CN106273697A - A kind of moisture absorption protection against the tide nonwoven adhesive interlining with shape memory function and preparation method thereof - Google Patents

A kind of moisture absorption protection against the tide nonwoven adhesive interlining with shape memory function and preparation method thereof Download PDF

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Publication number
CN106273697A
CN106273697A CN201610589221.6A CN201610589221A CN106273697A CN 106273697 A CN106273697 A CN 106273697A CN 201610589221 A CN201610589221 A CN 201610589221A CN 106273697 A CN106273697 A CN 106273697A
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China
Prior art keywords
layer
pla
shape memory
composite fibre
silk
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Granted
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CN201610589221.6A
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CN106273697B (en
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豆鑫帆
豆树华
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CHANGXING SHENFAN TEXTILE Co Ltd
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CHANGXING SHENFAN TEXTILE Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form
    • B32B3/10Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
    • B32B3/12Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by a layer of regularly- arranged cells, e.g. a honeycomb structure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/08Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
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    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/02Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising animal or vegetable substances, e.g. cork, bamboo, starch
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/045Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4374Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece using different kinds of webs, e.g. by layering webs
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    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
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    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4382Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/541Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/559Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving the fibres being within layered webs
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/13Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic System
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/155Halides of elements of Groups 2 or 12 of the Periodic System
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
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    • B32B2250/00Layers arrangement
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    • B32B2262/06Vegetal fibres
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    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145Rot proof, resistant to bacteria, mildew, mould, fungi
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    • B32B2437/00Clothing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
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    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/20Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50Modified hand or grip properties; Softening compositions

Abstract

The invention discloses a kind of moisture absorption protection against the tide nonwoven adhesive interlining with shape memory function, including base fabric and adhesive-layer, described base fabric is the nonwoven lining cloth of three hierarchical structures, upper strata is PLA/PP composite fibre layer, middle level is shape memory fiber layer, lower floor is antibacterial dehumidifying layer, described base fabric has adhesive-layer in the surface-coated of PLA/PP composite fibre layer, described PLA/PP composite fibre layer is made up of core-skin type PLA/PP composite fibre silk, described PLA/PP composite fibre silk is composited by PLA fibrocortex cladding PP core fiber layer, described shape memory fiber layer is made up of bombax cotton silk, described antibacterial dehumidifying layer is made up of chitin fiber silk.Present invention also offers the preparation method of a kind of moisture absorption protection against the tide nonwoven adhesive interlining with shape memory function, use degradable fiber be non-woven base cloth prepare fiber, the feature of environmental protection is good, and base fabric entirety is well-pressed, has antibacterial activity, hygroscopicity, the non-ironing and effect of stable form.

