CN106223046A - A kind of bidirectional inductive accumulation of energy insulation afterfinish method of fabric - Google Patents

A kind of bidirectional inductive accumulation of energy insulation afterfinish method of fabric Download PDF

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Publication number
CN106223046A
CN106223046A CN201610610300.0A CN201610610300A CN106223046A CN 106223046 A CN106223046 A CN 106223046A CN 201610610300 A CN201610610300 A CN 201610610300A CN 106223046 A CN106223046 A CN 106223046A
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CN
China
Prior art keywords
fabric
phase
bidirectional inductive
afterfinish method
accumulation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610610300.0A
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Chinese (zh)
Inventor
顾义师
唐志钢
周丽红
傅青
于拥军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Zhan Mushi Textile Co Ltd
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Jiangsu Zhan Mushi Textile Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Zhan Mushi Textile Co Ltd filed Critical Jiangsu Zhan Mushi Textile Co Ltd
Priority to CN201610610300.0A priority Critical patent/CN106223046A/en
Publication of CN106223046A publication Critical patent/CN106223046A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/12Processes in which the treating agent is incorporated in microcapsules
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B7/00Mercerising, e.g. lustring by mercerising
    • D06B7/08Mercerising, e.g. lustring by mercerising of fabrics of indefinite length
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C3/00Stretching, tentering or spreading textile fabrics; Producing elasticity in textile fabrics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C7/00Heating or cooling textile fabrics
    • D06C7/02Setting
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C9/00Singeing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32Polyesters

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

A kind of bidirectional inductive accumulation of energy insulation afterfinish method of fabric, belong to technical field of textile printing, the present invention is padded by using the padding liquid containing phase-change microcapsule during stentering forming at the postfinishing process of fabric, again through baking after tentering drying, phase-change microcapsule and fabric is made to issue biochemical cross-linking reaction in the effect of cross-linking agent.The method suitability compared with existing method is higher, and effect is more preferable, and it is the most convenient to operate.Present invention process be suitable for textile and regenerated celulose fibre pure spin or with intertexture and the blend fabric such as chemical fibre.

