CN107829297A - 一种抗皱柔软纤维织物面料及其整理方法 - Google Patents
一种抗皱柔软纤维织物面料及其整理方法 Download PDFInfo
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Abstract
本发明提供了一种抗皱柔软纤维织物面料及其整理方法，整理方法包括以下步骤：（1）柠檬酸改性的交联剂的制备，（2）纤维织物面料的抗皱处理，（3）纤维织物面料的柔软处理。采用本发明的整理方法整理后的面料折皱回复角增加、抗弯长度减小，从而表明面料的抗皱性能和织物的手感较好。从本发明所述的3个对比例得出，柠檬酸和苹果酸对织物的抗皱效果和柔软性能具有重要的贡献，并且经改性后的柠檬酸与未改性前相比对织物具有更好的抗皱、柔软效果。本发明的制备工艺简单，经济成本低，周期短，能耗小，无需复杂的专用设备，因此具有很大的应用前景。
Description
技术领域
本发明属于纺织技术领域，具体涉及一种抗皱柔软纤维织物面料及其整理方法。
背景技术
当前，纤维织物采用的防皱整理剂大多是一些小分子多元羧酸，其中1,2,3,4-丁烷四羧酸(BTCA)是目前公认防皱效果最好的多元羧酸类无甲醛防皱整理剂，但价格较高，限制了它的工业应用。经研究，柠檬酸、丙烷三羧酸、环戊烷四羧酸等20余种多元羧酸的整理效果与2D树脂相比还存在差距。因此为了使得这些小分子具有更好的抗皱整理效果，降低现有抗皱整理剂的制作成本，有必要对现有的小分子多元羧酸进行制备工艺的改进，使其产生更好的抗皱效果。
然而对纤维织物面料进行防皱整理后，织物的手感变硬、强力下降、吸湿透气性变差，因此，在防皱整理后，有必要对面料给予柔软处理，使其具有柔软的手感，满足人们的高品质需求。
发明内容
为了解决以上现有存在的问题，本发明的目的在于提供一种抗皱柔软纤维织物面料及其整理方法，在对纤维织物面料进行抗皱整理的同时，使其兼具柔顺的手感。
为了实现上述目的，本发明提供以下技术方案：
一种纤维织物面料的抗皱柔软整理方法，包括以下步骤：
（1）交联剂的制备：按照1：（1-5）的摩尔比称取丙烯酰氯、柠檬酸于三口瓶中，加入乙醇作为溶剂，将其置入加热磁力搅拌器上在60-70℃的条件下进行搅拌反应，三口瓶的一个端口插入冷凝回流管进行冷凝回流，另一个端口通入氮气，过夜反应后将反应产物取出，使用乙酸乙酯萃取获得乙酸乙酯层溶液，并将其在旋转蒸发仪上进行旋蒸获得终产物；
（2）纤维织物面料的抗皱处理：将纤维织物面料浸渍在含有质量浓度为10-20%的步骤（1）制备的交联剂溶液中，其中溶液中还含有8-15%的苹果酸、8-15%的壳聚糖、5-8%的次亚磷酸钠、0.2-0.5%的壬基酚聚氧乙烯醚，浸渍温度为25-30℃，浸渍时间为24-48h；然后将浸渍后的纤维织物面料在90-100℃的温度下干燥8-10min，然后将其在35-50℃的清水中洗涤；
（3）纤维织物面料的柔软处理：将步骤（2）处理后的纤维织物面料浸渍在柔软处理剂中，所述柔软处理剂包括质量浓度为10-20%的丝胶粉、3-6%的三乙醇胺、0.5-1%的氯化镁、5-10%的氧化烷基胺聚氧乙烯醚，浸渍温度为25-30℃，浸渍时间为12-24h；然后将浸渍后的纤维织物面料在90-95℃的温度下干燥3-5min，再在140-160℃的温度下烘焙2-4min，最后将纤维织物面料用清水彻底洗净后烘干，得到抗皱柔软纤维织物面料。
优选的，所述步骤（1）中丙烯酰氯、柠檬酸的摩尔比为1:2。