Description

A kind of moisture absorption protection against the tide nonwoven adhesive interlining with shape memory function and preparation method thereof
[technical field]
The present invention relates to the technical field of adhesive lining, particularly to a kind of moisture absorption protection against the tide nonwoven with shape memory function Adhesive lining and preparation method thereof.
[background technology]
Modern clothing stress wear embody in style comfortable, soft, slim and graceful and the most flexible.Adhesive lining is as " clothes The skeleton of dress ", it is the adjuvants that can not suddenly lack of clothing, adhesive lining is a kind of lining scribbling PUR, is that cloth art makes through commonly using One of adjuvant arrived.Adhesive lining is attached to the back side of cloth through pressing of heating, and " stitching with viscous generation " is greatly simplified production technology, and Widely applicable, itself and the reasonable coordination of fabric, the design philosophy of designer can not only be fully demonstrated, and can reach good Good takes effect.
Along with economic develops rapidly, gradually stepping up of people's living standard, people are more and more higher to the requirement of clothing, Do not require nothing more than apparel appearance natural, comfortable and easy to wear, and require that product is not required to safeguard, as having the performances such as non-ironing, crease-resistant, and greatly The macromolecular material of part synthetic is difficult to degrade in nature, and nondegradable macromolecular material causes environment White pollution, it has also become the polluter that environment is new.In order to improve the environmental-protecting performance of adhesive lining, reduce the pollution to environment, simultaneously Make lining cloth have the effect of ironing and anti-crease, it is necessary to propose a kind of moisture absorption protection against the tide nonwoven adhesive interlining with shape memory function and Its preparation method.
[summary of the invention]
It is an object of the invention to overcome above-mentioned the deficiencies in the prior art, it is provided that a kind of moisture absorption with shape memory function Moistureproof nonwoven adhesive interlining and preparation method thereof, it aims to solve the problem that the functional the most single of adhesion lining cloth in prior art, environment With serious pollution technical problem.
For achieving the above object, the present invention proposes a kind of moisture absorption protection against the tide nonwoven adhesive interlining with shape memory function, Including base fabric and adhesive-layer, described base fabric is the nonwoven lining cloth of three hierarchical structures, and upper strata is PLA/PP composite fibre layer, middle level For shape memory fiber layer, lower floor is antibacterial dehumidifying layer, and described base fabric has viscous in the surface-coated of PLA/PP composite fibre layer Glue-line, described PLA/PP composite fibre layer is made up of core-skin type PLA/PP composite fibre silk, described PLA/PP composite fibre Silk is composited by PLA fibrocortex cladding PP core fiber layer, and described shape memory fiber layer is made up of bombax cotton silk, institute The antibacterial dehumidifying layer stated is made up of chitin fiber silk.
As preferably, described PLA/PP composite fibre layer, shape memory fiber layer, antibacterial dehumidifying layer successively compound even Connect.
As preferably, described PLA/PP composite fibre layer, shape memory fiber layer, antibacterial dehumidifying layer are slim netted Structure.
As preferably, described PP core fiber layer is made up of several polypropylene filaments.
As preferably, the radical of described polypropylene filaments is 1~3.
The preparation method of a kind of moisture absorption protection against the tide nonwoven adhesive interlining with shape memory function, comprises the steps:
A) cellosilk is prepared: using 1~3 group of PP is core component, and PLA is as skin component, by composite spinning machine spinning system Obtain core-skin type PLA/PP composite fibre silk;Natural kawo fiber is selected to make bombax cotton silk;With dimethyl acetylamide as solvent, Anhydrous Lithium chloride is dispersant, after magnetic stirrer mix homogeneously, adds the chitin granule of 35%~85% (w/v), warp Cross sealing stirring, obtain thick transparent colloid spinning solution, obtain chitin fiber silk by wet spinning, standby;
B) fleece is prepared: respectively by the core-skin type PLA/PP composite fibre silk prepared in step a), bombax cotton silk, first Shell cellulose fiber silk carding, forms slim cancellated PLA/PP composite fibre layer, bombax cotton net and antibacterial dehumidifying layer;
