的制备方法，以提高织物的抗皱防缩性能。
为了实现上述目的，本发明提供以下技术方案：
一种抗皱防缩丝织面料的制备方法，包括以下步骤：
（1）将丝织面料质量分数为3-8％的氢氧化钠溶液中处理，处理温度为35-50℃，处理时间3-5h，然后将面料用去离子水超声机洗15-30min，超声功率为300-500W，将面料甩干烘干后备用；
（2）将三羟甲基丙烷三丙烯酸酯加入DMF溶剂中使其体积分数为30-50%，将步骤（1）制备的面料浸入三羟甲基丙烷三丙烯酸酯的DMF溶液中，在200-400r/min搅拌的条件下加入步骤（1）处理后的面料，然后加入最终质量分数为10-20%的光引发剂，在40-50℃的温度下继续搅拌反应15-22h，然后取出面料，将其置于玻璃板上盖上石英片，置入紫外光下进行紫外光辐射；辐射完成后，将面料取出用DMF溶液进行清洗3-5次，然后用水溶液清洗3-5次，得到表面接枝的面料；
（3）将步骤（2）接枝的面料在4-8wt％的乙二胺溶液中浸渍反应3-6h，再用去离子水清洗，然后再将其浸入含7-15wt％二甲基二羟基乙烯脲、5-10wt%八甲基环四硅氧烷的乙酸乙酯溶液中浸渍反应8-12h，然后用去离子水洗涤4-5次，将水分甩干后烘干面料；
（4）将纳米二氧化硅80-100份加入5-10倍重量份的含5-10wt% 4-二甲胺基吡啶的吡啶溶液中，在搅拌的状态下加入10-20份琥珀酸苷，于70-90℃的温度下搅拌反应4-6h，将反应溶液取出，加入冰水中，并调节冰水pH为2-3，然后用乙酸乙酯进行萃取，去除上层有机相，并用旋蒸仪对将溶剂旋干，收集旋干物；
（5）将步骤（4）收集的旋干物10-20份、二氯异氰尿酸钠12-18份、氟基烷基聚醚改性聚硅氧烷8-16份、壳聚糖10-18份、丝素蛋白9-15份、海藻酸钠6-10份加入30-50份乙醇溶液中，将各原料搅拌均匀后，将步骤（3）处理的面料加入混合溶液中浸渍处理4-6h，然后将面料取出甩干，置于烘箱中烘干制得成品。
优选的，所述步骤（2）中的光引发剂为4-（二甲氨基）苯甲酸乙酯。
优选的，所述步骤（3）中各原料的质量分数为：乙二胺6wt％、二甲基二羟基乙烯脲11wt％、八甲基环四硅氧烷7.5wt%。
优选的，所述步骤（5）中各原料的重量份为：步骤（4）收集的旋干物15份、二氯异氰尿酸钠15份、氟基烷基聚醚改性聚硅氧烷12份、壳聚糖14份、丝素蛋白12份、海藻酸钠8份、乙醇40份。
有益效果：本发明提供了一种抗皱防缩丝织面料的制备方法，本发明通过将抗皱原料接枝到面料的表面的方式制得抗皱防缩丝织面料，这种处理方式更大的提高了原料在面料表面的附着度，对提高面料的抗皱性能具有重要的作用。通过测试结果得出，经处理的面料的折皱回复角高达298°，与未处理的面料相比，其折皱回复角提高一倍以上，因此面料的回弹性具有较大的提高，具有良好的折皱回复性能。面料的断裂强度降为857N，强力保留率达到91.4%，因此，本发明制得面料与未处理的面料相比在抗皱性能方面具有更大的优势。
具体实施方式
下面结合具体实施例来进一步描述本发明，但实施例仅是范例性的，并不对本发明的范围构成任何限制。本领域技术人员应该理解的是，在不偏离本发明的精神和范围下可以对本发明技术方案的细节和形式进行修改或替换，但这些修改和替换均落入本发明的保护范围内。
实施例1
一种抗皱防缩丝织面料的制备方法，包括以下步骤：
