CN108137761A - 活性能量射线固化型树脂组合物、活性能量射线固化型乳液组合物和涂布剂组合物 - Google Patents
活性能量射线固化型树脂组合物、活性能量射线固化型乳液组合物和涂布剂组合物 Download PDFInfo
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- CN108137761A CN108137761A CN201680056902.4A CN201680056902A CN108137761A CN 108137761 A CN108137761 A CN 108137761A CN 201680056902 A CN201680056902 A CN 201680056902A CN 108137761 A CN108137761 A CN 108137761A
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- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
- 235000020778 linoleic acid Nutrition 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000001883 metal evaporation Methods 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- AYLRODJJLADBOB-QMMMGPOBSA-N methyl (2s)-2,6-diisocyanatohexanoate Chemical compound COC(=O)[C@@H](N=C=O)CCCCN=C=O AYLRODJJLADBOB-QMMMGPOBSA-N 0.000 description 1
- USUBUUXHLGKOHN-UHFFFAOYSA-N methyl 2-methylidenehexanoate Chemical compound CCCCC(=C)C(=O)OC USUBUUXHLGKOHN-UHFFFAOYSA-N 0.000 description 1
- UNBDCVXGGDKSCP-UHFFFAOYSA-N methyl 2-methylidenetetradecanoate Chemical compound CCCCCCCCCCCCC(=C)C(=O)OC UNBDCVXGGDKSCP-UHFFFAOYSA-N 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- IQSHMXAZFHORGY-UHFFFAOYSA-N methyl prop-2-enoate;2-methylprop-2-enoic acid Chemical compound COC(=O)C=C.CC(=C)C(O)=O IQSHMXAZFHORGY-UHFFFAOYSA-N 0.000 description 1
- OCINZYYLBMOJAQ-UHFFFAOYSA-N methyl prop-2-enoate;propane-1,2-diol Chemical compound CC(O)CO.COC(=O)C=C OCINZYYLBMOJAQ-UHFFFAOYSA-N 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 1
- YLGYACDQVQQZSW-UHFFFAOYSA-N n,n-dimethylprop-2-enamide Chemical compound CN(C)C(=O)C=C YLGYACDQVQQZSW-UHFFFAOYSA-N 0.000 description 1
- ZWRDBWDXRLPESY-UHFFFAOYSA-N n-benzyl-n-ethylethanamine Chemical compound CCN(CC)CC1=CC=CC=C1 ZWRDBWDXRLPESY-UHFFFAOYSA-N 0.000 description 1
- YPHQUSNPXDGUHL-UHFFFAOYSA-N n-methylprop-2-enamide Chemical compound CNC(=O)C=C YPHQUSNPXDGUHL-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- GSGDTSDELPUTKU-UHFFFAOYSA-N nonoxybenzene Chemical compound CCCCCCCCCOC1=CC=CC=C1 GSGDTSDELPUTKU-UHFFFAOYSA-N 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 229920002601 oligoester Polymers 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- HPAFOABSQZMTHE-UHFFFAOYSA-N phenyl-(2,4,6-trimethylphenyl)methanone Chemical class CC1=CC(C)=CC(C)=C1C(=O)C1=CC=CC=C1 HPAFOABSQZMTHE-UHFFFAOYSA-N 0.000 description 1
- LYXOWKPVTCPORE-UHFFFAOYSA-N phenyl-(4-phenylphenyl)methanone Chemical class C=1C=C(C=2C=CC=CC=2)C=CC=1C(=O)C1=CC=CC=C1 LYXOWKPVTCPORE-UHFFFAOYSA-N 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- QJFMCHRSDOLMHA-UHFFFAOYSA-N phenylmethanamine;hydrobromide Chemical compound Br.NCC1=CC=CC=C1 QJFMCHRSDOLMHA-UHFFFAOYSA-N 0.000 description 1
- 125000003170 phenylsulfonyl group Chemical group C1(=CC=CC=C1)S(=O)(=O)* 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 125000001476 phosphono group Chemical group [H]OP(*)(=O)O[H] 0.000 description 1
- 150000003021 phthalic acid derivatives Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 description 1
- 229960002226 polidocanol Drugs 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920000642 polymer Chemical class 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N sec-butylidene Natural products CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000001119 stannous chloride Substances 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- MVQLEZWPIWKLBY-UHFFFAOYSA-N tert-butyl 2-benzoylbenzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1C(=O)C1=CC=CC=C1 MVQLEZWPIWKLBY-UHFFFAOYSA-N 0.000 description 1
