CN106273697A - 一种具有形状记忆功能的吸湿防潮无纺粘合衬及其制备方法 - Google Patents

一种具有形状记忆功能的吸湿防潮无纺粘合衬及其制备方法 Download PDF

Info

Publication number
CN106273697A
CN106273697A CN201610589221.6A CN201610589221A CN106273697A CN 106273697 A CN106273697 A CN 106273697A CN 201610589221 A CN201610589221 A CN 201610589221A CN 106273697 A CN106273697 A CN 106273697A
Authority
CN
China
Prior art keywords
layer
pla
shape memory
composite fibre
silk
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610589221.6A
Other languages
English (en)
Other versions
CN106273697B (zh
Inventor
豆鑫帆
豆树华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHANGXING SHENFAN TEXTILE Co Ltd
Original Assignee
CHANGXING SHENFAN TEXTILE Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CHANGXING SHENFAN TEXTILE Co Ltd filed Critical CHANGXING SHENFAN TEXTILE Co Ltd
Priority to CN201610589221.6A priority Critical patent/CN106273697B/zh
Publication of CN106273697A publication Critical patent/CN106273697A/zh
Application granted granted Critical
Publication of CN106273697B publication Critical patent/CN106273697B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/10—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
    • B32B3/12—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by a layer of regularly- arranged cells, e.g. a honeycomb structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/08—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/02—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising animal or vegetable substances, e.g. cork, bamboo, starch
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/045—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4374—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece using different kinds of webs, e.g. by layering webs
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/541—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/559—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving the fibres being within layered webs
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/13—Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/03—3 layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/20—All layers being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0253—Polyolefin fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06—Vegetal fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06—Vegetal fibres
    • B32B2262/062—Cellulose fibres, e.g. cotton
    • B32B2262/065—Lignocellulosic fibres, e.g. jute, sisal, hemp, flax, bamboo
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/73—Hydrophobic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00—Clothing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Ceramic Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Nonwoven Fabrics (AREA)

Abstract

本发明公开了一种具有形状记忆功能的吸湿防潮无纺粘合衬，包括基布和粘胶层，所述的基布为三层级结构的无纺衬布，上层为PLA/PP复合纤维层，中层为形状记忆纤维层，下层为抗菌除湿层，所述的基布在PLA/PP复合纤维层的表面涂覆有粘胶层，所述的PLA/PP复合纤维层由皮芯型PLA/PP复合纤维丝构成，所述的PLA/PP复合纤维丝由PLA纤维皮层包覆PP纤维芯层复合而成，所述的形状记忆纤维层由木棉纤维丝构成，所述的抗菌除湿层由甲壳素纤维丝构成。本发明还提供了一种具有形状记忆功能的吸湿防潮无纺粘合衬的制备方法，采用可降解的纤维为无纺基布的制备纤维，环保性好，基布整体挺括，具有抗菌活性、吸湿性、免烫和稳定形态的效果。

