CN106087442B - 一种含竹活性炭粉环保多轴向经编粘合衬及其制备工艺 - Google Patents

一种含竹活性炭粉环保多轴向经编粘合衬及其制备工艺 Download PDF

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CN106087442B
CN106087442B CN201610586843.3A CN201610586843A CN106087442B CN 106087442 B CN106087442 B CN 106087442B CN 201610586843 A CN201610586843 A CN 201610586843A CN 106087442 B CN106087442 B CN 106087442B
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CN106087442A (zh
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豆鑫帆
豆树华
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Heshan Xinkangfu Garment Co., Ltd.
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Abstract

本发明公开了一种含竹活性炭粉环保多轴向经编粘合衬，包括基布和粘胶层，所述基布中固着有竹活性炭粉，所述基布为多轴向经编结构，所述基布从上而下依次为衬纬纱层、衬经纱层、第一斜向衬纱层、第二斜向衬纱层，所述的衬纬纱层和衬经纱层分别由皮芯复合纤维丝沿着经向、纬向排列而成，所述皮芯复合纤维丝由聚乳酸纤维皮层和聚丙烯纤维芯层复合而成，所述第一斜向衬纱层由壳聚糖纤维丝排列而成，所述第二斜向衬纱层由甲壳素纤维丝排列而成，所述基布的一面或者两面涂覆有粘胶层，还提供该粘合衬的制备工艺。本发明中的粘合衬具有挺括、环保、耐侯性强等优点，还具有抗菌活性、吸湿性、净化空气、消除异味、吸湿防霉、抑菌除虫的效果。

Description

一种含竹活性炭粉环保多轴向经编粘合衬及其制备工艺
【技术领域】
本发明涉及粘合衬的技术领域，特别涉及一种含竹活性炭粉环保多轴向经编粘合衬及其制备工艺。
【背景技术】
现代服装讲求在穿着风格上体现舒适、柔软、轻盈和随意有弹性。粘合衬作为“服装的骨架”，是服装不可忽缺的辅料，粘合衬是一种涂有热熔胶的衬里，是布艺制作经常用到的辅料之一。粘合衬经过加温熨压附着在布料的背面，“以粘代缝”大大简化生产工艺，且适用面广，其与面料的合理配合，不仅能充分体现服装设计师的设计思想，而且能够达到良好的服用效果。
但是随着高分子材料的快速发展，在肯定其优点的同时也发现了它的不足，即大部分人工合成的高分子材料在自然界中难以降解，不可降解的高分子材料造成了对环境的白色污染。而一些化学纤维的废弃物难以降解，已成为新的污染源。目前主要采用再生法、燃烧法和降解法来解决这个问题。且目前的布料的功能性较为单一，抗菌、保健性效果低，为了使粘合衬具有抗菌、保健性效果，同时还能降解，具有环保性，有必要提出一种含竹活性炭粉环保多轴向经编粘合衬及其制备工艺。
【发明内容】
本发明的目的在于克服上述现有技术的不足，提供一种含竹活性炭粉环保多轴向经编粘合衬及其制备工艺，其旨在解决现有技术中粘合衬布的功能性较为单一，抗菌、保健性效果低，难降解，环保性较低的技术问题。
