CN104003761B - A kind of new copper iron color glaze and the method with its making household china - Google Patents
A kind of new copper iron color glaze and the method with its making household china Download PDFInfo
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- CN104003761B CN104003761B CN201410262570.8A CN201410262570A CN104003761B CN 104003761 B CN104003761 B CN 104003761B CN 201410262570 A CN201410262570 A CN 201410262570A CN 104003761 B CN104003761 B CN 104003761B
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Abstract
The present invention relates to a kind of new copper iron color glaze, this glaze comprises following component and weight proportion number: 20 ~ 34 parts, quartz, kaolin 5 ~ 14 parts, 12 ~ 17 parts, calcite, bone meal 0 ~ 3 part, barium carbonate 2 ~ 8 parts, albite 30 ~ 50 parts, 2 ~ 2.5 parts, stannic oxide, cupric oxide 0.5 ~ 0.8 part, 0 ~ 2 part, talcum, 0 ~ 4 part, glass powder; The present invention also provides a kind of new copper iron color glaze to make the method for household china, the copper iron color glaze Glaze for chinaware face bright color that the method is obtained, and color development is even, and better, glaze plane defect is few, does not occur crackle for glossiness, brightness.
Description
Technical field
The present invention relates to a kind of new copper iron color glaze and the method with its making household china.
Background technology
Rough flambe take copper-containing substance as tinting material, through the red glaze of firing with reductive flame.Theoretically, do chromogenic reagent with cupric oxide, calcine in reducing flame, just can obtain bright-coloured redness, Here it is rough flambe.But since ancient times, this hunting pink person of burning till is extremely rare, by generation treasure.With the calcining of suitable reducing flame, can obtain beautiful redness, as long as slightly partially lose, reduction is incomplete, or partial oxidation, all may cause burnt hair, greening, blackout or burn the phenomenons such as mistake.From archaeological materials, China's the Tang Dynasty has started to utilize copper to burn redness, and namely Jiao cheng City, Shanxi Province kiln goes out white glaze erythema device; Copper red spot an ancient unit of weight vitreous enamel fired in a large number by Song dynasty Yu Xian, Henan an ancient unit of weight kiln; Bright just Jing Dezhen, unit end begins to burn red enamal organ of the same colour, wherein the most famous with bright just eternally happy, Xuande scarlet (also known as " ox blood ", " holding a memorial ceremony for red ").Bright mid-term, rough flambe was once once lost, changed that to burn alum red.Clear Kangxu, towards being recovered, burns till ox-blood glaze, the famous and precious kind such as cowpea red.
Redness is always considered to solemnly in China, noble, celebrating look, is also one of color that Chinese pottery device uses the earliest.But the redness on early stage pottery is all the look of the nature utilizing raw material, and temperature is not high, than being easier to process.Even if blusher on the glaze later on porcelain, take iron as photoghraphic coupler, redness is also not too bright-coloured.High temperature rough flambe is quite different, and it take copper as tinting material, fires and form in high temperature reducing atmospheres.The raw mineral materials of copper is black, is crushed into powder in brown, and it can be transformed into cyan and green by the kiln of high temperature fire in oxidizing atmosphere magically, forms bright-coloured redness in reducing atmosphere.
Ancient times, the manufacture craft of rough flambe was close to lost, in recent years, rough flambe technology is recovered through effort for many years, the technology of rough flambe ceramic obtains very large development, but due to complex manufacturing, yield rate is lower, therefore output is very low, superior in quality goods are rare, and market value is expensive, also far can not meet the demand of consumption.
Summary of the invention
The object of the present invention is to provide a kind of new copper iron color glaze and the method with its making household china, to solve Problems existing and defect in above-mentioned technology, improve the stability of color development in the vitreum of copper under reducing flame atmosphere, reduce production difficulty.
For achieving the above object, the present invention by the following technical solutions:
A kind of new copper iron color glaze, comprise following component and weight proportion number: 20 ~ 34 parts, quartz, kaolin 5 ~ 14 parts, 12 ~ 17 parts, calcite, bone meal 0 ~ 3 part, barium carbonate 2 ~ 8 parts, albite 30 ~ 50 parts, 2 ~ 2.5 parts, stannic oxide, cupric oxide 0.5 ~ 0.8 part, 0 ~ 2 part, talcum, 0 ~ 4 part, glass powder.
The present invention also provides a kind of preparation method of new copper iron color glaze household china, comprise the following steps: prepare material by described new copper iron color glaze formula, put into ball mill wet ball mill 24 hours, material: ball: water=1:1.8-2.1:0.8, fineness control 250 mesh sieves tail over≤0.25%, cross 180 ~ 200 mesh sieves for subsequent use.As glazing adopt glaze spraying technique time, then add CMC0.1% and grind 2 hours, after mixing, go out mill.
