CN106082670A - Foaming glaze and the glaze foamed ceramic made of it - Google Patents
Foaming glaze and the glaze foamed ceramic made of it Download PDFInfo
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- CN106082670A CN106082670A CN201610450805.5A CN201610450805A CN106082670A CN 106082670 A CN106082670 A CN 106082670A CN 201610450805 A CN201610450805 A CN 201610450805A CN 106082670 A CN106082670 A CN 106082670A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
- C04B2235/963—Surface properties, e.g. surface roughness
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
- C04B2235/9669—Resistance against chemicals, e.g. against molten glass or molten salts
- C04B2235/9692—Acid, alkali or halogen resistance
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
- Porous Artificial Stone Or Porous Ceramic Products (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The present invention relates to a kind of glaze and with the glaze foamed ceramic that it makes of foaming, belong to ceramic technology field.Foaming glaze includes the following component according to mass fraction meter: potassium feldspar 38 ~ 42 parts, Kaolin 13 ~ 16 parts, Zirconium orthosilicate. 5 ~ 8 parts, brium carbonate 8 ~ 11 parts, 7 ~ 12 parts of quartz, calcium carbonate 7 ~ 9 parts, zinc oxide 2 ~ 5 parts, 5 ~ 10 parts of Talcum, magnesium carbonate 0.8 ~ 1.3 part, carborundum 1 ~ 5 part, Dineodymium trioxide 2 ~ 4 parts, clay 8 ~ 11 parts, Borax 16 ~ 20 parts, manganese oxide 0.2 ~ 0.5 part, ferrum oxide 0.2 ~ 0.4 part, 18 ~ 24 parts of glass dust, low temperature frit 15 ~ 21 parts, wherein, described low temperature frit includes the following component according to mass fraction meter: Borax 47 ~ 51 parts, potassium feldspar 38 ~ 41 parts, calcium carbonate 11 ~ 13 parts, Kaolin 6 ~ 9 parts；The method making glaze foamed ceramic with described foaming glaze, comprises the steps: grinding, the regulation of glaze concentration, glazing, fires expanded, cooling, obtain glaze foamed ceramic.The present invention provides one to have discoloration effect, meanwhile, has the glaze foamed ceramic of the strongest acid-fast alkali-proof and pressure-proof and snap-resistent performance.
Description
Technical field
The invention belongs to ceramic technology field, be specifically related to a kind of glaze and glaze foamed ceramic of making of it of foaming.
Background technology
Glaze is to cover the nature of glass thin layer in billet surface such as pottery, enamel, and the raw material used by general glaze is raw mineral materials
Mix according to a certain ratio with chemical addition agent such as quartz, Anhydrite, Kaolin etc., through grinding, glazing, the step such as burn till
And obtain.Glaze surface smooths glossy, and has the waterproof performance being difficult to and staiing, and is possible not only to improve the physics of ceramic body
Performance, it is also possible to strengthen the outward appearance beautifying ceramic.
The foaming fired foaming of glaze, forms glaze foaming on ceramic, has the strongest appreciating, and have anti-
Fire heat insulation effect, but the acid-fast alkali-proof of existing foaming glaze pottery and pressure-proof and snap-resistent performance can not meet the demand of people.Application
Number it is the Chinese patent of 201210190895.0, discloses a kind of foamed ceramic material and preparation method thereof, adopt in cosolvent
With calcium fluoride, disagreing with the environmental protection that society is advocated now, in firing bulking step, heating rate is slow, when firing
Between long, be unfavorable for saving the energy, and the composition of raw materials used be less, the ceramic product that produces cannot meet society now
The vision of product is appreciated requirement.
The Chinese patent of Application No. 200710055292.9, discloses a kind of tuff glaze foam ceramic thermal insulation decoration
Brick and method of manufacturing technology, with the tufa stone of natural rich reserves as primary raw material, add cosolvent, foaming agent, antioxidant,
Form foamed ceramics, wherein, the rich reserves of raw material at 1050 DEG C ~ 1200 DEG C, be readily available, but in cooling procedure, still need to
To lower the temperature according to certain temperature range, and control certain cooling rate.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art, it is provided that a kind of foam glaze and with its glaze made foaming pottery
Porcelain, wherein, raw material used in the present invention easily obtains and is environmental protection raw material, has discoloration effect, meanwhile, has the strongest resistance to
Sour alkaline-resisting and pressure-proof and snap-resistent performance.
