CN107851835A - 石墨改性的锂金属电极 - Google Patents

石墨改性的锂金属电极 Download PDF

Info

Publication number
CN107851835A
CN107851835A CN201680042077.2A CN201680042077A CN107851835A CN 107851835 A CN107851835 A CN 107851835A CN 201680042077 A CN201680042077 A CN 201680042077A CN 107851835 A CN107851835 A CN 107851835A
Authority
CN
China
Prior art keywords
lithium metal
surface layer
lithium
graphite
electrochemical device
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201680042077.2A
Other languages
English (en)
Chinese (zh)
Inventor
L·J·克劳塞
L·D·简森
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of CN107851835A publication Critical patent/CN107851835A/zh
Pending legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/058—Construction or manufacture
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4235—Safety or regulating additives or arrangements in electrodes, separators or electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00—Hybrid cells; Manufacture thereof
    • H01M12/08—Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1393—Processes of manufacture of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/366—Composites as layered products
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/381—Alkaline or alkaline earth metals elements
    • H01M4/382—Lithium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Hybrid Cells (AREA)
CN201680042077.2A 2015-07-27 2016-07-21 石墨改性的锂金属电极 Pending CN107851835A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562197203P 2015-07-27 2015-07-27
US62/197,203 2015-07-27
PCT/US2016/043291 WO2017019436A1 (en) 2015-07-27 2016-07-21 Graphite modified lithium metal electrode

Publications (1)

Publication Number Publication Date
CN107851835A true CN107851835A (zh) 2018-03-27

Family

ID=57885257

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201680042077.2A Pending CN107851835A (zh) 2015-07-27 2016-07-21 石墨改性的锂金属电极

Country Status (6)

Country Link
US (1) US20180212270A1 (https=)
EP (1) EP3329538A4 (https=)
JP (1) JP2018527702A (https=)
KR (1) KR20180026460A (https=)
CN (1) CN107851835A (https=)
WO (1) WO2017019436A1 (https=)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110534704A (zh) * 2018-05-24 2019-12-03 通用汽车环球科技运作有限责任公司 用于含锂电极的保护涂层及其制造方法
CN111430663A (zh) * 2019-11-28 2020-07-17 蜂巢能源科技有限公司 锂负极极片及其制备方法和锂电池
CN114388746A (zh) * 2020-10-21 2022-04-22 安徽盟维新能源科技有限公司 锂金属负极、锂金属电池及其制备方法与抑制锂枝晶方法

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102018128451A1 (de) * 2018-11-13 2020-05-14 Bayerische Motoren Werke Aktiengesellschaft Kalorimetrisches Verfahren zur quantitativen Bestimmung von auf einer Anode einer Lithium-Ionen-Zelle abgeschiedenem metallischen Lithium
CN112993383B (zh) 2019-12-18 2023-04-11 财团法人工业技术研究院 电池
US20210351411A1 (en) 2020-05-06 2021-11-11 Samsung Electronics Co., Ltd. Secondary battery and method of preparing the same

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5387479A (en) * 1993-06-16 1995-02-07 Valence Technology, Inc. Electrodes for rechargeable lithium batteries
CN1400680A (zh) * 2001-07-31 2003-03-05 日本电气株式会社 可充电电池的负电极
US6537701B1 (en) * 1998-09-03 2003-03-25 Polyplus Battery Company, Inc. Coated lithium electrodes
EP0783769B1 (en) * 1994-09-29 2004-01-14 Mitsubishi Chemical Corporation Particulate interface for electrolytic cells and electrolytic process
CN101662014A (zh) * 2001-12-21 2010-03-03 三星Sdi株式会社 含石墨的组合物,用于锂二次电池的负极,以及锂二次电池
KR20130067920A (ko) * 2011-12-14 2013-06-25 한국전자통신연구원 탄소 분말을 리튬 표면에 코팅한 음극을 적용한 리튬 이차 전지