Glaze is glazing on biscuit, glazed thickness controls at 0.5-0.7mm, enter kiln to fire, concrete firing condition is: normal temperature oxidation atmosphere heats, and is slowly warmed up to 350 DEG C with the speed of 30 ~ 50 DEG C/h, then with the ramp of 70 ~ 90 DEG C/h to 900 DEG C, turn heavy reducing atmosphere and burn till 1180 DEG C with 60 ~ 70 DEG C/h speed, then with the speed reductive firing of 60 DEG C/h, be warmed up to 1290 DEG C, insulation 20min, naturally cools to room temperature.
In glaze, the color development of stannic oxide to cupric oxide plays a decisive role, and when this mass percentage of 2-2.5%, adopts above-mentioned calcining system to obtain the more saturated glaze paint of color development, bone meal in new copper iron color glaze product, mainly with P
2o
5generation effect, P
2o
5contribute to the color development of cupric oxide in vitreum, glaze paint glossiness and brightness can be improved simultaneously, improve glaze paint transparency; Albite in new copper iron color glaze product, mainly with Na
2o generation effect, Na
2caO, MgO color development to glaze in O and quartz has promoter action, also plays the effect of solubility promoter simultaneously, glaze paint can be made smooth, bright.
Compared with prior art, the present invention has following beneficial effect:
1. improve the stability of color development in the vitreum of copper under reducing flame atmosphere, reduce production difficulty;
2. the product glaze paint bright color fired, color development is even, and glossiness, brightness are better, and glaze plane defect is few, and goods not easily trickle sticky end, and glaze paint does not occur crackle.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1
Present embodiment discloses a kind of new copper iron color glaze, comprise component and weight proportion number for 22 parts, quartz, kaolin 5 parts, 17 parts, calcite, bone meal 3 parts, barium carbonate 8 parts, albite 47 parts, 2.2 parts, stannic oxide, cupric oxide 0.8 part.
Prepare material by above-mentioned formula, put into ball mill wet ball mill 24 hours, material: ball: water=1:1.8:0.8, fineness controls to tail over 0.25% at 250 mesh sieves, crosses 200 mesh sieves for subsequent use;
Adopt leaching glaze handicraft, glazing on biscuit, glazed thickness controls at 0.7mm, enters kiln and fire after oven dry, concrete firing condition is: normal temperature oxidation atmosphere heats, slowly be warmed up to 350 DEG C with the speed of 30 DEG C/h, then with the ramp of 70 DEG C/h to 900 DEG C, turn a heavy reducing atmosphere burn till 1180 DEG C with 70 DEG C/h speed, again with the speed reductive firing of 60 DEG C/h, be warmed up to 1290 DEG C, insulation 20min, naturally cools to room temperature.。
Copper iron color glaze household china product prepared by the present embodiment, redness is evenly pure and gorgeous, entire body up and down even before and after the change of glaze colours active, agile, glaze paint glossiness, brightness are excellent, bright and clean bright, and glass sense is strong.
Embodiment 2
Present embodiment discloses a kind of new copper iron color glaze, comprise component and weight proportion number for 33 parts, quartz, kaolin 5 parts, 16 parts, calcite, bone meal 0.5 part, barium carbonate 2 parts, albite 32 parts, 2 parts, stannic oxide, cupric oxide 0.5 part, 2 parts, talcum, 4 parts, glass powder.Prepare material by above-mentioned formula, put into ball mill wet ball mill 24 hours, material: ball: water=1:2.1:0.8, fineness controls to tail over 0.2% at 250 mesh sieves, crosses 200 mesh sieves, then adds CMC0.1% and grind 2 hours, goes out mill after mixing.
Ground-coat enamel comprises component and weight proportion number is potassium felspar sand 38 parts, 17 parts, calcite, kaolin 6.5 parts, 29.5 parts, quartz, 8 parts, zinc oxide, 2 parts, talcum, boron frit 1 part.After good by ground-coat enamel formula precise, load wet-milling 24 hours in ball mill, material: ball: water=1:1.8-2.1:0.8, fineness control 325 mesh sieves tail over≤0.1%, deironing, mistake 200 mesh sieves, make ground-coat enamel for subsequent use.
After biscuit leaching ground-coat enamel is dried, adopt glaze spraying technique, color glaze glazed thickness controls, at 0.5mm, to enter kiln after oven dry, concrete firing condition is: normal temperature oxidation atmosphere heats, slowly be warmed up to 350 DEG C with the speed of 40 DEG C/h, then with the ramp of 70 DEG C/h to 900 DEG C, turn a heavy reducing atmosphere burn till 1180 DEG C with 65 DEG C/h speed, again with the speed reductive firing of 60 DEG C/h, be warmed up to 1290 DEG C, insulation 20min, naturally cools to room temperature.
