CN107078343B - 锂硫电池 - Google Patents
锂硫电池 Download PDFInfo
- Publication number
- CN107078343B CN107078343B CN201580059497.7A CN201580059497A CN107078343B CN 107078343 B CN107078343 B CN 107078343B CN 201580059497 A CN201580059497 A CN 201580059497A CN 107078343 B CN107078343 B CN 107078343B
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- lithium
- sulfonated
- positive electrode
- electrolyte
- sulfur
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0567—Liquid materials characterised by the additives
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/4235—Safety or regulating additives or arrangements in electrodes, separators or electrolyte
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/381—Alkaline or alkaline earth metals elements
- H01M4/382—Lithium
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/625—Carbon or graphite
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/411—Organic material
- H01M50/414—Synthetic resins, e.g. thermoplastics or thermosetting resins
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/431—Inorganic material
- H01M50/434—Ceramics
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/449—Separators, membranes or diaphragms characterised by the material having a layered structure
- H01M50/451—Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/449—Separators, membranes or diaphragms characterised by the material having a layered structure
- H01M50/457—Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/489—Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
- H01M50/497—Ionic conductivity
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/30—Batteries in portable systems, e.g. mobile phone, laptop
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Materials Engineering (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Cell Electrode Carriers And Collectors (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2014-0147907 | 2014-10-29 | ||
| KR20140147907 | 2014-10-29 | ||
| KR1020150115013A KR101725650B1 (ko) | 2014-10-29 | 2015-08-14 | 리튬 황 전지 |
| KR10-2015-0115013 | 2015-08-14 | ||
| PCT/KR2015/010998 WO2016068534A1 (ko) | 2014-10-29 | 2015-10-19 | 리튬 황 전지 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107078343A CN107078343A (zh) | 2017-08-18 |
| CN107078343B true CN107078343B (zh) | 2019-11-19 |
Family
ID=56026264
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201580059497.7A Active CN107078343B (zh) | 2014-10-29 | 2015-10-19 | 锂硫电池 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US10468650B2 (enExample) |
| EP (1) | EP3203567B1 (enExample) |
| JP (1) | JP6917888B2 (enExample) |
| KR (1) | KR101725650B1 (enExample) |
| CN (1) | CN107078343B (enExample) |
Families Citing this family (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101725650B1 (ko) | 2014-10-29 | 2017-04-12 | 주식회사 엘지화학 | 리튬 황 전지 |