- MDDUHVRJJAFRAU-YZNNVMRBSA-N tert-butyl-[(1r,3s,5z)-3-[tert-butyl(dimethyl)silyl]oxy-5-(2-diphenylphosphorylethylidene)-4-methylidenecyclohexyl]oxy-dimethylsilane Chemical compound C1[C@@H](O[Si](C)(C)C(C)(C)C)C[C@H](O[Si](C)(C)C(C)(C)C)C(=C)\C1=C/CP(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 MDDUHVRJJAFRAU-YZNNVMRBSA-N 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- 125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical class Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- ALHBQZRUBQFZQV-UHFFFAOYSA-N tin;tetrahydrate Chemical compound O.O.O.O.[Sn] ALHBQZRUBQFZQV-UHFFFAOYSA-N 0.000 description 1
- KJAMZCVTJDTESW-UHFFFAOYSA-N tiracizine Chemical compound C1CC2=CC=CC=C2N(C(=O)CN(C)C)C2=CC(NC(=O)OCC)=CC=C21 KJAMZCVTJDTESW-UHFFFAOYSA-N 0.000 description 1
- KOECRLKKXSXCPB-UHFFFAOYSA-K triiodobismuthane Chemical compound I[Bi](I)I KOECRLKKXSXCPB-UHFFFAOYSA-K 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N ureidocarboxylic acid Natural products NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/06—Polymers provided for in subclass C08G
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
- C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/671—Unsaturated compounds having only one group containing active hydrogen
- C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
- C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dispersion Chemistry (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Paints Or Removers (AREA)
- Polymerisation Methods In General (AREA)
- Polyurethanes Or Polyureas (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2015-249753 | 2015-12-22 | ||
| JP2015249753 | 2015-12-22 | ||
| PCT/JP2016/088039 WO2017110843A1 (ja) | 2015-12-22 | 2016-12-21 | 活性エネルギー線硬化型樹脂組成物、活性エネルギー線硬化型エマルジョン組成物及びコーティング剤組成物 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108137761A true CN108137761A (zh) | 2018-06-08 |
Family
ID=59089435
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201680056902.4A Pending CN108137761A (zh) | 2015-12-22 | 2016-12-21 | 活性能量射线固化型树脂组合物、活性能量射线固化型乳液组合物和涂布剂组合物 |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPWO2017110843A1 (ja) |
| KR (1) | KR20180095687A (ja) |
| CN (1) | CN108137761A (ja) |
| TW (1) | TWI693263B (ja) |
| WO (1) | WO2017110843A1 (ja) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112239599A (zh) * | 2019-07-16 | 2021-01-19 | 荒川化学工业株式会社 | 活性能量线固化型树脂组合物及含水树脂组合物、涂布剂组合物、固化膜和膜 |
| CN114196316A (zh) * | 2020-09-02 | 2022-03-18 | 荒川化学工业株式会社 | 活性能量射线固化性树脂组合物、固化膜及膜 |
| CN114316649A (zh) * | 2020-09-30 | 2022-04-12 | 荒川化学工业株式会社 | 活性能量线硬化型树脂组合物及层叠体 |
| WO2022087885A1 (en) * | 2020-10-28 | 2022-05-05 | Dic Corporation | Active energy ray-curable aqueous resin composition, active energy ray-curable aqueous coating material, and article coated with the coating material |
| CN114685745A (zh) * | 2020-12-25 | 2022-07-01 | 昭和电工株式会社 | 氨基甲酸酯(甲基)丙烯酸酯及氨基甲酸酯(甲基)丙烯酸酯树脂的制造方法 |
| CN115975498A (zh) * | 2021-10-14 | 2023-04-18 | 荒川化学工业株式会社 | 水系乳液组合物、固化物以及积层体 |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6970542B2 (ja) * | 2017-07-05 | 2021-11-24 | 株式会社Kri | 撥水撥油性膜形成用塗布組成物及び撥水撥油性膜 |
| KR102647123B1 (ko) * | 2021-06-23 | 2024-03-14 | 강남제비스코 주식회사 | 우레탄 변성 아크릴수지 조성물 및 그의 제조방법 |
| WO2023132578A1 (ko) * | 2022-01-06 | 2023-07-13 | 동우화인켐 주식회사 | 점착제 조성물, 점착시트 및 광학필름 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5095066A (en) * | 1989-01-06 | 1992-03-10 | Bayer Aktiengesellschaft | Hydrophilic polyurethanes containing (meth)acryloyl groups, their use as reactive emulsifiers for radically curable synthetic resins, water-dispersible mixture of radically curable synthetic resins and an aqueous coating composition based on this mixture |
| JPH11124467A (ja) * | 1997-10-23 | 1999-05-11 | Nippon Shokubai Co Ltd | 複合微粒子、その製造方法および用途 |
| JP2008303258A (ja) * | 2007-06-06 | 2008-12-18 | Nippon Synthetic Chem Ind Co Ltd:The | 活性エネルギー線硬化型エマルジョン組成物、及び、コーティング剤組成物 |
| CN103113531A (zh) * | 2013-01-15 | 2013-05-22 | 烟台万华聚氨酯股份有限公司 | 一种具有可再乳化性的水性聚氨酯丙烯酸酯乳液及其制备方法 |
| JP2015004040A (ja) * | 2013-06-24 | 2015-01-08 | 宇部興産株式会社 | 光及び熱硬化性水性樹脂分散体及びエラストマー積層体 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5145639B2 (ja) * | 2006-01-18 | 2013-02-20 | 荒川化学工業株式会社 | 活性エネルギー線硬化性水中油型エマルジョン組成物 |
| JP2010065193A (ja) * | 2008-09-12 | 2010-03-25 | Mitsubishi Rayon Co Ltd | 硬化性組成物、硬化物及び光情報媒体 |
| TW201035134A (en) * | 2008-11-05 | 2010-10-01 | Nippon Kayaku Kk | Ultraviolet curable resin composition for optical disk and cured product thereof |
| JP5366682B2 (ja) | 2009-06-30 | 2013-12-11 | 日本合成化学工業株式会社 | 活性エネルギー線硬化型エマルジョン組成物及びそれを用いたコーティング剤組成物 |
| JP2011074266A (ja) * | 2009-09-30 | 2011-04-14 | Nippon Shokubai Co Ltd | 光ディスク用硬化性樹脂組成物、その硬化物及び光ディスク |
| JP2014177583A (ja) * | 2013-03-15 | 2014-09-25 | Mitsubishi Rayon Co Ltd | 硬化性組成物および積層体 |
-
2016
- 2016-12-21 CN CN201680056902.4A patent/CN108137761A/zh active Pending
- 2016-12-21 WO PCT/JP2016/088039 patent/WO2017110843A1/ja active Application Filing
- 2016-12-21 JP JP2016574471A patent/JPWO2017110843A1/ja active Pending
- 2016-12-21 KR KR1020187021009A patent/KR20180095687A/ko unknown
- 2016-12-22 TW TW105142581A patent/TWI693263B/zh active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5095066A (en) * | 1989-01-06 | 1992-03-10 | Bayer Aktiengesellschaft | Hydrophilic polyurethanes containing (meth)acryloyl groups, their use as reactive emulsifiers for radically curable synthetic resins, water-dispersible mixture of radically curable synthetic resins and an aqueous coating composition based on this mixture |
| JPH11124467A (ja) * | 1997-10-23 | 1999-05-11 | Nippon Shokubai Co Ltd | 複合微粒子、その製造方法および用途 |
| JP2008303258A (ja) * | 2007-06-06 | 2008-12-18 | Nippon Synthetic Chem Ind Co Ltd:The | 活性エネルギー線硬化型エマルジョン組成物、及び、コーティング剤組成物 |
| CN103113531A (zh) * | 2013-01-15 | 2013-05-22 | 烟台万华聚氨酯股份有限公司 | 一种具有可再乳化性的水性聚氨酯丙烯酸酯乳液及其制备方法 |
| JP2015004040A (ja) * | 2013-06-24 | 2015-01-08 | 宇部興産株式会社 | 光及び熱硬化性水性樹脂分散体及びエラストマー積層体 |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112239599A (zh) * | 2019-07-16 | 2021-01-19 | 荒川化学工业株式会社 | 活性能量线固化型树脂组合物及含水树脂组合物、涂布剂组合物、固化膜和膜 |
| CN114196316A (zh) * | 2020-09-02 | 2022-03-18 | 荒川化学工业株式会社 | 活性能量射线固化性树脂组合物、固化膜及膜 |
| CN114316649A (zh) * | 2020-09-30 | 2022-04-12 | 荒川化学工业株式会社 | 活性能量线硬化型树脂组合物及层叠体 |
| CN114316649B (zh) * | 2020-09-30 | 2023-11-14 | 荒川化学工业株式会社 | 活性能量线硬化型树脂组合物及层叠体 |
| WO2022087885A1 (en) * | 2020-10-28 | 2022-05-05 | Dic Corporation | Active energy ray-curable aqueous resin composition, active energy ray-curable aqueous coating material, and article coated with the coating material |
| CN114685745A (zh) * | 2020-12-25 | 2022-07-01 | 昭和电工株式会社 | 氨基甲酸酯(甲基)丙烯酸酯及氨基甲酸酯(甲基)丙烯酸酯树脂的制造方法 |
| CN115975498A (zh) * | 2021-10-14 | 2023-04-18 | 荒川化学工业株式会社 | 水系乳液组合物、固化物以及积层体 |
| CN115975498B (zh) * | 2021-10-14 | 2024-03-26 | 荒川化学工业株式会社 | 水系乳液组合物、固化物以及积层体 |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20180095687A (ko) | 2018-08-27 |
| TW201734146A (zh) | 2017-10-01 |
| TWI693263B (zh) | 2020-05-11 |
| JPWO2017110843A1 (ja) | 2018-10-11 |
| WO2017110843A1 (ja) | 2017-06-29 |
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