CN106165932B - A kind of adhesive lining with shape memory and temperature adjustment function and preparation method thereof - Google Patents
A kind of adhesive lining with shape memory and temperature adjustment function and preparation method thereof Download PDFInfo
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- CN106165932B CN106165932B CN201610584252.2A CN201610584252A CN106165932B CN 106165932 B CN106165932 B CN 106165932B CN 201610584252 A CN201610584252 A CN 201610584252A CN 106165932 B CN106165932 B CN 106165932B
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- shape memory
- temperature adjustment
- base fabric
- double
- layer
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-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/02—Layered materials
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D27/00—Details of garments or of their making
- A41D27/02—Linings
- A41D27/06—Stiffening-pieces
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form
- B32B3/02—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by features of form at particular places, e.g. in edge regions
- B32B3/08—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by added members at particular parts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/028—Net structure, e.g. spaced apart filaments bonded at the crossing points
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/02—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising animal or vegetable substances, e.g. cork, bamboo, starch
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B9/047—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material made of fibres or filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/18—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from other substances
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
- D06L1/14—De-sizing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic System
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
- D06M11/59—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with ammonia; with complexes of organic amines with inorganic substances
- D06M11/61—Liquid ammonia
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/12—Processes in which the treating agent is incorporated in microcapsules
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/30—Antimicrobial, e.g. antibacterial
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/02—2 layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/20—All layers being fibrous or filamentary
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/06—Vegetal fibres
- B32B2262/062—Cellulose fibres, e.g. cotton
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/08—Animal fibres, e.g. hair, wool, silk
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
- B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2437/00—Clothing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Abstract
The invention discloses a kind of adhesive lining with shape memory and temperature adjustment function,Including double-deck level base fabric and adhesive-layer,Described double-deck level base fabric is combined by shape memory layer and anti-bacterial wet-absorbing layer,The temperature adjustment microcapsules containing phase change material are also fixed with described double-deck level base fabric,Described shape memory layer is made up of the bombax cotton silk with shape memory function,Described anti-bacterial wet-absorbing layer is made up of chitin fiber silk,The one side or dual coating of described double-deck level base fabric have adhesive-layer,The invention also discloses a kind of preparation method of the adhesive lining with shape memory and temperature adjustment function,Using biodegradable fiber,The feature of environmental protection is good,Shape memory layer has the effect of non-ironing and stable form,Adhesive lining is well-pressed,Shape-retaining ability is good,Anti-bacterial wet-absorbing layer has antibacterial activity and hygroscopicity,The compatibility of skin is good,It is non-stimulated,Contain temperature adjustment microcapsules in adhesive lining,There is intelligent thermoregulating,Wearing comfort greatly improves.
Description
【Technical field】
The present invention relates to the technical field of adhesive lining, more particularly to a kind of adhesive lining with shape memory and temperature adjustment function
And preparation method thereof.
【Background technology】
Modern clothing stress embodied on style is worn it is comfortable, soft, slim and graceful and arbitrarily it is flexible.Adhesive lining is as " clothes
The skeleton of dress ", it is that clothes can not neglect scarce auxiliary material, adhesive lining is a kind of lining for scribbling PUR, is that fabrics is made through conventional
One of auxiliary material arrived.Adhesive lining is attached to the back side of cloth by heating pressing, and " being stitched with viscous generation " greatly simplifies production technology, and
It is widely applicable, its reasonable cooperation with fabric, the design philosophy of designer can not only be fully demonstrated, and can reach good
Good takes effect.
With developing rapidly for economy, people's living standard gradually steps up, requirement of the people to clothes also more and more higher,
It is natural, comfortable and easy to wear that apparel appearance is not required nothing more than, and requires that product is not required to safeguard, such as there is non-ironing, crease-resistant, intelligent thermoregulating
Performance, and most of artificial synthesized high polymer material is difficult to degrade in nature at present, nondegradable high polymer material
Cause the white pollution to environment, it has also become the new pollution sources of environment.In order to improve the environmental-protecting performance of adhesive lining, reduce to ring
The pollution in border, while make lining cloth that there is the effect of ironing and anti-crease, intelligent thermoregulating, it is necessary to propose a kind of there is shape memory with adjusting
Adhesive lining of temperature function and preparation method thereof.
