CN107735460B - 基于n-烷基葡糖胺的通用颜料分散体 - Google Patents

基于n-烷基葡糖胺的通用颜料分散体 Download PDF

Info

Publication number
CN107735460B
CN107735460B CN201680031132.8A CN201680031132A CN107735460B CN 107735460 B CN107735460 B CN 107735460B CN 201680031132 A CN201680031132 A CN 201680031132A CN 107735460 B CN107735460 B CN 107735460B
Authority
CN
China
Prior art keywords
pigment
component
pigment dispersion
comes
aqueous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201680031132.8A
Other languages
English (en)
Other versions
CN107735460A (zh
Inventor
R·库普费尔
C·泽芬
J·鲁格
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Clariant International Ltd
Original Assignee
Clariant International Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Clariant International Ltd filed Critical Clariant International Ltd
Publication of CN107735460A publication Critical patent/CN107735460A/zh
Application granted granted Critical
Publication of CN107735460B publication Critical patent/CN107735460B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
    • C09B67/0084—Dispersions of dyes
    • C09B67/0085—Non common dispersing agents
    • C09B67/0089—Non common dispersing agents non ionic dispersing agent, e.g. EO or PO addition products
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
    • C09B67/0084—Dispersions of dyes
    • C09B67/0085—Non common dispersing agents
    • C09B67/0086—Non common dispersing agents anionic dispersing agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/22—Compounds of iron
    • C09C1/24—Oxides of iron
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D17/00—Pigment pastes, e.g. for mixing in paints
    • C09D17/001—Pigment pastes, e.g. for mixing in paints in aqueous medium
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D17/00—Pigment pastes, e.g. for mixing in paints
    • C09D17/003—Pigment pastes, e.g. for mixing in paints containing an organic pigment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D17/00—Pigment pastes, e.g. for mixing in paints
    • C09D17/004—Pigment pastes, e.g. for mixing in paints containing an inorganic pigment
    • C09D17/007—Metal oxide
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02—Emulsion paints including aerosols
    • C09D5/024—Emulsion paints including aerosols characterised by the additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02—Emulsion paints including aerosols
    • C09D5/024—Emulsion paints including aerosols characterised by the additives
    • C09D5/027—Dispersing agents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

本发明涉及水性不含粘结剂的颜料分散体，其包含(A)至少一种有机和/或无机颜料，(B)一种或多种分散剂和/或表面活性剂，(C)至少一种式(I)的基础物质，其中，R1为表示H，C1‑C4‑烷基，CH2CH2OH或CH2CH(CH3)OH，(D)任选的一种或多种聚亚烷基二醇，(E)任选的另外的用于制备水性颜料分散体的常规添加剂，和(F)水。