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04248276A (ja) * 1991-01-25 1992-09-03 Matsushita Electric Ind Co Ltd リチウム二次電池
JPH0636759A (ja) * 1992-07-17 1994-02-10 Mitsubishi Cable Ind Ltd リチウム二次電池
US5720780A (en) 1996-11-04 1998-02-24 Valence Technology, Inc. Film forming method for lithium ion rechargeable batteries
JPH11135116A (ja) * 1997-10-27 1999-05-21 Fuji Elelctrochem Co Ltd リチウム二次電池用負極及びその負極を用いたリチウム二次電池、並びにそのリチウム二次電池用負極の製造方法
US6589299B2 (en) 2001-02-13 2003-07-08 3M Innovative Properties Company Method for making electrode
US7326497B2 (en) * 2001-12-21 2008-02-05 Samsung Sdi Co., Ltd. Graphite-containing composition, negative electrode for a lithium secondary battery, and lithium secondary battery
US6939383B2 (en) 2002-05-03 2005-09-06 3M Innovative Properties Company Method for making electrode
US7348102B2 (en) * 2004-03-16 2008-03-25 Toyota Motor Corporation Corrosion protection using carbon coated electron collector for lithium-ion battery with molten salt electrolyte
JP5167914B2 (ja) 2008-04-09 2013-03-21 トヨタ自動車株式会社 固体リチウム二次電池の製造方法
US8178241B2 (en) 2008-08-28 2012-05-15 3M Innovative Properties Company Electrode including current collector with nano-scale coating and method of making the same
WO2012067952A1 (en) * 2010-11-17 2012-05-24 3M Innovative Properties Company Electrochemically-conductive articles including current collectors having conductive coatings and methods of making same
CN104025343A (zh) 2011-12-16 2014-09-03 3M创新有限公司 用于制造电极的方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5387479A (en) * 1993-06-16 1995-02-07 Valence Technology, Inc. Electrodes for rechargeable lithium batteries
EP0783769B1 (en) * 1994-09-29 2004-01-14 Mitsubishi Chemical Corporation Particulate interface for electrolytic cells and electrolytic process
US6537701B1 (en) * 1998-09-03 2003-03-25 Polyplus Battery Company, Inc. Coated lithium electrodes
CN1400680A (zh) * 2001-07-31 2003-03-05 日本电气株式会社 可充电电池的负电极
CN101662014A (zh) * 2001-12-21 2010-03-03 三星Sdi株式会社 含石墨的组合物,用于锂二次电池的负极,以及锂二次电池
KR20130067920A (ko) * 2011-12-14 2013-06-25 한국전자통신연구원 탄소 분말을 리튬 표면에 코팅한 음극을 적용한 리튬 이차 전지

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110534704A (zh) * 2018-05-24 2019-12-03 通用汽车环球科技运作有限责任公司 用于含锂电极的保护涂层及其制造方法
CN111430663A (zh) * 2019-11-28 2020-07-17 蜂巢能源科技有限公司 锂负极极片及其制备方法和锂电池
CN114388746A (zh) * 2020-10-21 2022-04-22 安徽盟维新能源科技有限公司 锂金属负极、锂金属电池及其制备方法与抑制锂枝晶方法
CN114388746B (zh) * 2020-10-21 2024-01-23 安徽盟维新能源科技有限公司 锂金属负极、锂金属电池及其制备方法与抑制锂枝晶方法

Also Published As

Publication number Publication date
KR20180026460A (ko) 2018-03-12
EP3329538A4 (en) 2019-01-23
JP2018527702A (ja) 2018-09-20
US20180212270A1 (en) 2018-07-26
WO2017019436A1 (en) 2017-02-02
EP3329538A1 (en) 2018-06-06

Similar Documents

Publication Publication Date Title
Alexander et al. Electrochemical performance of a garnet solid electrolyte based lithium metal battery with interface modification
CN106104876B (zh) 电解铜箔、包含该电解铜箔的集电体、阴极以及锂电池
CN109326770B (zh) 通过气相沉积保形涂覆可充电锂离子电池的锂阳极
CN101627494B (zh) 纳米复合电极和相关装置
CN104969386B (zh) 复合活性物质、复合活性物质的制造方法和包含复合活性物质的锂二次电池
CN102148364B (zh) 电池电极的制造方法、所制造的电极和包括其的电池
TWI637550B (zh) 非水電解質蓄電池用負極材料及負極活性物質粒子之製造方法
CN106133966B (zh) 电解铜箔、包含该电解铜箔的集电体、阴极以及锂电池
US9748561B2 (en) Methods of forming carbon coatings
CN107851835A (zh) 石墨改性的锂金属电极
CN104335397B (zh) 锂二次电池用负极活性物质及包含该物质的锂二次电池
TW201810776A (zh) 用於改良的鋰金屬循環的介面層
CN110350151A (zh) 含锂电极的保护涂层及其制造方法
JP2013534027A (ja) アモルファス電極材料を有するリチウムイオンバッテリー
CN106099100A (zh) 负极活性物质和全固体二次电池
CN106797034A (zh) 非水电解质二次电池及其制造方法
KR20150056532A (ko) 그래핀 전극
CN103296237A (zh) 包括有机和无机混合物的涂层的隔膜和包括该隔膜的电池
CN104718657B (zh) 锂二次电池
CN111247673B (zh) 活性物质层形成用组合物、电池、电极片及相关制造方法
CN116470120A (zh) 包括保护层的无负极全固态电池及其制造方法
WO2019216216A1 (ja) 全固体電池用集電層、全固体電池、及び炭素材料
CN112420980A (zh) 锂离子二次电池用电极和锂离子二次电池
CN102800867A (zh) 一种用于锂离子电池的硅基负极材料
US20170271674A1 (en) Electrochemically modified carbon material for lithium-ion battery

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
AD01 Patent right deemed abandoned

Effective date of abandoning: 20210604

AD01 Patent right deemed abandoned