CN108603113B - 荧光体及其制造方法、含荧光体构件以及发光装置或投影仪 - Google Patents
荧光体及其制造方法、含荧光体构件以及发光装置或投影仪 Download PDFInfo
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- CN108603113B CN108603113B CN201780009385.XA CN201780009385A CN108603113B CN 108603113 B CN108603113 B CN 108603113B CN 201780009385 A CN201780009385 A CN 201780009385A CN 108603113 B CN108603113 B CN 108603113B
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- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims abstract description 315
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 20
- 239000013078 crystal Substances 0.000 claims abstract description 160
- 239000002245 particle Substances 0.000 claims abstract description 58
- 239000000203 mixture Substances 0.000 claims abstract description 54
- 238000010298 pulverizing process Methods 0.000 claims description 23
- 238000007789 sealing Methods 0.000 claims description 18
- 229910010272 inorganic material Inorganic materials 0.000 claims description 17
- 239000011147 inorganic material Substances 0.000 claims description 17
- 239000003566 sealing material Substances 0.000 description 30
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 24
- 238000000034 method Methods 0.000 description 22
- 239000000758 substrate Substances 0.000 description 22
- 238000009826 distribution Methods 0.000 description 18
- 239000000853 adhesive Substances 0.000 description 12
- 230000001070 adhesive effect Effects 0.000 description 12
- 238000010586 diagram Methods 0.000 description 11
- 238000010306 acid treatment Methods 0.000 description 10
- 239000000843 powder Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 7
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 5
- 239000004973 liquid crystal related substance Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 238000005245 sintering Methods 0.000 description 5
- 229910004298 SiO 2 Inorganic materials 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000000295 emission spectrum Methods 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 230000005284 excitation Effects 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 239000011812 mixed powder Substances 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 238000002310 reflectometry Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000005231 Edge Defined Film Fed Growth Methods 0.000 description 2
- 229910052688 Gadolinium Inorganic materials 0.000 description 2
- 229910052765 Lutetium Inorganic materials 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 230000001186 cumulative effect Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 229910052594 sapphire Inorganic materials 0.000 description 2
- 239000010980 sapphire Substances 0.000 description 2
- 238000005204 segregation Methods 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 238000003746 solid phase reaction Methods 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000037396 body weight Effects 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000002189 fluorescence spectrum Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 238000001095 inductively coupled plasma mass spectrometry Methods 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 102220043159 rs587780996 Human genes 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
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- C—CHEMISTRY; METALLURGY
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- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
- C09K11/7766—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing two or more rare earth metals
- C09K11/7774—Aluminates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F17/00—Compounds of rare earth metals
- C01F17/30—Compounds containing rare earth metals and at least one element other than a rare earth metal, oxygen or hydrogen, e.g. La4S3Br6