C) fleece arranges: abundant water after the bombax cotton net prepared in step b) carries out Liquid Ammonia Treatment 35~45min Wash, then carry out resin finishing, obtain the shape memory fiber layer with shape memory function;
D) base fabric is prepared: by PLA/PP composite fibre layer, shape memory fiber layer and antibacterial dehumidifying layer laying successively, and lead to Cross spun lacing, method hot rolling obtains base fabric;
E) coating pre-treatment: by step d) prepare base fabric rope form, tension-free under the conditions of carry out desizing and refine Processing, remove the oil preparation in base fabric and slurry, temperature is 85~95 DEG C, fully washes and is dried, then at height after 25~30min Carry out dyeing process in temperature high-pressure injection staining machine, on framing shaping machine, carry out heat treatment after having dyeed, pass through simultaneously Vacuum dehydration makes base fabric be in low-down band liquid status, then pads process post-drying in padding liquid;
F) double-dot coating: using layer based on PA PUR, retardation PES hot melt adhesive is tack coat, the base after step e) processes The PLA/PP composite fibre layer surface of cloth carries out double-dot coating, then carries out 170~185 DEG C, the time be 5~8min bake molten Melt, and cool down molding;
G) inspection is batched: after inspection, carry out batching packing by up-to-standard adhesive lining product.
As preferably, the time sealing stirring in described step a) is 3~4 days.
As preferably, in described step e), padding liquid is by organic fluorine waterproof agent, silicone softening agent, antistatic additive and steaming Distilled water forms, and the concentration of described organic fluorine waterproof agent is 10~15g/L, and the concentration of silicone softening agent is 20~35g/L, anti- Electrostatic agent is 2~5g/L.
Beneficial effects of the present invention: compared with prior art, a kind of suction with shape memory function that the present invention provides Wet moistureproof nonwoven adhesive interlining and preparation method thereof, uses and has degradable core-skin type PLA/PP composite fibre silk, bombax cotton Silk and chitin fiber silk are the fiber of preparing of non-woven base cloth, and the feature of environmental protection is good, will not be to environment;Bombax cotton passes through Liquid Ammonia Treatment and resin finishing have higher flexibility and resilience, have shape memory function, have non-ironing and stable form Effect;Chitin fiber silk has antibacterial activity and hygroscopicity, good to the affinity of skin, non-stimulated, also has and prevented Quick effect, is held on the core-skin type PLA/PP composite fibre silk layer of higher elasticity by the bombax cotton with shape memory effect And between the chitin fiber silk layer of anti-bacterial wet-absorbing, having stronger shape-retaining ability, base fabric entirety is well-pressed, has non-ironing and stable shape The effect of state.
Inventive feature and advantage will combine accompanying drawing by embodiment and be described in detail.
[accompanying drawing explanation]
Fig. 1 is the cross section signal of a kind of moisture absorption protection against the tide nonwoven adhesive interlining with shape memory function of the embodiment of the present invention Figure;
Fig. 2 is the schematic cross-section of the core-skin type PLA/PP composite fibre silk of the embodiment of the present invention.
In figure: 1-base fabric, 2-adhesive-layer, 3-PLA/PP composite fibre layer, 31-core-skin type PLA/PP composite fibre silk, 311-PLA fibrocortex, 312-PP core fiber layer, 313-polypropylene filaments, 4-shape memory fiber layer, 41-bombax cotton Silk, 5-antibacterial dehumidifying layer, 51-chitin fiber silk.
[detailed description of the invention]
For making the object, technical solutions and advantages of the present invention of greater clarity, below by accompanying drawing and embodiment, right The present invention is further elaborated.However, it should be understood that specific embodiment described herein is only in order to explain this Bright, it is not limited to the scope of the present invention.Additionally, in the following description, eliminate the description to known features and technology, with Avoid unnecessarily obscuring idea of the invention.
Refering to Fig. 1 and Fig. 2, the embodiment of the present invention provides a kind of moisture absorption protection against the tide nonwoven bonding with shape memory function Lining, including base fabric 1 and adhesive-layer 2, the described nonwoven lining cloth that base fabric 1 is three hierarchical structures, upper strata is PLA/PP composite fibre Layer 3, middle level is shape memory fiber layer 4, and lower floor is antibacterial dehumidifying layer 5, and described base fabric 1 is at PLA/PP composite fibre layer 3 Surface-coated has adhesive-layer 2, and described PLA/PP composite fibre layer 3 is made up of core-skin type PLA/PP composite fibre silk 31, described PLA/PP composite fibre silk 31 be coated with PP core fiber layer 312 by PLA fibrocortex 311 and be composited, described shape memory Fibrous layer 4 is made up of bombax cotton silk 41, and described antibacterial dehumidifying layer 5 is made up of chitin fiber silk 51.