Description

一种具有形状记忆功能的吸湿防潮无纺粘合衬及其制备方法
【技术领域】
本发明涉及粘合衬的技术领域，特别涉及一种具有形状记忆功能的吸湿防潮无纺粘合衬及其制备方法。
【背景技术】
现代服装讲求在穿着风格上体现舒适、柔软、轻盈和随意有弹性。粘合衬作为“服装的骨架”，是服装不可忽缺的辅料，粘合衬是一种涂有热熔胶的衬里，是布艺制作经常用到的辅料之一。粘合衬经过加温熨压附着在布料的背面，“以粘代缝”大大简化生产工艺，且适用面广，其与面料的合理配合，不仅能充分体现服装设计师的设计思想，而且能够达到良好的服用效果。
随着经济的迅速发展，人们生活水平的逐渐提高，人们对服装的要求也越来越高，不仅要求服装外观自然、穿着舒适，而且要求产品不需维护，如具有免烫、抗皱等性能，且大部分人工合成的高分子材料在自然界中难以降解，不可降解的高分子材料造成了对环境的白色污染，已成为环境新的污染源。为了提高粘合衬的环保性能，降低对环境的污染，同时使衬布具有免烫抗皱的效果，有必要提出一种具有形状记忆功能的吸湿防潮无纺粘合衬及其制备方法。
【发明内容】
本发明的目的在于克服上述现有技术的不足，提供一种具有形状记忆功能的吸湿防潮无纺粘合衬及其制备方法，其旨在解决现有技术中粘合衬布的功能性较为单一，环境污染严重的技术问题。
为实现上述目的，本发明提出了一种具有形状记忆功能的吸湿防潮无纺粘合衬，包括基布和粘胶层，所述的基布为三层级结构的无纺衬布，上层为PLA/PP复合纤维层，中层为形状记忆纤维层，下层为抗菌除湿层，所述的基布在PLA/PP复合纤维层的表面涂覆有粘胶层，所述的PLA/PP复合纤维层由皮芯型PLA/PP复合纤维丝构成，所述的PLA/PP复合纤维丝由PLA纤维皮层包覆PP纤维芯层复合而成，所述的形状记忆纤维层由木棉纤维丝构成，所述的抗菌除湿层由甲壳素纤维丝构成。
作为优选，所述的PLA/PP复合纤维层、形状记忆纤维层、抗菌除湿层依次复合连接。
作为优选，所述的PLA/PP复合纤维层、形状记忆纤维层、抗菌除湿层均为薄型网状结构。
作为优选，所述的PP纤维芯层由数根聚丙烯纤维丝组成。
作为优选，所述的聚丙烯纤维丝的根数为1～3根。
一种具有形状记忆功能的吸湿防潮无纺粘合衬的制备方法，包括如下步骤：
a)制备纤维丝：采用1～3组PP为芯组分，PLA作为皮组分，通过复合纺丝机纺丝制得皮芯型PLA/PP复合纤维丝；选用天然木棉纤维制成木棉纤维丝；以二甲基乙酰胺为溶剂，无水氯化锂为分散剂，经磁力搅拌机混合均匀后，加入35％～85％(w/v)的甲壳素颗粒，经过密封搅拌，得到粘稠状的透明胶质纺丝原液，通过湿法纺丝得到甲壳素纤维丝，备用；
b)制备纤维网：分别将步骤a)中制得的皮芯型PLA/PP复合纤维丝、木棉纤维丝、甲壳素纤维丝梳理成网，形成薄型网状结构的PLA/PP复合纤维层、木棉纤维网和抗菌除湿层；
c)纤维网整理：对步骤b)中制得的木棉纤维网进行液氨处理35～45min后充分水洗，然后进行树脂整理，得到具有形状记忆功能的形状记忆纤维层；
d)制备基布：将PLA/PP复合纤维层、形状记忆纤维层和抗菌除湿层依次铺叠，并通过水刺、热轧复合得到基布；