【The content of the invention】
It is an object of the invention to overcome above-mentioned the deficiencies in the prior art, there is provided one kind has shape memory and temperature adjustment function
Adhesive lining and preparation method thereof, it is aimed to solve the problem that, and the feature of adhesive lining in the prior art is more single, the feature of environmental protection is relatively low
Technical problem.
To achieve the above object, the present invention proposes a kind of adhesive lining with shape memory and temperature adjustment function, including double
Level base fabric and adhesive-layer, described double-deck level base fabric are combined by shape memory layer and anti-bacterial wet-absorbing layer, described bilayer
The temperature adjustment microcapsules containing phase change material are also fixed with level base fabric, described shape memory layer is by with shape memory function
Bombax cotton silk is formed, and described anti-bacterial wet-absorbing layer is made up of chitin fiber silk, the one side or double of described double-deck level base fabric
Face is coated with adhesive-layer.
Preferably, a diameter of 1~3 μm of described temperature adjustment microcapsules.
Preferably, described shape memory layer and anti-bacterial wet-absorbing layer is light and thin type network structure.
Preferably, described shape memory layer and the volume ratio of double-deck level base fabric are (65~70):100.
A kind of preparation method of the adhesive lining with shape memory and temperature adjustment function, comprises the following steps:
A) fiber is prepared:Bombax cotton silk is made from natural kawo fiber;Using dimethyl acetamide as solvent, anhydrous chlorine
Change lithium is dispersant, after magnetic stirrer is well mixed, 35%~85% (w/v) crust crude granule is added, by sealing
Stirring, obtains thick transparent colloid spinning solution, chitin fiber silk is obtained by wet spinning, standby;
B) web is prepared:The bombax cotton silk in step a) and chitin fiber silk (5) are entered respectively on carding machine
Row combs, and obtains the uniform bombax cotton net of thickness and chitin fiber net;
C) web arranges:Carry out Liquid Ammonia Treatment to obtained bombax cotton net in step b), abundant water after 35~45min
Wash, then dried after carrying out resin finishing, obtain the shape memory layer with shape memory function;
D) base fabric is prepared:Chitin fiber net in step b) and the shape memory layer in step c) are overlapped, pass through water
Thorn, method hot rolling obtain double-deck level base fabric;
E) temperature adjustment microcapsules are sprayed:Temperature adjustment microcapsules containing phase change material are mixed with distilled water, and added in right amount
Dispersant, 3~6min of ultrasonic oscillator is placed in after preliminary stirring, after being fully mixed to no precipitation, adds appropriate binder, then
It is secondary to be placed in 2~3min of ultrasonic oscillator, temperature adjustment microcapsules spray coating liquor is obtained, double-deck level is then vertically sprayed at using spraying process
In base fabric, after being dried at a temperature of 24~27 DEG C, double-deck level base fabric is soaped, removes unreacted and the composition of non-set;
F) coating pre-treatment:Double-deck level base fabric after step e) processing is subjected to desizing and refining treatment, go degreaser and
Slurry, temperature are 85~95 DEG C, fully wash and dry after 25~30min, are then carried out in HTHP Jet Dyeing Machine
Dyeing is handled, and carries out heat treatment after the completion of dyeing on framing shaping machine, while make at double-deck level base fabric by vacuum dehydration
In low-down band liquid status, then dried after padding processing in padding liquid;
G) double-dot coating:Using layer based on PA PURs, retardation PES hot melt adhesive is tack coat, double after step f) processing
The one side of level base fabric or two-sided carry out double-dot coating, 170~185 DEG C then being carried out, the time bakes melting for 5~8min's,
And it is cooled and shaped;
H) examine and batch:After inspection, up-to-standard adhesive lining product is carried out batching packing.