Description

基于N-烷基葡糖胺的通用颜料分散体
本发明提供了基于水的不含粘结剂的颜料分散体及其用于使所有类型的水性和溶剂型油漆、乳胶漆和光泽油漆着色的用途。
在市场上和文献中，有许多已知的水性颜料分散体，也被称为颜料糊剂，其用于使水性乳胶漆和清漆着色。这些颜料分散体在五金商店、油漆厂和专业艺术商店中用作调色糊剂。出于该目的，借助于计量添加和调色体系，将水性颜料糊剂添加到水性油漆和清漆中。为了改进与基础油漆的相容性，通常将颜料分散体用碱调节至碱性pH。出于该目的，本领域技术人员充分了解使用碱例如NaOH或KOH或胺碱，例如链烷醇胺如2-氨基-2-甲基丙-1-醇(AMP-90/95，来自Angus)，且这连同在α位置中支化的仲链烷醇胺例如描述于US2012/0024193中。
European Coatings Journal在2009年第07卷第26至28页中也教导了包含作为中和剂的这种仲链烷醇胺和共分散剂的蓝色颜料糊剂产生较高的颜色强度，并且使用2-(仲丁基氨基)乙醇( N41,来自Arkema)的实例指出，这可以降低调整色光油漆的成本。
以这种方式也可能用于使油漆和清漆着色。出于此目的，市场上可获得特定的基于溶剂的糊剂。此外，越来越多使用通用颜料分散体，该通用颜料分散体适用于使所有类型的水性和溶剂型油漆、乳胶漆和光泽油漆着色。
WO2013/016270教导了不含VOC的仲和叔链烷醇胺，其用于含粘结剂的油漆中并导致光泽和湿磨损方面的改进。
在US2011/0146536中教导了另外的不含VOC的氨基醇的制备及其在含粘结剂的油漆中作为中和剂的用途。
WO2010/126657和US2010/0326320中教导了三羟基单胺或三羟基二胺在水性含粘结剂的油漆中的中和能力。同样地，就粘度、覆面力、变黄、光泽度、耐湿磨损性和粘合力方面描述所得油漆和涂料的性质。
EP 1676831教导了可用于水性含粘结剂的印刷油墨的N,N-二烷基葡糖胺。
US 2002/04066教导了包含烷基-、羟烷基-或芳基胺的水性不含分散剂的印刷油墨。
在实践中发现，这些通用颜料分散体在溶剂型油漆和清漆中仅具有不足的相容性，其表现在所使用的水性颜料分散体不显示其全色强度或覆面力，因此必须添加更多的颜料分散体以达到所需的色相。这种额外的消耗导致在油漆和清漆着色方面更高的成本。此外，所述的胺碱有助于增加VOC含量。
因此，本发明的目的是提供与水性涂料和与溶剂型涂料均相容的水性不含粘结剂的颜料分散体。此外，不应将含有VOC的成分添加到颜料分散体中。
已经发现，上述目的出人意料地通过使用N-烷基葡糖胺用于pH调节和作为共分散剂的水性不含粘结剂的颜料分散体来实现。
本发明提供了水性颜料分散体，其包含
(A)至少一种有机和/或无机颜料，
(B)一种或多种分散剂和/或表面活性剂，
(C)至少一种式(I)的化合物
其中，R1为H，C1-C4-烷基，CH2CH2OH或CH2CH(CH3)OH，
(D)任选的一种或多种聚亚烷基二醇，
(E)任选的常规用于制备水性颜料分散体的另外的添加剂，和
(F)水。
优选的颜料制剂包含以下量的组分：
(A)5重量％至80重量％，
(B)0.1重量％至30重量％，
(C)0.1重量％至10重量％，
(D)0重量％至10重量％，
(E)0重量％至30重量％，
(F)加和至(ad)100％，
在每种情况下基于颜料分散体的总重量。
在进一步优选形式中，本发明的颜料分散体具有>7的pH，在特别优选的形式中在8和10之间的pH。
在进一步优选形式中，本发明的颜料分散体具有<1％的VOC含量，根据DIN11890-2进行测定。
本发明的颜料分散体的组分(A)优选为细分的有机或无机白色或彩色颜料或这类的各种颜料的混合物。作为特别优选的有机颜料的示例性选择，本文应该提及单偶氮和双偶氮颜料，特别是颜色指数颜料颜料黄1，颜料黄3，颜料黄12，颜料黄13，颜料黄14，颜料黄16，颜料黄17，颜料黄73，颜料黄74，颜料黄81，颜料黄83，颜料黄87，颜料黄97，颜料黄111，颜料黄126，颜料黄127，颜料黄128，颜料黄155，颜料黄174，颜料黄176，颜料黄191，颜料黄213，颜料黄214，颜料红38，颜料红144，颜料红214，颜料红242，颜料红262，颜料红266，颜料红269，颜料红274，颜料橙13，颜料橙34或颜料棕41；β-萘酚和萘酚AS颜料，尤其是颜色指数颜料颜料红2，颜料红3，颜料红4，颜料红5，颜料红9，颜料红12，颜料红14，颜料红53:1，颜料红112，颜料红146，颜料红147，颜料红170，颜料红184，颜料红187，颜料红188，颜料红210，颜料红247，颜料红253，颜料红254，颜料红256，颜料橙5，颜料橙38或颜料棕1；色淀偶氮和金属络合物颜料，尤其是颜色指数颜料颜料红48:2，颜料红48:3，颜料红48:4，颜料红57:1，颜料红257，颜料橙68或颜料橙70；苯并咪唑啉颜料，尤其是颜色指数颜料颜料黄120，颜料黄151，颜料黄154，颜料黄175，颜料黄180，颜料黄181，颜料黄194，颜料红175，颜料红176，颜料红185，颜料红208，颜料紫32，颜料橙36，颜料橙62，颜料橙72或颜料棕25；异吲哚啉酮和异吲哚啉颜料，特别是颜色指数颜料颜料黄139或颜料黄173；酞菁颜料，特别是颜色指数颜料颜料蓝15，颜料蓝15:1，颜料蓝15:2，颜料蓝15:3，颜料蓝15:4，颜料蓝15:6，颜料蓝16，颜料绿7或颜料绿36；蒽嵌蒽醌，蒽醌，喹吖啶酮，二噁嗪，靛蒽醌，苝，紫环酮和硫靛蓝颜料，特别是颜色指数颜料颜料黄196，颜料红122，颜料红149，颜料红168，颜料红177，颜料红179，颜料红181，颜料红207，颜料红209，颜料红263，颜料蓝60，颜料紫19，颜料紫23或颜料橙43；三芳基碳鎓颜料，特别是颜色指数颜料颜料红169，颜料蓝56或颜料蓝61。
合适的无机颜料是例如炭黑颜料，例如气黑或炉黑；二氧化钛，硫化锌，氧化锌，氧化铁，磁铁矿，锰铁氧化物，铬氧化物，群青，镍锑钛氧化物或铬锑钛氧化物，锰钛金红石，钴氧化物，钴和铝的混合氧化物，金红石混合相颜料，稀土的硫化物，钴与镍和锌的尖晶石，基于铁和铬与铜、锌和锰的尖晶石，钒酸铋和体质颜料。更特别地，使用颜色指数颜料颜料黄184，颜料黄53，颜料黄42，颜料黄棕24，颜料红101，颜料蓝28，颜料蓝36，颜料绿50，颜料绿17，颜料黑7，颜料黑11，颜料黑33和颜料白6。优选地，还经常使用无机颜料的混合物。有机与无机颜料的混合物同样经常使用。
本发明的颜料分散体的合适组分(B)是常规聚合物和表面活性剂型分散剂或这些物质的混合物。典型地，这些是本领域技术人员已知的非离子、阴离子或两性界面活性物质。在众多已知化合物中，在下文引用代表性选择，但不限制本发明的适用性。
作为特别优选的聚合物分散剂的示例性选择，本文应提及甲醛与具有1至20个碳原子的取代和未取代的长链和短链烷基酚的缩合产物及其烷氧基化产物，酚醛清漆和衍生物；苯乙烯-苯酚缩合物，包括由取代酚和苯乙烯形成的缩合产物，及其烷氧基化产物。另外，这些缩合产物可以采用离子衍生物的形式，例如硫酸根，磺酸根，琥珀酸单酯，磷酸根，膦酸根或羧酸根及其盐。还应该提及部分或完全中和的丙烯酸酯树脂，改性的聚丙烯酸酯和丙烯酸和/或甲基丙烯酸和/或其酯和/或其酰胺的共聚物。用于相应共聚物的其它单体单元可为马来酸和/或其酯，酰胺和/或其酸酐和/或苯乙烯。聚合物分散剂通常具有1000至100000g/mol，优选2000至50000g/mol之间的Mn的平均摩尔质量，并且可采用无规或嵌段聚合物的形式。
作为特别优选的表面活性剂型分散剂的示例性选择，本文应提及直链和支链、饱和和不饱和的烷基磺酸盐，例如十二烷基磺酸盐，月桂基磺酸盐和十八烷基磺酸盐以及相应的烷基磷酸盐。另外，可能使用非支链或支链、直链或环状的C3-C20烷基或取代或未取代的芳基或直链脂肪醇、脂肪酸、脂肪胺或脂肪酰胺的烷氧基化产物。合适的氧化烯的实例是氧化乙烯，氧化丙烯，氧化丁烯或氧化苯乙烯。这些烷氧基化产物可另外地提供有离子头基，例如硫酸根，磺酸根，琥珀酸单酯，磷酸根，膦酸根或羧酸根及其盐。另外合适的是卵磷脂和磺基琥珀酸盐。
在组分(C)的上下文中的化合物(I)是多羟基胺
其中R1可为H，C1-C4-烷基，CH2CH2OH或CH2CH(CH3)OH。
优选地，R1为H，甲基或CH2CH2OH。
多羟基单元为己糖，优选差向异构体葡萄糖。
用于制备式(I)的烷基葡糖胺的方法对于本领域技术人员是已知的。对于R＝C1-C4-烷基的化合物，例如，其通过EP-A-1676831中所述的方法，通过在氢和过渡金属催化剂存在下用醛或酮对N-烷基多羟基胺进行还原性烷基化来进行。羟乙基-和羟丙基-N-甲基葡糖胺可以通过N-甲基葡糖胺与氧化乙烯或氧化丙烯在水溶液中反应来制备。式(I)的化合物可以以纯物质的形式或以水溶液的形式使用。由于叔胺如二甲基葡糖胺和羟乙基-和羟丙基-N-甲基葡糖胺不易于形成亚硝胺，因此这些对于本发明的分散体是优选的。
本发明的分散体的组分(D)聚亚烷基二醇是氧化烯的均聚物或共聚物。合适的氧化烯的实例是氧化乙烯，氧化丙烯，氧化丁烯或氧化苯乙烯。另外，可能使用从一元、二元、三元、四元或五元醇开始的聚亚烷基二醇或具有支链或星形结构的一、二、三、四或五官能胺。所使用的聚亚烷基二醇通常含有4至1000mol的氧化烯，优选4至200mol。
常规用于制备水性颜料分散体的另外的添加剂(组分(E))可为防腐剂/杀生物剂，消泡剂，脱气剂，填料，溶剂，光稳定剂，抗氧化剂或增稠剂，抗沉降剂和流变添加剂。另外的润湿剂可为例如基于聚硅氧烷醚的润湿剂。
用于制备本发明的水性颜料分散体(组分(F))的水优选以蒸馏水或软化水的形式使用。也可能使用饮用水(自来水)和/或天然来源的水。
本发明还进一步提供了用于制备本发明的颜料分散体的方法。出于此目的，将通常以粉末、薄片或粒状物形式的组分(A)以本身常规方式在水(F)和组分(B)和(C)以及任选的(D)和(E)的存在下进行分散。随后，任选可能地混入另外的水(F)中，从而将获得的水性颜料分散体调节到所需浓度。优选地，首先将液体组分(B)、(C)、(F)和任选的(D)混合并匀化，然后将粉末、粒状物或薄片形式的固体组分(A)和(D)搅拌至初始装入的混合物，其中将颜料和任选的填料转化成糊剂和将其初步分散体。根据所使用的颜料的颗粒硬度，任选地随后在冷却的同时借助研磨或分散单元进行细分散或细分布。出于此目的，可能使用搅拌器系统，溶解器(锯齿搅拌器)，转子-定子磨机，球磨机，搅拌球磨机如砂磨机和珠磨机，高速混合机，捏合设备，辊磨机或高性能珠磨机。使颜料的细分散或研磨进行到所需的粒度分布，并且可以在0至100℃的温度，适当地在10和70℃之间，优选20至60℃的温度进行。在细分散后，可以用水(F)进一步稀释颜料制剂。然而，本发明的颜料分散体的制备不限于该方法，因此也可以例如仅在研磨之后加入组分(C)。
本发明的颜料分散体适用于所有类型的大分子材料的颜料着色和着色。本发明的颜料分散体特别适用于颜料着色或制备水性和溶剂型无色和覆面乳胶漆和其它油漆，基于分散体的清漆，印刷油墨(例如纺织品印刷，柔版印刷，装饰印刷或凹版印刷油墨)，壁纸油墨；水性、水稀释性和溶剂型的无色和覆面清漆，木材着色剂，木材防腐体系，和例如由金属，木材，塑料，玻璃，陶瓷，混凝土，纺织材料，纸或橡胶制成的制品的表面涂层的清漆。
本发明的颜料分散体的特定性质是它们作为通用调色糊剂的用途。通用调色糊剂适合用于使水性油漆着色和用于使含溶剂的漆调色。如果将水性颜料制剂用于使含溶剂的漆着色，则颜料会凝聚并且凝聚的颜料在清漆中漂浮，且这在彩色颜料的情况下由颜色强度的损失或在白色颜料的情况下覆面能力的损失而显示出来。
实施例
颜料分散体的VOC含量是分散体中的在101.3kPa沸点低于250℃的各组分的总和。因此，为了配制不含VOC的颜料分散体，只应选择沸点高于250℃的那些成分。在使用市场上常规的胺(实施例1和2，表1)的情况下，取决于其使用浓度，这些对分散体的VOC含量贡献100％。式(I)的多羟基胺由于其高熔点和沸点而具有低VOC水平。
表1：中和剂的沸点
实施例 中和剂 沸点[℃]
1(C) 2-氨基-2-甲基丙-1-醇 165
2(C) 2-(仲丁基氨基)乙醇 186
3 式(I)的化合物，其中R＝H >>250(m.p.130℃)
4 式(I)的化合物，其中R＝CH<sub>3</sub> >>250(m.p.90℃)
颜料分散体的制备
将粉末、粒状物或滤饼形式的颜料与分散剂和其它添加剂一起在去离子水中转化为糊剂，然后均化，并用溶解器(例如来自VMA-Getzmann GmbH，AE3-M1型)或其它合适的装置，优选借助分散盘进行预分散。对于分散，首先将液体组分、包含组分(B)和(C)以及另外的组分(D)和(F)的分散剂浓缩物装入研磨容器中并混合。随后，添加粉状组分(A)和任选的(E)并用溶解器预分散。随后的细分散借助于珠磨机(例如来自VMA-Getzmann的AE3-M1)或者另一种合适的分散单元来进行，所述研磨用尺寸d＝1.3-1.7mm的混合氧化锆珠利用冷却进行。随后，将研磨体移除并且将颜料制剂分离。
实施例5(对比例)：
65.5份 C.I.颜料红101( Red 130，来自Lanxess，组分(A))，
10.0份阴离子型和非离子型分散剂的混合物( AN 200，来自Clariant，组分(B))，
1.1份 氢氧化钠溶液(10％水溶液，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
16.9份 水(组分(F))
实施例6(对比例)：
65.5份 C.I.颜料红101( Red 130，来自Lanxess，组分(A))，10.0份阴离子型和非离子型分散剂的混合物( AN 200，来自Clariant，组分(B))，
0.3份 2-氨基-2-甲基丙-1-醇(95％水溶液，AMP-95，来自Angus，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
17.7份 水(组分(F))
实施例7(对比例):
65.5份 C.I.颜料红101( Red 130，来自Lanxess，组分(A))，
10.0份 阴离子型和非离子型分散剂的混合物( AN 200，来自Clariant，组分(B))，
0.4份 2-(仲丁基氨基)乙醇(( N41，来自Arkema)，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
17.6份 水(组分(F))
实施例8：
65.5份 C.I.颜料红101( Red 130，来自Lanxess，组分(A))，
10.0份 阴离子型和非离子型分散剂的混合物( AN200，来自Clariant，组分(B))，
1.5份 式(I)的化合物，其中R＝H(30％水溶液，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
16.5份 水(组分(F))
实施例9：
65.5份 C.I.颜料红101( Red 130，来自Lanxess，组分(A))，
10.0份 阴离子型和非离子型分散剂的混合物( AN 200，来自Clariant，组分(B))，
1.3份 式(I)的化合物，其中R＝CH3(50％水溶液，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
16.7份 水(组分(F))
实施例10(对比例)：
65.5份 C.I.颜料黄184( Gelb L 1100，来自BASF，组分(A))，
10.0份 阴离子型和非离子型分散剂的混合物( AN 200，来自Clariant，组分(B))，
1.0份 氢氧化钠溶液(10％水溶液，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
17.0份 水(组分(F))
实施例11(对比例):
65.5份 C.I.颜料黄184( Gelb L 1100，来自BASF，组分(A))，
10.0份 阴离子型和非离子型分散剂的混合物( AN 200，来自Clariant，组分(B))，
0.2份 2-氨基-2-甲基丙-1-醇(95％水溶液，AMP-95，来自Angus，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
17.8份 水(组分(F))
实施例12(对比例):
65.5份 C.I.颜料黄184( Gelb L 1100，来自BASF，组分(A))，
10.0份 阴离子型和非离子型分散剂的混合物( AN200，来自Clariant，组分(B))，
0.2份 2-(仲丁基氨基)乙醇(( N41，来自Arkema)，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
17.8份 水(组分(F))
实施例13：
65.5份 C.I.颜料黄184( Gelb L 1100，来自BASF，组分(A))，
10.0份 阴离子型和非离子型分散剂的混合物( AN200，来自Clariant，组分(B))，
1.4份 式(I)的化合物，其中R＝H(30％水溶液，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
16.6份 水(组分(F))
实施例14：
65.5份 C.I.颜料黄184( Gelb L 1100，来自BASF，组分(A))，
10.0份 阴离子型和非离子型分散剂的混合物(Dispersogen 200，来自Clariant，组分(B))，
1.4份 式(I)的化合物，其中R＝CH3(50％水溶液，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
16.6份 水(组分(F))
为了表征分散体，首先将它们在60℃老化7天；所有的糊剂在这个时期都是稳定的。此外，将颜料分散体的粘度在Haake VT 550流变仪中以1/60s的剪切速率和23℃的温度进行测定。结果列于表3中，且具有颜料典型的粘度。
为了测定基于各种基础涂料的颜料分散体的相容性，将2重量％的分散体搅拌到油漆和清漆AD(表2)中，并以200μm的涂层刮涂到对比卡上，并测定颜色强度。颜色强度结果列于表3中，并且对于本发明的式(I)的多羟基胺，对于红色(实施例8和9)和对于黄色(实施例13和14)都具有最高的颜色强度。包含2-(仲丁基氨基)乙醇的糊剂(对比例7和12)与溶剂型涂料不相容，并导致在使用中的絮凝，因此不适于比色测定。
表2：用于测试相容性的涂料
除非另有说明，份或百分比数字是重量份或重量百分数。
表3：实施例5-14的结果
对于白色颜料，在透明漆的情况下，颜色强度的测定是不合适的。在这里更适合的是测定覆面能力，作为颜料在油漆膜中的细分布的证据；完全不相容导致颜料包封，并且油漆膜显得透明(没有或几乎没有任何覆面能力)。出于此目的，接着用白色颜料制备颜料分散体(实施例11-15)，然后测定其覆面能力。出于此目的，将无色基础油漆与10重量％的钛分散体混合，并将400μm的油漆膜刮涂在黑色/白色对比卡上。干燥后，测定白色和黑色区域之间的对比度。
实施例15(对比例)：
65.5份 C.I.颜料白6(2160，来自Kronos，组分(A))，
10.0份 阴离子型和非离子型分散剂的混合物( AN 200，来自Clariant，组分(B))，
0.3份 2-氨基-2-甲基丙-1-醇(95％水溶液，AMP-95，来自Angus，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
17.7份 水(组分(F))
实施例16(对比例)：
65.5份 C.I.颜料白6(2160，来自Kronos，组分(A))，
10.0份 阴离子型和非离子型分散剂的混合物( AN200，来自Clariant，组分(B))，
0.8份 2-(仲丁基氨基)乙醇(( N41，来自Arkema)，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
17.2份 水(组分(F))
实施例17：
65.5份 C.I.颜料白6(2160，来自Kronos，组分(A))，
10.0份 阴离子型和非离子型分散剂的混合物( AN 200，来自Clariant，组分(B))，
1.5份 式(I)的化合物，其中R＝H(30％水溶液，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
16.5份 水(组分(F))
实施例18：
65.5份 C.I.颜料白6(2160，来自Kronos，组分(A))，
10.0份 阴离子型和非离子型分散剂的混合物( AN 200，来自Clariant，组分(B))，
1.3份 式(I)的化合物，其中R＝CH3(50％水溶液，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
16.7份 水(组分(F))
覆面能力测定的结果列于表4中。包含式(I)的多羟基胺的颜料分散体通常适用于在水性和溶剂型涂料中产生覆面能力。
式(I)的多羟基胺适合用作水性颜料分散体的中和剂，而不会对VOC含量有贡献。该糊剂适用于均使水性和溶剂型油漆、清漆和涂料着色，因为式(I)的多羟基胺确保了高的颜色接受性，并起到溶剂型和水性体系之间的介质的作用。
表4：实施例15-18的结果

