CN106714966B - 金属络合物的合成及其用途 - Google Patents

金属络合物的合成及其用途 Download PDF

Info

Publication number
CN106714966B
CN106714966B CN201580048681.1A CN201580048681A CN106714966B CN 106714966 B CN106714966 B CN 106714966B CN 201580048681 A CN201580048681 A CN 201580048681A CN 106714966 B CN106714966 B CN 106714966B
Authority
CN
China
Prior art keywords
group
certain embodiments
compound
metal carbonyl
optionally substituted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201580048681.1A
Other languages
English (en)
Chinese (zh)
Other versions
CN106714966A (zh
Inventor
翰·李
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novomer Inc
Original Assignee
Novomer Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Novomer Inc filed Critical Novomer Inc
Publication of CN106714966A publication Critical patent/CN106714966A/zh
Application granted granted Critical
Publication of CN106714966B publication Critical patent/CN106714966B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/86—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
    • C07D487/22—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains four or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/069—Aluminium compounds without C-aluminium linkages
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0202—Polynuclearity
    • B01J2531/0205—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/025—Ligands with a porphyrin ring system or analogues thereof, e.g. phthalocyanines, corroles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/0252—Salen ligands or analogues, e.g. derived from ethylenediamine and salicylaldehyde
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/31—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201580048681.1A 2014-07-25 2015-07-24 金属络合物的合成及其用途 Active CN106714966B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201462028993P 2014-07-25 2014-07-25
US62/028,993 2014-07-25
PCT/US2015/042124 WO2016015019A1 (en) 2014-07-25 2015-07-24 Synthesis of metal complexes and uses thereof

Publications (2)

Publication Number Publication Date
CN106714966A CN106714966A (zh) 2017-05-24
CN106714966B true CN106714966B (zh) 2021-02-02

Family

ID=53777038

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201580048681.1A Active CN106714966B (zh) 2014-07-25 2015-07-24 金属络合物的合成及其用途

Country Status (8)