Preferably, the time of sealing stirring is 3~4 days in described step a).
Preferably, the treatment fluid of Liquid Ammonia Treatment is by 2D resin finishing agents, MgCl in described step c)2·6H2O、
NH4Cl, softening agent and wetting agent composition, the concentration of 2D resin finishing agents is 92~95g/L, MgCl2·6H2O and NH4Cl's is dense
It is 30~40g/L to spend for 12~16g/L, softening agent, and wetting agent is 1~2g/L;The resin liquid of described resin finishing is by 2D trees
Fat finishing agent, MgCl2·6H2O、NH4Cl, softening agent and wetting agent composition, the concentration of 2D resin finishing agents is 80~90g/L,
MgCl2·6H2O and NH4Cl concentration is 8~10g/L, and softening agent is 40~50g/L, and wetting agent is 1~2g/L.
Preferably, MgCl in the treatment fluid of described Liquid Ammonia Treatment and the resin liquid of resin finishing2·6H2O and NH4Cl
Concentration ratio be 15:1, softening agent is silicone softening agent, wetting agent TRITONTMHW-1000。
Preferably, dispersant is polycaprolactone in described step e), binder is polyvinyl alcohol.
Beneficial effects of the present invention:Compared with prior art, one kind provided by the invention has shape memory and temperature adjustment work(
Adhesive lining of energy and preparation method thereof, use manufacture of the degradable bombax cotton silk with chitin fiber silk for double-deck level base fabric
Fiber, there is environment protection significance;After bombax cotton silk combs networking, by Liquid Ammonia Treatment and resin finishing, pliability is obtained
Height, resilience are good and have the shape memory layer of shape memory function, have the effect of non-ironing and stable form;Chitin is fine
Anti-bacterial wet-absorbing layer made of dimension silk has antibacterial activity and hygroscopicity, good to the compatibility of skin, non-stimulated, also has and prevented
Quick effect;The temperature adjustment microcapsules containing phase change material are bonded in double-deck level base fabric by spraying process so that adhesive lining has
There is intelligent thermoregulating, play a part of adjusting temperature, there is provided moist heat in comfortable clothes, wearing comfort are big
It is big to improve.
The feature and advantage of the present invention will be described in detail by embodiment combination accompanying drawing.
【Brief description of the drawings】
Fig. 1 is a kind of schematic cross-section of the adhesive lining with shape memory and temperature adjustment function of the embodiment of the present invention;
Fig. 2 is the partial enlarged drawing in A portions in Fig. 1.
In figure:1- bilayer levels base fabric, 11- shape memories layer, 12- anti-bacterial wet-absorbings layer, 2- adhesive-layers, 3- temperature adjustments microcapsules,
4- bombax cottons silk, 5- chitin fiber silks.
【Embodiment】
It is right below by accompanying drawing and embodiment to make the object, technical solutions and advantages of the present invention of greater clarity
The present invention is further elaborated.However, it should be understood that specific embodiment described herein is only explaining this hair
Scope that is bright, being not intended to limit the invention.In addition, in the following description, the description to known features and technology is eliminated, with
Avoid unnecessarily obscuring idea of the invention.
Refering to Fig. 1 and Fig. 2, the embodiment of the present invention provides a kind of adhesive lining with shape memory and temperature adjustment function, including
Double-deck level base fabric 1 and adhesive-layer 2, described double-deck level base fabric 1 are combined by shape memory layer 11 and anti-bacterial wet-absorbing layer 12, institute
The temperature adjustment microcapsules 3 containing phase change material are also fixed with the double-deck level base fabric 1 stated, described shape memory layer 11 is by with shape
The bombax cotton silk 4 of shape memory function is formed, and described anti-bacterial wet-absorbing layer 12 is made up of chitin fiber silk 5, described bilayer
The one side or dual coating of level base fabric 1 have adhesive-layer 2.