e)涂层前处理：将步骤d)中制得的基布在绳状、无张力的条件下进行退浆和精炼处理，去除基布上的油剂和浆料，温度为85～95℃，25～30min后充分水洗并干燥，然后在高温高压喷射染色机上进行染色处理，染色完成后在拉幅定型机上进行定型处理，同时通过真空吸水使基布处于非常低的带液状态，再在浸轧液中浸轧处理后烘干；
f)双点涂层：采用PA热熔胶为基础层，PES热熔胶为粘结层，在步骤e)处理后的基布的PLA/PP复合纤维层表面进行双点涂层，然后进行170～185℃，时间为5～8min的焙烘熔融，并冷却成型；
g)检验卷取：通过检验后，将质量合格的粘合衬产品进行卷取打包。
作为优选，所述的步骤a)中密封搅拌的时间为3～4天。
作为优选，所述的步骤e)中浸轧液由有机氟防水剂、有机硅柔软剂、抗静电剂及蒸馏水组成，所述的有机氟防水剂的浓度为10～15g/L，有机硅柔软剂的浓度为20～35g/L，抗静电剂为2～5g/L。
本发明的有益效果：与现有技术相比，本发明提供的一种具有形状记忆功能的吸湿防潮无纺粘合衬及其制备方法，采用具有可降解的皮芯型PLA/PP复合纤维丝、木棉纤维丝和甲壳素纤维丝为无纺基布的制备纤维，环保性好，不会对环境造成污染；木棉纤维通过液氨处理及树脂整理具有较高的柔软性和回弹性，有形状记忆功能，具有免烫和稳定形态的功效；甲壳素纤维丝具有抗菌活性和吸湿性，对皮肤的亲和性好，无刺激，还具有预防过敏的效果，将具有形状记忆功效的木棉纤维夹持于较高弹性的皮芯型PLA/PP复合纤维丝层与抗菌吸湿的甲壳素纤维丝层之间，具有较强的保型性，基布整体挺括，具有免烫和稳定形态的效果。
本发明的特征及优点将通过实施例结合附图进行详细说明。
【附图说明】
图1是本发明实施例一种具有形状记忆功能的吸湿防潮无纺粘合衬的截面示意图；
图2是本发明实施例的皮芯型PLA/PP复合纤维丝的截面示意图。
图中：1-基布、2-粘胶层、3-PLA/PP复合纤维层、31-皮芯型PLA/PP复合纤维丝、311-PLA纤维皮层、312-PP纤维芯层、313-聚丙烯纤维丝、4-形状记忆纤维层、41-木棉纤维丝、5-抗菌除湿层、51-甲壳素纤维丝。
【具体实施方式】
为使本发明的目的、技术方案和优点更加清楚明了，下面通过附图中及实施例，对本发明进行进一步详细说明。但是应该理解，此处所描述的具体实施例仅仅用以解释本发明，并不用于限制本发明的范围。此外，在以下说明中，省略了对公知结构和技术的描述，以避免不必要地混淆本发明的概念。
参阅图1和图2，本发明实施例提供一种具有形状记忆功能的吸湿防潮无纺粘合衬，包括基布1和粘胶层2，所述的基布1为三层级结构的无纺衬布，上层为PLA/PP复合纤维层3，中层为形状记忆纤维层4，下层为抗菌除湿层5，所述的基布1在PLA/PP复合纤维层3的表面涂覆有粘胶层2，所述的PLA/PP复合纤维层3由皮芯型PLA/PP复合纤维丝31构成，所述的PLA/PP复合纤维丝31由PLA纤维皮层311包覆PP纤维芯层312复合而成，所述的形状记忆纤维层4由木棉纤维丝41构成，所述的抗菌除湿层5由甲壳素纤维丝51构成。
