CN107007513A - Topical composition and skin cleaning mask with dispel blackhead and pore refining effect - Google Patents
Topical composition and skin cleaning mask with dispel blackhead and pore refining effect Download PDFInfo
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- CN107007513A CN107007513A CN201710388992.3A CN201710388992A CN107007513A CN 107007513 A CN107007513 A CN 107007513A CN 201710388992 A CN201710388992 A CN 201710388992A CN 107007513 A CN107007513 A CN 107007513A
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- pore refining
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/732—Starch; Amylose; Amylopectin; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/007—Preparations for dry skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/008—Preparations for oily skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/48—Thickener, Thickening system
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
- A61K2800/5922—At least two compounds being classified in the same subclass of A61K8/18
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/70—Biological properties of the composition as a whole
- A61K2800/72—Hypo-allergenic
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Abstract
There is dispel blackhead and the topical composition and skin cleaning mask of pore refining effect the invention discloses a kind of, aiming to provide one kind does not stimulate gently, the chip and grease in dissolving pore can effectively be softened, remove the blackhead in skin, promote skin without blocking, pore refining, while the topical composition of skin moisture is supplemented, and the skin cleaning mask containing said composition;Technical points, the topical composition mainly includes the composition of following weight parts:20 45 parts of plant compositions, 20 30 parts of flowers water, 5 20 parts of polyalcohol, 5 15 parts of deionized water;The skin cleaning mask has dispel blackhead and the 20wt% of topical composition 5 of pore refining effect containing above-mentioned;Belong to cosmetic technical field.
Description
Technical field
The present invention relates to a kind of topical composition, specifically a kind of external application with dispel blackhead and pore refining effect
Composition, is further related to containing this skin cleaning mask and its preparation side with dispel blackhead and the topical composition of pore refining effect
Method, belongs to cosmetic technical field.
Background technology
Blackhead is mainly one kind " bolt " the sample thing being made up of sebum, cell bits and bacterium, is blocked at hair follicle opening and is formed,
Plus the dust in air, dirt and oxidation, make a gradually blackening of its ingress of air, referred to as blackhead.Blackhead is hard
Carburetion fat obturator, typically occurs in the positions such as forehead, the nose of face, and when grease gland swashs by intermuscular needling, pore is full of more
Remaining grease and when causing obstruction, in nose and its peripheral part, often have greasy sensation.These greases are eventually hard
Change, the oxidized rear dot as black, these dots are exactly the grease obturator referred to as blackhead.The fell of usual long blackhead
Skin is all relatively rough, and pore is also very big, has many grease grains to block the pore opened, also there is hard one by one inside skin
Pimple, be always induced into small pox repeatedly, serious more has rough situation.The appearance of blackhead be personal skin quality with
Outside environmental elements are combined and caused, and any age, the people of any skin quality all occur the possibility of blackhead.Therefore, blackhead is
The problem of perplexing the urgent need to resolve of numerous people seeking beauties.
It is main by the following method that blackhead is dispelled at present:1. it will be ground using abrasive particle exposed to the blackhead of skin surface
Remove, this method effect is poor, it is impossible to reach the purpose of dredging pore;2. blackhead is pulled out from pore by viscous force, most
Common is exactly various nose patches, and this method is pullled skin, and pore mouthful relaxation can be caused to become big, restrained not in time after,
Blackhead can faster occur;3. blackhead emulsification softening is allowed easily to be discharged from pore by smearing plus fumigating, this method uses ratio
Cumbersome, many beauty parlors provide this service, and complex steps, and the time is longer, and being finished skin can be dry.Also have one on the market
The product of a little blackheads of dispelling, certain blackhead of dispelling that played to human body skin that can be in various degree is acted on and beautification function, but is contained
Some compositions skin can be had undesirable effect on the contrary, such as chemical bacteriostatic agent can destroy skin normal flora, and chloramphenicol etc. swashs
Element can make skin produce drug dependence, and the exfoliating element such as salicylic acid and tartaric acid easily causes allergic, and long-term use can cause
Skin vicious circle, fat secretion is more vigorous.
The content of the invention
For above-mentioned weak point of the prior art, the present invention, which is provided, a kind of has dispel blackhead and pore refining effect
Topical composition, the topical composition includes planting as made from Salvia japonica, sweet mary, Juniperus communis fruit, Saponaria officinalis and hypericum perforatum
Compositions, and flowers water, polyalcohol and deionized water, it is not stimulated gently, can effectively soften the chip in dissolving pore
And grease, it is easier to the blackhead in skin is removed, promotes skin without blocking, pore refining, while supplementing skin moisture.
The second object of the present invention is to provide a kind of skin cleaning mask containing above-mentioned topical composition.
To realize the purpose of the present invention, first technical scheme that the present invention is used is as follows:
It is a kind of that there is dispel blackhead and the topical composition of pore refining effect, include the composition of following weight parts: 20-45
Part plant composition, 20-30 parts of flowers water, 5-20 parts of polyalcohol, 5-15 parts of deionized water;Wherein described plant group
Compound is by 1-5 parts of 10-15 parts of Salvia japonica, 5-10 parts of sweet mary, 5-10 parts of Juniperus communis fruit, 1-5 parts of Saponaria officinalis and hypericum perforatum
Mixing is extracted obtained.
Further, it is above-mentioned it is a kind of there is dispel blackhead and the topical composition of pore refining effect, the flowers water is
In witch hazel water, in addition to honeysuckle flowers water, pot marigold water, Jasmine water any one or it is a variety of.