The present invention can be achieved through the following technical solutions:
A kind of foaming glaze, the following component including according to mass fraction meter: potassium feldspar 38 ~ 42 parts, Kaolin 13 ~ 16 parts, silicic acid
Zirconium 5 ~ 8 parts, brium carbonate 8 ~ 11 parts, 7 ~ 12 parts of quartz, calcium carbonate 7 ~ 9 parts, zinc oxide 2 ~ 5 parts, 5 ~ 10 parts of Talcum, magnesium carbonate 0.8 ~
1.3 parts, carborundum 1 ~ 5 part, Dineodymium trioxide 2 ~ 4 parts, clay 8 ~ 11 parts, Borax 16 ~ 20 parts, manganese oxide 0.2 ~ 0.5 part, ferrum oxide
0.2 ~ 0.4 part, 18 ~ 24 parts of glass dust, low temperature frit 15 ~ 21 parts, wherein, described low temperature frit includes according to mass fraction meter
Following component: Borax 47 ~ 51 parts, potassium feldspar 38 ~ 41 parts, calcium carbonate 11 ~ 13 parts, Kaolin 6 ~ 9 parts.
Further, the following component including according to mass fraction meter: potassium feldspar 40 parts, Kaolin 15 parts, Zirconium orthosilicate. 7
Part, brium carbonate 10 parts, 9 parts of quartz, calcium carbonate 8 parts, zinc oxide 2 parts, 8 parts of Talcum, magnesium carbonate 1 part, carborundum 1.6 parts, oxidation
Neodymium 3 parts, clay 9 parts, Borax 19 parts, manganese oxide 0.2 part, ferrum oxide 0.2 part, 20 parts of glass dust, low temperature frit 19 parts.
Further, described low temperature frit includes the following component according to mass fraction meter: Borax 48 parts, potassium feldspar 29
Part, calcium carbonate 12 parts, Kaolin 8 parts.
The method making glaze foamed ceramic with described foaming glaze, comprises the steps:
Step one, grinds:
According to described mass ratio, after being mixed by each raw material components, the water adding raw material gross mass 70% ~ 85% is ground, ball milling
Time is 40 ~ 45h, crosses screen cloth, obtains ball milling material；
Step 2, glaze concentration regulates:
Adding water in the ball milling material of step one gained, regulation, to 46 ~ 49 Baume degrees, obtains glaze slurry；
Step 3, glazing:
Using glaze method, the ceramic idiosome baked immerses step 2 gained glaze slurry, the dried glaze pottery half that must foam becomes
Product；
Step 4, fires expanded:
Step 3 gained foaming glaze ceramic semi-finished product is fired, specifically burns till as follows: with the programming rate of 20 ~ 35 DEG C/min
It is warming up to 800 DEG C, is warming up to 1100 DEG C with the programming rate of 15 ~ 18 DEG C/min, be warming up to the programming rate of 7 ~ 13 DEG C/min
1200 ~ 1280 DEG C, constant temperature fires natural cooling after 70 ~ 90min, obtains glaze foamed ceramic.
Further, in step one, rotating speed during described ball milling is 400 ~ 450r/min, and screen cloth is 200 eye mesh screens.
Further, in step 3, described be dried at temperature 60 C, humidity be 50% environment in carry out, drying time is
6h。
Further, described in fire in puffing process, specifically burn till as follows: be warming up to the programming rate of 26 DEG C/min
800 DEG C, it is warming up to 1100 DEG C with the programming rate of 17 DEG C/min, is warming up to 1200 ~ 1280 DEG C with the programming rate of 8 DEG C/min,
Constant temperature fires natural cooling after 70 ~ 90min, obtains glaze foamed ceramic.
Compared with prior art, it has the beneficial effect that the present invention
The foaming glaze of the present invention and the glaze foamed ceramic that makes of it, the raw material of employing the most easily obtains and is environment-friendly materials.