所述的PLA/PP复合纤维层3、形状记忆纤维层4、抗菌除湿层5依次复合连接，所述的PLA/PP复合纤维层3、形状记忆纤维层4、抗菌除湿层5均为薄型网状结构，所述的PP纤维芯层312由数根聚丙烯纤维丝313组成，所述的聚丙烯纤维丝313的根数为1～3根。
在本发明实施例中，聚丙烯纤维丝313的根数为3根。
本实施例还提供了一种具有形状记忆功能的吸湿防潮无纺粘合衬的制备方法，包括如下步骤：
a)制备纤维丝：采用1～3组PP为芯组分，PLA作为皮组分，通过复合纺丝机纺丝制得皮芯型PLA/PP复合纤维丝31；选用天然木棉纤维制成木棉纤维丝41；以二甲基乙酰胺为溶剂，无水氯化锂为分散剂，经磁力搅拌机混合均匀后，加入35％～85％(w/v)的甲壳素颗粒，经过密封搅拌，得到粘稠状的透明胶质纺丝原液，通过湿法纺丝得到甲壳素纤维丝51，备用。
其中，密封搅拌的时间为3～4天。
b)制备纤维网：分别将步骤a)中制得的皮芯型PLA/PP复合纤维丝31、木棉纤维丝41、甲壳素纤维丝51梳理成网，形成薄型网状结构的PLA/PP复合纤维层3、木棉纤维网和抗菌除湿层5。
c)纤维网整理：对步骤b)中制得的木棉纤维网进行液氨处理35～45min后充分水洗，然后进行树脂整理，得到具有形状记忆功能的形状记忆纤维层4。
其中，液氨处理的处理液由2D树脂整理剂、MgCl2·6H2O、NH4Cl、柔软剂和润湿剂组成，2D树脂整理剂的浓度为92～95g/L、MgCl2·6H2O和NH4Cl的浓度为12～16g/L，柔软剂为30～40g/L，润湿剂为1～2g/L；树脂整理的树脂液由2D树脂整理剂、MgCl2·6H2O、NH4Cl、柔软剂和润湿剂组成，2D树脂整理剂的浓度为80～90g/L、MgCl2·6H2O和NH4Cl的浓度为8～10g/L，柔软剂为40～50g/L，润湿剂为1～2g/L。
进一步地，液氨处理的处理液和树脂整理的树脂液中MgCl2·6H2O和NH4Cl的浓度比为15：1，柔软剂为有机硅柔软剂，润湿剂为TRITONTM HW-1000。
d)制备基布：将PLA/PP复合纤维层3、形状记忆纤维层4和抗菌除湿层5依次铺叠，并通过水刺、热轧复合得到基布1。
e)涂层前处理：将步骤d)中制得的基布1在绳状、无张力的条件下进行退浆和精炼处理，去除基布1上的油剂和浆料，温度为85～95℃，25～30min后充分水洗并干燥，然后在高温高压喷射染色机上进行染色处理，染色完成后在拉幅定型机上进行定型处理，同时通过真空吸水使基布1处于非常低的带液状态，再在浸轧液中浸轧处理后烘干。
其中，浸轧液由有机氟防水剂、有机硅柔软剂、抗静电剂及蒸馏水组成，所述的有机氟防水剂的浓度为10～15g/L，有机硅柔软剂的浓度为20～35g/L，抗静电剂为2～5g/L。
f)双点涂层：采用PA热熔胶为基础层，PES热熔胶为粘结层，在步骤e)处理后的基布1的PLA/PP复合纤维层3表面进行双点涂层，然后进行170～185℃，时间为5～8min的焙烘熔融，并冷却成型。
g)检验卷取：通过检验后，将质量合格的粘合衬产品进行卷取打包。
以上所述仅为本发明的较佳实施例而已，并不用以限制本发明，凡在本发明的精神和原则之内所作的任何修改、等同替换或改进等，均应包含在本发明的保护范围之内。