Copper iron color glaze household china product prepared by the present embodiment, glaze paint bright color, color development is even, and glossiness, brightness are better, and goods not easily trickle sticky end, and glaze paint does not occur crackle.
Embodiment 3
Present embodiment discloses a kind of new copper iron color glaze, comprise component and weight proportion number for 20 parts, quartz, kaolin 11 parts, 12 parts, calcite, barium carbonate 2 parts, albite 50 parts, 2.5 parts, stannic oxide, cupric oxide 0.5 part.
Prepare material by above-mentioned formula, put into ball mill wet ball mill 24 hours, material: ball: water=1:2:0.8, fineness controls to tail over 0.2% at 250 mesh sieves, crosses 200 mesh sieves for subsequent use.
Adopt leaching glaze handicraft, glazing on biscuit, glazed thickness controls at 0.6mm, enters kiln and fire after oven dry, concrete firing condition is: normal temperature oxidation atmosphere heats, slowly be warmed up to 350 DEG C with the speed of 40 DEG C/h, then with the ramp of 80 DEG C/h to 900 DEG C, turn a heavy reducing atmosphere burn till 1180 DEG C with 70 DEG C/h speed, again with the speed reductive firing of 60 DEG C/h, be warmed up to 1290 DEG C, insulation 20min, naturally cools to room temperature.。
Copper iron color glaze household china product prepared by the present embodiment, glaze paint is bright and colourful, and color development enriches, and glaze plane defect is few, is the excellent red glaze effect of an ancient unit of weight, does not have sagging sticky end phenomenon.
Claims (2)
1. a new copper iron color glaze, it is characterized in that, comprise following component and weight proportion number: 20 ~ 34 parts, quartz, kaolin 5 ~ 14 parts, 12 ~ 17 parts, calcite, bone meal 0.5 ~ 3 part, barium carbonate 2 ~ 8 parts, albite 30 ~ 50 parts, 2 ~ 2.5 parts, stannic oxide, cupric oxide 0.5 ~ 0.8 part, 0 ~ 2 part, talcum, 0 ~ 4 part, glass powder.
2. one kind makes the method for household china of new copper iron color glaze according to claim 1, it is characterized in that, comprise the following steps: prepare material by described new copper iron color glaze formula, put into ball mill wet ball mill 24 hours, material: ball: water=1:1.8-2.1:0.8, fineness control 250 mesh sieves tail over≤0.25%, cross 180 ~ 200 mesh sieves for subsequent use; Glaze is glazing on biscuit, glazed thickness controls at 0.5-0.7mm, enter kiln to fire, concrete firing condition is: normal temperature oxidation atmosphere heats, and is slowly warmed up to 350 DEG C with the speed of 30 ~ 50 DEG C/h, then with the ramp of 70 ~ 90 DEG C/h to 900 DEG C, turn heavy reducing atmosphere and burn till 1180 DEG C with 60 ~ 70 DEG C/h speed, then with the speed reductive firing of 60 DEG C/h, be warmed up to 1290 DEG C, insulation 20min, naturally cools to room temperature.
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CN106145683A (en) * | 2016-08-18 | 2016-11-23 | 温书强 | A kind of peacock blue pottery glaze and preparation method thereof |
CN108658465A (en) * | 2018-07-13 | 2018-10-16 | 佛山市天工嘉荟文化科技有限公司 | A kind of high imitative bright Xuande ruby red glaze |
CN112299715A (en) * | 2020-12-01 | 2021-02-02 | 禹州市正元钧窑有限公司 | Glazing process for colorful jun porcelain |
CN112479589A (en) * | 2020-12-24 | 2021-03-12 | 湖州海程塑业有限公司 | Light pink glaze and preparation method thereof |
CN114014544B (en) * | 2021-12-14 | 2023-07-14 | 景德镇陶瓷大学 | High Wen Jigong glaze and preparation method and application thereof |
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CN102276294A (en) * | 2011-07-15 | 2011-12-14 | 广东长城集团股份有限公司 | Copper red glaze and production method thereof, and method for preparing ceramic product therefrom |
CN102432344A (en) * | 2011-10-12 | 2012-05-02 | 上海高诚艺术包装有限公司 | Copper red variable glaze and its preparation method and use |
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CN102276294A (en) * | 2011-07-15 | 2011-12-14 | 广东长城集团股份有限公司 | Copper red glaze and production method thereof, and method for preparing ceramic product therefrom |
CN102432344A (en) * | 2011-10-12 | 2012-05-02 | 上海高诚艺术包装有限公司 | Copper red variable glaze and its preparation method and use |
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