Wherein, adding rare-earth oxidation neodymium, make use of the optical property that rare earth is unique, make ceramic product beautiful in colour, soft and moist, foam glaze
Adding Dineodymium trioxide, owing to Dineodymium trioxide has discoloration effect, the color making glaze foamed ceramic is various, product more appreciating；And
And, the product produced has the performance of excellence, and wherein, its acid resistance reaches 99%, and fastness to alkali reaches 98%, and comprcssive strength reaches
20MPa, rupture strength reaches 20MPa；Meanwhile, in manufacturing process, simple process, it is easy to control, only need certainly after having fired
So cool down, save the energy, be suitable for popularity.
Detailed description of the invention
Below by detailed description of the invention, the present invention is described in further detail, but those skilled in the art will manage
Solving, the following example is merely to illustrate the present invention, and should not be taken as limiting the scope of the invention.
Embodiment 1
A kind of foaming glaze, the following component including according to mass fraction meter: potassium feldspar 38 parts, Kaolin 13 parts, Zirconium orthosilicate. 5 parts,
Brium carbonate 8 parts, 7 parts of quartz, calcium carbonate 7 parts, zinc oxide 2 parts, 5 parts of Talcum, magnesium carbonate 0.8 part, carborundum 1 part, Dineodymium trioxide 2
Part, clay 8 parts, Borax 16 parts, manganese oxide 0.2 part, ferrum oxide 0.2 part, 18 parts of glass dust, low temperature frit 15 parts, wherein, described
Low temperature frit includes the following component according to mass fraction meter: Borax 47 parts, potassium feldspar 38 parts, calcium carbonate 11 parts, Kaolin 6
Part.
The method making glaze foamed ceramic with described foaming glaze, comprises the steps:
Step one, grinds:
According to described mass ratio, after being mixed by each raw material components, the water adding raw material gross mass 70% is ground, during ball milling
Rotating speed is 400r/min, and Ball-milling Time is 40h, crosses 200 eye mesh screens, obtains ball milling material；
Step 2, glaze concentration regulates:
Adding water in the ball milling material of step one gained, regulation, to 46 Baume degrees, obtains glaze slurry；
Step 3, glazing:
Using glaze method, the ceramic idiosome baked is immersed step 2 gained glaze slurry, at temperature 60 C, humidity is 50%
Being dried in environment, drying time is 6h, and must foam glaze ceramic semi-finished product；
Step 4, fires expanded:
Step 3 gained foaming glaze ceramic semi-finished product is fired, specifically burns till as follows: with the programming rate liter of 20 DEG C/min
Temperature is to 800 DEG C, then is warming up to 1100 DEG C with the programming rate of 15 DEG C/min, is finally warming up to the programming rate of 7 DEG C/min
1200 DEG C, constant temperature fires natural cooling after 70min, obtains glaze foamed ceramic.
Embodiment 2
A kind of foaming glaze, the following component including according to mass fraction meter: potassium feldspar 40 parts, Kaolin 15 parts, Zirconium orthosilicate. 7 parts,
Brium carbonate 10 parts, 9 parts of quartz, calcium carbonate 8 parts, zinc oxide 2 parts, 8 parts of Talcum, magnesium carbonate 1 part, carborundum 1.6 parts, Dineodymium trioxide 3
Part, clay 9 parts, Borax 19 parts, manganese oxide 0.2 part, ferrum oxide 0.2 part, 20 parts of glass dust, low temperature frit 19 parts.Wherein, described
Low temperature frit includes the following component according to mass fraction meter: Borax 48 parts, potassium feldspar 29 parts, calcium carbonate 12 parts, Kaolin 8
Part.