Further, it is above-mentioned it is a kind of there is dispel blackhead and the topical composition of pore refining effect, the polyalcohol is
Any one or more combination in butanediol, propane diols, dipropylene glycol.
Further, it is above-mentioned a kind of to there is dispel blackhead and the topical composition of pore refining effect, the plant society
Thing is by made from following methods:
(1) bulk drug is weighed according to weight, mixes and smash to 60-100 mesh;
(2) mixture after being crushed in (1) is added in 70-80% ethanol, the proportioning of mixture and ethanol is 1g:
10-15mL, uses frequency for 20-40kHZ ultrasonication 30-45min, and temperature is 60-70 DEG C, and filtrate is collected by filtration, from
The heart collects supernatant, and suction filtration collects filtrate;
(3) filtrate for obtaining step (2) is placed in evaporator, negative pressure is taken out to -0.08~-0.1Mpa, in 45-55 DEG C
Under conditions of carry out vacuum distillation so that ethanol is steamed completely, obtains plant composition.
Filtering is filtered using gauze wherein described in step (2), and the gauze is 100-200 mesh;The centrifugation turns
Number is 5000r/min, and centrifugation time is 10-15min;Suction filtration is carried out using filter aid diatomite in the suction filtration.
The topical composition of the present invention is included by Salvia japonica, sweet mary, Juniperus communis fruit, the five kinds of plants of Saponaria officinalis and hypericum perforatum
Obtained plant composition, synergy are extracted in thing mixing, so as to play the chip and grease in softening dissolving pore, go to allowance for bark
Blackhead in skin, promotes skin without blocking, pore refining reduces the effect to skin irritation.Effect of wherein five kinds plants
It is as follows:
Salvia japonica:There is convergence, cleaning, antibacterial, anti-oxidant and skin of releiving.It can help to balance sebum generation
Skin overdrying can be eliminated or excessively oily simultaneously.
Fragrant honeybee leaf:There is antibacterium, anti-inflammatory, calmness and skin of releiving.Its energy while scytitis is releived
Help to treat the harmful bacteria on skin.
Juniperus communis fruit:Have effects that to promote immune system.
Radices saponariae:It is rich in saponin(e, is referred to as natural detergent, with outstanding skin cleaning efficacy.
Hypericum perforatum:Discharge with liquid and discarded object in skin temperature rise effect and promotion organization.It has very simultaneously
Good antibiotic effect, can effectively treat acne and other scytitises.
The composition of the present invention also includes flowers water, wherein witch hazel water, with anti-irritant, convergence, cleaning, soften and
Releive effect of skin, it can help skin hydration to act on and stablize the barrier action of skin;Honeysuckle flowers water is antibacterial, convergence, clear
Hot merit effect is notable, while the effects such as having promotion wound healing and anti-acne;Pot marigold water can sterilize convergence wound, administer inflammation,
Dark sore, pore is thick, prevents the generation of scar, moreover it is possible to calm skin, improves sensitiveness skin quality, promotes the metabolism of skin,
Especially for dry skin, there is the moisturizing effect of height;Jasmine water can effective pore refining, can be with the grease of balance skin
Skin is cleaned in secretion, help, is driven away greasy and is gone acne, also with moisturizing and the effect for nursing one's health dry skin.
Polyalcohol in the topical composition of the present invention can effectively dissolve the active component in plant extracts, promote activity
The absorption of composition, also with certain antiseptic effect, while moisturizing and Glycerin can also be played a part of.
Inventor passes through multiple experiment, filters out Salvia japonica, sweet mary, Juniperus communis fruit, Saponaria officinalis and hypericum perforatum five
Plant is planted, and obtained plant composition is extracted according to certain ratio mixing, then is reasonably matched somebody with somebody with flowers water, polyalcohol
Than carrying out a certain degree of dilution, finally give the present invention has dispel blackhead and the topical composition of pore refining effect.
The latter solution that the present invention is provided is to provide has the clean of dispel blackhead and pore refining effect containing above-mentioned
Skin facial mask, it has dispel blackhead and the topical composition of pore refining effect containing 5-20wt%.
Specifically, above-mentioned is a kind of with dispel blackhead and the skin cleaning mask of pore refining effect, by following mass percents
Raw material be made:
Topical composition 5-20% with dispel blackhead and pore refining effect
Modified corn starch 1.5-3%
Double starch phosphate 1-3%
Acrylic acid (ester) analog copolymer 1.8-3.5%
Triethanolamine 0.18-0.35%
Dipropylene glycol 2-6%
Kaolin 40-56%
Extra large mud 1-5%
Cocoamidopropyl betaine 3.5-7%
O- cymene -5- alcohol 0.05-0.1%
Preservative 0.3-0.6%
Deionized water is to 100%.
The present invention also provides a kind of above-mentioned preparation method with dispel blackhead and the skin cleaning mask of pore refining effect, bag
Include following steps:
(1) deionized water is first heated to 80-90 DEG C, adds modified corn starch and the stirring gelatinization of double starch phosphates
Completely, acrylic acid (ester) analog copolymer dispersed with stirring is added uniformly, the triethanolamine high temperature for adding 1/3 consumption is neutralized;
(2) when the mixture in step (1) is cooled to 40-50 DEG C or so, adding has dispel blackhead and pore refining work(
The topical composition of effect stirs, and adds in the triethanolamine of remaining 2/3 consumption with completely, then adds dipropylene glycol
And preservative stirs;
(3) kaolin and extra large mud are added in the mixture that whipping step (2) is obtained, with product viscosity increase by
Mixing speed is gradually improved, Cocoamidopropyl betaine is stirring evenly and then adding into completely, o- cymene -5- alcohol is eventually adding and anti-
Rotten agent stirs, and cools to 38 DEG C with bottom discharge.
