CN1083499A - 有低硬度和高撕裂强度的模塑复合物 - Google Patents
有低硬度和高撕裂强度的模塑复合物 Download PDFInfo
- Publication number
- CN1083499A CN1083499A CN93109747A CN93109747A CN1083499A CN 1083499 A CN1083499 A CN 1083499A CN 93109747 A CN93109747 A CN 93109747A CN 93109747 A CN93109747 A CN 93109747A CN 1083499 A CN1083499 A CN 1083499A
- Authority
- CN
- China
- Prior art keywords
- weight
- composition
- filler
- tear strength
- fillers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 150000001875 compounds Chemical class 0.000 title claims description 5
- 238000000465 moulding Methods 0.000 title description 5
- 239000000203 mixture Substances 0.000 claims abstract description 118
- 239000000945 filler Substances 0.000 claims abstract description 66
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 61
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 56
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 26
- 239000000919 ceramic Substances 0.000 claims abstract description 9
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims abstract description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 3
- 230000003014 reinforcing effect Effects 0.000 claims abstract 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 24
- 239000003054 catalyst Substances 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 16
- 239000012530 fluid Substances 0.000 claims description 15
- 239000004615 ingredient Substances 0.000 claims description 10
- 239000004408 titanium dioxide Substances 0.000 claims description 10
- 239000003431 cross linking reagent Substances 0.000 claims description 7
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 6
- 229910004762 CaSiO Inorganic materials 0.000 claims description 4
- 229910044991 metal oxide Inorganic materials 0.000 claims description 4
- 150000004706 metal oxides Chemical class 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 230000003197 catalytic effect Effects 0.000 claims description 3
- 229920002545 silicone oil Polymers 0.000 claims description 3
- 150000004819 silanols Chemical class 0.000 claims 4
- 229920000620 organic polymer Polymers 0.000 claims 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 15
- 239000002245 particle Substances 0.000 abstract description 9
- 230000032683 aging Effects 0.000 abstract description 8
- 239000004971 Cross linker Substances 0.000 abstract 1
- 230000007774 longterm Effects 0.000 abstract 1
- 229910052882 wollastonite Inorganic materials 0.000 abstract 1
- 238000005266 casting Methods 0.000 description 29
- 238000012856 packing Methods 0.000 description 29
- 239000004809 Teflon Substances 0.000 description 28
- 229920006362 Teflon® Polymers 0.000 description 28
- 238000002156 mixing Methods 0.000 description 28
- 239000000654 additive Substances 0.000 description 26
- 230000000996 additive effect Effects 0.000 description 26
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 19
- 239000003795 chemical substances by application Substances 0.000 description 16
- 239000004205 dimethyl polysiloxane Substances 0.000 description 16
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 16
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 16
- -1 siloxanes Chemical class 0.000 description 16
- 239000000126 substance Substances 0.000 description 14
- 239000004594 Masterbatch (MB) Substances 0.000 description 13
- 238000004987 plasma desorption mass spectroscopy Methods 0.000 description 13
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 12
- 239000002585 base Substances 0.000 description 12
- 239000003546 flue gas Substances 0.000 description 12
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 12
- 235000012239 silicon dioxide Nutrition 0.000 description 12
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 11
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 10