A diameter of 1~3 μm of described temperature adjustment microcapsules 3, described shape memory layer 11 and anti-bacterial wet-absorbing layer 12 are
Light and thin type network structure, described shape memory layer 11 and the volume ratio of double-deck level base fabric 1 are (65~70):100.
The present embodiment also provides a kind of preparation method of the adhesive lining with shape memory and temperature adjustment function, including following step
Suddenly:
A) fiber is prepared:Bombax cotton silk 4 is made from natural kawo fiber;It is anhydrous using dimethyl acetamide as solvent
Lithium chloride is dispersant, after magnetic stirrer is well mixed, 35%~85% (w/v) crust crude granule is added, through overstocked
Envelope stirring, obtains thick transparent colloid spinning solution, chitin fiber silk 5 is obtained by wet spinning, standby.
Wherein, the time for sealing stirring is 3~4 days.
B) web is prepared:The bombax cotton silk 4 in step a) and chitin fiber silk 5 are carried out respectively on carding machine
Comb, obtain the uniform bombax cotton net of thickness and chitin fiber net.
C) web arranges:Carry out Liquid Ammonia Treatment to obtained bombax cotton net in step b), abundant water after 35~45min
Wash, then dried after carrying out resin finishing, obtain the shape memory layer 11 with shape memory function.
Wherein, the treatment fluid of Liquid Ammonia Treatment is by 2D resin finishing agents, MgCl2·6H2O、NH4Cl, softening agent and wetting agent group
Into the concentration of 2D resin finishing agents is 92~95g/L, MgCl2·6H2O and NH4Cl concentration is 12~16g/L, and softening agent is
30~40g/L, wetting agent are 1~2g/L;The resin liquid of described resin finishing is by 2D resin finishing agents, MgCl2·6H2O、
NH4Cl, softening agent and wetting agent composition, the concentration of 2D resin finishing agents is 80~90g/L, MgCl2·6H2O and NH4Cl's is dense
It is 40~50g/L to spend for 8~10g/L, softening agent, and wetting agent is 1~2g/L.
Further, MgCl in the treatment fluid of Liquid Ammonia Treatment and the resin liquid of resin finishing2·6H2O and NH4Cl concentration
Than for 15:1, softening agent is silicone softening agent, wetting agent TRITONTMHW-1000。
D) base fabric is prepared:Shape memory layer 11 in chitin fiber net in step b) and step c) is overlapping, pass through
Spun lacing, method hot rolling obtain double-deck level base fabric 1.
E) temperature adjustment microcapsules are sprayed:Temperature adjustment microcapsules 3 containing phase change material are mixed with distilled water, and added in right amount
Dispersant, 3~6min of ultrasonic oscillator is placed in after preliminary stirring, after being fully mixed to no precipitation, adds appropriate binder, then
It is secondary to be placed in 2~3min of ultrasonic oscillator, temperature adjustment microcapsules spray coating liquor is obtained, double-deck level is then vertically sprayed at using spraying process
In base fabric 1, after drying at a temperature of 24~27 DEG C, double-deck level base fabric 1 is soaped, remove unreacted and non-set into
Point.
Wherein, dispersant is polycaprolactone, and binder is polyvinyl alcohol.
F) coating pre-treatment:Double-deck level base fabric 1 after step e) processing is subjected to desizing and refining treatment, go degreaser and
Slurry, temperature are 85~95 DEG C, fully wash and dry after 25~30min, are then carried out in HTHP Jet Dyeing Machine
Dyeing is handled, and carries out heat treatment after the completion of dyeing on framing shaping machine, while make at double-deck level base fabric 1 by vacuum dehydration
In low-down band liquid status, then dried after padding processing in padding liquid.