The present invention's has dispel blackhead and the topical composition of pore refining effect, and its application is not limited in clean skin face
Film, can also be added to skin-care cosmetics, such as facial treatment milk, skin care cream, skin care aqua, skin care gel, facial treatment mask
Deng;Or cleaning class cosmetics, such as mildy wash, face cleaning cream, face cleaning gel.
In the present invention, the described topical composition with dispel blackhead and pore refining effect is mutually added as low temperature addition
It is added in the cosmetics.During concrete application, each composition in the composition of the present invention can respectively be added, can also be pre-mixed system
It is added to after standby in cosmetics, preferably is pre-mixed to add after preparation by the composition of the present invention and uses.
Compared with prior art, what the present invention was provided has dispel blackhead and the topical composition and clean skin of pore refining effect
Facial mask, its advantage is as follows:
1) topical composition of the invention is not stimulated gently, mainly based on a variety of natural plant extracts, and and flowers
Water, polyalcohol synergy, can soften the chip and grease in dissolving pore, it is easier to remove the blackhead in skin, promote skin
Skin is without blocking, pore refining.Flowers water auxiliary synergy, controls fat secretion, restrains, releives, calm skin, reduces sensitiveness,
Evening Primerose Oil effect;Polyalcohol can help the active component in effectively dissolving plant extracts, promote the absorption of active component,
Also there is certain antiseptic effect, while also acting as moisturizing and the effect of Glycerin.
2) skin cleaning mask collection of the invention is dispelled blackhead, cleaning, three kinds of effects of skin care, can effectively be nursed one's health skin grease, be restrained
Releive skin, reach comprehensive decontamination, the effect of replenishing water and preserving moisture, make skin recover clean, a variety of need of consumers in general can be met
Ask, with good application prospect and market prospects.
3) skin cleaning mask product formula of the invention is simplified, and its formula system is different from existing mud film product, is not one
As emulsification system, without compositions such as emulsifying agent, grease, thickeners, only by acrylic acid (ester) analog copolymer and modified corn
Starch carrys out thick stabilization system, but product stability is good;The functional component contained is in addition to plant composition, without other
The functional component of synthesis, therefore product is gentleer, will not cause stimulation.
Embodiment
The beneficial effect for describing the implementation process of the present invention in detail below by way of specific embodiment and producing, it is intended to which help is read
Reader more fully understand the present invention essence and feature, not as to this case can practical range restriction.
Flowers water in the present invention, can directly be extracted by the way of distillation and obtained, and can also be obtained by commercially available purchase.
Embodiment 1
It is a kind of with dispel blackhead and the topical composition of pore refining effect that the present invention is provided, and is made up of following components:
20g plant compositions, 30g witch hazel water, 5g butanediols, 15g deionized waters.
Wherein described plant composition is made by following methods:
(1) 1 part of 10 parts of Salvia japonica, 10 parts of sweet mary, 5 parts of Juniperus communis fruit, 5 parts of Saponaria officinalis and hypericum perforatum, mixing are weighed
And smash to 60 mesh;
(2) mixture in (1) is added in 80% ethanol, the proportioning of mixture and ethanol is 1g:10mL, is adopted
The ultrasonication 30min for being 40kHZ with frequency, temperature is 70 DEG C, and filtrate, 5000r/ are collected using the filtered through gauze of 100 mesh
Min centrifugations 15min collects supernatant, carries out suction filtration suction filtration using filter aid diatomite, collects filtrate;
(3) filtrate for obtaining step (2) is placed in evaporator, takes out negative pressure -0.08Mpa, is carried out under conditions of 45 DEG C
Vacuum distillation so that ethanol is steamed completely, obtains plant composition.
Embodiment 2
It is a kind of with dispel blackhead and the topical composition of pore refining effect that the present invention is provided, and is made up of following components:
32g plant compositions, 25g witch hazel water, 12g dipropylene glycols, 10g deionized waters.
Wherein described plant composition is made by following methods:
(1) 3 parts of 12 parts of Salvia japonica, 8 parts of sweet mary, 8 parts of Juniperus communis fruit, 3 parts of Saponaria officinalis and hypericum perforatum are weighed, mixing is simultaneously
Smash to 80 mesh;
(2) mixture in (1) is added in 75% ethanol, the proportioning of mixture and ethanol is 1g:13mL, is adopted
The ultrasonication 40min for being 30kHZ with frequency, temperature is 65 DEG C, and filtrate, 5000r/ are collected using the filtered through gauze of 150 mesh
Min centrifugations 13min collects supernatant, carries out suction filtration suction filtration using filter aid diatomite, collects filtrate;
(3) filtrate for obtaining step (2) is placed in evaporator, takes out negative pressure -0.09Mpa, is carried out under conditions of 50 DEG C
Vacuum distillation so that ethanol is steamed completely, obtains plant composition.
Embodiment 3
It is a kind of with dispel blackhead and the topical composition of pore refining effect that the present invention is provided, and is made up of following components:
45g plant compositions, 10g witch hazel water, 10g honeysuckle flowers water, 20g propane diols, 5g deionized waters.