Claims (14)

1.水性不含粘结剂的颜料分散体，其包含
(A)至少一种有机和/或无机颜料，
(B)一种或多种分散剂和/或表面活性剂，
(C)至少一种式(I)的化合物
其中，R1表示H，C1-C4-烷基，CH2CH2OH或CH2CH(CH3)OH，和
(F)水。
2.根据权利要求1所述的水性不含粘结剂的颜料分散体，其中R1表示甲基或CH2CH2OH。
3.根据权利要求1所述的水性不含粘结剂的颜料分散体，其中R1表示甲基。
4.根据权利要求1-3中任一项所述的水性不含粘结剂的颜料分散体，其特征在于，所述无机颜料为金属氧化物颜料。
5.根据权利要求1-3中任一项所述的水性不含粘结剂的颜料分散体，其特征在于，所述颜料分散体的pH值大于7。
6.根据权利要求1-3中任一项所述的水性不含粘结剂的颜料分散体，其特征在于，所述颜料分散体的pH值在8和10之间。
7.根据权利要求1-3中任一项所述的水性不含粘结剂的颜料分散体，其包含5重量％至80重量％的组分(A)，基于所述颜料分散体的总重量计。
8.根据权利要求1-3中任一项所述的水性不含粘结剂的颜料分散体，其包含0.1重量％至30重量％的组分(B)，基于所述颜料分散体的总重量计。
9.根据权利要求1-3中任一项所述的水性不含粘结剂的颜料分散体，其包含0.1重量％至10重量％的组分(C)，基于所述颜料分散体的总重量计。
10.根据权利要求1-3中任一项所述的水性不含粘结剂的颜料分散体，其包含0.1重量％至10重量％的量的一种或多种聚亚烷基二醇作为组分(D)，基于所述颜料分散体的总重量计。
11.根据权利要求1-3中任一项所述的水性不含粘结剂的颜料分散体，其包含0重量％至30重量％的量的另外的用于制备水性颜料分散体的常规添加剂作为组分(E)，基于所述颜料分散体的总重量计。
12.根据权利要求1-3中任一项所述的水性不含粘结剂的颜料分散体，其中其VOC含量根据DIN11890-2测定为小于0.2％。
13.根据权利要求1-12中任一项所述的水性不含粘结剂的颜料分散体的用途，用于使水性、水稀释性和含溶剂的漆和油墨着色。
14.根据权利要求1-12中任一项所述的水性不含粘结剂的颜料分散体的用途，用于使水性、水稀释性和含溶剂的油漆着色。
CN201680031132.8A 2015-10-09 2016-09-15 基于n-烷基葡糖胺的通用颜料分散体 Active CN107735460B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102015219608.9 2015-10-09
DE102015219608.9A DE102015219608B4 (de) 2015-10-09 2015-10-09 Universelle Pigmentdispersionen auf Basis von N-Alkylglukaminen
PCT/EP2016/071750 WO2017060051A1 (de) 2015-10-09 2016-09-15 Universelle pigmentdispersionen auf basis von n-alkylglukaminen

Publications (2)

Publication Number Publication Date
CN107735460A CN107735460A (zh) 2018-02-23
CN107735460B true CN107735460B (zh) 2019-07-16

Family

ID=57068046

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201680031132.8A Active CN107735460B (zh) 2015-10-09 2016-09-15 基于n-烷基葡糖胺的通用颜料分散体

Country Status (10)

Country Link
US (1) US10920080B2 (zh)
EP (1) EP3359605B1 (zh)
JP (1) JP6677807B2 (zh)
CN (1) CN107735460B (zh)
BR (1) BR112017022933A2 (zh)
DE (2) DE202015008045U1 (zh)
ES (1) ES2769774T3 (zh)
MX (1) MX2018004258A (zh)
PT (1) PT3359605T (zh)
WO (1) WO2017060051A1 (zh)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102014005771A1 (de) 2014-04-23 2015-10-29 Clariant International Ltd. Verwendung von wässrigen driftreduzierenden Zusammensetzungen
DE102014012020A1 (de) * 2014-08-13 2016-02-18 Clariant International Ltd. VOC-arme Amine als oberflächenaktiver Bestandteil in Dispersionen
DE202015008045U1 (de) 2015-10-09 2015-12-09 Clariant International Ltd. Universelle Pigmentdispersionen auf Basis von N-Alkylglukaminen
DE102015219651A1 (de) 2015-10-09 2017-04-13 Clariant International Ltd. Zusammensetzungen enthaltend Zuckeramin und Fettsäure
DE102016207877A1 (de) * 2016-05-09 2017-11-09 Clariant International Ltd Stabilisatoren für Silikatfarben
DE102017115798A1 (de) 2017-07-13 2019-01-17 Alanod Gmbh & Co. Kg Reflektierendes Verbundmaterial, insbesondere für oberflächenmontierte Bauelemente (SMD), und lichtemittierende Vorrichtung mit einem derartigen Verbundmaterial

