CN1067087C - 环状烯烃共聚物的生产方法及用该方法制造的共聚物 - Google Patents

环状烯烃共聚物的生产方法及用该方法制造的共聚物 Download PDF

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Publication number
CN1067087C
CN1067087C CN95103477A CN95103477A CN1067087C CN 1067087 C CN1067087 C CN 1067087C CN 95103477 A CN95103477 A CN 95103477A CN 95103477 A CN95103477 A CN 95103477A CN 1067087 C CN1067087 C CN 1067087C
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CN
China
Prior art keywords
carbon atoms
group
cyclopentadienyl
indenyl
formula
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Expired - Fee Related
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CN95103477A
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Chinese (zh)
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CN1112570A (zh
Inventor
阿部吉晴
相根敏裕
丰田昭德
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Ticona GmbH
Mitsui Chemical Industry Co Ltd
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Hoechst AG
Mitsui Chemical Industry Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F112/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F232/00—Copolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/903—Monomer polymerized in presence of transition metal containing catalyst and hydrocarbon additive affecting polymer properties of catalyst activity
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Printing Methods (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN95103477A 1994-04-22 1995-04-22 环状烯烃共聚物的生产方法及用该方法制造的共聚物 Expired - Fee Related CN1067087C (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP8472594 1994-04-22
JP084725/94 1994-04-22
JP084725/1994 1994-04-22

Publications (2)

Publication Number Publication Date
CN1112570A CN1112570A (zh) 1995-11-29
CN1067087C true CN1067087C (zh) 2001-06-13

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CN95103477A Expired - Fee Related CN1067087C (zh) 1994-04-22 1995-04-22 环状烯烃共聚物的生产方法及用该方法制造的共聚物

Country Status (7)

Country Link
US (1) US5559199A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
EP (1) EP0678530B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
KR (1) KR100231173B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CN (1) CN1067087C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CA (1) CA2147589C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
DE (1) DE69521826T2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
TW (1) TW312696B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)

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JP3672315B2 (ja) * 1994-09-30 2005-07-20 日本ゼオン株式会社 開環重合体水素添加物
JP3517471B2 (ja) * 1994-12-28 2004-04-12 三井化学株式会社 環状オレフィン共重合体の製造方法
JPH08239426A (ja) * 1995-03-01 1996-09-17 Mitsui Petrochem Ind Ltd 環状オレフィン共重合体の製造方法
IT1275856B1 (it) * 1995-03-03 1997-10-24 Spherilene Srl Composti metallocenici bis-fluorenilici, procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione
FI105196B (fi) * 1995-05-08 2000-06-30 Optatech Oy Amorfiset olefiini-ko/terpolymeerit
BR9708232A (pt) * 1996-03-27 1999-08-03 Dow Chemical Co Ativador de catalisador sistema de catalisador para polimerização de alfa-olefinas e processo de polimerização
DE19623707A1 (de) * 1996-06-14 1997-12-18 Hoechst Ag Übergangsmetallverbindung
JP3817015B2 (ja) * 1997-04-14 2006-08-30 三井化学株式会社 環状オレフィン系共重合体およびその用途
FR2787113B1 (fr) * 1998-12-11 2003-10-17 Sumitomo Chemical Co Copolymere, son procede de preparation et produit moule obtenu avec ce copolymere
EP1085025A1 (en) * 1999-02-04 2001-03-21 Idemitsu Petrochemical Co., Ltd. Catalyst for olefin polymerization, process for producing the same, and process for producing olefin polymer
US6150478A (en) * 1999-06-04 2000-11-21 Union Carbide Chemicals & Plastics Technology Corporation Ultrasonic catalyst feed for fluid bed olefin polymerization
US6875719B2 (en) 2000-04-27 2005-04-05 Industrial Technology Research Institute Catalyst composition for preparing olefin polymers
EP1179554A1 (en) * 2000-08-08 2002-02-13 Industrial Technology Research Institute Catalyst composition for preparing olefin polymers
CA2364756A1 (en) * 2001-12-10 2003-06-10 Nova Chemicals Corporation Catalyst activator
CN1697845A (zh) * 2003-01-23 2005-11-16 三井化学株式会社 乙烯/α－烯烃/非共轭多烯共聚物的制备方法和乙烯/α－烯烃/非共轭多烯共聚物
TWI255370B (en) * 2003-02-27 2006-05-21 Hon Hai Prec Ind Co Ltd Light guide plate used for liquid crystal display
US7022787B2 (en) * 2003-09-25 2006-04-04 E. I. Du Pont De Nemours And Company Olefin polymerization catalyst
US8168292B2 (en) * 2006-06-15 2012-05-01 Innegra Technologies, Llc Composite materials including amorphous thermoplastic fibers
KR101414347B1 (ko) * 2006-07-28 2014-07-02 후지필름 가부시키가이샤 노르보르넨계 중합체, 필름, 편광판 및 액정 표시 장치
JP4074879B1 (ja) 2006-10-18 2008-04-16 株式会社コナミデジタルエンタテインメント ゲーム装置、メッセージ表示方法、および、プログラム
DE102007015707A1 (de) 2007-04-02 2008-10-09 Topas Advanced Polymers Gmbh Cycloolefin-Copolymere, Verfahren zu ihrer Herstellung, deren Verwendung und Katalysatoren
WO2018191412A1 (en) 2017-04-12 2018-10-18 Urigen Pharmaceuticals, Inc. Article of manufacture comprising local anesthetic, buffer, and glycosaminoglycan in syringe with improved stability
CN111777702B (zh) * 2020-05-13 2022-07-01 拓烯科技(衢州)有限公司 一种改性环烯烃型无规共聚物及其制备方法
CN116194492A (zh) * 2020-07-17 2023-05-30 陶氏环球技术有限责任公司 用于限制几何构型主催化剂的烃基改性的甲基铝氧烷助催化剂
CN115894757B (zh) * 2021-09-30 2024-06-04 中国石油化工股份有限公司 乙烯-烯醇共聚物及其制备方法