Country Link
US (3) US20170225157A1 (https=)
EP (1) EP3171976B1 (https=)
JP (3) JP6670011B2 (https=)
KR (1) KR20170047248A (https=)
CN (1) CN106714966B (https=)
AU (1) AU2015292361B2 (https=)
SA (1) SA517380784B1 (https=)
WO (1) WO2016015019A1 (https=)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2707353B1 (en) 2011-05-13 2021-03-31 Novomer, Inc. Carbonylation catalysts and method
CN103987682B (zh) 2011-10-26 2017-06-16 诺沃梅尔公司 用于由环氧化物制备丙烯酸酯的工艺
EP3077091A4 (en) 2013-12-07 2017-12-20 Novomer, Inc. Nanofiltration membranes and methods of use
WO2015171372A1 (en) 2014-05-05 2015-11-12 Novomer, Inc. Catalyst recycle methods
EP3148959B1 (en) 2014-05-30 2023-11-22 Novomer Inc. Integrated methods for chemical synthesis
EP3171976B1 (en) 2014-07-25 2023-09-06 Novomer, Inc. Synthesis of metal complexes and uses thereof
US20180029005A1 (en) 2015-02-13 2018-02-01 Novomer, Inc. Flexible chemical production platform
MA41513A (fr) 2015-02-13 2017-12-19 Novomer Inc Procédé de distillation pour la production d'acide acrylique
HK1245308A1 (zh) 2015-02-13 2018-08-24 诺沃梅尔公司 聚丙内酯生产方法和系统
MA41514A (fr) 2015-02-13 2017-12-19 Novomer Inc Procédés intégrés de synthèse chimique
MA41508A (fr) 2015-02-13 2017-12-19 Novomer Inc Systèmes et procédés de production d'acide polyacrylique
MA41507A (fr) 2015-02-13 2017-12-19 Novomer Inc Systèmes et procédés de production de polymères
US10221150B2 (en) 2015-02-13 2019-03-05 Novomer, Inc. Continuous carbonylation processes
MA41510A (fr) 2015-02-13 2017-12-19 Novomer Inc Procédé de production d'acide acrylique
KR20180027631A (ko) 2015-07-31 2018-03-14 노보머, 인코포레이티드 아크릴산 및 이의 전구체를 위한 제조 시스템/제조 방법
JP6997459B2 (ja) 2016-03-21 2022-02-04 ノボマー， インコーポレイテッド 改良されたアクリル酸製造プロセス
US20180305286A1 (en) 2016-03-21 2018-10-25 Novomer, Inc. Systems and Processes for Producing Organic Acids Direct from Beta-Lactones
KR20180127429A (ko) 2016-03-21 2018-11-28 노보머, 인코포레이티드 초흡수성 중합체의 제조를 위한 시스템 및 방법
CA3042253A1 (en) 2016-11-02 2018-05-11 Han Lee Absorbent polymers, and methods and systems of producing thereof and uses thereof
US10144802B2 (en) 2016-12-05 2018-12-04 Novomer, Inc. Beta-propiolactone based copolymers containing biogenic carbon, methods for their production and uses thereof
US10500104B2 (en) 2016-12-06 2019-12-10 Novomer, Inc. Biodegradable sanitary articles with higher biobased content
KR20190126412A (ko) 2017-03-17 2019-11-11 노보머, 인코포레이티드 폴리아미드 및 이의 제조방법
US10065914B1 (en) 2017-04-24 2018-09-04 Novomer, Inc. Thermolysis of polypropiolactone to produce acrylic acid
US10676426B2 (en) 2017-06-30 2020-06-09 Novomer, Inc. Acrylonitrile derivatives from epoxide and carbon monoxide reagents
US10590099B1 (en) 2017-08-10 2020-03-17 Novomer, Inc. Processes for producing beta-lactone with heterogenous catalysts
CN112423962A (zh) 2018-07-13 2021-02-26 诺沃梅尔公司 聚内酯发泡体及其制造方法
CN113614064A (zh) 2019-03-08 2021-11-05 诺沃梅尔公司 用于产生酰胺和腈化合物的集成方法和系统
EP3750936A1 (de) 2019-06-12 2020-12-16 Covestro Deutschland AG Verfahren zur carbonylierung von epoxiden
JP2022543388A (ja) * 2019-08-02 2022-10-12 ノボマー， インコーポレイテッド 不均一触媒及びその用途
EP4015077A1 (de) 2020-12-15 2022-06-22 Covestro Deutschland AG Verfahren zur carbonylierung von epoxiden
KR20230138465A (ko) 2021-01-29 2023-10-05 노보머, 인코포레이티드 기체 반응물과 액체 반응물을 반응시키기 위한 개선된반응기 및 방법
EP4433210A1 (en) 2021-11-17 2024-09-25 Novomer, Inc. Synthesis of carbonylation catalysts
KR20260019652A (ko) 2023-06-16 2026-02-10 노보머, 인코포레이티드 코발트염으로부터 카보닐화 촉매의 합성
WO2024259298A1 (en) 2023-06-16 2024-12-19 Novomer, Inc. Synthesis of carbonylation catalyst using an alkylaluminum reduction

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5714596A (en) * 1980-06-30 1982-01-25 Denki Kagaku Kogyo Kk Accelerating method of disproportionation
CN1771238A (zh) * 2003-04-09 2006-05-10 国际壳牌研究有限公司 环氧化物的羰基化
WO2011123558A1 (en) * 2010-04-01 2011-10-06 Novomer, Inc. Synthesis of metal complexes
WO2012158573A1 (en) * 2011-05-13 2012-11-22 Novomer, Inc. Catalytic carbonylation catalysts and methods
WO2013063191A1 (en) * 2011-10-26 2013-05-02 Novomer, Inc. Process for production of acrylates from epoxides

