CN106758363A - The method of Acetylshikonin dyeing wool fabric - Google Patents
The method of Acetylshikonin dyeing wool fabric Download PDFInfo
- Publication number
- CN106758363A CN106758363A CN201611089888.6A CN201611089888A CN106758363A CN 106758363 A CN106758363 A CN 106758363A CN 201611089888 A CN201611089888 A CN 201611089888A CN 106758363 A CN106758363 A CN 106758363A
- Authority
- CN
- China
- Prior art keywords
- acetylshikonin
- ethanol
- dyeing
- wool fabric
- phenol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- WNFXUXZJJKTDOZ-HNNXBMFYSA-N [(1s)-1-(5,8-dihydroxy-1,4-dioxonaphthalen-2-yl)-4-methylpent-3-enyl] acetate Chemical compound C1=CC(O)=C2C(=O)C([C@@H](OC(C)=O)CC=C(C)C)=CC(=O)C2=C1O WNFXUXZJJKTDOZ-HNNXBMFYSA-N 0.000 title claims abstract description 28
- 239000004744 fabric Substances 0.000 title claims abstract description 28
- WNFXUXZJJKTDOZ-UHFFFAOYSA-N shikonin acetate Natural products C1=CC(O)=C2C(=O)C(C(OC(C)=O)CC=C(C)C)=CC(=O)C2=C1O WNFXUXZJJKTDOZ-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 238000004043 dyeing Methods 0.000 title claims abstract description 26
- 210000002268 wool Anatomy 0.000 title claims abstract description 21
- 238000000034 method Methods 0.000 title claims abstract description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 52
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 21
- SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000000243 solution Substances 0.000 claims abstract description 14
- 239000011259 mixed solution Substances 0.000 claims abstract description 13
- 239000004094 surface-active agent Substances 0.000 claims abstract description 9
- 229960002903 benzyl benzoate Drugs 0.000 claims abstract description 7
- 238000002604 ultrasonography Methods 0.000 claims description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 3
- -1 Benzyl Benzoate Ester Chemical class 0.000 claims 1
- 238000009413 insulation Methods 0.000 claims 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 229930192627 Naphthoquinone Natural products 0.000 description 1
- 241001442052 Symphytum Species 0.000 description 1
- 235000005865 Symphytum officinale Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 150000002791 naphthoquinones Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- SWGJCIMEBVHMTA-UHFFFAOYSA-K trisodium;6-oxido-4-sulfo-5-[(4-sulfonatonaphthalen-1-yl)diazenyl]naphthalene-2-sulfonate Chemical compound [Na+].[Na+].[Na+].C1=CC=C2C(N=NC3=C4C(=CC(=CC4=CC=C3O)S([O-])(=O)=O)S([O-])(=O)=O)=CC=C(S([O-])(=O)=O)C2=C1 SWGJCIMEBVHMTA-UHFFFAOYSA-K 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/34—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65125—Compounds containing ester groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/14—Wool
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
本发明提供了一种乙酰紫草素染色羊毛织物的方法，该方法包括如下步骤：将乙酰紫草素溶解于乙醇/苯酚混合溶液中，再加入表面活性剂苯甲酸苄酯，超声下得到透明溶液；将羊毛织物投入到上述染液中，振荡加热至30~60ºC染色。本染色技术不需要对乙酰紫草素进行改性，不采用高温染色，染色后织物色牢度高。The invention provides a method for dyeing wool fabric with acetylshikonin, which comprises the following steps: dissolving acetylshikonin in ethanol/phenol mixed solution, adding surfactant benzyl benzoate, obtaining transparent solution; put the wool fabric into the above dye solution, vibrate and heat to 30~60ºC for dyeing. This dyeing technology does not need to modify acetylshikonin, does not use high temperature dyeing, and the color fastness of the dyed fabric is high.
Description
技术领域technical field
本发明涉及一种纺织品染色技术领域，具体涉及一种乙酰紫草素染色羊毛织物的方法。The invention relates to the technical field of textile dyeing, in particular to a method for dyeing wool fabric with acetylshikonin.
背景技术Background technique
乙酰紫草素又称乙酰紫草醌，主要存在于紫草根部，为萘醌类色素，紫红色针状结晶。乙酰紫草素的疏水性侧键比较长，因此水溶性较差，一般可采用先媒染的方法对纤维素纤维织物进行染色。乙酰紫草素与环境相容性好，对人体健康无害。但是乙酰紫草素对羊毛等蛋白质纤维直接上染较差，且色牢度较差。Acetylshikonin, also known as acetylshikoninone, mainly exists in the roots of comfrey, and is a naphthoquinone pigment with purple-red needle-like crystals. Acetylshikonin has relatively long hydrophobic side bonds, so its water solubility is poor. Generally, cellulose fiber fabrics can be dyed by mordant dyeing first. Acetylshikonin has good compatibility with the environment and is harmless to human health. However, acetylshikonin is poor in directly dyeing protein fibers such as wool, and its color fastness is poor.
发明内容Contents of the invention
为了使乙酰紫草素有效染色羊毛织物，本发明采取如下技术方案。In order to make acetylshikonin effectively dye wool fabrics, the present invention adopts the following technical solutions.