Wherein described plant composition is made by following methods:
(1) 5 parts of 15 parts of Salvia japonica, 5 parts of sweet mary, 10 parts of Juniperus communis fruit, 1 part of Saponaria officinalis and hypericum perforatum, mixing are weighed
And smash to 100 mesh;
(2) mixture in (1) is added in 70% ethanol, the proportioning of mixture and ethanol is 1g:15mL, is adopted
The ultrasonication 45min for being 20kHZ with frequency, temperature is 60 DEG C, and filtrate, 5000r/ are collected using the filtered through gauze of 200 mesh
Min centrifugations 10min collects supernatant, carries out suction filtration suction filtration using filter aid diatomite, collects filtrate;
(3) filtrate for obtaining step (2) is placed in evaporator, takes out negative pressure -0.1Mpa, is subtracted under conditions of 55 DEG C
Pressure distillation so that ethanol is steamed completely, obtains plant composition.
Embodiment 4
It is a kind of with dispel blackhead and the topical composition of pore refining effect that the present invention is provided, and is made up of following components:
30g plant compositions, 18g witch hazel water, 7g Jasmine water, 5g butanediols, 5g dipropylene glycols, 12g deionized waters.
Wherein described plant composition is made by following methods:
(1) 2 parts of 11 parts of Salvia japonica, 9 parts of sweet mary, 6 parts of Juniperus communis fruit, 4 parts of Saponaria officinalis and hypericum perforatum are weighed, mixing is simultaneously
Smash to 80 mesh;
(2) mixture in (1) is added in 70% ethanol, the proportioning of mixture and ethanol is 1g:12mL, is adopted
The ultrasonication 40min for being 30kHZ with frequency, temperature is 65 DEG C, and filtrate, 5000r/ are collected using the filtered through gauze of 100 mesh
Min centrifugations 10min collects supernatant, carries out suction filtration suction filtration using filter aid diatomite, collects filtrate;
(3) filtrate for obtaining step (2) is placed in evaporator, takes out negative pressure -0.08Mpa, is carried out under conditions of 55 DEG C
Vacuum distillation so that ethanol is steamed completely, obtains plant composition.
Embodiment 5
It is a kind of with dispel blackhead and the topical composition of pore refining effect that the present invention is provided, and is made up of following components:
40g plant compositions, 10g witch hazel water, 6g honeysuckle flowers water, 6g pot marigold water, 10g butanediols, 4g propane diols, 4g double third is sweet
Alcohol, 8g deionized waters.
Wherein described plant composition is made by following methods:
(1) 4 parts of 14 parts of Salvia japonica, 6 parts of sweet mary, 9 parts of Juniperus communis fruit, 2 parts of Saponaria officinalis and hypericum perforatum are weighed, mixing is simultaneously
Smash to 100 mesh;
(2) mixture in (1) is added in 75% ethanol, the proportioning of mixture and ethanol is 1g:10mL, is adopted
The ultrasonication 30min for being 40kHZ with frequency, temperature is 70 DEG C, and filtrate, 5000r/ are collected using the filtered through gauze of 200 mesh
Min centrifugations 15min collects supernatant, carries out suction filtration suction filtration using filter aid diatomite, collects filtrate;
(3) filtrate for obtaining step (2) is placed in evaporator, takes out negative pressure -0.1Mpa, is subtracted under conditions of 45 DEG C
Pressure distillation so that ethanol is steamed completely, obtains plant composition.
Embodiment 6
It is a kind of with dispel blackhead and the topical composition of pore refining effect that the present invention is provided, and is made up of following components:
32g plant compositions, 7g witch hazel water, 7g honeysuckle flowers water, 7g pot marigold water, 5g Jasmine water, 4g butanediols, 4g the third two
Alcohol, 4g dipropylene glycols, 10g deionized waters.
Wherein described plant composition is made by following methods:
(1) 3 parts of 12 parts of Salvia japonica, 7 parts of sweet mary, 8 parts of Juniperus communis fruit, 3 parts of Saponaria officinalis and hypericum perforatum are weighed, mixing is simultaneously
Smash to 60 mesh;
(2) mixture in (1) is added in 75% ethanol, the proportioning of mixture and ethanol is 1g:13mL, is adopted
The ultrasonication 40min for being 30kHZ with frequency, temperature is 65 DEG C, and filtrate, 5000r/ are collected using the filtered through gauze of 100 mesh
Min centrifugations 10min collects supernatant, carries out suction filtration suction filtration using filter aid diatomite, collects filtrate;
(3) filtrate for obtaining step (2) is placed in evaporator, takes out negative pressure -0.08Mpa, is carried out under conditions of 50 DEG C
Vacuum distillation so that ethanol is steamed completely, obtains plant composition.
Embodiment 7
It is a kind of with dispel blackhead and the topical composition of pore refining effect that the present invention is provided, and is made up of following components:
25g plant compositions, 15g witch hazel water, 13g pot marigold water, 4g butanediols, 4g propane diols, 10g deionized waters.
Wherein described plant composition is made by following methods:
(2) 4 parts of 10 parts of Salvia japonica, 8 parts of sweet mary, 8 parts of Juniperus communis fruit, 2 parts of Saponaria officinalis and hypericum perforatum are weighed, mixing is simultaneously
Smash to 80 mesh;
(2) mixture in (1) is added in 70% ethanol, the proportioning of mixture and ethanol is 1g:14mL, is adopted
The ultrasonication 38min for being 35kHZ with frequency, temperature is 70 DEG C, and filtrate, 5000r/ are collected using the filtered through gauze of 200 mesh
Min centrifugations 15min collects supernatant, carries out suction filtration suction filtration using filter aid diatomite, collects filtrate;
(3) filtrate for obtaining step (2) is placed in evaporator, takes out negative pressure -0.1Mpa, is subtracted under conditions of 45 DEG C
Pressure distillation so that ethanol is steamed completely, obtains plant composition.