Family Cites Families (116)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2302321A (en) 1942-11-17 Process for the production of the
US2245404A (en) 1939-02-03 1941-06-10 Solvay Process Co Manufacture of succinic anhydride
US2469704A (en) 1946-04-06 1949-05-10 Eastman Kodak Co Continuous process of producing beta lactones at reduced pressure
US2526554A (en) 1947-07-28 1950-10-17 Goodrich Co B F Preparation of beta-hydroxy carboxylic acid esters by alcoholysis of linear polyesters derived from beta-lactones
GB762138A (en) 1953-05-07 1956-11-21 Pechiney Prod Chimiques Sa Improvements in or relating to processes for the preparation of hydracrylic esters
US3006942A (en) 1957-07-11 1961-10-31 Nat Distillers Chem Corp Recovery of by-product aluminum and preparation of aluminum alkyls
US3002017A (en) 1959-07-13 1961-09-26 Goodrich Co B F Method for preparing acrylic acid
US3326938A (en) 1962-11-09 1967-06-20 Du Pont Beta-lactone production
US3800006A (en) 1968-05-25 1974-03-26 Denki Onkyo Co Ltd Graft polymers from vinyl compounds with beta-propiolactone, epsilon-caprolactone and ethylene oxide
NL7002062A (https=) 1970-02-13 1970-04-22
DE2361988C3 (de) 1973-12-13 1982-06-16 Schering Ag, 1000 Berlin Und 4619 Bergkamen Verfahren zur Herstellung von Aluminiumtrialkylen
US4026967A (en) 1976-06-25 1977-05-31 E. I. Du Pont De Nemours And Company Process for making grafted polymeric material
US4081253A (en) 1976-12-10 1978-03-28 Texaco Development Corporation Production of purified synthesis gas and carbon monoxide
US4590293A (en) 1982-01-18 1986-05-20 Ashland Oil, Inc. Process and apparatus for further processing of pressurized exothermic reactions
US5198578A (en) 1986-07-17 1993-03-30 Union Carbide Chemicals Anhydrous diluents for the propylene oxidation reaction to acrolein and acrolein oxidation to acrylic acid
US4873378A (en) 1986-08-20 1989-10-10 Hoechst Celanese Corporation Process for making 1,3-diols from epoxides
CA1339317C (en) 1988-07-25 1997-08-19 Ann Marie Lauritzen Process for producing ethylene oxide
CA2034971A1 (en) 1990-02-05 1991-08-06 Eit Drent Carbonylation catalyst system
US5096470A (en) 1990-12-05 1992-03-17 The Boc Group, Inc. Hydrogen and carbon monoxide production by hydrocarbon steam reforming and pressure swing adsorption purification
HUP9901881A3 (en) 1995-10-27 1999-12-28 Hoechst Celanese Corp Somervil Process for improving productivity of a carbonylation catalyst solution and improved carbonylation of methanol
IT1298535B1 (it) 1998-02-02 2000-01-12 Lonza Spa Procedimento per la produzione di gamma-butirrolattone
US6147126A (en) 1998-02-10 2000-11-14 Exxon Research And Engineering Company Gas conversion using hydrogen from syngas gas and hydroconversion tail gas
US6392078B1 (en) 2000-06-12 2002-05-21 Catalytic Distillation Technologies Process and catalyst for making dialkyl carbonates
WO2002009781A2 (en) 2000-07-28 2002-02-07 The Dow Chemical Company Sulfonated substantially random interpolymer-based absorbent materials
US6573340B1 (en) 2000-08-23 2003-06-03 Biotec Biologische Naturverpackungen Gmbh & Co. Kg Biodegradable polymer films and sheets suitable for use as laminate coatings as well as wraps and other packaging materials
US6773578B1 (en) 2000-12-05 2004-08-10 Chevron U.S.A. Inc. Process for preparing lubes with high viscosity index values
KR100447932B1 (ko) 2001-10-19 2004-09-08 한국화학연구원 실리콘이 함유된 내유기용매성 폴리아미드 나노복합막과 이의 제조방법
ATE437854T1 (de) 2001-12-06 2009-08-15 Cornell Res Foundation Inc Katalytische carbonylierung von drei- und viergliedrigen heterocyklen