G) double-dot coating:Using layer based on PA PURs, retardation PES hot melt adhesive is tack coat, double after step f) processing
The one side of level base fabric 1 or two-sided carry out double-dot coating, 170~185 DEG C then being carried out, the time bakes melting for 5~8min's,
And it is cooled and shaped.
H) examine and batch:After inspection, up-to-standard adhesive lining product is carried out batching packing.
A kind of adhesive lining with shape memory and temperature adjustment function provided by the invention and preparation method thereof, use is degradable
Bombax cotton silk and chitin fiber silk be double-deck level base fabric manufacture fiber, there is environment protection significance;By bombax cotton silk
After combing networking, by Liquid Ammonia Treatment and resin finishing, it is good and with shape memory function to obtain pliability height, resilience
Shape memory layer 11, there is the effect of non-ironing and stable form;Anti-bacterial wet-absorbing layer 12 made of chitin fiber silk has antibacterial
Activity and hygroscopicity, it is good to the compatibility of skin, it is non-stimulated, also with pre- hypo-allergenic effect;Phase will be contained by spraying process
The temperature adjustment microcapsules 3 for becoming material are bonded in double-deck level base fabric so that adhesive lining has the function that intelligent thermoregulating, plays regulation temperature
The effect of degree, there is provided moist heat in comfortable clothes, wearing comfort greatly improve.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
Any modification, equivalent substitution or improvement made within refreshing and principle etc., should be included in the scope of the protection.
Claims (5)
1. a kind of adhesive lining with shape memory and temperature adjustment function, including double-deck level base fabric (1) and adhesive-layer (2), its feature
It is:Described double-deck level base fabric (1) is combined by shape memory layer (11) and anti-bacterial wet-absorbing layer (12), described shape note
It is light and thin type network structure to recall layer (11) and anti-bacterial wet-absorbing layer (12), described shape memory layer (11) and double-deck level base fabric
(1) volume ratio is (65~70):100, the micro- glue of the temperature adjustment containing phase change material is also fixed with described double-deck level base fabric (1)
Capsule (3), a diameter of 1~3 μm of described temperature adjustment microcapsules (3), described shape memory layer (11) is by with shape memory work(
The bombax cotton silk (4) of energy is formed, and described anti-bacterial wet-absorbing layer (12) is made up of chitin fiber silk (5), described double-deck level
The one side or dual coating of base fabric (1) have adhesive-layer (2), a kind of preparation side of the adhesive lining with shape memory and temperature adjustment function
Method, comprise the following steps:
A) fiber is prepared:Bombax cotton silk (4) is made from natural kawo fiber;Using dimethyl acetamide as solvent, anhydrous chlorine
Change lithium is dispersant, after magnetic stirrer is well mixed, 35%~85% (w/v) crust crude granule is added, by sealing
Stirring, obtains thick transparent colloid spinning solution, chitin fiber silk (5) is obtained by wet spinning, standby;
B) web is prepared:The bombax cotton silk (4) in step a) and chitin fiber silk (5) are carried out respectively on carding machine
Comb, obtain the uniform bombax cotton net of thickness and chitin fiber net;
C) web arranges:Liquid Ammonia Treatment is carried out to obtained bombax cotton net in step b), fully washed after 35~45min,
Dried after carrying out resin finishing again, obtain the shape memory layer (11) with shape memory function;
D) base fabric is prepared:Shape memory layer (11) in chitin fiber net in step b) and step c) is overlapping, pass through water
Thorn, method hot rolling obtain double-deck level base fabric (1);
E) temperature adjustment microcapsules are sprayed:Temperature adjustment microcapsules (3) containing phase change material are mixed with distilled water, and add appropriate point
Powder, 3~6min of ultrasonic oscillator is placed in after preliminary stirring, after being fully mixed to no precipitation, adds appropriate binder, again
2~3min of ultrasonic oscillator is placed in, obtains temperature adjustment microcapsules spray coating liquor, double-deck level base is then vertically sprayed at using spraying process
On cloth (1), after drying at a temperature of 24~27 DEG C, double-deck level base fabric (1) is soaped, remove unreacted and non-set into
Point;
F) coating pre-treatment:Double-deck level base fabric (1) after step e) processing is subjected to desizing and refining treatment, removes degreaser and slurry
Material, temperature are 85~95 DEG C, fully wash and dry after 25~30min, are then contaminated in HTHP Jet Dyeing Machine
Color processing, carries out heat treatment, while make double-deck level base fabric (1) place by vacuum dehydration on framing shaping machine after the completion of dyeing
In low-down band liquid status, then dried after padding processing in padding liquid;
G) double-dot coating:Using layer based on PA PURs, retardation PES hot melt adhesive is tack coat, the double-deck level after step f) processing
The one side of base fabric (1) or two-sided carry out double-dot coating, then 170~185 DEG C of progress, the melting that bakes that the time is 5~8min, and
It is cooled and shaped;
H) examine and batch:After inspection, up-to-standard adhesive lining product is carried out batching packing.