- 238000012360 testing method Methods 0.000 description 9
- 239000002131 composite material Substances 0.000 description 8
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 8
- 230000002708 enhancing effect Effects 0.000 description 7
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 4
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 4
- 230000000903 blocking effect Effects 0.000 description 3
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 239000012763 reinforcing filler Substances 0.000 description 3
- 229960001866 silicon dioxide Drugs 0.000 description 3
- PVGATNRYUYNBHO-UHFFFAOYSA-N (2,5-dioxopyrrolidin-1-yl) 4-(2,5-dioxopyrrol-1-yl)butanoate Chemical compound O=C1CCC(=O)N1OC(=O)CCCN1C(=O)C=CC1=O PVGATNRYUYNBHO-UHFFFAOYSA-N 0.000 description 2
- CSPHGSFZFWKVDL-UHFFFAOYSA-M (3-chloro-2-hydroxypropyl)-trimethylazanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC(O)CCl CSPHGSFZFWKVDL-UHFFFAOYSA-M 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229940063656 aluminum chloride Drugs 0.000 description 2
- 238000005660 chlorination reaction Methods 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000010449 novaculite Substances 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 125000005372 silanol group Chemical group 0.000 description 2
- 239000012974 tin catalyst Substances 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 229940055858 aluminum chloride anhydrous Drugs 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000003190 augmentative effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 229910002026 crystalline silica Inorganic materials 0.000 description 1
- 238000012217 deletion Methods 0.000 description 1
- 230000037430 deletion Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000001056 green pigment Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- BPILDHPJSYVNAF-UHFFFAOYSA-M sodium;diiodomethanesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C(I)I BPILDHPJSYVNAF-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- QLNOVKKVHFRGMA-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical group [CH2]CC[Si](OC)(OC)OC QLNOVKKVHFRGMA-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US93459192A | 1992-08-24 | 1992-08-24 | |
| US934,591 | 1992-08-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1083499A true CN1083499A (zh) | 1994-03-09 |
Family
ID=25465771
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN93109747A Pending CN1083499A (zh) | 1992-08-24 | 1993-08-24 | 有低硬度和高撕裂强度的模塑复合物 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US5397817A (enExample) |
| EP (1) | EP0586153A3 (enExample) |
| JP (1) | JPH06184444A (enExample) |
| CN (1) | CN1083499A (enExample) |
| TW (1) | TW250486B (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100340597C (zh) * | 1997-01-21 | 2007-10-03 | 通用电气公司 | 具有延长的使用寿命的硅氧烷模塑组合物 |
| CN101486822B (zh) * | 2003-08-01 | 2011-07-06 | 施敏打硬株式会社 | 固化性组合物及固化性组合物的制造方法 |
| CN103613935A (zh) * | 2013-12-09 | 2014-03-05 | 江苏天辰硅材料有限公司 | 低硬度挤出胶及其制造方法 |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5804447A (en) * | 1992-07-23 | 1998-09-08 | Basf Aktiengesellschaft | Use of compounds which absorb and/or fluoresce in the IR region as markers for liquids |
| FR2742763B1 (fr) * | 1995-12-22 | 1998-03-06 | Rhone Poulenc Chimie | Elastomere silicone a haute conductibilite thermique |
| DE19603628A1 (de) | 1996-02-01 | 1997-08-07 | Wacker Chemie Gmbh | Bei Raumtemperatur vulkanisierende, kondensationsvernetzende Siliconkautschuke |
| DE19645721A1 (de) | 1996-11-06 | 1998-05-07 | Wacker Chemie Gmbh | Vernetzbare Organopolysiloxanmassen |
| US7785098B1 (en) | 2001-06-05 | 2010-08-31 | Mikro Systems, Inc. | Systems for large area micro mechanical systems |
| EP1404501B1 (en) | 2001-06-05 | 2012-08-01 | Mikro Systems Inc. | Method and mold system for manufacturing three-dimensional devices |