EP1501779B1 (en) 2002-05-06 2009-12-23 Eastman Chemical Company Continuous carbonylation process
DE10221176A1 (de) 2002-05-13 2003-11-27 Basf Ag Verfahren zur Herstellung geruchsarmer Hydrogelbildender Polymerisate
DE10235316A1 (de) 2002-08-01 2004-02-12 Basf Ag Katalysator und Verfahren zur Carbonylierung von Oxiranen
US6872753B2 (en) 2002-11-25 2005-03-29 Conocophillips Company Managing hydrogen and carbon monoxide in a gas to liquid plant to control the H2/CO ratio in the Fischer-Tropsch reactor feed
KR101143206B1 (ko) 2003-07-25 2012-05-18 디에스엠 아이피 어셋츠 비.브이. 팔라듐 촉매 시스템을 사용하여 공액 다이엔을카본일화시키는 방법
MXPA06009440A (es) 2004-02-17 2007-03-15 Thomas E Johnson Metodos, composiciones y aparatos para la formacion de compuestos macrociclicos.
WO2005089106A2 (en) 2004-02-27 2005-09-29 Molecular Therapeutics, Inc. Degradable nanoparticles
WO2005095320A1 (en) 2004-04-02 2005-10-13 Ciba Specialty Chemicals Water Treatments Limited Preparation of acrylic acid derivatives from alpha or beta-hydroxy carboxylic acids
JP4759236B2 (ja) 2004-07-28 2011-08-31 住友精化株式会社 カルボキシル基含有水溶性重合体の製造方法
AU2005333585B2 (en) 2004-10-06 2010-12-16 Research Foundation Of Suny High flux and low fouling filtration media
GB2423300A (en) 2005-02-17 2006-08-23 Membrane Extraction Tech Ltd Separating enantiomers & isomers by formation, separation & decomposition of host-guest complex, & separation of host & guest molecules with membrane
DE102005017049A1 (de) 2005-04-12 2006-10-19 Basf Ag Verfahren zur Herstellung von Polyhydroxyalkanoaten
DE102005039156B4 (de) 2005-08-17 2014-12-24 Evonik Degussa Gmbh Verfahren zur Herstellung von (Meth)Acrylsäure mit Schwersiedeaufarbeitung durch Kristallisation
WO2007064841A2 (en) 2005-11-30 2007-06-07 North Carolina State University Porphyrinic compounds for use in flow cytometry
US7569709B2 (en) 2006-03-10 2009-08-04 Cornell Research Foundation, Inc. Low pressure carbonylation of heterocycles
DE102006019242A1 (de) 2006-04-21 2007-10-25 Bayer Technology Services Gmbh Prozessanalysensystem mit steriler Probenahme von mechanisch empfindlichem Material aus einem Bioreaktor
US7582792B2 (en) 2006-06-15 2009-09-01 Eastman Chemical Company Carbonylation process
KR101477491B1 (ko) 2006-09-15 2014-12-31 알케마 인코포레이티드 아크릴산의 제조방법
DE102006045282C5 (de) 2006-09-22 2012-11-22 Helmholtz-Zentrum Geesthacht Zentrum für Material-und Küstenforschung GmbH Isoporöse Membran und Verfahren zu ihrer Herstellung
CN104672473A (zh) 2007-03-12 2015-06-03 巴斯夫欧洲公司 再润湿的表面交联的超吸收剂的制备方法
US7858729B2 (en) 2008-05-29 2010-12-28 Novomer, Inc. Methods of controlling molecular weight distribution of polymers and compositions thereof
RU2503465C2 (ru) 2008-12-19 2014-01-10 Ска Хайджин Продактс Аб Супервпитывающий полимерный композит, содержащий супервпитывающий полимер и целлюлозные нанофибриллы
CA2757835A1 (en) 2009-04-08 2010-10-14 Novomer, Inc. Process for beta-lactone production
WO2010137974A1 (en) 2009-05-25 2010-12-02 Universiteit Twente Polymer composition comprising a blend of a multi-block thermoplastic elastomer and a polymer comprising a group 14 metal
US8829066B2 (en) 2009-07-03 2014-09-09 Lg Chem, Ltd. Polymerization reactor for producing super absorbent polymers and method of producing super absorbent polymers using the polymerization reactor
WO2011035195A1 (en) 2009-09-18 2011-03-24 Nano Terra Inc. Functional nanofibers and methods of making and using the same
JP5731390B2 (ja) 2009-09-30 2015-06-10 株式会社日本触媒 ポリアクリル酸（塩）系吸水性樹脂およびその製造方法
EP2325214B1 (en) 2009-11-20 2015-11-18 King Saud University Synthesis of acrylic or methacrylic acid/acrylate or methacrylate ester polymers using pervaporation