The method making glaze foamed ceramic with described foaming glaze, comprises the steps:
Step one, grinds:
According to described mass ratio, after being mixed by each raw material components, the water adding raw material gross mass 80% is ground, during ball milling
Rotating speed is 430r/min, and Ball-milling Time is 42h, crosses 200 eye mesh screens, obtains ball milling material；
Step 2, glaze concentration regulates:
Adding water in the ball milling material of step one gained, regulation, to 48 Baume degrees, obtains glaze slurry；
Step 3, glazing:
Using glaze method, the ceramic idiosome baked is immersed step 2 gained glaze slurry, at temperature 60 C, humidity is 50%
Being dried in environment, drying time is 6h, and must foam glaze ceramic semi-finished product；
Step 4, fires expanded:
Step 3 gained foaming glaze ceramic semi-finished product is fired, specifically burns till as follows: with the programming rate liter of 26 DEG C/min
Temperature is to 800 DEG C, then is warming up to 1100 DEG C with the programming rate of 17 DEG C/min, is finally warming up to the programming rate of 8 DEG C/min
1200 DEG C, constant temperature fires natural cooling after 70min, obtains glaze foamed ceramic.
Embodiment 3
A kind of foaming glaze, the following component including according to mass fraction meter: potassium feldspar 40 parts, Kaolin 15 parts, Zirconium orthosilicate. 7 parts,
Brium carbonate 10 parts, 9 parts of quartz, calcium carbonate 8 parts, zinc oxide 2 parts, 8 parts of Talcum, magnesium carbonate 1 part, carborundum 1.6 parts, Dineodymium trioxide 3
Part, clay 9 parts, Borax 19 parts, manganese oxide 0.2 part, ferrum oxide 0.2 part, 20 parts of glass dust, low temperature frit 19 parts.Wherein, described
Low temperature frit includes the following component according to mass fraction meter: Borax 48 parts, potassium feldspar 29 parts, calcium carbonate 12 parts, Kaolin 8
Part.
The method making glaze foamed ceramic with described foaming glaze, comprises the steps:
Step one, grinds:
According to described mass ratio, after being mixed by each raw material components, the water adding raw material gross mass 80% is ground, during ball milling
Rotating speed is 430r/min, and Ball-milling Time is 42h, crosses 200 eye mesh screens, obtains ball milling material；
Step 2, glaze concentration regulates:
Adding water in the ball milling material of step one gained, regulation, to 48 Baume degrees, obtains glaze slurry；
Step 3, glazing:
Using glaze method, the ceramic idiosome baked is immersed step 2 gained glaze slurry, at temperature 60 C, humidity is 50%
Being dried in environment, drying time is 6h, and must foam glaze ceramic semi-finished product；
Step 4, fires expanded:
Step 3 gained foaming glaze ceramic semi-finished product is fired, specifically burns till as follows: with the programming rate liter of 26 DEG C/min
Temperature is to 800 DEG C, then is warming up to 1100 DEG C with the programming rate of 17 DEG C/min, is finally warming up to the programming rate of 8 DEG C/min
1200 DEG C, constant temperature fires natural cooling after 70min, obtains glaze foamed ceramic.
The present invention is detected according to the glaze foamed ceramic obtained by embodiment 1, embodiment 2 and embodiment 3, result
As shown in table 1 below:
Table 1 test result
The above is the preferred embodiment of the present invention, it is noted that for those skilled in the art,
Under the premise without departing from the principles of the invention, it is also possible to make some improvements and modifications, these improvements and modifications are also considered as this
Bright protection domain.
Claims (7)
1. a foaming glaze, it is characterised in that include the following component according to mass fraction meter: potassium feldspar 38 ~ 42 parts, Kaolin
13 ~ 16 parts, Zirconium orthosilicate. 5 ~ 8 parts, brium carbonate 8 ~ 11 parts, 7 ~ 12 parts of quartz, calcium carbonate 7 ~ 9 parts, zinc oxide 2 ~ 5 parts, Talcum 5 ~ 10
Part, magnesium carbonate 0.8 ~ 1.3 part, carborundum 1 ~ 5 part, Dineodymium trioxide 2 ~ 4 parts, clay 8 ~ 11 parts, Borax 16 ~ 20 parts, manganese oxide 0.2 ~
0.5 part, ferrum oxide 0.2 ~ 0.4 part, 18 ~ 24 parts of glass dust, low temperature frit 15 ~ 21 parts, wherein, described low temperature frit include according to
The following component of mass fraction meter: Borax 47 ~ 51 parts, potassium feldspar 38 ~ 41 parts, calcium carbonate 11 ~ 13 parts, Kaolin 6 ~ 9 parts.