| KR20180025581A (ko) * | 2016-09-01 | 2018-03-09 | 주식회사 엘지화학 | 리튬 폴리설파이드 첨가제를 포함하는 리튬-공기 전지용 전해질 및 이를 포함하는 리튬-공기 전지 |
| KR101984724B1 (ko) | 2016-09-09 | 2019-05-31 | 주식회사 엘지화학 | 리튬-황 전지 |
| US10468202B2 (en) * | 2017-02-21 | 2019-11-05 | National Synchrotron Radiation Research Center | Conductive paper electrode, electrochemical capacitor and method for manufacturing the same |
| KR101897206B1 (ko) | 2017-02-22 | 2018-09-11 | 한국과학기술연구원 | 기능화된 금속산화물 나노입자 및 그를 포함하는 리튬-황 전지용 음극 |
| KR102081773B1 (ko) * | 2017-04-14 | 2020-02-26 | 주식회사 엘지화학 | 고분자 고체 전해질 및 이를 포함하는 리튬 이차전지 |
| KR20200014325A (ko) * | 2017-06-02 | 2020-02-10 | 나노텍 인스트러먼츠, 인코포레이티드 | 형상 순응 알칼리 금속-황 전지 |
| US11335946B2 (en) * | 2017-06-02 | 2022-05-17 | Global Graphene Group, Inc. | Shape-conformable alkali metal-sulfur battery |
| US11394058B2 (en) | 2017-06-02 | 2022-07-19 | Global Graphene Group, Inc. | Method of producing shape-conformable alkali metal-sulfur battery |
| US10454141B2 (en) | 2017-06-30 | 2019-10-22 | Global Graphene Group, Inc. | Method of producing shape-conformable alkali metal-sulfur battery having a deformable and conductive quasi-solid electrode |
| KR20200023365A (ko) * | 2017-06-30 | 2020-03-04 | 나노텍 인스트러먼츠, 인코포레이티드 | 변형 가능한 전도성 준고체 전극을 갖는 형상 순응 알칼리 금속-황 전지 |
| KR20240149447A (ko) | 2017-10-04 | 2024-10-14 | 나비타스 시스템즈, 엘엘씨 | 리튬 황 배터리들을 위한 분리기 |
| KR102229449B1 (ko) * | 2017-10-26 | 2021-03-17 | 주식회사 엘지화학 | 분리막 및 이를 포함하는 리튬-황 전지 |
| KR101965192B1 (ko) | 2017-10-27 | 2019-04-03 | 이화여자대학교 산학협력단 | 금속 산화물 나노시트-황 나노복합체 및 이를 이용한 리튬-황 배터리 |
| KR102120278B1 (ko) * | 2017-11-24 | 2020-06-08 | 주식회사 엘지화학 | 리튬 전극 및 그를 포함하는 리튬 이차전지 |
| US10873083B2 (en) | 2017-11-30 | 2020-12-22 | Global Graphene Group, Inc. | Anode particulates or cathode particulates and alkali metal batteries |
| US11417884B2 (en) | 2017-12-20 | 2022-08-16 | Cornell University | Titanium disulfide-sulfur composites |
| CN108376783B (zh) * | 2018-02-09 | 2020-10-23 | 四川华昆能源有限责任公司 | 一种锂阳极表面保护涂层及其制备方法 |
| CN108493414B (zh) * | 2018-03-20 | 2020-05-01 | 吉林师范大学 | 一种锂硫电池正极材料及其制备方法 |
| CN108822586B (zh) * | 2018-05-23 | 2020-08-11 | 广东工业大学 | 一种改性钛酸钡材料的制备方法、电池隔膜和锂离子电池 |
| KR102071138B1 (ko) * | 2018-05-24 | 2020-01-29 | 전남대학교산학협력단 | 폴리설파이드가 잠입된 리튬-황 이차전지용 양극 |
| WO2020013766A1 (en) * | 2018-07-13 | 2020-01-16 | Nanyang Technological University | Electrochemically active interlayers for rechargeable batteries |
| JP6992692B2 (ja) * | 2018-07-19 | 2022-01-13 | ブラザー工業株式会社 | リチウム硫黄電池、及びリチウム硫黄電池の製造方法 |
| CN109088101B (zh) * | 2018-09-21 | 2020-10-02 | 中南大学 | 一种电解液及其应用 |
| CN109860476B (zh) * | 2018-12-11 | 2021-12-14 | 华南师范大学 | 锂硫电池用二氧化钛胶体改性隔膜及其制备方法和锂硫电池 |
| CN111933863A (zh) * | 2019-05-13 | 2020-11-13 | 河北金力新能源科技股份有限公司 | 一种锂硫电池隔膜及其制备方法和锂硫电池 |