一种乙酰紫草素染色羊毛织物的方法，包括如下步骤：（1）将苯酚溶于乙醇中；（2）将乙酰紫草素溶解于乙醇/苯酚混合溶液中，再加入表面活性剂苯甲酸苄酯，超声下得到透明溶液；（3）将羊毛织物投入到上述染液中，振荡加热至30~60ºC，保温染色5~30min；（4）将染色后织物置于乙醇中洗涤，80ºC下烘干。A method for dyeing wool fabric with acetylshikonin, comprising the following steps: (1) dissolving phenol in ethanol; (2) dissolving acetylshikonin in ethanol/phenol mixed solution, and then adding surfactant benzoic acid Benzyl ester, obtain a transparent solution under ultrasound; (3) put the wool fabric into the above dyeing solution, oscillate and heat to 30~60ºC, and keep it warm for 5~30min; drying.
进一步的，所述的乙醇/苯酚混合溶液的乙醇与苯酚的质量比为1:0.1~3。Further, the mass ratio of ethanol to phenol in the ethanol/phenol mixed solution is 1:0.1~3.
进一步的，所述的表面活性剂苯甲酸苄酯与乙醇/苯酚混合溶液的质量比为1:2000~8000。Further, the mass ratio of the surfactant benzyl benzoate to the ethanol/phenol mixed solution is 1:2000-8000.
进一步的，所述的乙酰紫草素与乙醇/苯酚混合溶液的质量比为1:200~4000。Further, the mass ratio of the acetylshikonin to the ethanol/phenol mixed solution is 1:200-4000.
本发明的有益效果在于，不需要对乙酰紫草素进行改性，不采用高温染色，染色后织物色牢度高。The beneficial effect of the invention is that the acetylshikonin does not need to be modified, high-temperature dyeing is not used, and the color fastness of the dyed fabric is high.
具体实施方式detailed description
下文将结合具体实施例详细描述本发明。应当注意的是，下述实施例中描述的技术特征或者技术特征的组合不应当被认为是孤立的，它们可以被相互组合从而达到更好的技术效果。The present invention will be described in detail below in conjunction with specific embodiments. It should be noted that the technical features or combinations of technical features described in the following embodiments should not be regarded as isolated, and they can be combined with each other to achieve better technical effects.
实施例1Example 1
乙酰紫草素染色羊毛织物的方法详细步骤如下：The detailed steps of the method for dyeing wool fabric with acetylshikonin are as follows:
（1）将20g苯酚溶于180g乙醇中；(1) Dissolve 20g of phenol in 180g of ethanol;
（2）将1g乙酰紫草素溶解于上述乙醇/苯酚混合溶液中，再加入0.04g表面活性剂苯甲酸苄酯，超声下得到透明溶液；(2) Dissolve 1 g of acetylshikonin in the above ethanol/phenol mixed solution, then add 0.04 g of surfactant benzyl benzoate, and obtain a transparent solution under ultrasound;
（3）将10g羊毛织物投入到上述染液中，振荡加热至60ºC，保温染色30min；(3) Put 10g of wool fabric into the above dyeing solution, vibrate and heat to 60ºC, and keep it warm for 30 minutes;
（4）将染色后织物置于乙醇中洗涤，80ºC下烘干。(4) Wash the dyed fabric in ethanol and dry at 80ºC.
实施例2Example 2
乙酰紫草素染色羊毛织物的方法详细步骤如下：The detailed steps of the method for dyeing wool fabric with acetylshikonin are as follows:
（1）将300g苯酚溶于100g乙醇中；(1) Dissolve 300g phenol in 100g ethanol;
（2）将0.1g乙酰紫草素溶解于上述乙醇/苯酚混合溶液中，再加入0.08g表面活性剂苯甲酸苄酯，超声下得到透明溶液；(2) Dissolve 0.1g of acetylshikonin in the above ethanol/phenol mixed solution, then add 0.08g of surfactant benzyl benzoate, and obtain a transparent solution under ultrasound;
（3）将10g羊毛织物投入到上述染液中，振荡加热至30ºC，保温染色30min；(3) Put 10g of wool fabric into the above dyeing solution, vibrate and heat to 30ºC, and keep it warm for 30 minutes;
（4）将染色后织物置于乙醇中洗涤，80ºC下烘干。(4) Wash the dyed fabric in ethanol and dry at 80ºC.
实施例3Example 3
乙酰紫草素染色羊毛织物的方法详细步骤如下：The detailed steps of the method for dyeing wool fabric with acetylshikonin are as follows:
（1）将50g苯酚溶于250g乙醇中；(1) Dissolve 50g of phenol in 250g of ethanol;
（2）将1g乙酰紫草素溶解于上述乙醇/苯酚混合溶液中，再加入0.06g表面活性剂苯甲酸苄酯，超声下得到透明溶液；(2) Dissolve 1 g of acetylshikonin in the above ethanol/phenol mixed solution, then add 0.06 g of surfactant benzyl benzoate, and obtain a transparent solution under ultrasound;
（3）将10g羊毛织物投入到上述染液中，振荡加热至50ºC，保温染色10min；(3) Put 10g of wool fabric into the above dyeing solution, vibrate and heat to 50ºC, keep warm and dye for 10min;
（4）将染色后织物置于乙醇中洗涤，80ºC下烘干。(4) Wash the dyed fabric in ethanol and dry at 80ºC.