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1301285A (zh) * 1998-05-14 2001-06-27 帝国化学工业公司 颜料的分散体
EP1676831A1 (en) * 2004-11-11 2006-07-05 Air Products and Chemicals, Inc. N,N-dialkylpolyhydroxyalkylamines
CN103717556A (zh) * 2011-07-28 2014-04-09 安格斯化学公司 氨基醇化合物及其作为漆和涂料的零或低voc添加剂的应用

Family Cites Families (286)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1017277A (en) 1911-08-15 1912-02-13 Lacey Y Williams Dust-guard for car journal-boxes.
US1026525A (en) 1911-12-15 1912-05-14 Holden C Mckeel Flue-cleaner.
US2016962A (en) 1932-09-27 1935-10-08 Du Pont Process for producing glucamines and related products
US2192953A (en) * 1936-07-22 1940-03-12 Du Pont Coating composition
US2703798A (en) 1950-05-25 1955-03-08 Commercial Solvents Corp Detergents from nu-monoalkyl-glucamines
US2667478A (en) 1950-10-26 1954-01-26 Commercial Solvents Corp Acid esters of fatty acylated n-alkylglucamines
US2993887A (en) 1953-01-06 1961-07-25 Atlas Powder Co Anhydro amides
US2891052A (en) 1956-04-10 1959-06-16 Rohm & Haas Anhydrosorbityl amides and process of preparation
US3002923A (en) 1957-03-29 1961-10-03 Atlas Chem Ind Water-in-oil emulsion drilling fluid
US2982737A (en) 1957-05-27 1961-05-02 Rohm & Haas Detergent bars
GB1058609A (en) 1964-05-26 1967-02-15 May & Baker Ltd Hydroxybenzonitrile glucamine salts and herbicidal compositions containing them
DE1956509A1 (de) 1969-11-11 1971-05-19 Bayer Ag Verfahren zur Herstellung von Latices
DE2226872A1 (de) 1972-06-02 1973-12-20 Henkel & Cie Gmbh Waschmittel mit einem gehalt an vergrauungsverhuetenden zusaetzen
US4079078A (en) 1974-06-21 1978-03-14 The Procter & Gamble Company Liquid detergent compositions
DE2946500A1 (de) 1979-11-17 1981-05-27 Henkel KGaA, 4000 Düsseldorf Bindemittel auf basis von alkalimetallsilikatloesungen und deren verwendung
DE3017814A1 (de) 1980-05-09 1981-11-19 Henkel Kgaa Neuartige tenside, deren herstellung und verwendung in kosmetischen reinigungsmitteln sowie diese enthaltende hautfreundliche, kosmetische reinigungsmittel
DE3035554A1 (de) 1980-09-20 1982-05-06 Hoechst Ag, 6000 Frankfurt Herbizide mittel
US4565647B1 (en) 1982-04-26 1994-04-05 Procter & Gamble Foaming surfactant compositions
US4413087A (en) 1982-08-23 1983-11-01 Nalco Chemical Company Stable polymer solutions for spray drift control
DE3244522A1 (de) 1982-12-02 1984-06-07 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von nicotinsaeureamid
US4481186A (en) 1983-05-27 1984-11-06 Charles Of The Ritz Group Ltd. Non-irritating cosmetic composition containing glucamine fatty acid emulsifier soap
US4505827A (en) 1983-09-19 1985-03-19 The Dow Chemical Company Triblock polymers of the BAB type having hydrophobic association capabilities for rheological control in aqueous systems
US4654207A (en) 1985-03-13 1987-03-31 Helene Curtis Industries, Inc. Pearlescent shampoo and method for preparation of same
JPS6415136A (en) 1987-03-03 1989-01-19 Japan Tobacco Inc Catalyst for reducing carboxylic acid or its ester to alcohol compound
DE3711776A1 (de) 1987-04-08 1988-10-27 Huels Chemische Werke Ag Verwendung von n-polyhydroxyalkylfettsaeureamiden als verdickungsmittel fuer fluessige waessrige tensidsysteme
DE3809159A1 (de) 1988-03-18 1989-09-28 Hoechst Ag Fluessige herbizide mittel
US5711899A (en) 1988-12-23 1998-01-27 Henkel Kommanditgesellschaft Auf Aktien Free flowing pearlescent concentrate
NZ231897A (en) 1988-12-30 1992-09-25 Monsanto Co Dry water-soluble granular composition comprising glyphosate and a liquid surfactant
DE4021336A1 (de) 1989-07-08 1991-01-17 Hoechst Ag Entschaeumer fuer fluessige netzmittel und schaumarme fluessige pflanzenschutzmittel
YU47834B (sr) 1989-08-10 1996-01-09 Schering Agrochemical Limited Azolni pesticid
US4981684A (en) 1989-10-24 1991-01-01 Coopers Animal Health Limited Formation of adjuvant complexes
EP0539588A1 (en) 1990-07-05 1993-05-05 Nippon Soda Co., Ltd. Amine derivative
SK25193A3 (en) 1990-09-28 1993-07-07 Procter & Gamble Detergent composition containing polyhydroxy fatty acid amides and alkyl ester sulfonate surfactants
EP0550656B1 (en) 1990-09-28 1997-04-16 The Procter & Gamble Company Improved shampoo compositions
US5194639A (en) 1990-09-28 1993-03-16 The Procter & Gamble Company Preparation of polyhydroxy fatty acid amides in the presence of solvents
WO1992006161A1 (en) 1990-09-28 1992-04-16 The Procter & Gamble Company Detergent compositions containing polyhydroxy fatty acid amides and suds enhancing agent
BR9106906A (pt) 1990-09-28 1993-07-20 Procter & Gamble Detergente contiendo tensoativos de sulfato de alquila e de amida de acido polihidroxi graxo
CZ57693A3 (en) 1990-09-28 1994-04-13 Procter & Gamble Granulated cleansing preparation with enhanced stability and purifying efficiency of enzyme
BR9106899A (pt) 1990-09-28 1993-07-20 Procter & Gamble Composicoes detergentes contendo amida de acido graxo polihidroxi e sulfato de alquila alcoxilado
FR2672002B1 (fr) 1991-01-25 1995-05-24 Sabate Sa Bouchons Champagne Composition utilisable pour la fabrication de bouchon et procede de fabrication.
US5254281A (en) 1991-01-29 1993-10-19 The Procter & Gamble Company Soap bars with polyhydroxy fatty acid amides
CA2114106C (en) 1991-07-26 2002-05-28 Junan Kao Process for preparing n-alkyl polyhydroxyalkyl amines in aqueous/hydroxy solvents
US5449770A (en) 1992-01-14 1995-09-12 The Procter & Gamble Company Process for making N-alkylamino polyols
US5298195A (en) 1992-03-09 1994-03-29 Amway Corporation Liquid dishwashing detergent
US5283009A (en) 1992-03-10 1994-02-01 The Procter & Gamble Co. Process for preparing polyhydroxy fatty acid amide compositions
CA2131174C (en) 1992-03-25 1999-01-12 Michel Joseph Giret Cleansing compositions
EP0572723A1 (en) 1992-06-02 1993-12-08 The Procter & Gamble Company Structured liquid detergent compositions
DE4235783A1 (de) 1992-10-23 1994-04-28 Basf Ag Verfahren zur Herstellung von N-Alkanoyl-polyhydroxyalkylaminen
WO1994010273A1 (en) 1992-11-04 1994-05-11 The Procter & Gamble Company Detergent gels
DE4238211C2 (de) 1992-11-12 1997-11-13 Henkel Kgaa Verwendung von Detergensgemischen, enthaltend kationische Zuckertenside und weitere Tenside, zur Herstellung von Avivagemitteln
AU5618294A (en) 1992-11-30 1994-06-22 Procter & Gamble Company, The Detergent compositions with calcium ions and polyhydroxy fatty acid amide nonionic/selected anionic/soap surfactant mixture
EP0670885B1 (en) 1992-11-30 1997-08-20 The Procter & Gamble Company High sudsing detergent compositions with specially selected soaps
JP3201669B2 (ja) 1992-12-22 2001-08-27 三井化学株式会社 紙塗被用組成物
DE4307163A1 (de) 1993-03-06 1994-09-08 Hoechst Ag Verfahren zur Herstellung von tertiären Dialkylpolyhydroxyaminen
DK169734B1 (da) 1993-03-09 1995-01-30 Kvk Agro As Herbicidpræparat, fremgangsmåde til fremstilling heraf samt aktiverende additiv til opblanding med herbicidpræparater
DE4322874C2 (de) 1993-07-09 1995-07-20 Hoechst Ag Verfahren zur kontinuierlichen Herstellung von Polyhydroxyfettsäureamiden aus N-Alkylpolyhydroxyaminen und Fettsäurealkylestern
DE4331297A1 (de) 1993-09-15 1995-03-16 Henkel Kgaa Stückseifen
US5750748A (en) 1993-11-26 1998-05-12 The Procter & Gamble Company N-alkyl polyhydroxy fatty acid amide compositions and their method of synthesis
US5354425A (en) 1993-12-13 1994-10-11 The Procter & Gamble Company Tissue paper treated with polyhydroxy fatty acid amide softener systems that are biodegradable
US6238682B1 (en) 1993-12-13 2001-05-29 The Procter & Gamble Company Anhydrous skin lotions having antimicrobial components for application to tissue paper products which mitigate the potential for skin irritation
CA2177038A1 (en) 1993-12-13 1995-06-22 Alrick Vincent Warner Lotion composition for imparting soft, lubricious feel to tissue paper
WO1995017880A1 (en) 1993-12-30 1995-07-06 The Procter & Gamble Company High lathering and high depositing shampoos with mild surfactant system
US5550224A (en) 1994-01-03 1996-08-27 Hazen; James L. Guar as a drift control agent
DE4400632C1 (de) 1994-01-12 1995-03-23 Henkel Kgaa Tensidgemische und diese enthaltende Mittel
DE4402029A1 (de) 1994-01-25 1995-07-27 Basf Ag Wäßrige Lösungen oder Dispersionen von Copolymerisaten
WO1995023840A1 (en) 1994-03-04 1995-09-08 The Procter & Gamble Company Polyhydroxy amides to provide dye transfer inhibition benefits during fabric laundering
DE4409321A1 (de) 1994-03-18 1995-09-21 Henkel Kgaa Detergensgemische
WO1995030737A2 (en) 1994-05-10 1995-11-16 The Procter & Gamble Company Personal cleansing soap-synthetic bar compositions with low levels of nonionic, polyethylene/polypropylene glycol polymers for improved mildness
DE4416566A1 (de) 1994-05-11 1995-11-16 Huels Chemische Werke Ag Wäßrige viskoelastische Tensidlösungen zur Haar- und Hautreinigung