2. a kind of preparation method of adhesive lining with shape memory and temperature adjustment function as claimed in claim 1, its feature exist
In:The time of sealing stirring is 3~4 days in described step a).
3. a kind of preparation method of adhesive lining with shape memory and temperature adjustment function as claimed in claim 1, its feature exist
In:The treatment fluid of Liquid Ammonia Treatment is by 2D resin finishing agents, MgCl in described step c)2·6H2O、NH4Cl, softening agent and wetting
Agent forms, and the concentration of 2D resin finishing agents is 92~95g/L, MgCl2·6H2O and NH4Cl concentration is 12~16g/L, soft
Agent is 30~40g/L, and wetting agent is 1~2g/L;The resin liquid of described resin finishing is by 2D resin finishing agents, MgCl2·
6H2O、NH4Cl, softening agent and wetting agent composition, the concentration of 2D resin finishing agents is 80~90g/L, MgCl2·6H2O and NH4Cl
Concentration be 8~10g/L, softening agent is 40~50g/L, and wetting agent is 1~2g/L.
4. a kind of preparation method of adhesive lining with shape memory and temperature adjustment function as claimed in claim 3, its feature exist
In:MgCl in the treatment fluid of described Liquid Ammonia Treatment and the resin liquid of resin finishing2·6H2O and NH4Cl concentration ratio is 15:1,
Softening agent is silicone softening agent, wetting agent TRITONTMHW-1000。
5. a kind of preparation method of adhesive lining with shape memory and temperature adjustment function as claimed in claim 1, its feature exist
In:Dispersant is polycaprolactone in described step e), and binder is polyvinyl alcohol.
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CN107201664B (en) * | 2017-05-24 | 2019-08-30 | 东莞易昌塑胶布业有限公司 | A kind of production method of the lining cloth of adjustable temperature |
CN114921956B (en) * | 2022-06-02 | 2023-11-07 | 高梵(浙江)信息技术有限公司 | Manufacturing method of ultrathin down jacket fabric with waterproof constant temperature function |
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CN102499498A (en) * | 2011-09-30 | 2012-06-20 | 常熟市众望经纬编织造有限公司 | Antibacterial memory fabric |
CN203188031U (en) * | 2013-04-16 | 2013-09-11 | 福建百川资源再生科技有限公司 | Novel cloth with intelligent temperature regulation effect |
CN204690227U (en) * | 2015-05-12 | 2015-10-07 | 长兴圣帆纺织有限公司 | A kind of water-proof environmental protection adhesive interlining substrates |
CN204930484U (en) * | 2015-08-13 | 2016-01-06 | 长兴三马仕纺织品有限公司 | A kind of antibacterial, ventilating adhesion lining cloth |
CN205902851U (en) * | 2016-07-22 | 2017-01-25 | 长兴圣帆纺织有限公司 | Bonding lining with shape memory and function that adjusts temperature |
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