优选的，所述步骤（2）中纤维织物面料的抗皱处理溶液中含有15%的步骤（1）制备的交联剂、11%的苹果酸、11%的壳聚糖、6%的次亚磷酸钠、0.4%的壬基酚聚氧乙烯醚。
优选的，所述步骤（2）中浸渍温度为28℃，浸渍时间为36h；然后将浸渍后的纤维织物面料在95℃的温度下干燥9min，然后将其在42℃的清水中洗涤。
优选的，所述步骤（3）中所述柔软处理剂包括质量浓度为15%的丝胶粉、5%的三乙醇胺、0.8%的氯化镁、8%的氧化烷基胺聚氧乙烯醚。
优选的，所述步骤（3）中浸渍温度为28℃，浸渍时间为18h；然后将浸渍后的纤维织物面料在93℃的温度下干燥4min，再在150℃的温度下烘焙3min。
本发明所述的纤维织物面料的抗皱整理方法获得的抗皱柔软纤维织物面料。
有益效果：本发明提供了一种抗皱柔软纤维织物面料及其整理方法，采用本发明的整理方法整理后的面料折皱回复角增加、抗弯长度减小，从而表明面料的抗皱性能和织物的手感较好。从本发明所述的3个对比例得出，柠檬酸和苹果酸对织物的抗皱效果和柔软性能具有重要的贡献，并且经改性后的柠檬酸与未改性前相比对织物具有更好的抗皱、柔软效果。本发明的制备工艺简单，经济成本低，周期短，能耗小，无需复杂的专用设备，因此具有很大的应用前景。
具体实施方式
下面结合具体实施例来进一步描述本发明，但实施例仅是范例性的，并不对本发明的范围构成任何限制。本领域技术人员应该理解的是，在不偏离本发明的精神和范围下可以对本发明技术方案的细节和形式进行修改或替换，但这些修改和替换均落入本发明的保护范围内。
实施例1
一种纤维织物面料的抗皱柔软整理方法，包括以下步骤：
（1）交联剂的制备：按照1：2的摩尔比称取丙烯酰氯、柠檬酸于三口瓶中，加入乙醇作为溶剂，将其置入加热磁力搅拌器上在65℃的条件下进行搅拌反应，三口瓶的一个端口插入冷凝回流管进行冷凝回流，另一个端口通入氮气，过夜反应后将反应产物取出，使用乙酸乙酯萃取获得乙酸乙酯层溶液，并将其在旋转蒸发仪上进行旋蒸获得终产物；
（2）纤维织物面料的抗皱处理：将纤维织物面料浸渍在含有质量浓度为15%的步骤（1）制备的交联剂溶液中，其中溶液中还含有11%的苹果酸、11%的壳聚糖、6%的次亚磷酸钠、0.4%的壬基酚聚氧乙烯醚，浸渍温度为28℃，浸渍时间为36h；然后将浸渍后的纤维织物面料在95℃的温度下干燥9min，然后将其在42℃的清水中洗涤；
（3）纤维织物面料的柔软处理：将步骤（2）处理后的纤维织物面料浸渍在柔软处理剂中，所述柔软处理剂包括质量浓度为15%的丝胶粉、5%的三乙醇胺、0.8%的氯化镁、8%的氧化烷基胺聚氧乙烯醚，浸渍温度为28℃，浸渍时间为18h；然后将浸渍后的纤维织物面料在93℃的温度下干燥4min，再在150℃的温度下烘焙3min，最后将纤维织物面料用清水彻底洗净后烘干，得到抗皱柔软纤维织物面料。
实施例2
一种纤维织物面料的抗皱柔软整理方法，包括以下步骤：
（1）交联剂的制备：按照1：1的摩尔比称取丙烯酰氯、柠檬酸于三口瓶中，加入乙醇作为溶剂，将其置入加热磁力搅拌器上在60℃的条件下进行搅拌反应，三口瓶的一个端口插入冷凝回流管进行冷凝回流，另一个端口通入氮气，过夜反应后将反应产物取出，使用乙酸乙酯萃取获得乙酸乙酯层溶液，并将其在旋转蒸发仪上进行旋蒸获得终产物；
（2）纤维织物面料的抗皱处理：将纤维织物面料浸渍在含有质量浓度为10%的步骤（1）制备的交联剂溶液中，其中溶液中还含有8%的苹果酸、8%的壳聚糖、5%的次亚磷酸钠、0.2%的壬基酚聚氧乙烯醚，浸渍温度为25℃，浸渍时间为24h；然后将浸渍后的纤维织物面料在90℃的温度下干燥8min，然后将其在35℃的清水中洗涤；