Claims (8)

1.一种具有形状记忆功能的吸湿防潮无纺粘合衬，包括基布(1)和粘胶层(2)，其特征在于：所述的基布(1)为三层级结构的无纺衬布，上层为PLA/PP复合纤维层(3)，中层为形状记忆纤维层(4)，下层为抗菌除湿层(5)，所述的基布(1)在PLA/PP复合纤维层(3)的表面涂覆有粘胶层(2)，所述的PLA/PP复合纤维层(3)由皮芯型PLA/PP复合纤维丝(31)构成，所述的PLA/PP复合纤维丝(31)由PLA纤维皮层(311)包覆PP纤维芯层(312)复合而成，所述的形状记忆纤维层(4)由木棉纤维丝(41)构成，所述的抗菌除湿层(5)由甲壳素纤维丝(51)构成。
2.如权利要求1所述的一种具有形状记忆功能的吸湿防潮无纺粘合衬，其特征在于：所述的PLA/PP复合纤维层(3)、形状记忆纤维层(4)、抗菌除湿层(5)依次复合连接。
3.如权利要求2所述的一种具有形状记忆功能的吸湿防潮无纺粘合衬，其特征在于：所述的PLA/PP复合纤维层(3)、形状记忆纤维层(4)、抗菌除湿层(5)均为薄型网状结构。
4.如权利要求1所述的一种具有形状记忆功能的吸湿防潮无纺粘合衬，其特征在于：所述的PP纤维芯层(312)由数根聚丙烯纤维丝(313)组成。
5.如权利要求4所述的一种具有形状记忆功能的吸湿防潮无纺粘合衬，其特征在于：所述的聚丙烯纤维丝(313)的根数为1～3根。
6.一种具有形状记忆功能的吸湿防潮无纺粘合衬的制备方法，其特征在于：包括如下步骤：
a)制备纤维丝：采用1～3组PP为芯组分，PLA作为皮组分，通过复合纺丝机纺丝制得皮芯型PLA/PP复合纤维丝(31)；选用天然木棉纤维制成木棉纤维丝(41)；以二甲基乙酰胺为溶剂，无水氯化锂为分散剂，经磁力搅拌机混合均匀后，加入35％～85％(w/v)的甲壳素颗粒，经过密封搅拌，得到粘稠状的透明胶质纺丝原液，通过湿法纺丝得到甲壳素纤维丝(51)，备用；
b)制备纤维网：分别将步骤a)中制得的皮芯型PLA/PP复合纤维丝(31)、木棉纤维丝(41)、甲壳素纤维丝(51)梳理成网，形成薄型网状结构的PLA/PP复合纤维层(3)、木棉纤维网和抗菌除湿层(5)；
c)纤维网整理：对步骤b)中制得的木棉纤维网进行液氨处理35～45min后充分水洗，然后进行树脂整理，得到具有形状记忆功能的形状记忆纤维层(4)；
d)制备基布：将PLA/PP复合纤维层(3)、形状记忆纤维层(4)和抗菌除湿层(5)依次铺叠，并通过水刺、热轧复合得到基布(1)；
e)涂层前处理：将步骤d)中制得的基布(1)在绳状、无张力的条件下进行退浆和精炼处理，去除基布(1)上的油剂和浆料，温度为85～95℃，25～30min后充分水洗并干燥，然后在高温高压喷射染色机上进行染色处理，染色完成后在拉幅定型机上进行定型处理，同时通过真空吸水使基布(1)处于非常低的带液状态，再在浸轧液中浸轧处理后烘干；
f)双点涂层：采用PA热熔胶为基础层，PES热熔胶为粘结层，在步骤e)处理后的基布(1)的PLA/PP复合纤维层(3)表面进行双点涂层，然后进行170～185℃，时间为5～8min的焙烘熔融，并冷却成型；
g)检验卷取：通过检验后，将质量合格的粘合衬产品进行卷取打包。
7.如权利要求6所述的一种具有形状记忆功能的吸湿防潮无纺粘合衬的制备方法，其特征在于：所述的步骤a)中密封搅拌的时间为3～4天。
8.如权利要求6所述的一种具有形状记忆功能的吸湿防潮无纺粘合衬的制备方法，其特征在于：所述的步骤e)中浸轧液由有机氟防水剂、有机硅柔软剂、抗静电剂及蒸馏水组成，所述的有机氟防水剂的浓度为10～15g/L，有机硅柔软剂的浓度为20～35g/L，抗静电剂为2～5g/L。
CN201610589221.6A 2016-07-22 2016-07-22 一种具有形状记忆功能的吸湿防潮无纺粘合衬及其制备方法 Active CN106273697B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610589221.6A CN106273697B (zh) 2016-07-22 2016-07-22 一种具有形状记忆功能的吸湿防潮无纺粘合衬及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610589221.6A CN106273697B (zh) 2016-07-22 2016-07-22 一种具有形状记忆功能的吸湿防潮无纺粘合衬及其制备方法

Publications (2)

Publication Number Publication Date
CN106273697A true CN106273697A (zh) 2017-01-04
CN106273697B CN106273697B (zh) 2018-04-10

Family

ID=57652154

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610589221.6A Active CN106273697B (zh) 2016-07-22 2016-07-22 一种具有形状记忆功能的吸湿防潮无纺粘合衬及其制备方法