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2062201A1 (en) * 1991-03-09 1992-09-10 Michael-Joachim Brekner Process for the preparation of chemically homogeneous cycloolefin copolymers
US5225503A (en) * 1991-11-11 1993-07-06 Mitsui Petrochemical Industries, Ltd. Process for preparing cycloolefin random copolymer

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JPS61115916A (ja) * 1984-11-12 1986-06-03 Mitsui Petrochem Ind Ltd 新重合体
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JPH0713084B2 (ja) * 1985-03-26 1995-02-15 三井石油化学工業株式会社 環状オレフイン系共重合体の製法
US5179171A (en) * 1985-05-24 1993-01-12 Mitsui Petrochemical Industries, Ltd. Random copolymer, and process for production thereof
US5003019A (en) * 1987-03-02 1991-03-26 Mitsui Petrochemical Industries, Ltd. Cyclo-olefinic random copolymer, olefinic random copolymer, and process for producing cyclo-olefinic random copolymers
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JP2730940B2 (ja) * 1988-12-27 1998-03-25 三井化学株式会社 環状オレフィン系共重合体の製造方法
DE3922546A1 (de) * 1989-07-08 1991-01-17 Hoechst Ag Verfahren zur herstellung von cycloolefinpolymeren
JP2868569B2 (ja) * 1990-02-13 1999-03-10 三井化学株式会社 環状オレフィン系ランダム共重合体の製造方法
ATE212042T1 (de) * 1990-03-06 2002-02-15 Mitsui Chemicals Inc Statistische cycloolefincopolymere und verfahren zu ihrer herstellung
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JPH05320258A (ja) * 1992-05-15 1993-12-03 Mitsui Petrochem Ind Ltd 環状オレフィン共重合用触媒および環状オレフィンの共重合方法
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Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2062201A1 (en) * 1991-03-09 1992-09-10 Michael-Joachim Brekner Process for the preparation of chemically homogeneous cycloolefin copolymers
US5225503A (en) * 1991-11-11 1993-07-06 Mitsui Petrochemical Industries, Ltd. Process for preparing cycloolefin random copolymer

Also Published As

Publication number Publication date
KR950032326A (ko) 1995-12-20
US5559199A (en) 1996-09-24
DE69521826D1 (de) 2001-08-30
TW312696B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1997-08-11
CA2147589A1 (en) 1995-10-23
EP0678530B1 (en) 2001-07-25
EP0678530A1 (en) 1995-10-25
DE69521826T2 (de) 2002-04-11
KR100231173B1 (ko) 1999-11-15
CN1112570A (zh) 1995-11-29
CA2147589C (en) 2006-04-18

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Owner name: MITSUI CHEMICALS, INC.; TERKAU CO., LTD.

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Effective date: 20010817

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Patentee after: Ticona GmbH

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Patentee before: Hoechst AG

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