（3）纤维织物面料的柔软处理：将步骤（2）处理后的纤维织物面料浸渍在柔软处理剂中，所述柔软处理剂包括质量浓度为10%的丝胶粉、3%的三乙醇胺、0.5%的氯化镁、5%的氧化烷基胺聚氧乙烯醚，浸渍温度为25℃，浸渍时间为12h；然后将浸渍后的纤维织物面料在90℃的温度下干燥3min，再在140℃的温度下烘焙2min，最后将纤维织物面料用清水彻底洗净后烘干，得到抗皱柔软纤维织物面料。
实施例3
一种纤维织物面料的抗皱柔软整理方法，包括以下步骤：
（1）交联剂的制备：按照1：5的摩尔比称取丙烯酰氯、柠檬酸于三口瓶中，加入乙醇作为溶剂，将其置入加热磁力搅拌器上在70℃的条件下进行搅拌反应，三口瓶的一个端口插入冷凝回流管进行冷凝回流，另一个端口通入氮气，过夜反应后将反应产物取出，使用乙酸乙酯萃取获得乙酸乙酯层溶液，并将其在旋转蒸发仪上进行旋蒸获得终产物；
（2）纤维织物面料的抗皱处理：将纤维织物面料浸渍在含有质量浓度为20%的步骤（1）制备的交联剂溶液中，其中溶液中还含有15%的苹果酸、15%的壳聚糖、8%的次亚磷酸钠、0.5%的壬基酚聚氧乙烯醚，浸渍温度为30℃，浸渍时间为48h；然后将浸渍后的纤维织物面料在100℃的温度下干燥10min，然后将其在50℃的清水中洗涤；
（3）纤维织物面料的柔软处理：将步骤（2）处理后的纤维织物面料浸渍在柔软处理剂中，所述柔软处理剂包括质量浓度为20%的丝胶粉、6%的三乙醇胺、1%的氯化镁、10%的氧化烷基胺聚氧乙烯醚，浸渍温度为30℃，浸渍时间为24h；然后将浸渍后的纤维织物面料在95℃的温度下干燥5min，再在160℃的温度下烘焙4min，最后将纤维织物面料用清水彻底洗净后烘干，得到抗皱柔软纤维织物面料。
实施例4
一种纤维织物面料的抗皱柔软整理方法，包括以下步骤：
（1）交联剂的制备：按照1：3的摩尔比称取丙烯酰氯、柠檬酸于三口瓶中，加入乙醇作为溶剂，将其置入加热磁力搅拌器上在68℃的条件下进行搅拌反应，三口瓶的一个端口插入冷凝回流管进行冷凝回流，另一个端口通入氮气，过夜反应后将反应产物取出，使用乙酸乙酯萃取获得乙酸乙酯层溶液，并将其在旋转蒸发仪上进行旋蒸获得终产物；
（2）纤维织物面料的抗皱处理：将纤维织物面料浸渍在含有质量浓度为18%的步骤（1）制备的交联剂溶液中，其中溶液中还含有12%的苹果酸、15%的壳聚糖、5%的次亚磷酸钠、0.5%的壬基酚聚氧乙烯醚，浸渍温度为28℃，浸渍时间为40h；然后将浸渍后的纤维织物面料在98℃的温度下干燥10min，然后将其在40℃的清水中洗涤；
（3）纤维织物面料的柔软处理：将步骤（2）处理后的纤维织物面料浸渍在柔软处理剂中，所述柔软处理剂包括质量浓度为12%的丝胶粉、6%的三乙醇胺、0.5%的氯化镁、6%的氧化烷基胺聚氧乙烯醚，浸渍温度为25℃，浸渍时间为24h；然后将浸渍后的纤维织物面料在95℃的温度下干燥5min，再在155℃的温度下烘焙3min，最后将纤维织物面料用清水彻底洗净后烘干，得到抗皱柔软纤维织物面料。
对比例1
将实施例1中步骤（2）使用的步骤（1）制备的交联剂溶液替换成柠檬酸，其他步骤与实施例1相同。
对比例2
将实施例1中步骤（2）中的苹果酸去掉，其他步骤与实施例1相同。
对比例3
将实施例1中步骤（2）中的交联剂和苹果酸去掉，其他步骤与实施例1相同。