Country Status (1)

Country Link
CN (1) CN106273697B (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110667213A (zh) * 2019-10-25 2020-01-10 福建冠泓工业有限公司 一种高性能无纺布及其制备方法
CN114561744A (zh) * 2022-02-08 2022-05-31 江阴市中兴无纺布有限公司 一种过滤用抑菌透气无纺布及其制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102499498A (zh) * 2011-09-30 2012-06-20 常熟市众望经纬编织造有限公司 一种抗菌记忆面料
CN204690227U (zh) * 2015-05-12 2015-10-07 长兴圣帆纺织有限公司 一种防水环保粘合衬基布
CN205890015U (zh) * 2016-07-22 2017-01-18 长兴圣帆纺织有限公司 一种具有形状记忆功能的吸湿防潮无纺粘合衬

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102499498A (zh) * 2011-09-30 2012-06-20 常熟市众望经纬编织造有限公司 一种抗菌记忆面料
CN204690227U (zh) * 2015-05-12 2015-10-07 长兴圣帆纺织有限公司 一种防水环保粘合衬基布
CN205890015U (zh) * 2016-07-22 2017-01-18 长兴圣帆纺织有限公司 一种具有形状记忆功能的吸湿防潮无纺粘合衬

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110667213A (zh) * 2019-10-25 2020-01-10 福建冠泓工业有限公司 一种高性能无纺布及其制备方法
CN114561744A (zh) * 2022-02-08 2022-05-31 江阴市中兴无纺布有限公司 一种过滤用抑菌透气无纺布及其制备方法
CN114561744B (zh) * 2022-02-08 2023-09-01 江阴市中兴无纺布有限公司 一种过滤用抑菌透气无纺布及其制备方法

Also Published As

Publication number Publication date
CN106273697B (zh) 2018-04-10

Similar Documents

Publication Publication Date Title
CN106087442B (zh) 一种含竹活性炭粉环保多轴向经编粘合衬及其制备工艺
CN102199803B (zh) 一种高弹性免烫纤维素纤维及其制备方法
CN103126140B (zh) 一种羊绒衬布的生产工艺
CN105671777B (zh) 一种超薄抗撕裂防水涤纶面料及其制备工艺
CN105813491A (zh) 具有不连续弹性聚合物成分的体形增强衣
CN103494357A (zh) 一种新型抗皱西服
CN106592223A (zh) 一种衬衫的防水防油防污型免烫整理液及其整理方法
CN106223059A (zh) 一种有纺衬里粘合衬布及其制备方法
CN110468497A (zh) 一种抗菌复合面料及其制造方法
CN111743218B (zh) 可机洗羊毛西服及其缝制方法
CN205890015U (zh) 一种具有形状记忆功能的吸湿防潮无纺粘合衬
CN105124811B (zh) 一种具有高吸湿透气性能的无纺布领衬的制备工艺
CN106012580A (zh) 一种衬布及其制作方法
CN106273697B (zh) 一种具有形状记忆功能的吸湿防潮无纺粘合衬及其制备方法
CN103462262A (zh) 一种新型抗皱西服的加工方法
CN112323213A (zh) 一种竹纤维与羊毛的面料
CN104195712A (zh) 一种舒适型儿童保暖面料
CN205893783U (zh) 一种含竹活性炭粉环保多轴向经编粘合衬
CN103767200B (zh) 一种莫代尔双点衬的制备工艺
CN106072936B (zh) 一种含竹活性炭粉的可降解环保无纺粘合衬及其制备方法
CN209436287U (zh) 一种驼绒羽绒防寒服装
CN101086140A (zh) 聚安亚酯类粘合衬布及其制造方法
CN106087443B (zh) 一种含竹活性炭粉的可降解环保机织粘合衬及其制备工艺
CN106165932B (zh) 一种具有形状记忆与调温功能的粘合衬及其制备方法
CN205902851U (zh) 一种具有形状记忆与调温功能的粘合衬

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant