CN1067045C - 醇的羰基化方法 - Google Patents

醇的羰基化方法 Download PDF

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Publication number
CN1067045C
CN1067045C CN95117948A CN95117948A CN1067045C CN 1067045 C CN1067045 C CN 1067045C CN 95117948 A CN95117948 A CN 95117948A CN 95117948 A CN95117948 A CN 95117948A CN 1067045 C CN1067045 C CN 1067045C
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China
Prior art keywords
carbon monoxide
reaction
mmol
bar
autoclave
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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CN95117948A
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English (en)
Chinese (zh)
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CN1129690A (zh
Inventor
爱沃特·让·迪策尔
迈克尔·大卫·琼斯
安德鲁·大卫·普尔
约翰·格兰·桑利
罗伯特·约翰·瓦特
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BP Chemicals Ltd
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BP Chemicals Ltd
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Publication of CN1129690A publication Critical patent/CN1129690A/zh
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24
    • C07C2531/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24 of the platinum group metals, iron group metals or copper
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CN95117948A 1995-02-21 1995-10-09 醇的羰基化方法 Expired - Lifetime CN1067045C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9503382.5 1995-02-21
GBGB9503382.5A GB9503382D0 (en) 1995-02-21 1995-02-21 Process

Publications (2)

Publication Number Publication Date
CN1129690A CN1129690A (zh) 1996-08-28
CN1067045C true CN1067045C (zh) 2001-06-13

Family

ID=10769961

Family Applications (1)

Application Number Title Priority Date Filing Date
CN95117948A Expired - Lifetime CN1067045C (zh) 1995-02-21 1995-10-09 醇的羰基化方法

Country Status (17)

Country Link
US (1) US5939585A (enExample)
EP (1) EP0728727B1 (enExample)
JP (1) JP3875289B2 (enExample)
KR (1) KR100636586B1 (enExample)
CN (1) CN1067045C (enExample)
BR (1) BR9503691A (enExample)
CA (1) CA2154029A1 (enExample)
DE (1) DE69508733T2 (enExample)
FI (1) FI954030L (enExample)
GB (1) GB9503382D0 (enExample)
MY (1) MY112954A (enExample)
NO (1) NO952782L (enExample)
NZ (1) NZ272615A (enExample)
SA (1) SA96160517B1 (enExample)
TW (1) TW302357B (enExample)
UA (1) UA46712C2 (enExample)
ZA (1) ZA956284B (enExample)

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GB9626317D0 (en) * 1996-12-19 1997-02-05 Bp Chem Int Ltd Process
GB9626429D0 (en) * 1996-12-19 1997-02-05 Bp Chem Int Ltd Process
GB9802027D0 (en) * 1998-01-31 1998-03-25 Bp Chem Int Ltd Chemical process
CA2325478C (en) * 1998-03-31 2006-01-24 Haldor Topsoe A/S Process for production of acetic acid
US6303813B1 (en) * 1999-08-31 2001-10-16 Celanese International Corporation Rhodium/inorganic iodide catalyst system for methanol carbonylation process with improved impurity profile
WO2001051445A2 (en) * 2000-01-14 2001-07-19 Bp Chemicals Limited Co-production of carboxylic acids and/or their esters
FR2820422B1 (fr) * 2001-02-08 2003-04-25 Acetex Chimie Modification du systeme catalytique dans un procede industriel de fabrication d'acide acetique et/ou d'acetate de methyle
US7005541B2 (en) * 2002-12-23 2006-02-28 Celanese International Corporation Low water methanol carbonylation process for high acetic acid production and for water balance control
JP5075336B2 (ja) * 2004-12-20 2012-11-21 株式会社ダイセル 酢酸の製造方法
JP4526381B2 (ja) * 2004-12-27 2010-08-18 ダイセル化学工業株式会社 酢酸の製造方法
US7053241B1 (en) * 2005-02-24 2006-05-30 Celanese International Corporation Acetic acid production methods incorporating at least one metal salt as a catalyst stabilizer
TWI465424B (zh) * 2006-03-21 2014-12-21 Bp Chem Int Ltd 製造醋酸的方法
CN101153002B (zh) * 2006-09-28 2011-04-20 中国石油化学工业开发股份有限公司 羧酸的制造方法
TW200930698A (en) * 2008-01-07 2009-07-16 China Petrochemical Dev Corp Method for manufacturing carboxylic acid anhydride
EP2093209A1 (en) 2008-02-19 2009-08-26 BP Chemicals Limited Process for the production of acetic acid
SG186330A1 (en) 2010-06-14 2013-01-30 Celanese Int Corp Carbonylation process
US8785684B2 (en) 2010-06-14 2014-07-22 Celanese International Corporation Methanol carbonylation process with rhodium catalyst, an iodide salt and a metallic co-catalyst selected from transition metals, indium, strontium, barium, zinc, tin and heteropoly acids
US8835681B2 (en) 2010-06-14 2014-09-16 Celanese International Corporation Methanol carbonylation process with rhodium catalyst and a lanthanide metal co-catalyst
TW201209034A (en) * 2010-08-31 2012-03-01 China Petrochemical Dev Corp Production method for carboxylic acid anhydride
CN102476988A (zh) * 2010-11-22 2012-05-30 中国石油化学工业开发股份有限公司 羧酸酐的制造方法
US8742168B2 (en) 2011-05-31 2014-06-03 Lyondell Chemical Technology, L.P. Process for the production of acetic acid
CN102266795B (zh) * 2011-06-15 2013-09-11 陕西煤业化工技术开发中心有限责任公司 一种用于低水醋酸合成工艺的催化剂及其制备和使用方法
CN102319587B (zh) * 2011-06-15 2013-08-28 陕西煤业化工技术开发中心有限责任公司 一种用于羰基化合成醋酐联产醋酸的催化剂及其制备和使用方法
CN105001048B (zh) * 2015-06-29 2017-02-01 中国科学院化学研究所 一种由二氧化碳氢化反应合成乙醇及其高级醇的方法
CN111111775A (zh) * 2018-11-01 2020-05-08 中国科学院大连化学物理研究所 有机含膦聚合物载体负载的Rh基催化剂及其制备和应用
GB202005016D0 (en) 2020-04-06 2020-05-20 Bp Chem Int Ltd Process for producing acetic acid
GB202014657D0 (en) 2020-09-17 2020-11-04 Bp Chem Int Ltd Processes and apparatuses for treating offgas in an acetic acid production unit
GB202015835D0 (en) 2020-10-06 2020-11-18 Bp Chem Int Ltd Processes and apparatuses for distillation of an acetic acid and propionic acid-containing stream in an acetic acid production unit

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0636599A1 (en) * 1993-07-27 1995-02-01 Korea Institute Of Science And Technology Process for the carbonylation of methanol to form acetic acid, methyl acetate and acetic anhydride

Family Cites Families (23)

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SE364254B (enExample) 1967-04-05 1974-02-18 Monsanto Co
US3769329A (en) 1970-03-12 1973-10-30 Monsanto Co Production of carboxylic acids and esters
SE413891B (sv) 1973-09-04 1980-06-30 Halcon International Inc Sett att framstella en anhydrid av en monokarbonsyra.
DE2450965C2 (de) * 1974-10-26 1983-06-09 Hoechst Ag, 6230 Frankfurt Verfahren zur Herstellung von Essigsäureanhydrid
CA1058636A (en) * 1975-03-10 1979-07-17 Nabil Rizkalla Process for preparing carboxylic acid anhydrides
US4101450A (en) * 1977-05-09 1978-07-18 Celanese Corporation Catalyst for production of acetic acid
JPS5538369A (en) 1978-09-01 1980-03-17 Texaco Development Corp Manufacture of carboxylic acids and their esters
DE3064657D1 (en) * 1979-12-21 1983-09-29 Shell Int Research Process for the co-production of carboxylic acids and carboxylic acid esters
FR2507597B1 (fr) * 1981-06-12 1985-12-13 Rhone Poulenc Chim Base Procede de carbonylation de l'acetate de methyle
EP0072055B1 (en) * 1981-08-06 1985-05-02 Shell Internationale Researchmaatschappij B.V. Process for the co-production of carboxylic acids and carboxylic acid esters
DE3267033D1 (en) * 1981-09-22 1985-11-28 Shell Int Research Process for the co-production of carboxylic acids and carboxylic acid esters
DE3267030D1 (en) * 1981-09-22 1985-11-28 Shell Int Research Process for the co-production of carboxylic acids and carboxylic acid esters
US4640802A (en) * 1981-12-10 1987-02-03 Shell Oil Company Process for the co-production of carboxylic acids and carboxylic acid esters
CA1194033A (en) * 1981-12-10 1985-09-24 Eit Drent Process for the co-production of carboxylic acids and carboxylic acid esters
US4664851A (en) * 1981-12-30 1987-05-12 Shell Oil Company Process for the co-production of carboxylic acids and carboxylic acid esters
NZ203226A (en) * 1982-02-13 1985-08-30 Bp Chemical Ltd Production of acetic anhydride from methanol and carbon monoxide
DE3206095A1 (de) 1982-02-19 1983-09-01 Hunter Douglas Industries B.V., 3008 Rotterdam Lichtmastarmaturgehaeuse zur universellen anwendung bei der montage auf verschiedenartigen auslagern von armaturtraegern
US4514336A (en) * 1982-05-28 1985-04-30 Shell Oil Company Homologous carboxylic acids production
US4681707A (en) * 1982-09-30 1987-07-21 The British Petroleum Company P.L.C. Process for the production of carboxylic acid esters and/or carboxylic acids
DE3463257D1 (en) * 1983-03-25 1987-05-27 Texaco Development Corp A process for producing carboxylic acids by carbonylation of alkanols over a carbon catalyst
GB8406126D0 (en) * 1984-03-08 1984-04-11 Bp Chem Int Ltd Esters
FR2670779A1 (fr) * 1990-12-20 1992-06-26 Rhone Poulenc Chimie Procede de preparation de l'acide adipique par hydrocarboxylation d'acides penteniques.
US5672743A (en) * 1993-09-10 1997-09-30 Bp Chemicals Limited Process for the production of acetic acid

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0636599A1 (en) * 1993-07-27 1995-02-01 Korea Institute Of Science And Technology Process for the carbonylation of methanol to form acetic acid, methyl acetate and acetic anhydride

Also Published As

Publication number Publication date
TW302357B (enExample) 1997-04-11
SA96160517B1 (ar) 2006-08-15
NO952782L (no) 1996-08-22
MY112954A (en) 2001-10-31
GB9503382D0 (en) 1995-04-12
US5939585A (en) 1999-08-17
FI954030A7 (fi) 1996-08-22
BR9503691A (pt) 1997-09-16
FI954030A0 (fi) 1995-08-28
UA46712C2 (uk) 2002-06-17
DE69508733T2 (de) 1999-07-29
FI954030L (fi) 1996-08-22
JP3875289B2 (ja) 2007-01-31
CA2154029A1 (en) 1996-08-22
KR960031418A (ko) 1996-09-17
EP0728727A1 (en) 1996-08-28
DE69508733D1 (de) 1999-05-06
NO952782D0 (no) 1995-07-13
ZA956284B (en) 1997-01-27
CN1129690A (zh) 1996-08-28
EP0728727B1 (en) 1999-03-31
KR100636586B1 (ko) 2007-03-28
JPH08245492A (ja) 1996-09-24
NZ272615A (en) 1996-11-26

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