Embodiment 8
It is a kind of with dispel blackhead and the skin cleaning mask of pore refining effect that the present invention is provided, by the raw material of following weight number
It is made:Prepared by embodiment 1 has dispel blackhead and the topical composition 5g of pore refining effect, modified corn starch 3g, double shallow lakes
Powder phosphate 1g, acrylic acid (ester) analog copolymer 1.8g, triethanolamine 0.18g, dipropylene glycol 6g, kaolin 56g, extra large mud
1g, Cocoamidopropyl betaine 7g, o- cymene -5- alcohol 0.1g, preservative 0.3g, deionized water to 100g.
Embodiment 9
It is a kind of with dispel blackhead and the skin cleaning mask of pore refining effect that the present invention is provided, by the raw material of following weight number
It is made:Prepared by embodiment 2 has dispel blackhead and the topical composition 13g of pore refining effect, modified corn starch 2g, double shallow lakes
Powder phosphate 2g, acrylic acid (ester) analog copolymer 2.5g, triethanolamine 0.25g, dipropylene glycol 4g, kaolin 48g, extra large mud
2g, Cocoamidopropyl betaine 5.5g, o- cymene -5- alcohol 0.08g, preservative 0.4g, deionized water to 100g.
Embodiment 10
It is a kind of with dispel blackhead and the skin cleaning mask of pore refining effect that the present invention is provided, by the raw material of following weight number
It is made:Prepared by embodiment 3, which have, dispels blackhead and the topical composition 20g of pore refining effect, modified corn starch 1.5g, double
Starch phosphate 3g, acrylic acid (ester) analog copolymer 3.5g, triethanolamine 0.35g, dipropylene glycol 2g, kaolin 40g, extra large mud
5g, Cocoamidopropyl betaine 3.5g, o- cymene -5- alcohol 0.05g, preservative 0.6g, deionized water to 100g.
Embodiment 11
It is a kind of with dispel blackhead and the skin cleaning mask of pore refining effect that the present invention is provided, by the raw material of following weight number
It is made:Prepared by embodiment 4, which have, dispels blackhead and the topical composition 12g of pore refining effect, modified corn starch 1.5g, double
Become silted up in starch phosphate 2.5g, acrylic acid (ester) analog copolymer 2.8g, triethanolamine 0.28g, dipropylene glycol 5g, kaolin 46g, sea
Mud 3.5g, Cocoamidopropyl betaine 5.0g, o- cymene -5- alcohol 0.07g, preservative 0.5g, deionized water to 100g.
Embodiment 12
It is a kind of with dispel blackhead and the skin cleaning mask of pore refining effect that the present invention is provided, by the raw material of following weight number
It is made:Prepared by embodiment 5, which have, dispels blackhead and the topical composition 8g of pore refining effect, modified corn starch 2.5g, double
Starch phosphate 1g, acrylic acid (ester) analog copolymer 3.0g, triethanolamine 0.3g, dipropylene glycol 6g, kaolin 52g, extra large mud
4g, Cocoamidopropyl betaine 4.5g, o- cymene -5- alcohol 0.06g, preservative 0.6g, deionized water to 100g.
Embodiment 13
It is a kind of with dispel blackhead and the skin cleaning mask of pore refining effect that the present invention is provided, by the raw material of following weight number
It is made:Prepared by embodiment 6, which have, dispels blackhead and the topical composition 11g of pore refining effect, modified corn starch 2.0g, double
Become silted up in starch phosphate 1.5g, acrylic acid (ester) analog copolymer 2.2g, triethanolamine 0.22g, dipropylene glycol 4g, kaolin 50g, sea
Mud 1.5g, Cocoamidopropyl betaine 5.2g, o- cymene -5- alcohol 0.07g, preservative 0.5g, deionized water to 100g.
Embodiment 14
It is a kind of with dispel blackhead and the skin cleaning mask of pore refining effect that the present invention is provided, by the raw material of following weight number
It is made:Prepared by embodiment 7, which have, dispels blackhead and the topical composition 16g of pore refining effect, modified corn starch 1.8g, double
Become silted up in starch phosphate 2.2g, acrylic acid (ester) analog copolymer 2.0g, triethanolamine 0.20g, dipropylene glycol 3g, kaolin 44g, sea
Mud 1.2g, Cocoamidopropyl betaine 6.0g, o- cymene -5- alcohol 0.09g, preservative 0.4g, deionized water to 100g.
The preparation method of embodiment 8-14 skin cleaning mask is as follows:
(1) deionized water is first heated to 80-90 DEG C, adds modified corn starch and the stirring gelatinization of double starch phosphates
Completely, acrylic acid (ester) analog copolymer dispersed with stirring is added uniformly, the triethanolamine high temperature for adding 1/3 consumption is neutralized;
(2) when the mixture in step (1) is cooled to 40-50 DEG C or so, adding has dispel blackhead and pore refining work(
The topical composition of effect stirs, and adds in the triethanolamine of remaining 2/3 consumption with completely, then adds dipropylene glycol
And preservative stirs;
(3) kaolin and extra large mud are added in the mixture that whipping step (2) is obtained, with product viscosity increase by
Cumulative plus mixing speed, is stirring evenly and then adding into Cocoamidopropyl betaine completely, is eventually adding o- cymene -5- alcohol and anti-
Rotten agent stirs, and cools to 38 DEG C with bottom discharge.