WO1995033033A1 (en) 1994-06-01 1995-12-07 The Procter & Gamble Company Laundry detergent compositions
WO1995033035A1 (en) 1994-06-01 1995-12-07 The Procter & Gamble Company Oleoyl sarcosinate containing detergent compositions
AU2554095A (en) 1994-06-01 1995-12-21 Procter & Gamble Company, The Liquid detergent composition containing oleoyl sarcosinates and anionic surfactants
JPH0812993A (ja) 1994-07-01 1996-01-16 Ajinomoto Co Inc 洗浄剤組成物
GB9415452D0 (en) 1994-07-30 1994-09-21 Procter & Gamble Cleansing compositions
DE4435383C1 (de) 1994-10-04 1995-11-09 Henkel Kgaa Kosmetische Mittel
EP0709449A1 (en) 1994-10-28 1996-05-01 The Procter & Gamble Company Non-aqueous compositions comprising polyhydroxy fatty acid amides
DE4439091A1 (de) 1994-11-02 1996-05-09 Henkel Kgaa Oberflächenaktive Mittel
US5559078A (en) 1994-12-01 1996-09-24 Henkel Corporation Agriculturally active composition comprising polyhydroxy acid amide adjuvant
DE4443643A1 (de) 1994-12-08 1996-06-13 Henkel Kgaa Anionische Detergensgemische
US5560873A (en) 1994-12-30 1996-10-01 Chen; Pu Mild cold pearlizing concentrates
DE19507531C2 (de) 1995-03-03 1998-07-09 Henkel Kgaa Verwendung von Fettsäure-N-alkylpolyhydroxyalkylamiden
AU5309596A (en) 1995-03-13 1996-10-02 Abbott Laboratories Synergists of bacillus thuringiensis delta-endotoxin
US5585104A (en) 1995-04-12 1996-12-17 The Procter & Gamble Company Cleansing emulsions
DE19517794A1 (de) 1995-05-15 1996-11-21 Hoechst Ag Verwendung von Kohlenhydrat-Verbindungen als Hilfsmittel zum Färben und Bedrucken von Fasermaterialien
GB9510833D0 (en) 1995-05-27 1995-07-19 Procter & Gamble Cleansing compositions
GB9510839D0 (en) 1995-05-27 1995-07-19 Procter & Gamble Cleansing Compositions
US5777165A (en) 1995-06-07 1998-07-07 The Procter & Gamble Company Process for preparing amides of N-alkyl polyhydroxyalkyl amines
TW396207B (en) 1995-07-12 2000-07-01 Kyowa Hakko Kogyo Kk Detergent composition
EP0756000A1 (en) 1995-07-24 1997-01-29 The Procter & Gamble Company Detergent compositions comprising specific amylase and linear alkyl benzene sulfonate surfactant
DE19527120A1 (de) 1995-07-25 1997-01-30 Henkel Kgaa Fließfähiges Perlglanzkonzentrat
DE19533539A1 (de) 1995-09-11 1997-03-13 Henkel Kgaa O/W-Emulgatoren
DE19538751A1 (de) 1995-10-18 1997-04-24 Huels Chemische Werke Ag Entschäumerdispersionen für wäßrige Tensidsysteme
DE19542288A1 (de) 1995-11-14 1997-05-15 Huels Chemische Werke Ag Antischaumdispersion für wäßrige Tensidsysteme
DE19623763C2 (de) 1996-06-14 1999-08-26 Henkel Kgaa Kosmetische Zubereitungen
GB9613941D0 (en) 1996-07-03 1996-09-04 Procter & Gamble Cleansing compositions
DE19641274C1 (de) 1996-10-07 1998-02-12 Henkel Kgaa Sonnenschutzmittel in Form von O/W-Mikroemulsionen
DE19701127A1 (de) 1997-01-15 1998-07-16 Henkel Kgaa Schaumarme Tensidkonzentrate für den Einsatz im Bereich der Förderung des Pflanzenwachstums
BR9808183A (pt) 1997-03-06 2000-05-16 Rhodia Concentrados de perolização fria branda
US5919312A (en) 1997-03-18 1999-07-06 The Procter & Gamble Company Compositions and methods for removing oily or greasy soils
EP1003605A4 (en) 1997-06-12 2001-04-18 Henkel Corp USE OF ALKYL POLYGLYCOSIDES IMPROVING THE STABILIZATION OF AMPHOACETATE FOAMS
IN191344B (zh) 1997-12-04 2003-11-22 Lever Hindustan Ltd
JPH11246890A (ja) 1998-03-03 1999-09-14 Lion Corp 洗浄剤組成物
DE19808824C1 (de) 1998-03-03 1999-10-28 Wella Ag Haarbehandlungsmittel mit einem Gehalt an mit Polyhydroxyaminen neutralisierten sauren Polymeren
US6610645B2 (en) 1998-03-06 2003-08-26 Eugene Joseph Pancheri Selected crystalline calcium carbonate builder for use in detergent compositions
GB9807269D0 (en) 1998-04-03 1998-06-03 Unilever Plc Detergent compositions
US6274126B1 (en) 1998-08-21 2001-08-14 Helene Curtis, Inc. Composition for lightening and highlighting hair
DE19846429A1 (de) 1998-10-08 2000-04-13 Cognis Deutschland Gmbh Stückseifen
DE19849000A1 (de) 1998-10-23 2000-04-27 Roche Diagnostics Gmbh Funktionsschichten mit hoher Präzision, Verfahren zu ihrer Herstellung und Teststreifen enthaltend diese Funktionsschichten
DE19916090A1 (de) 1999-04-09 2000-10-12 Clariant Gmbh Hautpflegemittel
DE19917285A1 (de) 1999-04-16 2000-10-19 Clariant Gmbh Wäßrige Kunststoff-Dispersionen mit erhöhter Stabilität
AU4659900A (en) 1999-04-27 2000-11-10 Procter & Gamble Company, The Treating compositions comprising polysaccharides
DE19921187C2 (de) 1999-05-07 2001-06-28 Cognis Deutschland Gmbh Verfahren zur kalten Herstellung von perlglänzenden Tensidzubereitungen
JP2003504380A (ja) 1999-07-16 2003-02-04 インペリアル・ケミカル・インダストリーズ・ピーエルシー 農薬組成物及び界面活性剤化合物
DE19940116A1 (de) 1999-08-24 2001-03-01 Clariant Gmbh Tensidmischungen aus Fettsäure-N-Alkylpolyhydroxyamiden und Fettsäureamidoalkoxylaten
US6818607B1 (en) 1999-08-27 2004-11-16 Procter & Gamble Company Bleach boosting components, compositions and laundry methods
DE19956236A1 (de) 1999-11-23 2001-05-31 Cognis Deutschland Gmbh Schaumarme Tensidkonzentrate für den Einsatz im Bereich der Förderung des Pflanzenwachstums
DE19961256A1 (de) 1999-12-18 2001-06-21 Clariant Gmbh Kosmetische Zubereitungen
DE19962999A1 (de) 1999-12-24 2001-07-05 Clariant Gmbh Verfahren zur Herstellung von Fettsäure-N-Alkylpolyhydroxyamiden
DE10007044A1 (de) 2000-02-16 2001-08-23 Clariant Gmbh Copolymere und deren Verwendung als drift control agents
US6261595B1 (en) 2000-02-29 2001-07-17 Zars, Inc. Transdermal drug patch with attached pocket for controlled heating device
US6635702B1 (en) 2000-04-11 2003-10-21 Noveon Ip Holdings Corp. Stable aqueous surfactant compositions
US7332457B2 (en) 2000-09-18 2008-02-19 Honeywell International Inc. Agricultural chemical suspensions
DE10049202A1 (de) 2000-10-05 2002-04-11 Clariant Gmbh Verfahren zur Herstellung von flüssigen Pigmentpräparationen
DE10102005A1 (de) 2001-01-18 2002-07-25 Cognis Deutschland Gmbh Perlglanzmittel
DE10117993A1 (de) 2001-04-10 2002-10-17 Clariant Gmbh Pestizidzubereitungen enthaltend Copolymere
ATE536345T1 (de) 2001-05-31 2011-12-15 Nihon Nohyaku Co Ltd Substituierte anilidderivate, deren zwischenprodukte, chemikalien für die landwirtschaft und den gartenbau und deren verwendung
US20030004929A1 (en) 2001-06-15 2003-01-02 Julian Arnold James Method and apparatus for a computer-implemented system for the maintainence of a business relationship between a seller and a buyer
US7270828B2 (en) 2001-06-20 2007-09-18 The Procter & Gamble Company Personal care composition comprising hydrophobic gel
DE10130357A1 (de) 2001-06-23 2003-01-02 Clariant Gmbh Pestizidzubereitungen enthaltend Copolymere
US6933269B2 (en) 2001-08-03 2005-08-23 The Procter & Gamble Company Polyaspartate derivatives for use in detergent compositions
DE10146264A1 (de) 2001-09-20 2003-04-17 Ecolab Gmbh & Co Ohg Verwendung von O/W-Emulsionen zur Kettenschmierung
DE10162026A1 (de) 2001-12-18 2003-07-03 Cognis Deutschland Gmbh Hochkonzentriert fließfähige Perlglanzkonzentrate
DE10162024A1 (de) 2001-12-18 2003-07-03 Cognis Deutschland Gmbh Hochkonzentriert fließfähige Perlglanzkonzentrate
EP1485442A4 (en) 2002-03-01 2009-11-11 Cesi Chemical A Flotek Co COMPOSITION AND METHOD FOR CLEANING A WELL
CA2482038A1 (en) 2002-04-22 2003-10-30 The Procter & Gamble Company Shampoo containing a cationic guar derivative
US8012495B2 (en) 2002-05-07 2011-09-06 Georgia-Pacific Consumer Products Lp Lotion-treated tissue and towel
GB2388610A (en) 2002-05-17 2003-11-19 Procter & Gamble Detergent composition containing silicone and fatty acid
US8367048B2 (en) 2002-06-04 2013-02-05 The Procter & Gamble Company Shampoo containing a gel network
GB0213715D0 (en) 2002-06-14 2002-07-24 Syngenta Ltd Chemical compounds
AU2003259789A1 (en) 2002-08-13 2004-02-25 Mcintyre Group, Ltd. High concentration surfactant compositions and methods
JP4157555B2 (ja) 2002-11-12 2008-10-01 ユニリーバー・ナームローゼ・ベンノートシヤープ 毛髪を洗浄およびコンディショニングする組成物
FR2847465B1 (fr) 2002-11-21 2006-03-17 Oreal Composition liquide de nettoyage a base de savons et de tensio-actifs synthetiques; utilisations pour le nettoyage des matieres keratiniques humaines
ES2310676T3 (es) 2002-12-20 2009-01-16 Pfizer Products Inc. Formas de dosificacion que comprenden un inhibidor de cetp y un inhibidor de hmg-coa reductasa.
US7250392B1 (en) 2003-03-07 2007-07-31 Cognis Corporation Surfactant blend for cleansing wipes
US20050004164A1 (en) 2003-04-30 2005-01-06 Caggiano Thomas J. 2-Cyanopropanoic acid amide and ester derivatives and methods of their use
TWI312272B (en) 2003-05-12 2009-07-21 Sumitomo Chemical Co Pyrimidine compound and pests controlling composition containing the same
UA79404C2 (en) 2003-10-02 2007-06-11 Basf Ag 2-cyanobenzenesulfonamide for controlling pests