BR112012021569A2 (pt) 2010-03-09 2020-08-25 Polymers Crc Ltd composição de polímero, membrana, processo para a preparação de uma membrana, uso da composição de polímero, e, composto oligo- ou poliuretano.
EP2371869A1 (en) 2010-03-30 2011-10-05 Evonik Stockhausen GmbH A process for the production of a superabsorbent polymer
WO2011163309A2 (en) 2010-06-22 2011-12-29 Cornell University Carbonylative polymerization methods
EP2609090A4 (en) 2010-08-28 2013-12-25 Novomer Inc AMMONIC ACID ANHYDRIDE FROM ETHYLENE OXIDE
WO2012051219A2 (en) 2010-10-11 2012-04-19 Novomer, Inc. Polymer blends
EP2476724A1 (en) 2011-01-17 2012-07-18 ETH Zurich Pourous polymer membranes
US20110319849A1 (en) 2011-07-01 2011-12-29 Dimitris Ioannis Collias Absorbent article comprising a synthetic polymer derived from a renewable resource and methods of producing said article
WO2013067460A1 (en) 2011-11-04 2013-05-10 Novomer, Inc. Metal complexes for the copolymerization of carbon dioxide and epoxides
PH12014500980A1 (en) 2011-11-09 2019-06-26 Evonik Membrane Extraction Tech Ltd Membrane-based processes for reducing at least one impurity and making a concentrate comprising at least one natural component from a non-marine fatty acid oil mixture , and compositions resulting thereof
US9403788B2 (en) 2012-02-13 2016-08-02 Novomer, Inc. Process for the production of acid anhydrides from epoxides
RS58521B1 (sr) 2012-02-22 2019-04-30 Novomer Inc Postupci dobijanja akrilne kiseline
US10106484B2 (en) 2012-04-11 2018-10-23 The Procter & Gamble Company Catalysts for the conversion of hydroxypropionic acid or its derivatives to acrylic acid or its derivatives
US20150136690A1 (en) 2012-06-01 2015-05-21 National Unibersity of Singapore Method of making a membrane and a membrane for water filtration
CN104350034B (zh) 2012-06-08 2018-07-31 Cj 第一制糖株式会社 可再生丙烯酸生产和自其制备的产物
JP2015522091A (ja) 2012-06-27 2015-08-03 ノボマー， インコーポレイテッド ポリエステル生成のための触媒および方法
BR112015000002A2 (pt) 2012-07-02 2017-06-27 Novomer Inc processo para produção de acrilato
DE102012212437A1 (de) 2012-07-16 2014-01-16 Basf Se Verfahren zur Herstellung von Acrylsäure aus Ethylenoxid und Kohlenmonoxid
DE102012212424A1 (de) 2012-07-16 2014-01-16 Basf Se Verfahren zur Herstellung von Acrylsäure durch eine mit wenigstens einer molekularen Wirkverbindung katalysierte Thermolyse von Poly-3-hydroxypropionat
KR20180069137A (ko) 2013-09-25 2018-06-22 후지필름 가부시키가이샤 고체 전해질 조성물, 이를 이용한 전지용 전극 시트 및 전고체 이차전지
EP3077091A4 (en) 2013-12-07 2017-12-20 Novomer, Inc. Nanofiltration membranes and methods of use
CN105916527B (zh) 2014-01-24 2019-06-18 巴斯夫欧洲公司 一种通过使单体溶液的液滴聚合来制备吸水聚合物颗粒的方法
CN103822811B (zh) 2014-02-28 2016-01-27 中国地质大学（武汉） 一种测试有机物类样品14c丰度的前处理方法和设备
CA2941714A1 (en) 2014-03-14 2015-09-17 Novomer, Inc. Catalysts for epoxide carbonylation
WO2015171372A1 (en) 2014-05-05 2015-11-12 Novomer, Inc. Catalyst recycle methods
EP3148959B1 (en) 2014-05-30 2023-11-22 Novomer Inc. Integrated methods for chemical synthesis
EP3171976B1 (en) 2014-07-25 2023-09-06 Novomer, Inc. Synthesis of metal complexes and uses thereof
MA41514A (fr) 2015-02-13 2017-12-19 Novomer Inc Procédés intégrés de synthèse chimique
MA41508A (fr) 2015-02-13 2017-12-19 Novomer Inc Systèmes et procédés de production d'acide polyacrylique
US10221150B2 (en) 2015-02-13 2019-03-05 Novomer, Inc. Continuous carbonylation processes
MA41510A (fr) 2015-02-13 2017-12-19 Novomer Inc Procédé de production d'acide acrylique
US20180029005A1 (en) 2015-02-13 2018-02-01 Novomer, Inc. Flexible chemical production platform