| KR102485668B1 (ko) | 2019-05-17 | 2023-01-05 | 주식회사 엘지에너지솔루션 | 전기화학소자용 분리막 및 이를 포함하는 전기화학소자 |
| CN113812017B (zh) * | 2019-09-24 | 2025-01-17 | 株式会社Lg新能源 | 具有图案的锂硫二次电池用正极、其制造方法以及包含所述正极的锂硫二次电池 |
| CN113054247B (zh) * | 2019-12-27 | 2022-11-04 | 张家港市国泰华荣化工新材料有限公司 | 一种复合型固态电解质及其制备方法和固态锂硫电池 |
| CN111477815A (zh) * | 2020-04-03 | 2020-07-31 | 陈璞 | 多孔隔膜及其制备方法和应用 |
| CN111682209A (zh) * | 2020-05-22 | 2020-09-18 | 浙江中科玖源新材料有限公司 | 一种锂离子电池用粘结剂及其制备方法和锂离子电池 |
| CN111933997A (zh) * | 2020-08-10 | 2020-11-13 | 中山耀锂新能源科技有限公司 | 一种锂硫电池错位电芯结构 |
| CN112599754B (zh) * | 2021-01-09 | 2022-04-12 | 福州大学 | 一种锂硫电池用聚合物改性复合正极及其制备方法 |
| US12469851B2 (en) | 2021-04-01 | 2025-11-11 | Lyten, Inc. | Anode protective layer for lithium-sulfur cells |
| US20240194955A1 (en) * | 2021-04-15 | 2024-06-13 | Giner, Inc. | Electrolytes of rechargeable lithium-sulfur batteries and lithium-sulfur batteries including the same |
| US12009470B2 (en) | 2021-07-23 | 2024-06-11 | Lyten, Inc. | Cylindrical lithium-sulfur batteries |
| US11670826B2 (en) * | 2021-07-23 | 2023-06-06 | Lyten, Inc. | Length-wise welded electrodes incorporated in cylindrical cell format lithium-sulfur batteries |
| JP2023066787A (ja) * | 2021-10-29 | 2023-05-16 | 株式会社Abri | リチウム硫黄電池用正極およびリチウム硫黄電池 |
| FR3136594B1 (fr) * | 2022-06-14 | 2024-12-13 | Accumulateurs Fixes | Electrode négative pour élément électrochimique primaire au lithium |
| WO2025207951A1 (en) | 2024-03-27 | 2025-10-02 | Livent Lithium USA | Lithium-sulfur batteries with prelithiated cathodes |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102891274A (zh) * | 2012-10-22 | 2013-01-23 | 中国电子科技集团公司第十八研究所 | 纤维素膜在锂硫二次电池中的应用 |
| KR101338131B1 (ko) * | 2012-12-05 | 2013-12-06 | 에스케이 테크놀로지 이노베이션 컴퍼니 | 분리막, 그를 이용한 리튬 유황 이차전지 및 그의 제조 방법 |
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| JPH10284053A (ja) | 1997-04-10 | 1998-10-23 | Matsushita Electric Ind Co Ltd | 二次電池用電極およびそれを用いた二次電池、並びに二次電池用電極の製造方法 |
| JP3817045B2 (ja) | 1997-09-12 | 2006-08-30 | 四国化成工業株式会社 | 溶融塩型高分子電解質 |
| JP2938430B1 (ja) | 1998-03-17 | 1999-08-23 | 株式会社東芝 | リチウム二次電池 |
| KR100385357B1 (ko) | 2001-06-01 | 2003-05-27 | 삼성에스디아이 주식회사 | 리튬-황 전지 |
| KR100454030B1 (ko) * | 2002-08-07 | 2004-10-20 | 삼성에스디아이 주식회사 | 리튬-황 전지용 양극, 이의 제조 방법 및 이를 포함하는리튬-황 전지 |
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Also Published As
| Publication number | Publication date |
|---|---|
| KR101725650B1 (ko) | 2017-04-12 |
| EP3203567A4 (en) | 2018-03-28 |
| JP6917888B2 (ja) | 2021-08-11 |
| US10468650B2 (en) | 2019-11-05 |
| CN107078343A (zh) | 2017-08-18 |
| EP3203567A1 (en) | 2017-08-09 |
| KR20160051574A (ko) | 2016-05-11 |
| EP3203567B1 (en) | 2019-02-20 |
| US20170331150A1 (en) | 2017-11-16 |
| JP2017535036A (ja) | 2017-11-24 |
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