Description

A kind of bidirectional inductive accumulation of energy insulation afterfinish method of fabric
Technical field
The invention belongs to technical field of textile printing, be specifically related to a kind of bidirectional inductive accumulation of energy heat preserving finishing method.
Background technology
Tradition medicated clothing, mainly by the low feature of air pyroconductivity, uses the method improving fabric still air Reducing the transmission of heat, its insulation effect depends primarily on thickness and the density of fabric, and its heat insulation effect is by ambient pressure With the impact of moisture, effect is very big by surrounding environment influence, and the body-sensing feeding back to human body is the most delayed.
Later, people, in the manufacturing process of the chemical fibre raw material such as terylene or chinlon, were incubated by addition spray webbing when Particle, makes insulation fibre, although this method can play the effect of insulation, but fibers material itself is airtight, hygroscopicity Poor, institute's in this way limitation is bigger, it is impossible to be used on shirt, underwear, family's textile fabric.
People have studied phase-change accumulation energy microcapsule (or phase-change microcapsule emulsion), such as Application No. at present " the phase-change accumulation energy microcapsule that organic-inorganic is compound and preparation method thereof " of CN201310548439.3 discloses one The preparation method of phase-change accumulation energy microcapsule, to being used for energy storage, heat insulation building, clothes by the phase-change accumulation energy made microcapsule Dress production technical field;" the wax phase change accumulation energy microcapsule of a kind of multilamellar capsule skin such as Application No. CN201510598879.9 Preparation method " disclose the phase-change accumulation energy microcapsule preparing a kind of good hydrophilic property;And Application No. " preparation method of a kind of wax phase change microcapsule adjustable fabric " of CN201610194541.1 not only discloses phase-change microcapsule Preparation method, also the phase-change microcapsule made directly is coated on weaving face fabric, heated after form heat-insulation layer, with improve The heat insulating ability of fabric.
But, the above method still can not solve fabric and have einnehmen function ventilative, hygroscopic, it is thus impossible to It is applied in large quantities on daily quilt, clothes.
Summary of the invention
Present invention aim at proposing a kind of not only having there is heat insulating ability but also had ventilative and certain hygroscopic, wearability The preferably bidirectional inductive accumulation of energy insulation afterfinish method of fabric.
The present invention includes carrying out grey cloth successively singing, desizing, mercerising, stentering forming, bake and preshrunk processes, its feature It is: when stentering forming, uses the padding liquid containing phase-change microcapsule to pad post-drying.
The present invention by when the stentering forming of the postfinishing process of fabric use containing phase-change microcapsule pad immersion Roll, tentering dry after again through baking, make phase-change microcapsule and fabric issue biochemical crosslinking in the effect of cross-linking agent anti- Should.The method suitability compared with existing method is higher, and effect is more preferable, and it is the most convenient to operate.Present invention process be suitable for textile and Regenerated celulose fibre is pure spin or with intertexture and the blend fabric such as chemical fibre.
By applying phase-change microcapsule on fabric, can be changed by solid-liquid and reach storage or the effect of release heat Really.When ambient temperature raises and arrives phase-change material fusing point, microcapsule phase change material inside melts heat absorption;When ambient temperature reduces When arriving phase-change material freezing point, the solidification heat release of microcapsule phase change material inside.
No matter the fabric ambient temperature using the inventive method Final finishing raises or reduces, it is at human body and clothing The effect of an actuator, the change of buffering ambient temperature can be played between thing, medicated clothing and external environment, the most also have Washability, its breathability and water absorption also conform to the demand of bedding and clothing fabric, and the present invention can be that human body provides comfortable moist heat Be completely newly incubated mechanism, it is possible to thermal conditioning and be not only thermal isolation.
Further, the padding liquid containing phase-change microcapsule of the present invention is by phase-change microcapsule emulsion, cross-linking agent, infiltration Agent, acetic acid and water composition.
Conventional sizing padding liquid is made up of softening agent, penetrating agent, acetic acid and water.
The present invention then have employed phase-change microcapsule emulsion and cross-linking agent in padding liquid, by phase-change microcapsule auxiliary agent, friendship Connection agent is diffused into fabric under penetrating agent effect, and penetrating agent is conducive to auxiliary agent rapid osmotic to enter fabric, and disperses Uniformly.Under certain acid condition, through uniform temperature, phase-change microcapsule and cross-linking agent in acid condition with fabric Learn cross-linking reaction, make phase-change microcapsule auxiliary agent be combined with fabric securely.
Further, in the padding liquid containing phase-change microcapsule of the present invention, phase-change microcapsule emulsion accounting be 15~ 40g/L, cross-linking agent 2~5g/L, penetrating agent 1~2g/L, acetic acid 1~2g/L.
When microcapsule consumption is at more than 15g/l, fabric has obvious heat insulation effect, consider be defined as 15 ~ 40g/l, dosage of crosslinking agent is 10% relative to microcapsule consumption, now can react complete.Between regulation working liquid ph 4 ~ 5, suitable Under amount penetrating agent effect, phase-change microcapsule and cross-linking agent can be dispersed in fabric very well.
During stentering forming of the present invention, drying room temperature is preferably 130~160 DEG C, and the temperature of padding liquid is preferably 55~65 DEG C. Drying room temperature combines forming machine equipment performance and production capacity, sets setting temperature as 130~160 DEG C, and the too low fabric of temperature is difficult to dry Dry, speed is slow;The too high fabric of temperature is easily generated xanthochromia, and energy consumption is big.
Padding liquid temperature need to be maintained at more than 55 DEG C, and such microcapsule emulsion has preferable dissolubility, disperses evenly, The too high production of temperature is difficult to.
The requirement it addition, the present invention singes: singing clear, cloth cover is bright and clean.
Desizing rate >=99% of grey cloth, the capillary effect >=5cm/5min of fabric after desizing.So that the fabric of pretreatment is when padding Can material feeding abundant.
During described mercerising, fabric is padded Caustic soda through mercerizing range, be 30~60 through the action time of sodium hydroxide solution Second, then by the hot water wash of flowing except grey cloth face caustic lye of soda, after mercerising, the pH value of fabric is 7~8.This mercerization can be further Ensure that fabric shrinkage is stablized and cloth cover quality.
It addition, the temperature environment baked is 150~170 DEG C, the time of baking is 45~180 seconds.When reaching 150 DEG C in temperature Time start cross-linking reaction, the response time, temperature is the highest can suitably shorten the time of baking, and makes end reaction between 45~180 seconds Completely.
Detailed description of the invention
One, 55/45 polyester-cotton blend woven base face is carried out Final finishing:
Fabric prepares: grey cloth stand seam positive and negative is consistent, and margin to seam is flat, straight, neat, firm.
Singe operation: requiring to singe clear, cloth cover is bright and clean, and desizing requires that desizing is clean.The desizing rate of grey cloth reaches more than 99%, Capillary effect reaches 5cm/5min, it is ensured that feel and capillary effect after desizing, fully prepares for follow-up sizing material feeding.
Mercerizing process: pad Caustic soda through mercerizing range, is 30~60 seconds through sodium hydroxide solution action time, then with stream Dynamic hot water (temperature range 55~65 DEG C) eccysis grey cloth face caustic lye of soda, until cloth cover pH value is 7~8.
Stentering forming operation: padding applying phase-change microcapsule auxiliary agent and carry out on framing shaping machine, drying room temperature controls 130~160 DEG C.
Wherein, padding liquid used consists of: phase-change microcapsule emulsion 15~40g/L, cross-linking agent 2~5g/L, penetrating agent 1~ 2g/L, acetic acid 1~2g/L, remaining is water;Padding liquid temperature controls between 55~65 DEG C.
Bake operation: pad the fabric after drying and carry out baking reaction through baker, the oven temperature 150~170 baked DEG C, bake time 45~180 seconds.
Shrinking processes: technique routinely, carry out process adjustments according to fabric.
Two, testing result:
Measure the fabric arranged through phase-change microcapsule with DSC differential thermometric analysis instrument, it has the most melted and peak crystallization, Heating up with 2 DEG C/min, recording peak crystallization is 22 DEG C, and heat content is 16J/g, and crystal region is 13~30 DEG C, and melting peak is 34 DEG C, heat content For 13J/g, melting range is 23~36 DEG C, and i.e. when fabric temperature is less than 22 DEG C, heat release reaches maximum;Material temperature is higher than 34 DEG C face to face Time, heat absorption reaches maximum, and this fabric of surface has the automatic regulation function of neither endothermic nor exothermic.
Water absorption testing result through to fabric:
Suitable with conventional finish fabric, as a example by 50 textile plains cloth, JIS L1907 climbed up to 7cm/30 minute.
It addition, at pure cotton fabric, regenerated celulose fibre is pure spins, or textile interweave with chemical fibre, or regenerated celulose fibre Interweave in the grey cloth formed with chemical fibre, use the technology of the present invention also can obtain ideal effect.
By testing explanation above: use present invention process to make fabric both have heat insulating ability, have again ventilative and certain Hygroscopicity, wearability is preferable.