MA41507A (fr) 2015-02-13 2017-12-19 Novomer Inc Systèmes et procédés de production de polymères
MA41513A (fr) 2015-02-13 2017-12-19 Novomer Inc Procédé de distillation pour la production d'acide acrylique
HK1245308A1 (zh) 2015-02-13 2018-08-24 诺沃梅尔公司 聚丙内酯生产方法和系统
CN107922602A (zh) 2015-07-01 2018-04-17 诺沃梅尔公司 由生物基乙醇制造的聚合物组合物
US20170001946A1 (en) 2015-07-02 2017-01-05 Sadesh Sookraj Terephthalate derivatives and compositions thereof
KR20180027631A (ko) 2015-07-31 2018-03-14 노보머, 인코포레이티드 아크릴산 및 이의 전구체를 위한 제조 시스템/제조 방법
KR20180127429A (ko) 2016-03-21 2018-11-28 노보머, 인코포레이티드 초흡수성 중합체의 제조를 위한 시스템 및 방법
US20180305286A1 (en) 2016-03-21 2018-10-25 Novomer, Inc. Systems and Processes for Producing Organic Acids Direct from Beta-Lactones
JP6997459B2 (ja) 2016-03-21 2022-02-04 ノボマー， インコーポレイテッド 改良されたアクリル酸製造プロセス
US20180282251A1 (en) 2017-03-21 2018-10-04 Novomer, Inc. Systems and processes for producing organic acids direct from beta-lactones
CA3042253A1 (en) 2016-11-02 2018-05-11 Han Lee Absorbent polymers, and methods and systems of producing thereof and uses thereof
KR20190083349A (ko) 2016-11-02 2019-07-11 노보머, 인코포레이티드 흡수성 중합체, 및 이의 제조 방법 및 이의 용도
US20180155490A1 (en) 2016-12-05 2018-06-07 Novomer, Inc. Biodegradable polyols having higher biobased content
US10144802B2 (en) 2016-12-05 2018-12-04 Novomer, Inc. Beta-propiolactone based copolymers containing biogenic carbon, methods for their production and uses thereof
US10500104B2 (en) 2016-12-06 2019-12-10 Novomer, Inc. Biodegradable sanitary articles with higher biobased content
AR110833A1 (es) 2017-01-19 2019-05-08 Novomer Inc Métodos y sistemas para el tratamiento de óxido de etileno
KR20190126412A (ko) 2017-03-17 2019-11-11 노보머, 인코포레이티드 폴리아미드 및 이의 제조방법
US10065914B1 (en) 2017-04-24 2018-09-04 Novomer, Inc. Thermolysis of polypropiolactone to produce acrylic acid
US10676426B2 (en) 2017-06-30 2020-06-09 Novomer, Inc. Acrylonitrile derivatives from epoxide and carbon monoxide reagents
US10781156B2 (en) 2017-06-30 2020-09-22 Novomer, Inc. Compositions for improved production of acrylic acid
US20190002385A1 (en) 2017-06-30 2019-01-03 Novomer, Inc. Compositions for improved production of acrylic acid
US10899622B2 (en) 2017-06-30 2021-01-26 Novomer, Inc. Biobased carbon fibers and carbon black and methods of making the same
US10961209B2 (en) 2017-08-10 2021-03-30 Novomer, Inc. Processes for producing beta-lactone and beta-lactone derivatives with heterogenous catalysts
CN111094237A (zh) 2017-09-09 2020-05-01 诺沃梅尔公司 酰胺化合物和腈化合物及其生产与使用方法
US20190076835A1 (en) 2017-09-11 2019-03-14 Novomer, Inc. Processses using multifunctional catalysts
US20190076834A1 (en) 2017-09-11 2019-03-14 Novomer, Inc. Processes Using Multifunctional Catalysts
EP3691785A4 (en) 2017-10-05 2021-08-04 Novomer, Inc. ISOCYANATES, DERIVATIVES AND METHOD FOR THEIR MANUFACTURING
US11685809B2 (en) 2018-03-22 2023-06-27 Novomer, Inc. Phosphorus-containing polymers, and methods of producing thereof
JP7495123B2 (ja) 2018-04-06 2024-06-04 ノボマー， インコーポレイテッド ポリプロピオラクトンフィルム及びその製造方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5714596A (en) * 1980-06-30 1982-01-25 Denki Kagaku Kogyo Kk Accelerating method of disproportionation
CN1771238A (zh) * 2003-04-09 2006-05-10 国际壳牌研究有限公司 环氧化物的羰基化
WO2011123558A1 (en) * 2010-04-01 2011-10-06 Novomer, Inc. Synthesis of metal complexes
WO2012158573A1 (en) * 2011-05-13 2012-11-22 Novomer, Inc. Catalytic carbonylation catalysts and methods
WO2013063191A1 (en) * 2011-10-26 2013-05-02 Novomer, Inc. Process for production of acrylates from epoxides