- C01F17/32—Compounds containing rare earth metals and at least one element other than a rare earth metal, oxygen or hydrogen, e.g. La4S3Br6 oxide or hydroxide being the only anion, e.g. NaCeO2 or MgxCayEuO
- C01F17/34—Aluminates, e.g. YAlO3 or Y3-xGdxAl5O12
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- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
- C30B29/10—Inorganic compounds or compositions
- C30B29/16—Oxides
- C30B29/22—Complex oxides
- C30B29/28—Complex oxides with formula A3Me5O12 wherein A is a rare earth metal and Me is Fe, Ga, Sc, Cr, Co or Al, e.g. garnets
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- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
- C30B29/60—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape characterised by shape
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- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B33/00—After-treatment of single crystals or homogeneous polycrystalline material with defined structure
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03B—APPARATUS OR ARRANGEMENTS FOR TAKING PHOTOGRAPHS OR FOR PROJECTING OR VIEWING THEM; APPARATUS OR ARRANGEMENTS EMPLOYING ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ACCESSORIES THEREFOR
- G03B21/00—Projectors or projection-type viewers; Accessories therefor
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- G—PHYSICS
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- G03B—APPARATUS OR ARRANGEMENTS FOR TAKING PHOTOGRAPHS OR FOR PROJECTING OR VIEWING THEM; APPARATUS OR ARRANGEMENTS EMPLOYING ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ACCESSORIES THEREFOR
- G03B21/00—Projectors or projection-type viewers; Accessories therefor
- G03B21/14—Details
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03B—APPARATUS OR ARRANGEMENTS FOR TAKING PHOTOGRAPHS OR FOR PROJECTING OR VIEWING THEM; APPARATUS OR ARRANGEMENTS EMPLOYING ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ACCESSORIES THEREFOR
- G03B21/00—Projectors or projection-type viewers; Accessories therefor
- G03B21/14—Details
- G03B21/20—Lamp housings
- G03B21/2006—Lamp housings characterised by the light source
- G03B21/2033—LED or laser light sources
- G03B21/204—LED or laser light sources using secondary light emission, e.g. luminescence or fluorescence
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S5/00—Semiconductor lasers
- H01S5/02—Structural details or components not essential to laser action
- H01S5/022—Mountings; Housings
- H01S5/0239—Combinations of electrical or optical elements
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/80—Constructional details
- H10H20/85—Packages
- H10H20/851—Wavelength conversion means
- H10H20/8511—Wavelength conversion means characterised by their material, e.g. binder
- H10H20/8512—Wavelength conversion materials
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/32—Thermal properties
- C01P2006/37—Stability against thermal decomposition
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Metallurgy (AREA)
- Optics & Photonics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electromagnetism (AREA)
- Multimedia (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Luminescent Compositions (AREA)
- Projection Apparatus (AREA)
- Led Device Packages (AREA)
- Semiconductor Lasers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016018448A JP6871665B2 (ja) | 2016-02-02 | 2016-02-02 | 蛍光体含有部材及びその製造方法、及び発光装置又はプロジェクター |
| JP2016-018448 | 2016-02-02 | ||
| PCT/JP2017/003793 WO2017135373A1 (ja) | 2016-02-02 | 2017-02-02 | 蛍光体及びその製造方法、蛍光体含有部材、及び発光装置又はプロジェクター |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108603113A CN108603113A (zh) | 2018-09-28 |