Embodiment 8-14 skin cleaning mask continuous constant temperature 30 days under the conditions of 48 ± 1 DEG C (high temperature), -15 ± 1 DEG C respectively
24h, which colds and heat succeed each other, under the conditions of continuously being freezed 30 days, 48 ± 1 DEG C and -15 ± 1 DEG C under the conditions of (low temperature) circulates 30 days, then recovery room
Temperature keeps more than 8h, is thinning, retrogradation, layering occur, separate out particle or other inhomogenous phenomenons, illustrates the tool of the present invention
The skin cleaning mask for having dispel blackhead and pore refining effect has good stability.
Comparative example 1
A kind of to have dispel blackhead and the topical composition of pore refining effect, wherein plant composition only includes Salvia japonica 12
The preparation method be the same as Example 6 of part, 7 parts of sweet mary, other raw materials and plant composition.
Comparative example 2
A kind of to have dispel blackhead and the topical composition of pore refining effect, wherein plant composition only includes Juniperus communis fruit
8 parts, 3 parts of 3 parts of Saponaria officinalis and hypericum perforatum, the preparation method be the same as Example 6 of other raw materials and plant composition.
Comparative example 3
It is a kind of that there is dispel blackhead and the topical composition of pore refining effect, it is made up of following components:32g plant societys
Thing, 4g butanediols, 4g propane diols, 4g dipropylene glycols, 10g deionized waters.The wherein preparation method be the same as Example of plant composition
6。
Comparative example 4
It is a kind of that there is dispel blackhead and the skin cleaning mask of pore refining effect, there is dispel blackhead and contraction hair using comparative example 1
Prepared by the topical composition equivalent substitution embodiment 6 of hole effect has dispel blackhead and the topical composition of pore refining effect,
Other compositions and preparation method be the same as Example 9.
Comparative example 5
It is a kind of that there is dispel blackhead and the skin cleaning mask of pore refining effect, there is dispel blackhead and contraction hair using comparative example 2
Prepared by the topical composition equivalent substitution embodiment 6 of hole effect has dispel blackhead and the topical composition of pore refining effect,
Other compositions and preparation method be the same as Example 9.
Comparative example 6
It is a kind of that there is dispel blackhead and the skin cleaning mask of pore refining effect, there is dispel blackhead and contraction hair using comparative example 3
Prepared by the topical composition equivalent substitution embodiment 6 of hole effect has dispel blackhead and the topical composition of pore refining effect,
Other compositions and preparation method be the same as Example 9.
Comparative example 7
A kind of skin cleaning mask, has dispel blackhead and the topical composition of pore refining effect without prepared by embodiment 6, its
His composition and preparation method be the same as Example 9.
Efficacy test
The topical composition of test example 1 dissolves the ability of blackhead
Experimental method:
Blackhead is extracted from mankind volunteer using acne extractor, the plate of 24 or 96 orifice plates is placed them in
In, and it is immersed in about 100 microlitres of every kind of test sample, at room temperature lasting 24h, gray card is used below, and use
Microscope is measured in the case of without stirring under 40 times.Plate Parafilm is covered to avoid evaporation, and in 24h time shifts
Except each test and is dried overnight it at solution.The amount of the blackhead of dissolving is classified according to 1-7 scale, and 1 is insoluble, and 7 have been
Fully dissolved, it is specific as shown in table 1.It the results are shown in Table 2.
The grading scale of table 1
The result of table 2
Test sample | 24h result |
The composition of embodiment 1 | 5.90±0.35 |
The composition of embodiment 2 | 5.94±0.32 |
The composition of embodiment 3 | 6.00±0.21 |
The composition of embodiment 4 | 6.13±0.28 |
The composition of embodiment 5 | 6.20±0.35 |
The composition of embodiment 6 | 6.38±0.30 |
The composition of embodiment 7 | 6.09±0.26 |
The composition of comparative example 1 | 4.13±0.15 |
The composition of comparative example 2 | 4.72±0.22 |
The composition of comparative example 3 | 5.05±0.25 |
Deionized water | 2.00±0.03 |
It can be seen from the result of table 2, composition of the invention has the ability of good dissolving blackhead.Comparative example 1 and 2 groups
The ability of the dissolving blackhead of compound is significantly lower than the composition of embodiment 6, illustrates Salvia japonica, sweet mary, Juniperus communis fruit, Saponaria officinalis
Mutually acted synergistically with hypericum perforatum, effectively the chip and grease in softening and dissolving pore, reach the purpose for blackhead of dispelling;Contrast
The ability of the dissolving blackhead of the composition of example 3 is significantly lower than the composition of embodiment 6, illustrates that there is flowers water synergy dissolving to dispel black
The ability of head.The topical composition excitant of test example 2 is evaluated
The external eye irritations of SN/T 2329-2009-chick chorioallantoic membrane experiment (HET-CAM methods) is quoted, evaluates and implements
The excitant of example 1-6 composition and comparative example 1-3 composition.As a result show, embodiment 1- 6 composition and right
Terminal scoring is 0 obtained by ratio 1-3 composition, illustrates the topical composition of the present invention without eye irritation.
The skin cleaning mask efficacy assessments of test example 3
Part I:
1st, test sample:Skin cleaning mask prepared by skin cleaning mask and comparative example 4-7 prepared by Example 9,11,13;
2nd, experimental method:The personnel 70 at age 22-35 Sui are selected, each half of masculinity femininity, skin has obvious blackhead, nothing
Any skin disease and allergic history, are divided into 7 groups, every group of 10 people, and every group is smeared different test samples respectively.First 2 days of test
Can not use must not use any cosmetics beyond test sample in any cosmetics, process of the test.Subject is clean with clear water
Behind face, test sample is uniformly applied to face, after 10-15 minutes, is cleaned with clear water, dries, weekly using 3-4 times, continuously make
With two months.
Corneometer CM825 are tested before and using follow-up and survey respectively after two months using moisture content of skin
Once, selection subject's nose areas is as tested region, and measurement 3 times, average every time, the moisture of analyzing skin for examination
Situation of change, concrete outcome is shown in Table 3.
Using skin image analyzer test skin pore aperture, selection nose areas makes respectively as test position
Measured after two months with preceding and use.Selection is imaged to same position pore, and analysis draws pore pore size, for commenting
Estimate the effect of present composition pore refining, concrete outcome is shown in Table 4.
Table 3 uses front and rear moisture content of skin change (μ g/cm2)
As shown in Table 3, using embodiment 9,11,13 skin cleaning mask after two months, the water content of nose areas substantially increases
Plus, 8.80 are all higher than using front and rear difference, and use after the skin cleaning mask of embodiment 9,11,13, skin moisture content change
Difference is substantially into increased trend, wherein with the moisturizing best results of the skin cleaning mask of embodiment 13, using front and rear nose areas
Water content difference reaches 9.66, illustrates plant composition and a variety of flowers water, polyalcohol in the topical composition that the present invention is added
The moisturizing moisturizing effect of compounding will be substantially better than the effect with single flowers water and polyalcohol compounding.It is clean with embodiment 9,11,13
Skin facial mask is compared, and lacks some components in the topical composition in comparative example 4-6 skin cleaning mask formulas, its replenishing water and preserving moisture effect is equal
Less than embodiment 9,11,13, illustrate the Multiple components synergy in the topical composition of the present invention, can be only achieved good benefit
Water moistening effect.Comparative example 7 is then entirely free of plant composition, and replenishing water and preserving moisture effect is substantially less than embodiment 9,11,13, explanation
The topical composition and skin cleaning mask of dispel blackhead and the pore refining of the present invention are with good replenishing water and preserving moisture effect.
Table 4 uses front and rear skin pore aperture
As shown in Table 4, using embodiment 9,11,13 skin cleaning mask after two months, skin pore aperture reduces, and uses
After the skin cleaning mask of comparative example 7, skin pore aperture is substantially unchanged, illustrates to add in skin cleaning mask of the present invention and skin cleaning mask
Plus topical composition there is the effect of obvious pore refining.
Using embodiment 9,11,13 prepare skin cleaning mask after two months, the degree of hair pore shrinkage is presented increased successively
The pore refining best results of trend, the wherein skin cleaning mask of embodiment 13,33.6 are reduced using front and rear pore aperture, illustrate this
The moisturizing moisturizing effect for inventing the plant composition in the topical composition of addition and a variety of flowers water, polyalcohol compounding wants obvious
Better than the effect with single flowers water and polyalcohol compounding.
Using embodiment 9 skin cleaning mask after two months, skin pore reduce degree apparently higher than use the He of comparative example 4
The pore intensity of variation of 5 skin cleaning masks, illustrates the plant composition composition in the topical composition of addition:Salvia japonica, sweet mary,
Juniperus communis fruit, Saponaria officinalis and hypericum perforatum have synergy.
Using embodiment 9 skin cleaning mask after two months, skin pore reduce degree apparently higher than using comparative example 6 it is clean
The pore aperture decrement of skin facial mask, illustrates in Salvia japonica, sweet mary, Juniperus communis fruit, Saponaria officinalis and hypericum perforatum various plants
On the basis of composition compounding, then compounded with flowers water, the significantly more efficient diminution pore of energy makes skin become careful smooth.
Part II:
1st, test sample:Skin cleaning mask prepared by Example 8-10,12,14 and comparative example 4-7;
2nd, method of testing:The personnel 270 at age 22-35 Sui are selected, each half of masculinity femininity, skin has obvious blackhead,
Without any skin disease and allergic history, it is divided into 7 groups, every group of 30 people, every group is smeared different test samples respectively.Test preceding 2
It can not use any cosmetics that must not be used in any cosmetics, process of the test beyond test sample.Subject's clear water
After face cleaning, test sample is uniformly applied to face, after 10-15 minutes, is cleaned, dried, weekly using 3-4 times, continuously with clear water
Use two months.
3rd, test assessment result see the table below 5-6.
The feedback conclusive table on probation of the embodiment group skin cleaning mask of table 5
The feedback conclusive table on probation of the comparative example 4-7 skin cleaning masks of table 6
From upper table 5-6:The overall merit effect of the skin cleaning mask of embodiment 8-10,12,14 is preferable, hence it is evident that better than contrast
Example 4-7 skin cleaning mask.Subject represents that the effect of the blackhead of dispelling of the skin cleaning mask of embodiment 8-10,12,14 is good, after use
Feel that skin of nose is totally salubrious, pore is significantly reduced, and moistening effect is good, it is glossy to reduce.The non-someone of user occurs simultaneously
Allergic phenomena, the composition and skin cleaning mask for illustrating the present invention is all that safety is gentle, non-stimulated.
Represent to there are no obvious dispel blackhead and pore refining effect using the subject of the skin cleaning mask of comparative example 7, with
The evaluation result of embodiment 8-10,12,14 compares, and illustrates the external application group added in skin cleaning mask of the present invention and skin cleaning mask
Compound has the effect of significantly dispel blackhead, replenishing water and preserving moisture and pore refining, can reach the multiple of blackhead of dispelling, cleaning and skin care
Effect, meets the multiple demand of consumer.
Although all containing dispel blackhead and the topical composition of pore refining effect in comparative example 4-6 skin cleaning mask formula,
But the composition in composition all has obvious difference with the composition in the topical composition that is added in embodiment, therefore it is integrated
Evaluation effect is significantly lower than the skin cleaning mask of embodiment 8-10,12,14, and illustrate the present invention has dispel blackhead and pore refining
The topical composition of effect is played a role by its various component collaboration.
Claims (9)
1. it is a kind of have dispel blackhead and the topical composition of pore refining effect, it is characterised in that including following weight parts into
Point:20-45 parts of plant compositions, 20-30 parts of flowers water, 5-20 parts of polyalcohols, 5-15 parts of deionized waters;
Described plant composition is by 10-15 parts of bulk drug Salvia japonica, 5-10 parts of sweet mary, 5-10 parts of Juniperus communis fruit, soap
Made from the careless 1-5 parts mixture extraction with 1-5 parts of hypericum perforatum.
2. according to claim 1 have dispel blackhead and the topical composition of pore refining effect, it is characterised in that described
Flowers water is witch hazel water.
3. according to claim 2 have dispel blackhead and the topical composition of pore refining effect, it is characterised in that described
Flowers water is also including any one in honeysuckle flowers water, pot marigold water, Jasmine water or a variety of.
4. topical composition according to claim 1, it is characterised in that the polyalcohol is butanediol, propane diols, double third
Any one or more combination in glycol.
5. according to claim 1 have dispel blackhead and the topical composition of pore refining effect, it is characterised in that described
Plant composition is passed sequentially through made from following methods:
(1) bulk drug is weighed according to weight described in claim 1, mixes and smash to 60-100 mesh;
(2) mixture after being crushed in (1) is added in 70-80% ethanol, the proportioning of mixture and ethanol is 1g:10-
15mL, uses frequency for 20-40kHZ ultrasonication 30-45min, and temperature is 60-70 DEG C, and filtrate is collected by filtration, and centrifugation is received
Collect supernatant, suction filtration collects filtrate;
(3) filtrate for obtaining step (2) is placed in evaporator, negative pressure is taken out to -0.08~-0.1Mpa, in 45-55 DEG C of condition
Lower carry out vacuum distillation so that ethanol is steamed completely, obtains plant composition.
6. the preparation method of plant composition according to claim 5, it is characterised in that:The filtering was carried out using gauze
Filter, the gauze is 100-200 mesh;The centrifuge RPMs are 5000r/min, and centrifugation time is 10-15min;In the suction filtration
Suction filtration is carried out using filter aid diatomite.
7. a kind of have dispel blackhead and the skin cleaning mask of pore refining effect, it is characterised in that the institute of the claim 1 containing 5-20wt%
That states has dispel blackhead and the topical composition of pore refining effect.
8. it is according to claim 7 a kind of with dispel blackhead and the skin cleaning mask of pore refining effect, it is characterised in that by
The raw material of following mass percents is made:
Topical composition 5-20% with dispel blackhead and pore refining effect
Modified corn starch 1.5-3%
Double starch phosphate 1-3%
Acrylic acid (ester) analog copolymer 1.8-3.5%
Triethanolamine 0.18-0.35%
Dipropylene glycol 2-6%
Kaolin 40-56%
Extra large mud 1-5%
Cocoamidopropyl betaine 3.5-7%
O- cymene -5- alcohol 0.05-0.1%
Preservative 0.3-0.6%
Deionized water is to 100%.
9. prepare the method with dispel blackhead and the skin cleaning mask of pore refining effect described in claim 8, it is characterised in that
Comprise the following steps:
(1) deionized water is first heated to 80-90 DEG C, adds modified corn starch and the stirring of double starch phosphates has been gelatinized
Entirely, acrylic acid (ester) analog copolymer dispersed with stirring is added uniformly, the triethanolamine high temperature for adding 1/3 consumption is neutralized;
(2) when the mixture in step (1) is cooled to 40-50 DEG C or so, add with dispel blackhead and pore refining effect
Topical composition stirs, and adds in the triethanolamine of remaining 2/3 consumption and completely, then add dipropylene glycol and
Preservative stirs;
(3) kaolin and extra large mud are added in the mixture that whipping step (2) is obtained, is gradually carried with the increase of product viscosity
High mixing speed, is stirring evenly and then adding into Cocoamidopropyl betaine completely, is eventually adding o- cymene -5- alcohol and preservative
Stir, cool to 38 DEG C with bottom discharge.
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CN113274322A (en) * | 2021-05-12 | 2021-08-20 | 广州雅纯化妆品制造有限公司 | Blackhead or whitehead guiding composition |
CN113274322B (en) * | 2021-05-12 | 2023-02-28 | 广州雅纯化妆品制造有限公司 | Blackhead or whitehead guiding composition |
CN116270371A (en) * | 2023-05-23 | 2023-06-23 | 广州瑞誉化工科技有限公司 | Mild pore-shrinking blackhead-removing composition, blackhead liquid, nose patch and daily chemical product |
CN116270371B (en) * | 2023-05-23 | 2023-08-04 | 广州瑞誉化工科技有限公司 | Mild pore-shrinking blackhead-removing composition, blackhead liquid, nose patch and daily chemical product |
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