Also Published As

Publication number Publication date
JP2020019014A (ja) 2020-02-06
EP3171976B1 (en) 2023-09-06
AU2015292361B2 (en) 2019-07-18
JP6933872B2 (ja) 2021-09-08
US20190030520A1 (en) 2019-01-31
SA517380784B1 (ar) 2021-07-12
JP2017523038A (ja) 2017-08-17
US20210291153A1 (en) 2021-09-23
WO2016015019A1 (en) 2016-01-28
US20170225157A1 (en) 2017-08-10
US12377405B2 (en) 2025-08-05
EP3171976A1 (en) 2017-05-31
JP2020097035A (ja) 2020-06-25
KR20170047248A (ko) 2017-05-04
CN106714966A (zh) 2017-05-24
AU2015292361A1 (en) 2017-02-16
US10974234B2 (en) 2021-04-13
JP6670011B2 (ja) 2020-03-18

Similar Documents

Publication Publication Date Title
CN106714966B (zh) 金属络合物的合成及其用途
US10927091B2 (en) Continuous carbonylation processes
US9156803B2 (en) Succinic anhydride from ethylene oxide
CN104245659B (zh) 由环氧化物生产酸酐的方法
CN103827128B (zh) 金属络合物
EP2707353B1 (en) Carbonylation catalysts and method
EP3798247A1 (en) Process and system for production of polypropiolactone
WO2018200471A1 (en) Systems and processes for thermolysis of polylactones to produce organic acids
JP2017511303A (ja) エポキシドカルボニル化のための触媒
WO2011123558A1 (en) Synthesis of metal complexes
Al-Qaisi et al. Synthesis, structure and catalytic activity of bis (phenoxyiminato) iron (III) complexes in coupling reaction of CO2 and epoxides
HK1237300A1 (en) Synthesis of metal complexes and uses thereof
Kim Synthetic and Structural Studies of Novel 1, 10-Phenanthroline Derivatives
HK1241850A1 (zh) 连续羰基化方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
REG Reference to a national code

Ref country code: HK

Ref legal event code: DE

Ref document number: 1237300

Country of ref document: HK

GR01 Patent grant
GR01 Patent grant
REG Reference to a national code

Ref country code: HK

Ref legal event code: WD

Ref document number: 1237300

Country of ref document: HK