为实现上述目的，本发明提出了一种含竹活性炭粉环保多轴向经编粘合衬，包括基布和粘胶层，所述的基布中固着有竹活性炭粉，所述的基布为多轴向经编结构，由衬纬纱层、衬经纱层、第一斜向衬纱层、第二斜向衬纱层通过编织纱以编链组织的方式经编为一体结构，所述的基布从上而下依次为衬纬纱层、衬经纱层、第一斜向衬纱层、第二斜向衬纱层，所述的衬纬纱层和衬经纱层分别由皮芯复合纤维丝沿着经向、纬向排列而成，所述的皮芯复合纤维丝由聚乳酸纤维皮层和聚丙烯纤维芯层复合而成，所述的第一斜向衬纱层由壳聚糖纤维丝排列而成，所述的第二斜向衬纱层由甲壳素纤维丝排列而成，所述的基布的一面或者两面涂覆有粘胶层。
作为优选，所述的第一斜向衬纱层上的壳聚糖纤维丝与衬经纱层上的皮芯复合纤维丝呈正30～60°，所述的第二斜向衬纱层上的甲壳素纤维丝与衬经纱层上的皮芯复合纤维丝呈负30～60°。
作为优选，所述的壳聚糖纤维丝与甲壳素纤维丝关于经向对称。
作为优选，所述的竹活性炭粉的粒径为150～200nm。
作为优选，所述的编织纱为高强低伸型涤纶纤维长丝。
一种含竹活性炭粉环保多轴向经编粘合衬的制备工艺，包括如下步骤：
步骤一、制备纤维丝：采用1～3组PP为芯组分，PLA作为皮组分，通过复合纺丝机纺丝制得PLA/PP皮芯复合纤维丝；以壳聚糖为原料，采用醋酸为溶剂制备纺丝溶液，以NaOH水溶液为凝固浴，通过湿法纺丝得到壳聚糖纤维丝；以二甲基乙酰胺为溶剂，无水氯化锂为分散剂，经磁力搅拌机混合均匀后，加入35％～85％(w/v)的甲壳素颗粒，经过密封搅拌，得到粘稠状的透明胶质纺丝原液，通过湿法纺丝得到甲壳素纤维丝，备用；
步骤二、整经处理：在整经机上对PLA/PP皮芯复合纤维丝、壳聚糖纤维丝、甲壳素纤维丝进行整经处理；
步骤三、坯布织造：在经编机上进行四轴向经编坯布的织造，先用甲壳素纤维丝在经编机上铺设一层负30～60°的第二斜向衬纱层，再用壳聚糖纤维丝在第二斜向衬纱层上铺设一层正30～60°的第一斜向衬纱层，然后采用PLA/PP皮芯复合纤维丝依次铺设一层衬经纱层和一层衬纬纱层，采用高强低伸型涤纶纤维长丝编织纱以编链组织的方式将四个纱层编织为一体，得到坯布；
步骤四、涂层前处理：将步骤三得到的坯布在绳状、无张力的条件下进行退浆和精炼，去除坯布上的油剂和浆料，温度为85～95℃，25～30min后充分水洗并干燥，然后在高温高压喷射染色机上进行染色处理，染色完成后在拉幅定型机上进行定型处理，同时通过真空吸水使坯布处于非常低的带液状态，再在浸轧液中浸轧处理；
步骤五、固着竹活性炭粉：按一定的质量比选取蒸馏水和竹活性炭粉，并加入适量的分散剂，初步搅拌后置于超声波振荡器3～6min，充分混合至无沉淀后，加入适量粘合剂，再次置于超声波振荡器2～4min，得到竹活性炭粉喷涂液，然后采用喷涂法垂直喷涂于基布上，并阴凉处晾干；
步骤六、双点涂层：采用PA热熔胶为基础层，PES热熔胶为粘结层，在基布的一面或两面进行双点涂层，然后进行170～185℃，时间为5～8min的焙烘熔融，并冷却成型；
步骤七、检验卷取：通过检验后，将质量合格的粘合衬产品进行卷取打包。
作为优选，所述的步骤一中密封搅拌时间为3～4天。
作为优选，所述的步骤四中浸轧液由有机氟防水剂、有机硅柔软剂、抗静电剂及蒸馏水组成，所述的有机氟防水剂的浓度为8～12g/L，有机硅柔软剂的浓度为20～35g/L，抗静电剂为2～5g/L。
作为优选，所述的步骤五中蒸馏水和竹活性炭粉的质量比为1：(0.1～0.2)，所述的分散剂为聚己内酯，粘合剂为聚乙烯醇。
本发明的有益效果：与现有技术相比，本发明提供的一种含竹活性炭粉环保多轴向经编粘合衬及其制备工艺，采用具有生物降解性的PLA/PP皮芯复合纤维丝、壳聚糖纤维丝、甲壳素纤维丝为机织衬布的制造纤维，可通过生物降解法进行自然降解，不会对环境造成污染，具有较高的环保性能，同时PLA/PP皮芯复合纤维丝具有良好的稳定性、亲水性、染色性、弹性、热粘合性、热封性和耐气候性，壳聚糖和甲壳素纤维具有抗菌活性和吸湿性，有保健功能，通过固着竹活性炭粉后，使多轴向经编粘合衬具有净化空气、消除异味、吸湿防霉、抑菌除虫、挺括的效果，采用PA热熔胶为基础层，PES热熔胶为粘结层，通过双点法涂层使得粘合衬具有较好的手感和耐干洗水洗性能。
本发明的特征及优点将通过实施例结合附图进行详细说明。
【附图说明】
图1是本发明实施例一种含竹活性炭粉环保多轴向经编粘合衬的截面示意图；
图2是本发明实施例的基布的组织结构主视图；
图3是本发明实施例的基布的组织结构右视图；
图4是本发明实施例的皮芯复合纤维丝的截面结构示意图。
图中：1-基布、11-衬纬纱层、12-衬经纱层、13-第一斜向衬纱层、14-第二斜向衬纱层、15-编织纱、2-粘胶层、3-竹活性炭粉、4-皮芯复合纤维丝、41-聚乳酸纤维皮层、42-聚丙烯纤维芯层、5-壳聚糖纤维丝、6-甲壳素纤维丝。
【具体实施方式】
为使本发明的目的、技术方案和优点更加清楚明了，下面通过附图中及实施例，对本发明进行进一步详细说明。但是应该理解，此处所描述的具体实施例仅仅用以解释本发明，并不用于限制本发明的范围。此外，在以下说明中，省略了对公知结构和技术的描述，以避免不必要地混淆本发明的概念。
参阅图1至图4，本发明实施例提供一种含竹活性炭粉环保多轴向经编粘合衬，包括基布1和粘胶层2，所述的基布1中固着有竹活性炭粉3，所述的基布1为多轴向经编结构，由衬纬纱层11、衬经纱层12、第一斜向衬纱层13、第二斜向衬纱层14通过编织纱15以编链组织的方式经编为一体结构，所述的基布1从上而下依次为衬纬纱层11、衬经纱层12、第一斜向衬纱层13、第二斜向衬纱层14，所述的衬纬纱层11和衬经纱层12分别由皮芯复合纤维丝4沿着经向、纬向排列而成，所述的皮芯复合纤维丝4由聚乳酸纤维皮层41和聚丙烯纤维芯层42复合而成，所述的第一斜向衬纱层13由壳聚糖纤维丝5排列而成，所述的第二斜向衬纱层14由甲壳素纤维丝6排列而成，所述的基布1的一面或者两面涂覆有粘胶层2。
所述的第一斜向衬纱层13上的壳聚糖纤维丝5与衬经纱层12上的皮芯复合纤维丝4呈正30～60°，所述的第二斜向衬纱层14上的甲壳素纤维丝6与衬经纱层12上的皮芯复合纤维丝4呈负30～60°，所述的壳聚糖纤维丝5与甲壳素纤维丝6关于经向对称，所述的竹活性炭粉3的粒径为150～200nm，所述的编织纱15为高强低伸型涤纶纤维长丝。
在本发明实施例中，皮芯复合纤维丝4中聚丙烯纤维芯层42由3根聚丙烯纤维组成，第一斜向衬纱层13上的壳聚糖纤维丝5及第二斜向衬纱层14上的甲壳素纤维丝6与经向的夹角均为60°。
本实施例还提供一种含竹活性炭粉环保多轴向经编粘合衬的制备工艺，包括如下步骤：
步骤一、制备纤维丝：采用1～3组PP为芯组分，PLA作为皮组分，通过复合纺丝机纺丝制得PLA/PP皮芯复合纤维丝4；以壳聚糖为原料，采用醋酸为溶剂制备纺丝溶液，以NaOH水溶液为凝固浴，通过湿法纺丝得到壳聚糖纤维丝5；以二甲基乙酰胺为溶剂，无水氯化锂为分散剂，经磁力搅拌机混合均匀后，加入35％～85％(w/v)的甲壳素颗粒，经过密封搅拌，得到粘稠状的透明胶质纺丝原液，通过湿法纺丝得到甲壳素纤维丝6，备用。
其中，密封搅拌时间为3～4天。
步骤二、整经处理：在整经机上对PLA/PP皮芯复合纤维丝4、壳聚糖纤维丝5、甲壳素纤维丝6进行整经处理。
步骤三、坯布织造：在经编机上进行四轴向经编坯布的织造，先用甲壳素纤维丝6在经编机上铺设一层负30～60°的第二斜向衬纱层14，再用壳聚糖纤维丝5在第二斜向衬纱层14上铺设一层正30～60°的第一斜向衬纱层13，然后采用PLA/PP皮芯复合纤维丝4依次铺设一层衬经纱层12和一层衬纬纱层11，采用高强低伸型涤纶纤维长丝编织纱15以编链组织的方式将四个纱层编织为一体，得到坯布。
步骤四、涂层前处理：将步骤三得到的坯布在绳状、无张力的条件下进行退浆和精炼，去除坯布上的油剂和浆料，温度为85～95℃，25～30min后充分水洗并干燥，然后在高温高压喷射染色机上进行染色处理，染色完成后在拉幅定型机上进行定型处理，同时通过真空吸水使坯布处于非常低的带液状态，再在浸轧液中浸轧处理。
其中，浸轧液由有机氟防水剂、有机硅柔软剂、抗静电剂及蒸馏水组成，所述的有机氟防水剂的浓度为8～12g/L，有机硅柔软剂的浓度为20～35g/L，抗静电剂为2～5g/L。
步骤五、固着竹活性炭粉：按一定的质量比选取蒸馏水和竹活性炭粉，并加入适量的分散剂，初步搅拌后置于超声波振荡器3～6min，充分混合至无沉淀后，加入适量粘合剂，再次置于超声波振荡器2～4min，得到竹活性炭粉喷涂液，然后采用喷涂法垂直喷涂于基布1上，并阴凉处晾干。
其中，蒸馏水和竹活性炭粉的质量比为1：(0.1～0.2)，所述的分散剂为聚己内酯，粘合剂为聚乙烯醇。
步骤六、双点涂层：采用PA热熔胶为基础层，PES热熔胶为粘结层，在基布1的一面或两面进行双点涂层，然后进行170～185℃，时间为5～8min的焙烘熔融，并冷却成型。
步骤七、检验卷取：通过检验后，将质量合格的粘合衬产品进行卷取打包。
以上所述仅为本发明的较佳实施例而已，并不用以限制本发明，凡在本发明的精神和原则之内所作的任何修改、等同替换或改进等，均应包含在本发明的保护范围之内。

Claims (4)

1.一种含竹活性炭粉环保多轴向经编粘合衬，包括基布(1)和粘胶层(2)，其特征在于：所述的基布(1)中固着有竹活性炭粉(3)，所述的基布(1)为多轴向经编结构，由衬纬纱层(11)、衬经纱层(12)、第一斜向衬纱层(13)、第二斜向衬纱层(14)通过编织纱(15)以编链组织的方式经编为一体结构，所述的基布(1)从上而下依次为衬纬纱层(11)、衬经纱层(12)、第一斜向衬纱层(13)、第二斜向衬纱层(14)，所述的衬纬纱层(11)和衬经纱层(12)分别由皮芯复合纤维丝(4)沿着经向、纬向排列而成，所述的皮芯复合纤维丝(4)由聚乳酸纤维皮层(41)和聚丙烯纤维芯层(42)复合而成，所述的第一斜向衬纱层(13)由壳聚糖纤维丝(5)排列而成，所述的第二斜向衬纱层(14)由甲壳素纤维丝(6)排列而成，所述的基布(1)的一面或者两面涂覆有粘胶层(2)；所述的第一斜向衬纱层(13)上的壳聚糖纤维丝(5)与衬经纱层(12)上的皮芯复合纤维丝(4)呈正30～60°，所述的第二斜向衬纱层(14)上的甲壳素纤维丝(6)与衬经纱层(12)上的皮芯复合纤维丝(4)呈负30～60°，所述的壳聚糖纤维丝(5)与甲壳素纤维丝(6)关于经向对称，所述的竹活性炭粉(3)的粒径为150～200nm，所述的编织纱(15)为高强低伸型涤纶纤维长丝，该含竹活性炭粉环保多轴向经编粘合衬的制备工艺，包括如下步骤：