Foaming glaze the most according to claim 1, it is characterised in that include the following component according to mass fraction meter: potassium is long
40 parts of stone, Kaolin 15 parts, Zirconium orthosilicate. 7 parts, brium carbonate 10 parts, 9 parts of quartz, calcium carbonate 8 parts, zinc oxide 2 parts, 8 parts of Talcum, carbon
1 part of magnesium of acid, carborundum 1.6 parts, Dineodymium trioxide 3 parts, clay 9 parts, Borax 19 parts, manganese oxide 0.2 part, ferrum oxide 0.2 part, glass dust
20 parts, low temperature frit 19 parts.
Foaming glaze the most according to claim 1, it is characterised in that described low temperature frit include according to mass fraction meter as
Lower component: Borax 48 parts, potassium feldspar 29 parts, calcium carbonate 12 parts, Kaolin 8 parts.
4. the method making glaze foamed ceramic with foaming glaze according to claim 1, it is characterised in that include walking as follows
Rapid:
Step one, grinds:
According to described mass ratio, after being mixed by each raw material components, the water adding raw material gross mass 70% ~ 85% is ground, ball milling
Time is 40 ~ 45h, crosses screen cloth, obtains ball milling material；
Step 2, glaze concentration regulates:
Adding water in the ball milling material of step one gained, regulation, to 46 ~ 49 Baume degrees, obtains glaze slurry；
Step 3, glazing:
Using glaze method, the ceramic idiosome baked immerses step 2 gained glaze slurry, the dried glaze pottery half that must foam becomes
Product；
Step 4, fires expanded:
Step 3 gained foaming glaze ceramic semi-finished product is fired, specifically burns till as follows: with the programming rate of 20 ~ 35 DEG C/min
It is warming up to 800 DEG C, is warming up to 1100 DEG C with the programming rate of 15 ~ 18 DEG C/min, be warming up to the programming rate of 7 ~ 13 DEG C/min
1200 ~ 1280 DEG C, constant temperature fires natural cooling after 70 ~ 90min, obtains glaze foamed ceramic.
The method that foaming glaze the most according to claim 4 makes foaming glaze pottery, it is characterised in that described in step one
Rotating speed during ball milling is 400 ~ 450r/min, and screen cloth is 200 eye mesh screens.
The method that foaming glaze the most according to claim 4 makes glaze foamed ceramic, it is characterised in that institute in step 3
State and be dried at temperature 60 C, humidity be 50% environment in carry out, drying time is 6h.
The method that foaming glaze the most according to claim 4 makes glaze foamed ceramic, it is characterised in that institute in step 4
State and fire in puffing process, specifically burn till as follows: be warming up to 800 DEG C with the programming rate of 26 DEG C/min, with the liter of 17 DEG C/min
Temperature speed is warming up to 1100 DEG C, is warming up to 1200 ~ 1280 DEG C with the programming rate of 8 DEG C/min, constant temperature fire after 70 ~ 90min from
So cooling, obtains glaze foamed ceramic.
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| CN201610450805.5A CN106082670B (en) | 2016-06-22 | 2016-06-22 | Foam glaze and the glaze paint foamed ceramic with its production |
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|---|---|---|---|
| CN201610450805.5A CN106082670B (en) | 2016-06-22 | 2016-06-22 | Foam glaze and the glaze paint foamed ceramic with its production |
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| CN106082670B CN106082670B (en) | 2018-12-11 |
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| CN112408792A (en) * | 2020-12-16 | 2021-02-26 | 广东欧文莱陶瓷有限公司 | Low-color-difference ceramic glaze |
| CN112979271A (en) * | 2021-03-24 | 2021-06-18 | 江西金唯冠建材有限公司 | Preparation method of light high-strength pure-color glazed brick |
| CN113024226A (en) * | 2021-03-29 | 2021-06-25 | 亚细亚建筑材料股份有限公司 | Respiratory function rock plate |
| CN114956559A (en) * | 2021-02-24 | 2022-08-30 | 福建省春秋陶瓷实业有限公司 | Ceramic handicraft |
| CN114956568A (en) * | 2021-02-26 | 2022-08-30 | 福建省春秋陶瓷实业有限公司 | Formula and preparation process of ceramic glaze |
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