Claims (8)

1. a bidirectional inductive accumulation of energy insulation afterfinish method for fabric, including carrying out grey cloth successively singing, desizing, mercerising, Stentering forming, bake and preshrunk process, it is characterised in that: when stentering forming, use containing phase-change microcapsule pad immersion Roll post-drying.
The bidirectional inductive accumulation of energy insulation afterfinish method of fabric the most according to claim 1, it is characterised in that: described containing phase The padding liquid becoming microcapsule is made up of phase-change microcapsule emulsion, cross-linking agent, penetrating agent, acetic acid and water.
The bidirectional inductive accumulation of energy insulation afterfinish method of fabric the most according to claim 2, it is characterised in that: containing phase transformation In the padding liquid of microcapsule, phase-change microcapsule emulsion accounting is 15~40g/L, cross-linking agent 2~5g/L, penetrating agent 1~2g/L, vinegar Acid 1~2g/L.
4. it is incubated afterfinish method according to the bidirectional inductive accumulation of energy of fabric described in claim 1 or 2 or 3, it is characterised in that: tentering During sizing, drying room temperature is 130~160 DEG C, and the temperature of padding liquid is 55~65 DEG C.
The bidirectional inductive accumulation of energy insulation afterfinish method of fabric the most according to claim 1, it is characterised in that: singe after singing Clearly, cloth cover is bright and clean.
The bidirectional inductive accumulation of energy insulation afterfinish method of fabric the most according to claim 5, it is characterised in that: during described desizing Grey cloth desizing rate >=99%, the capillary effect >=5cm/5min of fabric after desizing.
The bidirectional inductive accumulation of energy insulation afterfinish method of fabric the most according to claim 6, it is characterised in that: described mercerising Time, fabric is padded Caustic soda through mercerizing range, is 30~60 seconds through the action time of sodium hydroxide solution, then by the heat of flowing Washing is except grey cloth face caustic lye of soda, and after mercerising, the pH value of fabric is 7~8.
The bidirectional inductive accumulation of energy insulation afterfinish method of fabric the most according to claim 7, it is characterised in that bake described in: Temperature environment is 150~170 DEG C, and the time of baking is 45~180 seconds.
CN201610610300.0A 2016-07-29 2016-07-29 A kind of bidirectional inductive accumulation of energy insulation afterfinish method of fabric Pending CN106223046A (en)

