CN1609061A - Nanometer glaze with far infrared radiating function and its application - Google Patents
Nanometer glaze with far infrared radiating function and its application Download PDFInfo
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- CN1609061A CN1609061A CN 200310101684 CN200310101684A CN1609061A CN 1609061 A CN1609061 A CN 1609061A CN 200310101684 CN200310101684 CN 200310101684 CN 200310101684 A CN200310101684 A CN 200310101684A CN 1609061 A CN1609061 A CN 1609061A
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Abstract
The nanometer glaze with far infrared radiating function consists of flux 35-65 wt%, fluxing agent 1-35 wt%, refractory agent 0-25 wt%, adhesive 0.1-5 wt%, far infrared powder material 0.5-30 wt% and nanometer material 0.5-10 wt% mixed together. It is mixed with water and ground into glaze material of 200-325 mesh fineness, the glaze material is coated to plain ceramic surface, and the ceramic is sintered at 1120-1350 deg.c to obtain ceramic product with far infrared radiating function. The ceramic product can maintain the smooth and beautiful surface owing to the nanometer material, and has antibiotic effect of preventing bacteria and virus to attach and propagate, far infrared radiating effect to activate the molecular characteristic of the held or contacted matter and to raise the function of the matter.
Description
Technical field
The present invention relates to a kind of surface that is coated in ceramic green embryo or plain embryo, and sinter the glaze of ceramic together with ceramic stock into far-infrared radiation effect and tool nano-meter characteristic.
Background technology
Press, generally be applied to the ceramic of Food container, building materials, sanitation etc., mainly be through steps such as mixing, ball milling, shapings with ceramic powder particles such as clay, feldspar, quartz, make ceramic idiosome, the degree of roughness that reflects die surface that the surface of ceramic green embryo can be loyal and the appearance and the size of the ceramic powder particle that uses; Also promptly, the particle of starting raw material is big more, and the roughness on surface also will be big more.
The surface of general ceramic product all can be applied in last layer glaze A, and as shown in Figure 1, the raw material of glaze A is similar with the main component of giving birth to embryo or plain embryo B raw material; More at the glassy phase that burns till the back glaze, make the surface of idiosome comparatively level and smooth and bright and glassy phase is mobile whereby, often add colorant in the glaze again, the glaze decapacitation is covered outside the yellow idiosome of color, more can produce different colours, reach purpose attractive in appearance.
But because of the raw material of glaze also is the same with ceramic material powder. must prepare through steps such as mixing, ball millings, so glaze laminar surface degree of roughness is subject to the influence of its feedstock particle size, certainly also can be subjected to the roughness influence on idiosome surface simultaneously, add when burning till, idiosome and glaze all can shrink, and cause the surface that the existence of defectives such as uneven and pin hole is often arranged.These rough surfaces and pin hole will become the position of accumulating that produces dirt and bacterium, these dirts and bacterium be accumulation and breeding constantly, make that the surface of ceramic product is dirty, and must be usually to scrub and mode such as chlorohydric acid pickling could be removed crude removal and bacterium, cause many inconvenience.
So that, in the streets promptly have at ceramic surface spraying photocatalyst and under ultraviolet irradiation, produce the hydroxyl free radical that is enough to the break virus structure, but so its sterilizing function of the practice not only will disappear along with the disengaging of photocatalyst, and it must have sterilizing function below the irradiation of UV-light, and the corresponding anti-microbial effect of germicidal action is more passive, and can't really reach the purpose that prevents the virus diffusion as expection.
Again, also be common in adding far-infrared powder material in the pottery on the market, so that pottery has the effect of far infrared irradiation, it is the far infrared rays powder to be adopted in large quantities directly be mixed in the pottery, through drawing embryo to sinter feeder into, can make this pottery reach effective emitting far infrared ray ripple, and stick effect by this interface material, fill up function and effectively isolate water body and can do pore the pottery surface, but the raw material of this far infrared rays powder is by iron, manganese, metal such as copper or chromium constitutes, so its color only can maintain only several colors such as native black, can't reach the use of colorful color and luster.