（1）将丝织面料质量分数为5.5％的氢氧化钠溶液中处理，处理温度为42℃，处理时间4h，然后将面料用去离子水超声机洗23min，超声功率为400W，将面料甩干烘干后备用；
（2）将三羟甲基丙烷三丙烯酸酯加入DMF溶剂中使其体积分数为40%，将步骤（1）制备的面料浸入三羟甲基丙烷三丙烯酸酯的DMF溶液中，在300r/min搅拌的条件下加入步骤（1）处理后的面料，然后加入最终质量分数为15%的光引发剂4-（二甲氨基）苯甲酸乙酯，在45℃的温度下继续搅拌反应18h，然后取出面料，将其置于玻璃板上盖上石英片，置入紫外光下进行紫外光辐射；辐射完成后，将面料取出用DMF溶液进行清洗3-5次，然后用水溶液清洗3-5次，得到表面接枝的面料；
（3）将步骤（2）接枝的面料在6wt％的乙二胺溶液中浸渍反应3-6h，再用去离子水清洗，然后再将其浸入含11wt％二甲基二羟基乙烯脲、7.5wt%八甲基环四硅氧烷的乙酸乙酯溶液中浸渍反应8-12h，然后用去离子水洗涤4-5次，将水分甩干后烘干面料；
（4）将纳米二氧化硅90份加入7.5倍重量份的含8wt% 4-二甲胺基吡啶的吡啶溶液中，在搅拌的状态下加入15份琥珀酸苷，于80℃的温度下搅拌反应5h，将反应溶液取出，加入冰水中，并调节冰水pH为2.5，然后用乙酸乙酯进行萃取，去除上层有机相，并用旋蒸仪对将溶剂旋干，收集旋干物；
（5）将步骤（4）收集的旋干物15份、二氯异氰尿酸钠15份、氟基烷基聚醚改性聚硅氧烷12份、壳聚糖14份、丝素蛋白12份、海藻酸钠8份加入40份乙醇溶液中，将各原料搅拌均匀后，将步骤（3）处理的面料加入混合溶液中浸渍处理4-6h，然后将面料取出甩干，置于烘箱中烘干制得成品。
实施例2
一种抗皱防缩丝织面料的制备方法，包括以下步骤：
（1）将丝织面料质量分数为3％的氢氧化钠溶液中处理，处理温度为35℃，处理时间3h，然后将面料用去离子水超声机洗15min，超声功率为300W，将面料甩干烘干后备用；
（2）将三羟甲基丙烷三丙烯酸酯加入DMF溶剂中使其体积分数为30%，将步骤（1）制备的面料浸入三羟甲基丙烷三丙烯酸酯的DMF溶液中，在200r/min搅拌的条件下加入步骤（1）处理后的面料，然后加入最终质量分数为10%的光引发剂4-（二甲氨基）苯甲酸乙酯，在40℃的温度下继续搅拌反应15h，然后取出面料，将其置于玻璃板上盖上石英片，置入紫外光下进行紫外光辐射；辐射完成后，将面料取出用DMF溶液进行清洗3-5次，然后用水溶液清洗3-5次，得到表面接枝的面料；
（3）将步骤（2）接枝的面料在4wt％的乙二胺溶液中浸渍反应3h，再用去离子水清洗，然后再将其浸入含7wt％二甲基二羟基乙烯脲、5wt%八甲基环四硅氧烷的乙酸乙酯溶液中浸渍反应8h，然后用去离子水洗涤4-5次，将水分甩干后烘干面料；
（4）将纳米二氧化硅80份加入5倍重量份的含5wt% 4-二甲胺基吡啶的吡啶溶液中，在搅拌的状态下加入10份琥珀酸苷，于70℃的温度下搅拌反应4h，将反应溶液取出，加入冰水中，并调节冰水pH为2，然后用乙酸乙酯进行萃取，去除上层有机相，并用旋蒸仪对将溶剂旋干，收集旋干物；
（5）将步骤（4）收集的旋干物10份、二氯异氰尿酸钠12份、氟基烷基聚醚改性聚硅氧烷8份、壳聚糖10份、丝素蛋白9份、海藻酸钠6份加入30份乙醇溶液中，将各原料搅拌均匀后，将步骤（3）处理的面料加入混合溶液中浸渍处理4h，然后将面料取出甩干，置于烘箱中烘干制得成品。
实施例3