EP1529832A1 (de) 2003-11-04 2005-05-11 Metall-Chemie Handelsgesellschaft mbH &amp; Co. KG Metallbearbeitungsflüssigkeiten
US7985569B2 (en) 2003-11-19 2011-07-26 Danisco Us Inc. Cellulomonas 69B4 serine protease variants
GB0329744D0 (en) 2003-12-23 2004-01-28 Koninkl Philips Electronics Nv A beverage maker incorporating multiple beverage collection chambers
US20050158270A1 (en) 2004-01-15 2005-07-21 Seren Frantz Pearlizer concentrate and its use in personal care compositions
KR20060129257A (ko) 2004-01-20 2006-12-15 헌츠만 페트로케미칼 코포레이션 신규한 아실알킬이세티오네이트 에스테르 및 소비재에서의적용
KR101099330B1 (ko) 2004-02-18 2011-12-26 이시하라 산교 가부시끼가이샤 안트라닐아미드계 화합물, 그의 제조 방법 및 그것을 함유하는 유해 생물 방제제
ZA200607637B (en) 2004-03-05 2008-05-28 Nissan Chemical Ind Ltd Isoxazoline-substituted benzamide compound and noxious organism control agent
DE102004032734A1 (de) 2004-03-18 2005-10-06 Henkel Kgaa Präbiotisch wirksame Substanzen für Deodorantien
EP1747260A4 (en) 2004-04-15 2008-07-30 Rhodia Structured surfactant compositions
US6903057B1 (en) 2004-05-19 2005-06-07 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Personal product liquid cleansers stabilized with starch structuring system
DE102004026938A1 (de) 2004-06-01 2005-12-22 Bayer Cropscience Gmbh Schaumarme wäßrige Formulierungen für den Pflanzenschutz
CN1309812C (zh) 2004-07-06 2007-04-11 中国石油化工集团公司 一种润滑油组合物及其应用
EP1803712B1 (en) 2004-10-20 2015-12-30 Kumiai Chemical Industry Co., Ltd. 3-triazolylphenyl sulfide derivative and insecticide/acaricide/nematicide containing the same as active ingredient
US7282471B2 (en) 2005-09-08 2007-10-16 Conopco, Inc. Personal care compositions with glycerin and hydroxypropyl quaternary ammonium salts
US7279446B2 (en) 2004-11-15 2007-10-09 Rhodia Inc. Viscoelastic surfactant fluids having enhanced shear recovery, rheology and stability performance
JP2006143828A (ja) * 2004-11-18 2006-06-08 Seiko Epson Corp 水性インク組成物、インクジェット記録方法及びインクジェット記録物
US20060110415A1 (en) 2004-11-22 2006-05-25 Bioderm Research Topical Delivery System for Cosmetic and Pharmaceutical Agents
CA2586520A1 (en) 2004-11-26 2006-06-01 Basf Aktiengesellschaft Novel 2-cyano-3-(halo)alkoxy-benzenesulfonamide compounds for combating animal pests
US7776318B2 (en) 2004-11-26 2010-08-17 L'oreal S.A. Liquid cleaning composition comprising at least one anionic surfactant and its use for cleansing human keratin materials
JP2006183030A (ja) 2004-11-30 2006-07-13 Lion Corp ペースト状洗浄剤組成物
JP4527655B2 (ja) 2004-11-30 2010-08-18 ライオン株式会社 フォーマー容器入り洗浄剤組成物
DE102004059041A1 (de) 2004-12-07 2006-06-08 Schülke & Mayr GmbH Verwendung von Formaldehyd und Formaldehyd freisetzenden Verbindungen in einer Zusammensetzung zur Bekämpfung von Mykobakterien
EP1671621B1 (en) 2004-12-16 2007-02-14 KPSS-Kao Professional Salon Services GmbH Shampoo composition
FR2880354B1 (fr) 2004-12-31 2007-03-02 Michelin Soc Tech Composition elastomerique renforcee d'une charge de polyvinylaromatique fonctionnalise
US20060171979A1 (en) 2005-02-01 2006-08-03 Jose-Luis Calvo Fungicide mixture formulations
RU2007134258A (ru) 2005-02-17 2009-03-27 Хенкель Коммандитгезелльшафт Ауф Акциен (DE) Композиции шампуней на основе катионных поверхностно-активных веществ
DE102005008021A1 (de) 2005-02-22 2006-08-24 Bayer Cropscience Ag Spiroketal-substituierte cyclische Ketoenole
CA2601072A1 (en) 2005-03-24 2006-09-28 Basf Aktiengesellschaft 2-cyanobenzenesulfonamide compounds for seed treatment
ES2318380T3 (es) 2005-04-30 2009-05-01 Cognis Ip Management Gmbh Composiciones limpiadoras suaves.
PL1947098T3 (pl) 2005-10-06 2012-03-30 Nippon Soda Co Cykliczne związki aminowe i środek do zwalczania szkodników
EP1776945A1 (de) 2005-10-20 2007-04-25 Cognis IP Management GmbH Styrolcopolymere enthaltende Trübungsmittel
JP2009516667A (ja) 2005-11-21 2009-04-23 ビーエーエスエフ ソシエタス・ヨーロピア ３−アミノ−１，２−ベンゾイソチアゾール誘導体を用いた殺虫方法
TW200803740A (en) 2005-12-16 2008-01-16 Du Pont 5-aryl isoxazolines for controlling invertebrate pests
GB0526231D0 (en) * 2005-12-22 2006-02-01 Eastman Kodak Co Dispersant for reducing viscosity of solids
EP1997820A4 (en) 2006-03-09 2009-03-04 Univ East China Science & Tech METHOD OF PREPARATION AND USE OF COMPOUNDS HAVING BIOCIDAL ACTION
DE602007011414D1 (de) 2006-03-13 2011-02-03 Evonik Goldschmidt Gmbh Agrarchemikalienzusammensetzungen mit alkylendiol-modifizierten polysiloxanen
DE102006015468A1 (de) 2006-03-31 2007-10-04 Bayer Cropscience Ag Substituierte Enaminocarbonylverbindungen
DE102006015467A1 (de) 2006-03-31 2007-10-04 Bayer Cropscience Ag Substituierte Enaminocarbonylverbindungen
DE102006015470A1 (de) 2006-03-31 2007-10-04 Bayer Cropscience Ag Substituierte Enaminocarbonylverbindungen
EP1842526A1 (en) 2006-03-31 2007-10-10 Johnson & Johnson Consumer France SAS Clear cleansing composition
ES2293825B1 (es) 2006-06-07 2008-12-16 Kao Corporation, S.A. Composicion que contiene una mezcla de mono-di, y trigliceridos y glicerina.
EP1869978A1 (de) 2006-06-21 2007-12-26 Bayer CropScience AG Schaumarme Zubereitungen für den Pflanzenschutz
TWI381811B (zh) 2006-06-23 2013-01-11 Dow Agrosciences Llc 用以防治可抵抗一般殺蟲劑之昆蟲的方法
DE102006033572A1 (de) 2006-07-20 2008-01-24 Bayer Cropscience Ag N'-Cyano-N-halogenalkyl-imidamid Derivate
US20080026974A1 (en) 2006-07-27 2008-01-31 Barnhart Ronald A Antimicrobial hand wash
JP5047588B2 (ja) 2006-10-31 2012-10-10 Ｍｅｉｊｉ Ｓｅｉｋａファルマ株式会社 キノリン誘導体およびそれを含んでなる農園芸用殺虫剤
RU2461597C2 (ru) 2006-11-02 2012-09-20 Эйвери Деннисон Корпорейшн Эмульсионный клей для смываемой пленки
EP2107060B1 (en) 2006-11-30 2011-12-28 Meiji Seika Pharma Co., Ltd. Pest control agent
DE102006057036A1 (de) 2006-12-04 2008-06-05 Bayer Cropscience Ag Biphenylsubstituierte spirocyclische Ketoenole
US8153560B2 (en) 2007-03-01 2012-04-10 Basf Se Pesticidal active mixtures comprising aminothiazoline compounds
US20080318630A1 (en) 2007-06-25 2008-12-25 Qualcomm Incorporated Graceful coexistence for multiple communication protocols
US8210263B2 (en) 2007-07-03 2012-07-03 Baker Hughes Incorporated Method for changing the wettability of rock formations
DE102007034438A1 (de) 2007-07-20 2009-01-22 Evonik Goldschmidt Gmbh Wässrige tensidische Formulierung enthaltend Polypropylenglykol(3)myristylether
US20120010113A1 (en) 2007-07-31 2012-01-12 Chevron U.S.A. Inc. Metalworking fluid compositions and preparation thereof
AU2008293652B2 (en) 2007-08-24 2013-02-21 Advanced Liquid Logic, Inc. Bead manipulations on a droplet actuator
US8220564B2 (en) 2007-08-27 2012-07-17 Vermeer Manufacturing Company Devices and methods for dynamic boring procedure reconfiguration
FR2920967B1 (fr) 2007-09-14 2009-10-23 Sederma Soc Par Actions Simpli Utilisation de l'hydroxymethionine en tant qu'actif anti age
GB0720126D0 (en) 2007-10-15 2007-11-28 Syngenta Participations Ag Chemical compounds
US8124061B2 (en) 2007-11-02 2012-02-28 Kimberly-Clark Worldwide, Inc. Cleansing compositions including modified sorbitan siloxanes and use thereof
FR2926083B1 (fr) * 2008-01-04 2010-04-09 Arkema France Agent de neutralisation et de co-dispersion a fort pouvoir de developpement de la force colorante, et les peintures et concentres pigmentaires le contenant.
FR2927801B1 (fr) 2008-02-22 2010-03-05 Sederma Sa Composition cosmetique hydratante comprenant une combinaison d'homarine et d'erythritol
US20090253612A1 (en) 2008-04-02 2009-10-08 Symrise Gmbh & Co Kg Particles having a high load of fragrance or flavor oil
EP2110121B1 (en) 2008-04-14 2012-02-01 Dr. Straetmans Chemische Produkte GmbH Cosmetic and dermatological compositions in particular for the treatment of keratin containing substrates
WO2010005692A2 (en) 2008-06-16 2010-01-14 E. I. Du Pont De Nemours And Company Insecticidal cyclic carbonyl amidines
JP5268461B2 (ja) 2008-07-14 2013-08-21 Ｍｅｉｊｉ Ｓｅｉｋａファルマ株式会社 Ｐｆ１３６４物質、その製造方法、生産菌株、及び、それを有効成分とする農園芸用殺虫剤
ES2567786T3 (es) 2008-07-17 2016-04-26 Bayer Cropscience Ag Compuestos heterocíclicos como pesticidas
JP5468221B2 (ja) 2008-08-04 2014-04-09 株式会社 メドレックス 難溶性薬物の静注用分散製剤
AR075294A1 (es) 2008-10-31 2011-03-23 Dow Agrosciences Llc Control de la dispersion de la pulverizacion de pesticidas con esteres auto emulsificables
EP2379526B1 (de) 2008-12-18 2015-05-27 Bayer Intellectual Property GmbH Tetrazolsubstituierte Anthranilsäureamide als Pestizide
DK2369921T3 (en) 2008-12-26 2016-11-21 Dow Agrosciences Llc STABLE-sulfoximine Insecticidal
PL2369935T3 (pl) 2008-12-26 2017-04-28 Dow Agrosciences, Llc Trwałe kompozycje owadobójcze oraz sposoby ich wytwarzania
WO2010126657A1 (en) 2009-04-29 2010-11-04 Angus Chemical Company Tertiary aminoalcohols as low voc additives for paints and coatings
FR2945950A1 (fr) 2009-05-27 2010-12-03 Elan Pharma Int Ltd Compositions de nanoparticules anticancereuses et procedes pour les preparer