Described PLA/PP composite fibre layer 3, shape memory fiber layer 4, antibacterial dehumidifying layer 5 composite joint successively, described PLA/PP composite fibre layer 3, shape memory fiber layer 4, antibacterial dehumidifying layer 5 be slim network structure, described PP fiber Sandwich layer 312 is made up of several polypropylene filaments 313, and the radical of described polypropylene filaments 313 is 1~3.
In embodiments of the present invention, the radical of polypropylene filaments 313 is 3.
The present embodiment additionally provides the preparation method of a kind of moisture absorption protection against the tide nonwoven adhesive interlining with shape memory function, bag Include following steps:
A) cellosilk is prepared: using 1~3 group of PP is core component, and PLA is as skin component, by composite spinning machine spinning system Obtain core-skin type PLA/PP composite fibre silk 31;Natural kawo fiber is selected to make bombax cotton silk 41;With dimethyl acetylamide it is Solvent, anhydrous Lithium chloride is dispersant, after magnetic stirrer mix homogeneously, adds the chitin of 35%~85% (w/v) Grain, through sealing stirring, obtains thick transparent colloid spinning solution, obtains chitin fiber silk 51 by wet spinning, Standby.
Wherein, the time sealing stirring is 3~4 days.
B) fleece is prepared: respectively by the core-skin type PLA/PP composite fibre silk 31 prepared in step a), bombax cotton silk 41, chitin fiber silk 51 carding, forms slim cancellated PLA/PP composite fibre layer 3, bombax cotton net and resists Bacterium dehumidifying layer 5.
C) fleece arranges: abundant water after the bombax cotton net prepared in step b) carries out Liquid Ammonia Treatment 35~45min Wash, then carry out resin finishing, obtain the shape memory fiber layer 4 with shape memory function.
Wherein, the treatment fluid of Liquid Ammonia Treatment is by 2D resin finishing agent, MgCl2·6H2O、NH4Cl, softening agent and wetting agent group Becoming, the concentration of 2D resin finishing agent is 92~95g/L, MgCl2·6H2O and NH4The concentration of Cl is 12~16g/L, and softening agent is 30~40g/L, wetting agent is 1~2g/L;The resin liquid of resin finishing is by 2D resin finishing agent, MgCl2·6H2O、NH4Cl, soft Soft dose and wetting agent composition, the concentration of 2D resin finishing agent is 80~90g/L, MgCl2·6H2O and NH4The concentration of Cl be 8~ 10g/L, softening agent is 40~50g/L, and wetting agent is 1~2g/L.
Further, MgCl in the treatment fluid of Liquid Ammonia Treatment and the resin liquid of resin finishing2·6H2O and NH4The concentration of Cl Ratio is 15:1, and softening agent is silicone softening agent, and wetting agent is TRITONTM HW-1000。
D) base fabric is prepared: by PLA/PP composite fibre layer 3, shape memory fiber layer 4 and antibacterial dehumidifying layer 5 laying successively, And obtain base fabric 1 by spun lacing, method hot rolling.
E) coating pre-treatment: by step d) prepare base fabric 1 rope form, tension-free under the conditions of carry out desizing and refine Processing, remove the oil preparation in base fabric 1 and slurry, temperature is 85~95 DEG C, fully washes and is dried, then exist after 25~30min Carry out dyeing process in HTHP Jet Dyeing Machine, on framing shaping machine, carry out heat treatment after having dyeed, lead to simultaneously Crossing vacuum dehydration makes base fabric 1 be in low-down band liquid status, then pads process post-drying in padding liquid.
Wherein, padding liquid is made up of organic fluorine waterproof agent, silicone softening agent, antistatic additive and distilled water, and described has The concentration of machine fluoro water proofing agent is 10~15g/L, and the concentration of silicone softening agent is 20~35g/L, and antistatic additive is 2~5g/L.
F) double-dot coating: using layer based on PA PUR, retardation PES hot melt adhesive is tack coat, the base after step e) processes PLA/PP composite fibre layer 3 surface of cloth 1 carries out double-dot coating, then carries out 170~185 DEG C, and the time is 5~8min bake Melted, and cool down molding.
G) inspection is batched: after inspection, carry out batching packing by up-to-standard adhesive lining product.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention Any amendment, equivalent or the improvement etc. made within god and principle, should be included within the scope of the present invention.