步骤一、制备纤维丝：采用1～3组PP为芯组分，PLA作为皮组分，通过复合纺丝机纺丝制得PLA/PP皮芯复合纤维丝(4)；以壳聚糖为原料，采用醋酸为溶剂制备纺丝溶液，以NaOH水溶液为凝固浴，通过湿法纺丝得到壳聚糖纤维丝(5)；以二甲基乙酰胺为溶剂，无水氯化锂为分散剂，经磁力搅拌机混合均匀后，加入35％～85％(w/v)的甲壳素颗粒，经过密封搅拌，得到粘稠状的透明胶质纺丝原液，通过湿法纺丝得到甲壳素纤维丝(6)，备用；
步骤二、整经处理：在整经机上对PLA/PP皮芯复合纤维丝(4)、壳聚糖纤维丝(5)、甲壳素纤维丝(6)进行整经处理；
步骤三、坯布织造：在经编机上进行四轴向经编坯布的织造，先用甲壳素纤维丝(6)在经编机上铺设一层负30～60°的第二斜向衬纱层(14)，再用壳聚糖纤维丝(5)在第二斜向衬纱层(14)上铺设一层正30～60°的第一斜向衬纱层(13)，然后采用PLA/PP皮芯复合纤维丝(4)依次铺设一层衬经纱层(12)和一层衬纬纱层(11)，采用高强低伸型涤纶纤维长丝编织纱(15)以编链组织的方式将四个纱层编织为一体，得到坯布；
步骤四、涂层前处理：将步骤三得到的坯布在绳状、无张力的条件下进行退浆和精炼，去除坯布上的油剂和浆料，温度为85～95℃，25～30min后充分水洗并干燥，然后在高温高压喷射染色机上进行染色处理，染色完成后在拉幅定型机上进行定型处理，同时通过真空吸水使坯布处于非常低的带液状态，再在浸轧液中浸轧处理；
步骤五、固着竹活性炭粉：按一定的质量比选取蒸馏水和竹活性炭粉，并加入适量的分散剂，初步搅拌后置于超声波振荡器3～6min，充分混合至无沉淀后，加入适量粘合剂，再次置于超声波振荡器2～4min，得到竹活性炭粉喷涂液，然后采用喷涂法垂直喷涂于基布(1)上，并阴凉处晾干；
步骤六、双点涂层：采用PA热熔胶为基础层，PES热熔胶为粘结层，在基布(1)的一面或两面进行双点涂层，然后进行170～185℃，时间为5～8min的焙烘熔融，并冷却成型；
步骤七、检验卷取：通过检验后，将质量合格的粘合衬产品进行卷取打包。
2.如权利要求1所述的一种含竹活性炭粉环保多轴向经编粘合衬，其特征在于：所述的步骤一中密封搅拌时间为3～4天。
3.如权利要求1所述的一种含竹活性炭粉环保多轴向经编粘合衬，其特征在于：所述的步骤四中浸轧液由有机氟防水剂、有机硅柔软剂、抗静电剂及蒸馏水组成，所述的有机氟防水剂的浓度为8～12g/L，有机硅柔软剂的浓度为20～35g/L，抗静电剂为2～5g/L。
4.如权利要求1所述的一种含竹活性炭粉环保多轴向经编粘合衬，其特征在于：所述的步骤五中蒸馏水和竹活性炭粉的质量比为1：(0.1～0.2)，所述的分散剂为聚己内酯，粘合剂为聚乙烯醇。
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CN105671777A (zh) * 2016-03-15 2016-06-15 浙江青松轻纺股份有限公司 一种超薄抗撕裂防水涤纶面料及其制备工艺
CN105671990A (zh) * 2016-03-15 2016-06-15 浙江青松轻纺股份有限公司 一种有机硅树脂与聚氨酯复合的防污防水面料及其制备工艺
CN205893783U (zh) * 2016-07-22 2017-01-18 长兴圣帆纺织有限公司 一种含竹活性炭粉环保多轴向经编粘合衬

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