JP5580411B2 (ja) 2009-06-26 2014-08-27 アンガス ケミカル カンパニー 塗料およびコーティングのための低臭気、低ｖｏｃの多官能添加剤としてのポリヒドロキシジアミン
EP2289485A1 (en) 2009-08-31 2011-03-02 Cognis IP Management GmbH Cosmetic compositions comprising Manilkara multinervis and extracts thereof
DE102009041003A1 (de) 2009-09-10 2011-03-24 Clariant International Limited Pestizidzubereitungen
BR112012013667B1 (pt) 2009-12-17 2021-07-06 Dow Global Technologies Llc método para reduzir o conteúdo de composto orgânico volátil de um revestimento ou tinta base aquosa, composto, revestimento ou tinta base aquosa e processo para preparar um composto
FR2954123B1 (fr) 2009-12-22 2012-02-03 Oreal Composition cosmetique de nettoyage comprenant un derive d'acide jasmonique et un tensioactif
US8729323B2 (en) 2009-12-23 2014-05-20 Phillips 66 Company Production of hydrocarbon from high free fatty acid containing feedstocks
FR2954111B1 (fr) 2009-12-23 2012-03-16 Oreal Composition cosmetique comprenant au moins un alcane lineaire volatil, au moins une silicone aminee de teneur particuliere et au moins une huile vegetale
US8618179B2 (en) 2010-01-18 2013-12-31 Basf Se Composition comprising a pesticide and an alkoxylate of 2-propylheptylamine
US7998911B1 (en) 2010-03-02 2011-08-16 Oil Chem Technologies Environmental friendly fracturing and stimulation composition and method of using the same
US8263538B2 (en) 2010-03-31 2012-09-11 Conopco, Inc. Personal wash cleanser with mild surfactant systems comprising defined alkanoyl compounds and defined fatty acyl isethionate surfactant product
FR2959666B1 (fr) 2010-05-07 2012-07-20 Oreal Composition cosmetique moussante a base d'acide ellagique ou d'un de ses derives et d'huile essentielle.
US8501808B2 (en) 2010-07-12 2013-08-06 Conopco, Inc. Foam enhancement of fatty acyl glycinate surfactants
CN103052427B (zh) 2010-08-18 2015-12-09 荷兰联合利华有限公司 抗头皮屑洗发香波
US20130216491A1 (en) 2010-08-31 2013-08-22 Otsuka Pharmaceutical Co., Ltd. Composition for cleaning scalp and head hair
WO2012036701A1 (en) 2010-09-17 2012-03-22 Ecolab Usa Inc. Cleaning compositions and emulsions or microemulsions employing extended chain nonionic surfactants
US8453741B2 (en) 2010-09-23 2013-06-04 Halliburton Energy Services, Inc. Tethered polymers used to enhance the stability of microemulsion fluids
CN103260594B (zh) 2010-11-11 2015-11-25 荷兰联合利华有限公司 包含12-羟基硬脂酸的留存型非固体皮肤调理组合物
EP2680692B1 (en) 2011-02-28 2017-04-12 Basf Se Composition comprising a pesticide, an alkoxylate of 2-propylheptylamine and a further surfactant
FR2976483B1 (fr) * 2011-06-17 2013-07-26 Oreal Composition cosmetique comprenant un tensioactif anionique, un tensioactif non ionique ou amphotere et un alcool gras solide et procede de traitement cosmetique
HUE032612T2 (en) 2011-06-24 2017-10-30 Sca Tissue France Body cleaning composition containing gelling and blowing agents for tissue impregnation
US8653018B2 (en) 2011-07-28 2014-02-18 Conopco, Inc. Fatty acyl amido based surfactant concentrates
JP6001070B2 (ja) * 2011-07-28 2016-10-05 アンガス ケミカル カンパニー アミノアルコール化合物ならびに塗料およびコーティング用ゼロまたは低ｖｏｃ添加剤としてのそれらの使用
WO2013064442A1 (de) 2011-11-03 2013-05-10 Basf Se Zubereitung zur passivierung von metallischen oberflächen enthaltend säuregruppenhaltige polymere und ti- oder zr-verbindungen
CN104039750A (zh) 2011-11-22 2014-09-10 阿彻丹尼尔斯米德兰德公司 富含不饱和脂肪酸的棕榈油
US20130189212A1 (en) 2012-01-24 2013-07-25 Galaxy Surfactants Ltd. Novel Surfactant Composition
US10265253B2 (en) 2012-05-30 2019-04-23 Clariant International Ltd. N-methyl-N-acylglucamine-containing composition
JP2015523341A (ja) 2012-05-30 2015-08-13 クラリアント・ファイナンス・（ビーブイアイ）・リミテッド Ｎ−メチル−ｎ−アシルグルカミン含有組成物
EP2854950B1 (de) 2012-05-30 2016-12-14 Clariant International Ltd Verwendung von n-methyl-n-acylglucaminen als kältestabilisatoren in tensidlösungen
ES2599504T3 (es) 2012-05-30 2017-02-02 Clariant International Ltd Utilización de N-metil-N-acil-glucaminas como agentes solubilizantes
EP2854951B1 (de) 2012-05-30 2016-09-07 Clariant International Ltd. Zusammensetzung enthaltend aminosäuretenside, betaine und n-methyl-n-acylglucamine mit verbesserter schaumqualität und höherer viskosität
BR112014029754B1 (pt) 2012-05-30 2020-04-28 Clariant Finance Bvi Ltd soluções de tensoativos que contêm n-metil-noleilglucaminas e n-metil-n-c12-c14 acilglucaminas e seu uso, processo para produzir composições cosméticas e composição
IN2014DN10140A (zh) 2012-05-30 2015-08-21 Clariant Finance Bvi Ltd
BR112014029774A2 (pt) 2012-05-30 2017-06-27 Clariant Finance Bvi Ltd uso de n-metil-n-acilglucaminas como agentes espessantes em soluções de tensoativos
CN104640965A (zh) 2012-05-30 2015-05-20 科莱恩金融(Bvi)有限公司 包含n-甲基-n-酰基葡糖胺的组合物
JP6416754B2 (ja) 2012-05-30 2018-10-31 クラリアント・ファイナンス・（ビーブイアイ）・リミテッド 脂肪アルコール、カチオン性界面活性剤及びｎ−アシル−ｎ−メチルグルカミンを含む組成物
JP6087438B2 (ja) 2012-08-23 2017-03-01 ギャラクシー サーファクタンツ リミテッド 触媒としてｎ−アシルアミノ酸界面活性剤またはその対応する無水物を使用するｎ−アシルアミノ酸界面活性剤を製造する方法
US20140096969A1 (en) 2012-10-04 2014-04-10 Syed Afaq Ali Compositions and methods for preventing emulsion formation
PT2906644T (pt) * 2012-10-09 2017-01-03 Clariant Int Ltd Agentes dispersantes, compostos de matérias-primas renováveis, para preparações de pigmentos isentas de agentes ligantes
ES2644728T3 (es) 2012-10-24 2017-11-30 Clariant International Ltd Composiciones que reducen la deriva
DE102012021647A1 (de) 2012-11-03 2014-05-08 Clariant International Ltd. Wässrige Adjuvant-Zusammensetzungen
BR112015021683A2 (pt) 2013-03-05 2017-07-18 Procter & Gamble composições de açúcar misturadas
EP2986345B1 (de) 2013-04-20 2017-06-14 Clariant International Ltd Zusammensetzung enthaltend ölkörper, fettsäuren, aminosäuretenside und n-methyl-n-acylglucamine
WO2014206555A2 (de) 2013-06-28 2014-12-31 Clariant International Ltd Verwendung von speziellen n-alkyl-n-acylglucaminen zur haarkonditionierung in haarwaschmitteln
ES2754727T3 (es) 2013-06-28 2020-04-20 Clariant Int Ltd Uso de N-alquil-N-acilglucaminas especiales en productos de limpieza para la piel
KR101660369B1 (ko) 2013-07-26 2016-09-27 삼성전자주식회사 초음파 장치 및 초음파 영상 생성 방법
CN103468382B (zh) 2013-08-30 2015-07-08 广州机械科学研究院有限公司 一种无硼、无氯、无甲醛微乳化切削液及其应用
CN103468362B (zh) 2013-09-12 2014-12-24 广西大学 铅及其合金箔材冷轧润滑剂
EP2870957A1 (en) 2013-11-07 2015-05-13 OTC GmbH Optically clear isethionate aqueous concentrate for cosmetic use
EP2876103A1 (de) 2013-11-20 2015-05-27 Clariant International Ltd. Teikristalline Glucamid-Zusammensetzungen und Verfahren zu deren Herstellung
DE102013018001A1 (de) 2013-11-29 2015-06-03 Clariant International Ltd. Verwendung von Glucamiden zur Verbesserung der Silikondeposition
DE102013018000A1 (de) 2013-11-29 2015-06-03 Clariant International Ltd. Konditioniershampoos enthaltend anionische Tenside, Glucamide und Fettalkohole
US20170002297A1 (en) 2013-12-03 2017-01-05 Clariant International Ltd. Glucamides In Syndet Soaps
DE202013011412U1 (de) 2013-12-20 2014-01-27 Clariant International Ltd. Glucamide zur Verbesserung der Silikondeposition
DE202013011413U1 (de) 2013-12-20 2014-01-27 Clariant International Ltd. Konditioniershampoos enthaltend anionische Tenside, Glucamide und Fettalkohole
DE202014008415U1 (de) 2014-02-19 2014-11-25 Clariant International Ltd. Wässrige Adjuvant-Zusammensetzung zur Wirkungssteigerung von Elektrolyt-Wirkstoffen
DE202014008418U1 (de) 2014-02-19 2014-11-14 Clariant International Ltd. Schaumarme agrochemische Zusammensetzungen
DE102014003367B4 (de) 2014-03-06 2017-05-04 Clariant International Ltd. Verwendung von N-Methyl-N-acylglucamin als Korrosionsinhibitor
DE102014003215A1 (de) 2014-03-06 2015-05-28 Clariant International Ltd. Korrosionsinhibierende Zusammensetzungen
DE202014008417U1 (de) 2014-04-30 2014-11-24 Clariant International Ltd. Tensidkonzentrate zur Förderung von Bodenbefeuchtung und Pflanzenwachstum
US9668956B2 (en) 2014-05-21 2017-06-06 Galaxy Surfactants, Ltd. Low viscous, sulfate-free cold-dispersible pearlescent concentrate
DE102014012020A1 (de) 2014-08-13 2016-02-18 Clariant International Ltd. VOC-arme Amine als oberflächenaktiver Bestandteil in Dispersionen
BR112017002945A2 (pt) 2014-09-19 2017-12-05 Clariant Int Ltd composições de fluido de serviço de poço e método para usar microemulsões como auxiliares de fluido de retorno
DE102014014124A1 (de) 2014-09-30 2016-03-31 Clariant International Ltd. Zusammensetzungen agrochemischer Wirkstoffe, deren Herstellung und Verwendung
ES2818799T3 (es) 2014-11-13 2021-04-14 Clariant Int Ltd Proceso continuo para la preparación de un tensioactivo en un reactor tubular
DE202015008050U1 (de) 2015-07-14 2015-12-08 Clariant International Ltd. N,N-Dialkylglucamine zur Stabilisierung von Polymerdispersionen
DE202015008045U1 (de) 2015-10-09 2015-12-09 Clariant International Ltd. Universelle Pigmentdispersionen auf Basis von N-Alkylglukaminen