Claims (8)

1. there is a moisture absorption protection against the tide nonwoven adhesive interlining for shape memory function, including base fabric (1) and adhesive-layer (2), its feature Being: the described nonwoven lining cloth that base fabric (1) is three hierarchical structures, upper strata is PLA/PP composite fibre layer (3), and middle level is shape Memory fiber layer (4), lower floor is antibacterial dehumidifying layer (5), and described base fabric (1) is coated with on the surface of PLA/PP composite fibre layer (3) Being covered with adhesive-layer (2), described PLA/PP composite fibre layer (3) is made up of core-skin type PLA/PP composite fibre silk (31), described PLA/PP composite fibre silk (31) by PLA fibrocortex (311) cladding PP core fiber layer (312) be composited, described shape Shape memory fiber layer (4) is made up of bombax cotton silk (41), and described antibacterial dehumidifying layer (5) is by chitin fiber silk (51) structure Become.
A kind of moisture absorption protection against the tide nonwoven adhesive interlining with shape memory function, it is characterised in that: institute The PLA/PP composite fibre layer (3) stated, shape memory fiber layer (4), antibacterial dehumidifying layer (5) composite joint successively.
A kind of moisture absorption protection against the tide nonwoven adhesive interlining with shape memory function, it is characterised in that: institute The PLA/PP composite fibre layer (3) stated, shape memory fiber layer (4), antibacterial dehumidifying layer (5) are slim network structure.
A kind of moisture absorption protection against the tide nonwoven adhesive interlining with shape memory function, it is characterised in that: institute The PP core fiber layer (312) stated is made up of several polypropylene filaments (313).
A kind of moisture absorption protection against the tide nonwoven adhesive interlining with shape memory function, it is characterised in that: institute The radical of the polypropylene filaments (313) stated is 1~3.
6. the preparation method of a moisture absorption protection against the tide nonwoven adhesive interlining with shape memory function, it is characterised in that: include as follows Step:
A) cellosilk is prepared: using 1~3 group of PP is core component, and PLA, as skin component, prepares skin by composite spinning machine spinning Core pattern PLA/PP composite fibre silk (31);Natural kawo fiber is selected to make bombax cotton silk (41);With dimethyl acetylamide it is Solvent, anhydrous Lithium chloride is dispersant, after magnetic stirrer mix homogeneously, adds the chitin of 35%~85% (w/v) Grain, through sealing stirring, obtains thick transparent colloid spinning solution, obtains chitin fiber silk by wet spinning (51), standby;
B) fleece is prepared: respectively by core-skin type PLA/PP composite fibre silk (31) prepared in step a), bombax cotton silk (41), chitin fiber silk (51) carding, form slim cancellated PLA/PP composite fibre layer (3), bombax cotton Net and antibacterial dehumidifying layer (5);
C) fleece arranges: fully wash, so after the bombax cotton net prepared in step b) is carried out Liquid Ammonia Treatment 35~45min After carry out resin finishing, obtain the shape memory fiber layer (4) with shape memory function;
D) base fabric is prepared: PLA/PP composite fibre layer (3), shape memory fiber layer (4) and antibacterial dehumidifying layer (5) are spread successively Folded, and obtain base fabric (1) by spun lacing, method hot rolling;
E) coating pre-treatment: by step d) prepare base fabric (1) rope form, tension-free under the conditions of carry out at desizing and refine Reason, removes the oil preparation in base fabric (1) and slurry, and temperature is 85~95 DEG C, fully washes and is dried, then exist after 25~30min Carry out dyeing process in HTHP Jet Dyeing Machine, on framing shaping machine, carry out heat treatment after having dyeed, lead to simultaneously Crossing vacuum dehydration makes base fabric (1) be in low-down band liquid status, then pads process post-drying in padding liquid;
F) double-dot coating: using layer based on PA PUR, retardation PES hot melt adhesive is tack coat, the base fabric (1) after step e) processes PLA/PP composite fibre layer (3) surface carry out double-dot coating, then carry out 170~185 DEG C, the time is 5~8min bake Melted, and cool down molding;
G) inspection is batched: after inspection, carry out batching packing by up-to-standard adhesive lining product.
A kind of preparation method of the moisture absorption protection against the tide nonwoven adhesive interlining with shape memory function, its It is characterised by: the time sealing stirring in described step a) is 3~4 days.
A kind of preparation method of the moisture absorption protection against the tide nonwoven adhesive interlining with shape memory function, its It is characterised by: in described step e), padding liquid is by organic fluorine waterproof agent, silicone softening agent, antistatic additive and distilled water group Becoming, the concentration of described organic fluorine waterproof agent is 10~15g/L, and the concentration of silicone softening agent is 20~35g/L, antistatic additive It is 2~5g/L.
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Publication number Priority date Publication date Assignee Title
CN110667213A (en) * 2019-10-25 2020-01-10 福建冠泓工业有限公司 High-performance non-woven fabric and preparation method thereof
CN114561744A (en) * 2022-02-08 2022-05-31 江阴市中兴无纺布有限公司 Bacteriostatic breathable non-woven fabric for filtration and preparation method thereof

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CN102499498A (en) * 2011-09-30 2012-06-20 常熟市众望经纬编织造有限公司 Antibacterial memory fabric
CN204690227U (en) * 2015-05-12 2015-10-07 长兴圣帆纺织有限公司 A kind of water-proof environmental protection adhesive interlining substrates
CN205890015U (en) * 2016-07-22 2017-01-18 长兴圣帆纺织有限公司 Dampproofing non woven adhesive interlining of moisture absorption with shape memory function

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Publication number Priority date Publication date Assignee Title
CN102499498A (en) * 2011-09-30 2012-06-20 常熟市众望经纬编织造有限公司 Antibacterial memory fabric
CN204690227U (en) * 2015-05-12 2015-10-07 长兴圣帆纺织有限公司 A kind of water-proof environmental protection adhesive interlining substrates
CN205890015U (en) * 2016-07-22 2017-01-18 长兴圣帆纺织有限公司 Dampproofing non woven adhesive interlining of moisture absorption with shape memory function

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110667213A (en) * 2019-10-25 2020-01-10 福建冠泓工业有限公司 High-performance non-woven fabric and preparation method thereof
CN114561744A (en) * 2022-02-08 2022-05-31 江阴市中兴无纺布有限公司 Bacteriostatic breathable non-woven fabric for filtration and preparation method thereof
CN114561744B (en) * 2022-02-08 2023-09-01 江阴市中兴无纺布有限公司 Antibacterial breathable non-woven fabric for filtering and preparation method thereof

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