实施例4Example 4
乙酰紫草素染色羊毛织物的方法详细步骤如下：The detailed steps of the method for dyeing wool fabric with acetylshikonin are as follows:
（1）将200g苯酚溶于200g乙醇中；(1) Dissolve 200g phenol in 200g ethanol;
（2）将0.7g乙酰紫草素溶解于上述乙醇/苯酚混合溶液中，再加入0.01g表面活性剂苯甲酸苄酯，超声下得到透明溶液；(2) Dissolve 0.7g of acetylshikonin in the above ethanol/phenol mixed solution, then add 0.01g of surfactant benzyl benzoate, and obtain a transparent solution under ultrasound;
（3）将10g羊毛织物投入到上述染液中，振荡加热至40ºC，保温染色15min；(3) Put 10g of wool fabric into the above dyeing solution, vibrate and heat to 40ºC, and keep it warm for 15 minutes;
（4）将染色后织物置于乙醇中洗涤，80ºC下烘干。(4) Wash the dyed fabric in ethanol and dry at 80ºC.
本文虽然已经给出了本发明的一些实施例，但是本领域的技术人员应当理解，在不脱离本发明精神的情况下，可以对本文的实施例进行改变。上述实施例只是示例性的，不应以本文的实施例作为本发明权利范围的限定。Although some embodiments of the present invention have been given herein, those skilled in the art should understand that the embodiments herein can be changed without departing from the spirit of the present invention. The above-mentioned embodiments are only exemplary, and the embodiments herein should not be used as limitations on the scope of rights of the present invention.
Claims (4)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611089888.6A CN106758363A (en) | 2016-12-01 | 2016-12-01 | The method of Acetylshikonin dyeing wool fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611089888.6A CN106758363A (en) | 2016-12-01 | 2016-12-01 | The method of Acetylshikonin dyeing wool fabric |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106758363A true CN106758363A (en) | 2017-05-31 |
Family
ID=58913556
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611089888.6A Pending CN106758363A (en) | 2016-12-01 | 2016-12-01 | The method of Acetylshikonin dyeing wool fabric |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106758363A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101666044A (en) * | 2008-09-03 | 2010-03-10 | 上海市长宁区少年科技指导站 | Application of alkannin serving as dye |
-
2016
- 2016-12-01 CN CN201611089888.6A patent/CN106758363A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101666044A (en) * | 2008-09-03 | 2010-03-10 | 上海市长宁区少年科技指导站 | Application of alkannin serving as dye |
Non-Patent Citations (3)
| Title |
|---|
| 何瑾馨: "《染料化学第2版》", 31 October 2016 * |
| 余志成等: "紫草色素的稳定性及在羊毛上的染色性能", 《毛纺科技》 * |
| 贾丽霞等: "磺化紫草色素对羊毛针织物染色性能的研究", 《针织工业》 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106758363A (en) | The method of Acetylshikonin dyeing wool fabric | |
| CN106758335A (en) | Colouring method of the Acetylshikonin to wool fabric | |
| CN106592271A (en) | Method of using safflower red to dye wool fabric | |
| CN106758334A (en) | The method of Acetylshikonin dyed cotton fabric | |
| CN106758355A (en) | The method of Acetylshikonin dyed polyester textiles | |
| CN106758339A (en) | The method of shikonin dyed polyester textiles | |
| CN106702774A (en) | Method for dyeing silk fabric by utilizing acetylshikonin | |
| CN106544897A (en) | The method of shikonin dyeing wool fabric | |
| CN106544899A (en) | The method that shikonin dyes silk fabric | |
| CN106758344A (en) | Colouring method of the shikonin to wool fabric | |
| CN106758354A (en) | The method of shikonin dyed cotton fabric | |
| CN106758347A (en) | Colouring method of the Acetylshikonin to silk fabric | |
| CN106702770A (en) | Dyeing method of shikonin on polyester fabric | |
| CN106758333A (en) | Colouring method of the shikonin to bafta | |
| CN106638029A (en) | Method for dyeing cotton fabric through acetyl shikonin | |
| CN106638050A (en) | Method for dyeing silk fabric with shikonin | |
| CN106758350A (en) | Colouring method of the Acetylshikonin to dacron | |
| CN106758348A (en) | The method of safflower red pigment dyed cotton fabric | |
| CN106702768A (en) | Method for dyeing silk fabric by using curcumin | |
| CN106638052A (en) | Method for dyeing cotton fabric with rutamine | |
| CN106544896A (en) | The method of gardenin dyed cotton fabric | |
| CN106758356A (en) | Colouring method of the alizarin to dacron | |
| CN106758353A (en) | Colouring method of the gardenin to wool fabric | |
| CN106758343A (en) | The method that safflower red pigment dyes silk fabric | |
| CN106702773A (en) | Method for dyeing wool fabric with gardenin |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170531 |