| CN108603113B true CN108603113B (zh) | 2022-07-05 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201780009385.XA Active CN108603113B (zh) | 2016-02-02 | 2017-02-02 | 荧光体及其制造方法、含荧光体构件以及发光装置或投影仪 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US11525082B2 (enExample) |
| EP (1) | EP3412752B1 (enExample) |
| JP (1) | JP6871665B2 (enExample) |
| CN (1) | CN108603113B (enExample) |
| WO (1) | WO2017135373A1 (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6917244B2 (ja) * | 2017-08-23 | 2021-08-11 | 日本特殊陶業株式会社 | 蛍光体ホイール、ホイールデバイスおよびプロジェクター |
| JP7224579B2 (ja) * | 2018-02-09 | 2023-02-20 | 株式会社タムラ製作所 | 波長変換部材 |
| JP7037082B2 (ja) * | 2019-09-27 | 2022-03-16 | 日亜化学工業株式会社 | 希土類アルミン酸塩蛍光体の製造方法、希土類アルミン酸塩蛍光体及び発光装置 |
| JP7429346B2 (ja) * | 2019-10-03 | 2024-02-08 | 国立研究開発法人物質・材料研究機構 | 波長変換部材 |
| EP4443120A3 (en) | 2020-02-13 | 2024-12-25 | Hamamatsu Photonics K.K. | Imaging unit and measurement device |
| JP2022039095A (ja) | 2020-08-27 | 2022-03-10 | セイコーエプソン株式会社 | 蛍光体粒子、波長変換素子、光源装置、蛍光体粒子の製造方法、波長変換素子の製造方法、及びプロジェクター |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1560332A (zh) * | 2004-02-23 | 2005-01-05 | 中国科学院上海光学精密机械研究所 | 掺三价铈离子的钇铝石榴石闪烁晶体的制备方法 |
| CN103820859A (zh) * | 2013-12-31 | 2014-05-28 | 西南技术物理研究所 | 掺杂钇铝石榴石陶瓷转变为单晶的制备方法 |
| WO2015060254A1 (ja) * | 2013-10-23 | 2015-04-30 | 株式会社光波 | 単結晶蛍光体及び発光装置 |
| CN105283526A (zh) * | 2013-10-23 | 2016-01-27 | 株式会社光波 | 单晶荧光体、含荧光体构件以及发光装置 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5620562B2 (enExample) | 1972-12-04 | 1981-05-14 | ||
| JPH09291279A (ja) * | 1996-04-25 | 1997-11-11 | Noritake Co Ltd | 粉末蛍光体およびその製造方法 |
| JP4583076B2 (ja) * | 2004-06-11 | 2010-11-17 | スタンレー電気株式会社 | 発光素子 |
| US20150083967A1 (en) * | 2012-04-24 | 2015-03-26 | Koha Co., Ltd. | Phosphor, Method for Manufacturing same, and light-emitting device |
| DE112016003272T5 (de) * | 2015-07-22 | 2018-04-05 | Panasonic Intellectual Property Management Co., Ltd. | Granatverbindung und Verfahren zu deren Herstellung, lichtemittierende Vorrichtung und Dekorgegenstand, bei denen die Granatverbindung verwendet wird, und Verfahren zur Verwendung der Granatverbindung |
| JP2017120864A (ja) * | 2015-12-28 | 2017-07-06 | 株式会社タムラ製作所 | 発光装置 |
| KR102675945B1 (ko) * | 2018-09-18 | 2024-06-17 | 삼성전자주식회사 | 발광 장치 |
-
2016
- 2016-02-02 JP JP2016018448A patent/JP6871665B2/ja active Active
-
2017
- 2017-02-02 EP EP17747524.1A patent/EP3412752B1/en active Active
- 2017-02-02 US US16/074,163 patent/US11525082B2/en active Active
- 2017-02-02 CN CN201780009385.XA patent/CN108603113B/zh active Active
- 2017-02-02 WO PCT/JP2017/003793 patent/WO2017135373A1/ja not_active Ceased
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1560332A (zh) * | 2004-02-23 | 2005-01-05 | 中国科学院上海光学精密机械研究所 | 掺三价铈离子的钇铝石榴石闪烁晶体的制备方法 |
| WO2015060254A1 (ja) * | 2013-10-23 | 2015-04-30 | 株式会社光波 | 単結晶蛍光体及び発光装置 |
| CN105283526A (zh) * | 2013-10-23 | 2016-01-27 | 株式会社光波 | 单晶荧光体、含荧光体构件以及发光装置 |
| CN103820859A (zh) * | 2013-12-31 | 2014-05-28 | 西南技术物理研究所 | 掺杂钇铝石榴石陶瓷转变为单晶的制备方法 |
Non-Patent Citations (2)
| Title |
|---|
| Properties of Czochralski grown Ce,Gd:Y3Al5O12 single crystal for white;Anastasiya Latynina et al.,;《Journal of Alloys and Compounds》;20121123;第553卷;第89-92页 * |
| Single-Crystal Phosphors for;Encarnación G. Víllora et al.,;《Journal of the Japanese Association for Crystal Growth》;20151231;第42卷(第2期);第119-129页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2017135373A1 (ja) | 2017-08-10 |
| EP3412752B1 (en) | 2024-11-13 |
| JP6871665B2 (ja) | 2021-05-12 |
| US20210122975A1 (en) | 2021-04-29 |
| EP3412752A1 (en) | 2018-12-12 |
| US11525082B2 (en) | 2022-12-13 |
| JP2017137394A (ja) | 2017-08-10 |
| CN108603113A (zh) | 2018-09-28 |
| EP3412752A4 (en) | 2019-09-25 |
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