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Application Number Priority Date Filing Date Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110295500A (en) * 2018-03-23 2019-10-01 上海水星家用纺织品股份有限公司 A kind of material treatment method for making pure-cotton fabric have imitative mercerising cool feeling
CN115142269A (en) * 2022-08-10 2022-10-04 湖南梦洁家纺股份有限公司 Finishing process of nanometer phase change microcapsule temperature-adjusting antibacterial textile
CN115387001A (en) * 2022-09-30 2022-11-25 东丽酒伊织染(南通)有限公司 Breathable quick-drying sun-proof air window fabric and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102605614A (en) * 2012-03-08 2012-07-25 宏大研究院有限公司 Novel heating fiber material with bidirectional temperature regulating function and preparation method thereof
CN102660836A (en) * 2012-04-19 2012-09-12 浙江真爱毯业科技有限公司 Production process of temperature adjusting raschel blanket
CN102733192A (en) * 2012-04-09 2012-10-17 福建众和股份有限公司 Finishing technology of nano-grade phase-change microcapsule heat-accumulation temperature-adjustment intelligent textile fabric printed cloth
CN103343455A (en) * 2013-06-21 2013-10-09 黄惠标 Aromatic fabric production method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102605614A (en) * 2012-03-08 2012-07-25 宏大研究院有限公司 Novel heating fiber material with bidirectional temperature regulating function and preparation method thereof
CN102733192A (en) * 2012-04-09 2012-10-17 福建众和股份有限公司 Finishing technology of nano-grade phase-change microcapsule heat-accumulation temperature-adjustment intelligent textile fabric printed cloth
CN102660836A (en) * 2012-04-19 2012-09-12 浙江真爱毯业科技有限公司 Production process of temperature adjusting raschel blanket
CN103343455A (en) * 2013-06-21 2013-10-09 黄惠标 Aromatic fabric production method

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110295500A (en) * 2018-03-23 2019-10-01 上海水星家用纺织品股份有限公司 A kind of material treatment method for making pure-cotton fabric have imitative mercerising cool feeling
CN110295500B (en) * 2018-03-23 2022-05-31 上海水星家用纺织品股份有限公司 Fabric finishing method for enabling pure cotton fabric to have silky light cool feeling
CN115142269A (en) * 2022-08-10 2022-10-04 湖南梦洁家纺股份有限公司 Finishing process of nanometer phase change microcapsule temperature-adjusting antibacterial textile
CN115142269B (en) * 2022-08-10 2024-03-08 湖南梦洁家纺股份有限公司 Finishing process of temperature-regulating antibacterial textile with nano phase-change microcapsules
CN115387001A (en) * 2022-09-30 2022-11-25 东丽酒伊织染(南通)有限公司 Breathable quick-drying sun-proof air window fabric and preparation method thereof
CN115387001B (en) * 2022-09-30 2024-05-17 东丽酒伊织染(南通)有限公司 Breathable quick-drying sun-proof air window fabric and preparation method thereof

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Application publication date: 20161214