将微处理的纤维织物，实施例1-4、对比例1-3整理后的纤维织物在恒温恒湿室（温度21±1℃湿度为65±2%）平衡至少4小时，待测。对整理织物进行各项指标测试，具体如下：
抗皱性能测试参照AATCC66-2003标准进行测试，断裂强力测试参照GB3923 .1-1997纺织品织物拉伸性能第1部分进行测试，断裂强力和断裂伸长率的测定，使用强力测试仪进行测定，其结果如表1所示。使用柔软度测定仪对样本的抗弯长度进行测定，其结果如表2所示。
从表中得出，使用本发明整理方法整理后的面料的折皱回复角增加，并且织物的抗弯长度逐渐减小，折皱回复角越大、抗弯长度越小，面料的抗皱性能和织物的手感越好。
表1
表2
Claims (7)
1.一种纤维织物面料的抗皱柔软整理方法，其特征在于，包括以下步骤：
（1）交联剂的制备：按照1：（1-5）的摩尔比称取丙烯酰氯、柠檬酸于三口瓶中，加入乙醇作为溶剂，将其置入加热磁力搅拌器上在60-70℃的条件下进行搅拌反应，三口瓶的一个端口插入冷凝回流管进行冷凝回流，另一个端口通入氮气，过夜反应后将反应产物取出，使用乙酸乙酯萃取获得乙酸乙酯层溶液，并将其在旋转蒸发仪上进行旋蒸获得终产物；
（2）纤维织物面料的抗皱处理：将纤维织物面料浸渍在含有质量浓度为10-20%的步骤（1）制备的交联剂溶液中，其中溶液中还含有8-15%的苹果酸、8-15%的壳聚糖、5-8%的次亚磷酸钠、0.2-0.5%的壬基酚聚氧乙烯醚，浸渍温度为25-30℃，浸渍时间为24-48h；然后将浸渍后的纤维织物面料在90-100℃的温度下干燥8-10min，然后将其在35-50℃的清水中洗涤；
（3）纤维织物面料的柔软处理：将步骤（2）处理后的纤维织物面料浸渍在柔软处理剂中，所述柔软处理剂包括质量浓度为10-20%的丝胶粉、3-6%的三乙醇胺、0.5-1%的氯化镁、5-10%的氧化烷基胺聚氧乙烯醚，浸渍温度为25-30℃，浸渍时间为12-24h；然后将浸渍后的纤维织物面料在90-95℃的温度下干燥3-5min，再在140-160℃的温度下烘焙2-4min，最后将纤维织物面料用清水彻底洗净后烘干，得到抗皱柔软纤维织物面料。
2.根据权利要求1所述的一种纤维织物面料的抗皱柔软整理方法，其特征在于，所述步骤（1）中丙烯酰氯、柠檬酸的摩尔比为1:2。
3.根据权利要求1所述的一种纤维织物面料的抗皱柔软整理方法，其特征在于，所述步骤（2）中纤维织物面料的抗皱处理溶液中含有15%的步骤（1）制备的交联剂、11%的苹果酸、11%的壳聚糖、6%的次亚磷酸钠、0.4%的壬基酚聚氧乙烯醚。
4.根据权利要求1所述的一种纤维织物面料的抗皱柔软整理方法，其特征在于，所述步骤（2）中浸渍温度为28℃，浸渍时间为36h；然后将浸渍后的纤维织物面料在95℃的温度下干燥9min，然后将其在42℃的清水中洗涤。
5.根据权利要求1所述的一种纤维织物面料的抗皱柔软整理方法，其特征在于，所述步骤（3）中所述柔软处理剂包括质量浓度为15%的丝胶粉、5%的三乙醇胺、0.8%的氯化镁、8%的氧化烷基胺聚氧乙烯醚。
6.根据权利要求1所述的一种纤维织物面料的抗皱柔软整理方法，其特征在于，所述步骤（3）中浸渍温度为28℃，浸渍时间为18h；然后将浸渍后的纤维织物面料在93℃的温度下干燥4min，再在150℃的温度下烘焙3min。
7.权利要求1-6任一项所述的整理方法获得的抗皱柔软纤维织物面料。
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