一种抗皱防缩丝织面料的制备方法，包括以下步骤：
（1）将丝织面料质量分数为4％的氢氧化钠溶液中处理，处理温度为40℃，处理时间3.5h，然后将面料用去离子水超声机洗20min，超声功率为350W，将面料甩干烘干后备用；
（2）将三羟甲基丙烷三丙烯酸酯加入DMF溶剂中使其体积分数为35%，将步骤（1）制备的面料浸入三羟甲基丙烷三丙烯酸酯的DMF溶液中，在250r/min搅拌的条件下加入步骤（1）处理后的面料，然后加入最终质量分数为12%的光引发剂4-（二甲氨基）苯甲酸乙酯，在42℃的温度下继续搅拌反应17h，然后取出面料，将其置于玻璃板上盖上石英片，置入紫外光下进行紫外光辐射；辐射完成后，将面料取出用DMF溶液进行清洗3-5次，然后用水溶液清洗3-5次，得到表面接枝的面料；
（3）将步骤（2）接枝的面料在5wt％的乙二胺溶液中浸渍反应4h，再用去离子水清洗，然后再将其浸入含9wt％二甲基二羟基乙烯脲、6wt%八甲基环四硅氧烷的乙酸乙酯溶液中浸渍反应9h，然后用去离子水洗涤4-5次，将水分甩干后烘干面料；
（4）将纳米二氧化硅85份加入6倍重量份的含6wt% 4-二甲胺基吡啶的吡啶溶液中，在搅拌的状态下加入13份琥珀酸苷，于75℃的温度下搅拌反应4.5h，将反应溶液取出，加入冰水中，并调节冰水pH为2.2，然后用乙酸乙酯进行萃取，去除上层有机相，并用旋蒸仪对将溶剂旋干，收集旋干物；
（5）将步骤（4）收集的旋干物12份、二氯异氰尿酸钠14份、氟基烷基聚醚改性聚硅氧烷10份、壳聚糖12份、丝素蛋白11份、海藻酸钠8份加入35份乙醇溶液中，将各原料搅拌均匀后，将步骤（3）处理的面料加入混合溶液中浸渍处理4.5h，然后将面料取出甩干，置于烘箱中烘干制得成品。
实施例4
一种抗皱防缩丝织面料的制备方法，包括以下步骤：
（1）将丝织面料质量分数为8％的氢氧化钠溶液中处理，处理温度为50℃，处理时间5h，然后将面料用去离子水超声机洗30min，超声功率为500W，将面料甩干烘干后备用；
（2）将三羟甲基丙烷三丙烯酸酯加入DMF溶剂中使其体积分数为50%，将步骤（1）制备的面料浸入三羟甲基丙烷三丙烯酸酯的DMF溶液中，在400r/min搅拌的条件下加入步骤（1）处理后的面料，然后加入最终质量分数为20%的光引发剂4-（二甲氨基）苯甲酸乙酯，在50℃的温度下继续搅拌反应22h，然后取出面料，将其置于玻璃板上盖上石英片，置入紫外光下进行紫外光辐射；辐射完成后，将面料取出用DMF溶液进行清洗3-5次，然后用水溶液清洗3-5次，得到表面接枝的面料；
（3）将步骤（2）接枝的面料在8wt％的乙二胺溶液中浸渍反应6h，再用去离子水清洗，然后再将其浸入含15wt％二甲基二羟基乙烯脲、10wt%八甲基环四硅氧烷的乙酸乙酯溶液中浸渍反应12h，然后用去离子水洗涤4-5次，将水分甩干后烘干面料；
（4）将纳米二氧化硅100份加入10倍重量份的含10wt% 4-二甲胺基吡啶的吡啶溶液中，在搅拌的状态下加入20份琥珀酸苷，于90℃的温度下搅拌反应6h，将反应溶液取出，加入冰水中，并调节冰水pH为3，然后用乙酸乙酯进行萃取，去除上层有机相，并用旋蒸仪对将溶剂旋干，收集旋干物；
（5）将步骤（4）收集的旋干物20份、二氯异氰尿酸钠18份、氟基烷基聚醚改性聚硅氧烷16份、壳聚糖18份、丝素蛋白15份、海藻酸钠10份加入50份乙醇溶液中，将各原料搅拌均匀后，将步骤（3）处理的面料加入混合溶液中浸渍处理6h，然后将面料取出甩干，置于烘箱中烘干制得成品。