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1301285A (zh) * 1998-05-14 2001-06-27 帝国化学工业公司 颜料的分散体
EP1676831A1 (en) * 2004-11-11 2006-07-05 Air Products and Chemicals, Inc. N,N-dialkylpolyhydroxyalkylamines
CN103717556A (zh) * 2011-07-28 2014-04-09 安格斯化学公司 氨基醇化合物及其作为漆和涂料的零或低voc添加剂的应用

Also Published As

Publication number Publication date
ES2769774T3 (es) 2020-06-29
WO2017060051A1 (de) 2017-04-13
EP3359605B1 (de) 2019-11-06
MX2018004258A (es) 2018-08-01
JP6677807B2 (ja) 2020-04-08
US20180291208A1 (en) 2018-10-11
DE202015008045U1 (de) 2015-12-09
JP2018536042A (ja) 2018-12-06
PT3359605T (pt) 2020-02-19
EP3359605A1 (de) 2018-08-15
DE102015219608A1 (de) 2017-04-13
US10920080B2 (en) 2021-02-16
CN107735460A (zh) 2018-02-23
DE102015219608B4 (de) 2018-05-03
BR112017022933A2 (pt) 2018-07-17

Similar Documents

Publication Publication Date Title
CN107735460B (zh) 基于n-烷基葡糖胺的通用颜料分散体
US7938900B2 (en) Water-based pigment preparation
KR101477322B1 (ko) 알릴 및 비닐 에터에 기초한 비이온성 첨가제를 갖는 수성 안료 제제
US8202361B2 (en) Aqueous pigment preparations comprising anionic additives based on allyl ether and vinyl ether
US7135067B2 (en) Water-based pigment dispersions, the production thereof and the use of the same
US7905955B2 (en) Aqueous pigment preparations
US9340662B2 (en) Fatty acid condensation products as dispersing agent in pigment preparations
US9303144B2 (en) Dispersing agent from renewable raw materials for binding agent-free pigment preparations
US20070131144A1 (en) Water-based pigment preparations
EP3337857B1 (en) Universal pigment preparations for point-of-sale use
US8383749B2 (en) Dry pigment preparations comprising non-ionic additives
US20150000566A1 (en) Inorganic pigment dispersions containing fatty acid ethanol amide ethoxylates and amines
US9187619B2 (en) Derivatives of sulphosuccinic acid as a dispersing agent in aqueous binder-free pigment preparations
US20160257825A1 (en) Anionic Fatty Amides Used As A Dispersant For Pigment Preparations
US20220275236A1 (en) Aqueous pigment preparations and their use in tinting systems and for dyeing coating agents
US9187614B2 (en) Binding agent free-pigment preparations containing phosphoric acid ester
US20130165580A1 (en) Sedimentation-Stabilized Water-Based Pigment Preparations
DE102013009706A1 (de) Mischungen anionischer und nichtionischer Tenside als Dispergiermittel für Pigmentpräparationen
DE102013009704A1 (de) Ethersulfate enthaltende, bindemittelfreie Pigmentpräparationen

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant