CN107938322A - 一种羊毛帽子专用拒水抗起球整理液 - Google Patents

一种羊毛帽子专用拒水抗起球整理液 Download PDF

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CN107938322A
CN107938322A CN201711236376.2A CN201711236376A CN107938322A CN 107938322 A CN107938322 A CN 107938322A CN 201711236376 A CN201711236376 A CN 201711236376A CN 107938322 A CN107938322 A CN 107938322A
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water repellent
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李佳
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Anhui Zhongfu Wool Cap Co Ltd
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Abstract

本发明公开了一种羊毛帽子专用拒水抗起球整理液，其原料按重量份包括：交联淀粉3‑15份、含硅丙烯酸树脂3‑10份、牛奶蛋白2‑10份、丝素肽1‑5份、改性石墨烯10‑25份、六羟甲基三聚氰胺1‑5份、氨基甲酸乙酯3‑10份、甘油2‑10份、聚氧乙烯辛基苯基醚2‑5份、大豆卵磷脂0.3‑2份、纳米微晶纤维素1‑3份、增强剂0.3‑2份、有机酸0.3‑2份、水100份。本发明提出的羊毛帽子专用拒水抗起球整理液，其稳定性好，处理羊毛帽子后能赋予羊毛帽子优异的拒水性、抗菌性和抗起球性。

Description

一种羊毛帽子专用拒水抗起球整理液
技术领域
本发明涉及帽子技术领域，尤其涉及一种羊毛帽子专用拒水抗起球整理液。
背景技术
羊毛帽子具有手感柔软、色泽鲜艳、穿着轻盈舒适等特点，但是其防水性不是很好，且在穿戴和洗涤过程中，由于不断受到摩擦，会发生“起球”现象，从而极易使污物、灰尘沾附在羊毛帽子上，使帽子的穿着性能和外观受到严重影响，无法满足人们的要求。
发明内容
基于背景技术存在的技术问题，本发明提出了一种羊毛帽子专用拒水抗起球整理液，其稳定性好，处理羊毛帽子后能赋予羊毛帽子优异的拒水性、抗菌性和抗起球性。
本发明提出的一种羊毛帽子专用拒水抗起球整理液，其原料按重量份包括：交联淀粉3-15份、含硅丙烯酸树脂3-10份、牛奶蛋白2-10份、丝素肽1-5份、改性石墨烯10-25份、六羟甲基三聚氰胺1-5份、氨基甲酸乙酯3-10份、甘油2-10份、聚氧乙烯辛基苯基醚2-5份、大豆卵磷脂0.3-2份、纳米微晶纤维素1-3份、增强剂0.3-2份、有机酸0.3-2份、水100份。
优选地，所述改性石墨烯按照以下工艺进行制备：将过硫酸铵和硫酸铁加入水中搅拌均匀得到溶液A；将氧化石墨烯加入水中配置成分散液，调节pH值为3-4，然后加入苄乙烯基三甲基氯化铵和2-(全氟辛基)乙基甲基丙烯酸酯，超声震荡30-50min后加入溶液A，通入保护性气体，在室温下搅拌反应30-45h，反应结束后过滤、洗涤、干燥得到所述改性石墨烯。
优选地，氧化石墨烯、苄乙烯基三甲基氯化铵、2-(全氟辛基)乙基甲基丙烯酸酯的重量比为2-10：3-8：2-9。
优选地，加入的溶液A中过硫酸铵的重量为氧化石墨烯重量的1-3％；硫酸铁的重量为氧化石墨烯重量的0.3-1.2％。
优选地，所述增强剂为六羟甲基三聚氰胺、N,N,N’,N’-四甲基-1,6-己二胺、1,3,5-三氧杂环己烷中的一种或者多种的混合物。
优选地，所述有机酸为冰醋酸、柠檬酸、酒石酸、苹果酸中的一种或者多种的混合物。
优选地，其原料按重量份包括：交联淀粉10份、含硅丙烯酸树脂7份、牛奶蛋白5份、丝素肽3份、改性石墨烯21份、六羟甲基三聚氰胺3份、氨基甲酸乙酯7份、甘油8份、聚氧乙烯辛基苯基醚3.5份、大豆卵磷脂1.6份、纳米微晶纤维素2份、六羟甲基三聚氰胺1.6份、柠檬酸0.3份、酒石酸1份、水100份。
本发明所述羊毛帽子专用拒水抗起球整理液，其原料中，加入了含硅丙烯酸树脂，其与交联淀粉和牛奶蛋白配合，赋予羊毛帽子更好的抗起球性，不影响手感的情况下，降低了羊毛帽子的缩水率，同时增大了羊毛帽子的表面疏水性；在改性石墨烯的制备过程中，以苄乙烯基三甲基氯化铵和2-(全氟辛基)乙基甲基丙烯酸酯为原料对氧化石墨烯进行了改性，并控制了反应的条件，使苄乙烯基三甲基氯化铵和2-(全氟辛基)乙基甲基丙烯酸酯在氧化石墨烯表面发生了原位聚合，得到了改性石墨烯，将其加入体系中，与体系中的丝素肽、纳米微晶纤维素配合，赋予羊毛帽子优异的拒水性和抗菌性。
具体实施方式
下面，通过具体实施例对本发明的技术方案进行详细说明。
实施例1
本发明提出的一种羊毛帽子专用拒水抗起球整理液，其原料按重量份包括：交联淀粉15份、含硅丙烯酸树脂3份、牛奶蛋白10份、丝素肽1份、改性石墨烯25份、六羟甲基三聚氰胺1份、氨基甲酸乙酯10份、甘油2份、聚氧乙烯辛基苯基醚5份、大豆卵磷脂0.3份、纳米微晶纤维素3份、增强剂0.3份、有机酸0.3份、水100份。
实施例2
本发明提出的一种羊毛帽子专用拒水抗起球整理液，其原料按重量份包括：交联淀粉3份、含硅丙烯酸树脂10份、牛奶蛋白2份、丝素肽5份、改性石墨烯10份、六羟甲基三聚氰胺5份、氨基甲酸乙酯3份、甘油10份、聚氧乙烯辛基苯基醚2份、大豆卵磷脂2份、纳米微晶纤维素1份、增强剂2份、有机酸2份、水100份。
实施例3
本发明提出的一种羊毛帽子专用拒水抗起球整理液，其原料按重量份包括：交联淀粉13份、含硅丙烯酸树脂4.5份、牛奶蛋白8份、丝素肽2份、改性石墨烯21份、六羟甲基三聚氰胺2.3份、氨基甲酸乙酯8.3份、甘油3.2份、聚氧乙烯辛基苯基醚4.3份、大豆卵磷脂0.7份、纳米微晶纤维素2.6份、增强剂0.7份、有机酸1.6份、水100份；
其中，所述改性石墨烯按照以下工艺进行制备：将过硫酸铵和硫酸铁加入水中搅拌均匀得到溶液A；将氧化石墨烯加入水中配置成分散液，调节pH值为4，然后加入苄乙烯基三甲基氯化铵和2-(全氟辛基)乙基甲基丙烯酸酯，其中，氧化石墨烯、苄乙烯基三甲基氯化铵、2-(全氟辛基)乙基甲基丙烯酸酯的重量比为2：8：2，超声震荡50min后加入溶液A，其中，加入的溶液A中过硫酸铵的重量为氧化石墨烯重量的1％；硫酸铁的重量为氧化石墨烯重量的1.2％，通入保护性气体，在室温下搅拌反应30h，反应结束后过滤、洗涤、干燥得到所述改性石墨烯；
所述增强剂为N,N,N’,N’-四甲基-1,6-己二胺、1,3,5-三氧杂环己烷的混合物，且N,N,N’,N’-四甲基-1,6-己二胺、1,3,5-三氧杂环己烷的质量比为3:2；
所述有机酸为冰醋酸。
实施例4
本发明提出的一种羊毛帽子专用拒水抗起球整理液，其原料按重量份包括：交联淀粉6份、含硅丙烯酸树脂8.3份、牛奶蛋白3.6份、丝素肽4份、改性石墨烯16份、六羟甲基三聚氰胺4.3份、氨基甲酸乙酯4份、甘油9份、聚氧乙烯辛基苯基醚2.6份、大豆卵磷脂1.6份、纳米微晶纤维素1.5份、增强剂1.6份、有机酸0.8份、水100份；
其中，所述改性石墨烯按照以下工艺进行制备：将过硫酸铵和硫酸铁加入水中搅拌均匀得到溶液A；将氧化石墨烯加入水中配置成分散液，调节pH值为3，然后加入苄乙烯基三甲基氯化铵和2-(全氟辛基)乙基甲基丙烯酸酯，其中，氧化石墨烯、苄乙烯基三甲基氯化铵、2-(全氟辛基)乙基甲基丙烯酸酯的重量比为10：3：9，超声震荡30min后加入溶液A，其中，加入的溶液A中过硫酸铵的重量为氧化石墨烯重量的3％；硫酸铁的重量为氧化石墨烯重量的0.3％，通入保护性气体，在室温下搅拌反应45h，反应结束后过滤、洗涤、干燥得到所述改性石墨烯；
所述增强剂为六羟甲基三聚氰胺；
所述有机酸为冰醋酸、柠檬酸、酒石酸的混合物，且冰醋酸、柠檬酸、酒石酸的质量比为3:4:2。
实施例5
本发明提出的一种羊毛帽子专用拒水抗起球整理液，其原料按重量份包括：交联淀粉10份、含硅丙烯酸树脂7份、牛奶蛋白5份、丝素肽3份、改性石墨烯21份、六羟甲基三聚氰胺3份、氨基甲酸乙酯7份、甘油8份、聚氧乙烯辛基苯基醚3.5份、大豆卵磷脂1.6份、纳米微晶纤维素2份、六羟甲基三聚氰胺1.6份、柠檬酸0.3份、酒石酸1份、水100份；
其中，所述改性石墨烯按照以下工艺进行制备：将过硫酸铵和硫酸铁加入水中搅拌均匀得到溶液A；将氧化石墨烯加入水中配置成分散液，调节pH值为3.5，然后加入苄乙烯基三甲基氯化铵和2-(全氟辛基)乙基甲基丙烯酸酯，其中，氧化石墨烯、苄乙烯基三甲基氯化铵、2-(全氟辛基)乙基甲基丙烯酸酯的重量比为7：5：6，超声震荡40min后加入溶液A，其中，加入的溶液A中过硫酸铵的重量为氧化石墨烯重量的2％；硫酸铁的重量为氧化石墨烯重量的1％，通入保护性气体，在室温下搅拌反应40h，反应结束后过滤、洗涤、干燥得到所述改性石墨烯。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。

Claims (7)

1.一种羊毛帽子专用拒水抗起球整理液，其特征在于，其原料按重量份包括：交联淀粉3-15份、含硅丙烯酸树脂3-10份、牛奶蛋白2-10份、丝素肽1-5份、改性石墨烯10-25份、六羟甲基三聚氰胺1-5份、氨基甲酸乙酯3-10份、甘油2-10份、聚氧乙烯辛基苯基醚2-5份、大豆卵磷脂0.3-2份、纳米微晶纤维素1-3份、增强剂0.3-2份、有机酸0.3-2份、水100份。
2.根据权利要求1所述羊毛帽子专用拒水抗起球整理液，其特征在于，所述改性石墨烯按照以下工艺进行制备：将过硫酸铵和硫酸铁加入水中搅拌均匀得到溶液A；将氧化石墨烯加入水中配置成分散液，调节pH值为3-4，然后加入苄乙烯基三甲基氯化铵和2-(全氟辛基)乙基甲基丙烯酸酯，超声震荡30-50min后加入溶液A，通入保护性气体，在室温下搅拌反应30-45h，反应结束后过滤、洗涤、干燥得到所述改性石墨烯。
3.根据权利要求2所述羊毛帽子专用拒水抗起球整理液，其特征在于，氧化石墨烯、苄乙烯基三甲基氯化铵、2-(全氟辛基)乙基甲基丙烯酸酯的重量比为2-10：3-8：2-9。
4.根据权利要求2或3所述羊毛帽子专用拒水抗起球整理液，其特征在于，加入的溶液A中过硫酸铵的重量为氧化石墨烯重量的1-3％；硫酸铁的重量为氧化石墨烯重量的0.3-1.2％。
5.根据权利要求1-4中任一项所述羊毛帽子专用拒水抗起球整理液，其特征在于，所述增强剂为六羟甲基三聚氰胺、N,N,N’,N’-四甲基-1,6-己二胺、1,3,5-三氧杂环己烷中的一种或者多种的混合物。
6.根据权利要求1-5中任一项所述羊毛帽子专用拒水抗起球整理液，其特征在于，所述有机酸为冰醋酸、柠檬酸、酒石酸、苹果酸中的一种或者多种的混合物。
7.根据权利要求1-6中任一项所述羊毛帽子专用拒水抗起球整理液，其特征在于，其原料按重量份包括：交联淀粉10份、含硅丙烯酸树脂7份、牛奶蛋白5份、丝素肽3份、改性石墨烯21份、六羟甲基三聚氰胺3份、氨基甲酸乙酯7份、甘油8份、聚氧乙烯辛基苯基醚3.5份、大豆卵磷脂1.6份、纳米微晶纤维素2份、六羟甲基三聚氰胺1.6份、柠檬酸0.3份、酒石酸1份、水100份。
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