将实施例1-4制得的面料进行以下性能测试，折皱回复角按GB 3819—1997测定，每种样品测5经5纬并取平均值，测得的折皱回复角为织物经向和纬向的折皱回复角之和；织物断裂强力参照GB 3923．1-1997测定，每种样品经向测3次并取平均值，测试结构如表1所示，经处理的面料的折皱回复角高达298°，与未处理的面料相比，其折皱回复角提高一倍以上，因此面料的回弹性具有较大的提高，具有良好的折皱回复性能。面料的断裂强度降为857N，强力保留率达到91.4%，因此，本发明制得面料与未处理的面料相比在抗皱性能方面具有更大的优势。
表1
。

Claims (4)

1.一种抗皱防缩丝织面料的制备方法，其特征在于，包括以下步骤：
（1）将丝织面料质量分数为3-8％的氢氧化钠溶液中处理，处理温度为35-50℃，处理时间3-5h，然后将面料用去离子水超声机洗15-30min，超声功率为300-500W，将面料甩干烘干后备用；
（2）将三羟甲基丙烷三丙烯酸酯加入DMF溶剂中使其体积分数为30-50%，将步骤（1）制备的面料浸入三羟甲基丙烷三丙烯酸酯的DMF溶液中，在200-400r/min搅拌的条件下加入步骤（1）处理后的面料，然后加入最终质量分数为10-20%的光引发剂，在40-50℃的温度下继续搅拌反应15-22h，然后取出面料，将其置于玻璃板上盖上石英片，置入紫外光下进行紫外光辐射；辐射完成后，将面料取出用DMF溶液进行清洗3-5次，然后用水溶液清洗3-5次，得到表面接枝的面料；
（3）将步骤（2）接枝的面料在4-8wt％的乙二胺溶液中浸渍反应3-6h，再用去离子水清洗，然后再将其浸入含7-15wt％二甲基二羟基乙烯脲、5-10wt%八甲基环四硅氧烷的乙酸乙酯溶液中浸渍反应8-12h，然后用去离子水洗涤4-5次，将水分甩干后烘干面料；
（4）将纳米二氧化硅80-100份加入5-10倍重量份的含5-10wt% 4-二甲胺基吡啶的吡啶溶液中，在搅拌的状态下加入10-20份琥珀酸苷，于70-90℃的温度下搅拌反应4-6h，将反应溶液取出，加入冰水中，并调节冰水pH为2-3，然后用乙酸乙酯进行萃取，去除上层有机相，并用旋蒸仪对将溶剂旋干，收集旋干物；
（5）将步骤（4）收集的旋干物10-20份、二氯异氰尿酸钠12-18份、氟基烷基聚醚改性聚硅氧烷8-16份、壳聚糖10-18份、丝素蛋白9-15份、海藻酸钠6-10份加入30-50份乙醇溶液中，将各原料搅拌均匀后，将步骤（3）处理的面料加入混合溶液中浸渍处理4-6h，然后将面料取出甩干，置于烘箱中烘干制得成品。
2.根据权利要求1所述的一种抗皱防缩丝织面料的制备方法，其特征在于，所述步骤（2）中的光引发剂为4-（二甲氨基）苯甲酸乙酯。
3.根据权利要求1所述的一种抗皱防缩丝织面料的制备方法，其特征在于，所述步骤（3）中各原料的质量分数为：乙二胺6wt％、二甲基二羟基乙烯脲11wt％、八甲基环四硅氧烷7.5wt%。
4.根据权利要求1所述的一种抗皱防缩丝织面料的制备方法，其特征在于，所述步骤（5）中各原料的重量份为：步骤（4）收集的旋干物15份、二氯异氰尿酸钠15份、氟基烷基聚醚改性聚硅氧烷12份、壳聚糖14份、丝素蛋白12份、海藻酸钠8份、乙醇40份。
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