| US6737494B2 (en) * | 2001-11-09 | 2004-05-18 | General Electric Company | Synthesis and use of alkylalkoxyacyloxysilanes and blends thereof for use as a crosslinking agent in moisture curing RTV'S |
| US20050156362A1 (en) * | 2003-11-29 | 2005-07-21 | Joe Arnold | Piezoelectric device and method of manufacturing same |
| US7772141B2 (en) * | 2005-12-05 | 2010-08-10 | Milliken & Company | Coatings for airbag fabrics, coated airbag fabrics, and methods for making the same |
| US20070244249A1 (en) * | 2006-04-06 | 2007-10-18 | General Electric Company | Two-part translucent silicone rubber-forming composition |
| DE102006033236A1 (de) * | 2006-07-18 | 2008-01-24 | Wacker Chemie Ag | Zusammensetzung auf der Basis von Organosiliciumverbindungen |
| EP2170994B1 (en) * | 2007-06-29 | 2016-02-10 | Saint-Gobain Performance Plastics Corporation | Silicone compositions, articles, and methods of making such silicone compositions |
| US9315663B2 (en) | 2008-09-26 | 2016-04-19 | Mikro Systems, Inc. | Systems, devices, and/or methods for manufacturing castings |
| WO2010042668A1 (en) | 2008-10-07 | 2010-04-15 | Ross Technology Corporation | Spill resistant surfaces having hydrophobic and oleophobic borders |
| CN101544830B (zh) * | 2009-04-29 | 2011-04-06 | 陕西华星线绕电阻有限公司 | 大功率电子元器件封装使用硅酮模塑料 |
| MX2012010669A (es) * | 2010-03-15 | 2013-02-07 | Ross Technology Corp | Destacadores y metodos para producir supreficies hidrofobas. |
| MX2013009609A (es) | 2011-02-21 | 2013-09-16 | Ross Technology Corp | Revestimiento suoerhidrofobos y oleofobos con sistemas aglutinantes con bajo contenido de compuestos organicos volatiles. |
| US8813824B2 (en) | 2011-12-06 | 2014-08-26 | Mikro Systems, Inc. | Systems, devices, and/or methods for producing holes |
| JP7068357B2 (ja) | 2017-06-29 | 2022-05-16 | エルケム・シリコーンズ・フランス・エスアエス | シリコーンエラストマー型の製造方法 |
| CN114573875B (zh) * | 2022-05-05 | 2023-09-12 | 华北理工大学 | 纳米二氧化硅-硅酸钙晶须及改性酚醛树脂的制备方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE556585A (enExample) * | 1956-04-11 | |||
| US3635743A (en) * | 1969-01-06 | 1972-01-18 | Gen Electric | Reinforcing silica filler |
| US3696127A (en) * | 1970-07-09 | 1972-10-03 | Dow Corning | High filler content silicone elastomer with increased extrusion rate |
| US4505955A (en) * | 1981-07-30 | 1985-03-19 | Dow Corning Corporation | Mineral particles bound with silicone elastomeric emulsion |
| FR2592656B1 (fr) * | 1986-01-09 | 1988-05-20 | Rhone Poulenc Spec Chim | Composition organopolysiloxane elastomerique vulcanisable a chaud, a resistance a la reversion et a la tenue aux huiles ameliorees. |
| FR2649115B1 (fr) * | 1989-06-29 | 1994-10-28 | Rhone Poulenc Chimie | Dispersion aqueuse a base d'huiles silicones et de (co)polymere organique reticulant en un elastomere par elimination de l'eau |
| US5036131A (en) * | 1990-05-16 | 1991-07-30 | Dow Corning Corporation | Protective coating for electrical components |
-
1993
- 1993-05-03 TW TW082103507A patent/TW250486B/zh active
- 1993-08-20 EP EP19930306615 patent/EP0586153A3/en not_active Withdrawn
- 1993-08-24 JP JP5209116A patent/JPH06184444A/ja not_active Withdrawn
- 1993-08-24 CN CN93109747A patent/CN1083499A/zh active Pending
-
1994
- 1994-07-27 US US08/281,316 patent/US5397817A/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100340597C (zh) * | 1997-01-21 | 2007-10-03 | 通用电气公司 | 具有延长的使用寿命的硅氧烷模塑组合物 |
| CN101486822B (zh) * | 2003-08-01 | 2011-07-06 | 施敏打硬株式会社 | 固化性组合物及固化性组合物的制造方法 |
| CN103613935A (zh) * | 2013-12-09 | 2014-03-05 | 江苏天辰硅材料有限公司 | 低硬度挤出胶及其制造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0586153A3 (en) | 1994-05-18 |
| US5397817A (en) | 1995-03-14 |
| TW250486B (enExample) | 1995-07-01 |
| EP0586153A2 (en) | 1994-03-09 |
| JPH06184444A (ja) | 1994-07-05 |
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