Summary of the invention
Main purpose of the present invention is to provide a kind of surface that is coated in ceramic green embryo or plain embryo, and sinter the glaze of ceramic into together with ceramic stock with far-infrared radiation effect and tool nano-meter characteristic, make this ceramic surface usually effectively keep bright and clean, attractive in appearance, and produce to have and prevent that bacterium, virus from adhering to the anti-microbial effect that grows, and normal imitate activation institute's splendid attire or the molecular characterization by material, to promote the function of this material.
To achieve these goals, the technical solution used in the present invention is:
The nanometer glaze of a kind of tool far-infrared radiation effect, wherein:
This nanometer glaze comprises:
35～65% flux, 1～35% fusing assistant, 0～25% flame-proofing agent, 0.1～5% glutinous agent, 0.5～30% far-infrared powder material and 0.5～10% nano material, all percentage ratios are weight percentage.
Wherein, this flux is a kind of in feldspar, boron, boric acid, borax, borosilicate and the silica powder or several.This boron can be obtained in the compound by boric acid, borax, borosilicate or boron.
This fusing assistant is lime carbonate, barium carbonate, Quilonum Retard. a kind of in magnesiumcarbonate, zinc oxide and the talcum powder or several.
This flame-proofing agent is one or both in kaolin and the frog order soil.
Should glutinous agent be constituted by 38.42% silicon-dioxide, 17.13% magnesium oxide, 0.69% aluminium sesquioxide, 0.11% ferric oxide, 3.25% calcium oxide, 4.96% sodium oxide, 0.07% potassium oxide, 0.72% Lithium Oxide 98min and 24.84% inorganic resin.
This far-infrared powder material is a zr element.
This nano material is the composition of silver, silicon, aluminium, sodium, potassium, magnesium, calcium, titanium, iron, elemental lithium.
This nano material or be the oxide compound of silver, silicon, aluminium, sodium, potassium, magnesium, calcium, titanium, iron, elemental lithium composition.
A kind of method of application of aforementioned nanometer glaze, wherein:
Should mixed nanometer glaze adding water, to grind to form concentration be 350 ± 20g/200cc, fineness is 200～325 purpose glaze, and when actual applying, be the surface that is coated in ceramic green embryo or plain embryo, temperature with 1120 ℃～1350 ℃ sinters the ceramic that has the far-infrared radiation effect and have nano-meter characteristic into, be able to often imitate the bright and clean of this ceramic surface of maintenance via the characteristic of nano material, attractive in appearance, and generation has the bacterium of preventing, virus is adhered to the anti-microbial effect that grows, and via the far-infrared radiation function of this ceramic, normal imitate activation institute's splendid attire or the molecular characterization by material, and promoted the function of this material.
Description of drawings
Fig. 1 is that general ceramic glaze sprays the synoptic diagram on idiosome;
Fig. 2 is the synoptic diagram of nanometer glaze of the present invention on idiosome;
[figure number explanation]
The A glaze
B gives birth to embryo or plain embryo
1 nanometer glaze
Embodiment
For the clear structure of the present invention of your auditor is formed, and the overall operation mode, existing conjunction with figs. is described as follows:
The nanometer glaze of a kind of tool far-infrared radiation of the present invention effect, the constituent of its whole glaze includes:
A. flux can be made of feldspar, boron, boric acid, borax, borosilicate or silica powder, and its ratio accounts for 35～65% of glaze content.
B. fusing assistant can be by lime carbonate, barium carbonate, Quilonum Retard. and magnesiumcarbonate, zinc oxide or talcum powder are constituted, and its ratio accounts for 1～35% of glaze content.
C. flame-proofing agent can be made of kaolin or frog order soil, and its ratio accounts for 0～25% of glaze content.
D. glutinous agent, can be made of 38.42% silicon-dioxide, 17.13% magnesium oxide, 0.69% aluminium sesquioxide, 0.11% ferric oxide, 3.25% calcium oxide, 4.96% sodium oxide, 0.07% potassium oxide, 0.72% Lithium Oxide 98min and 24.84% inorganic resin, its ratio accounts for 0.1～5% of glaze content.
E. the far-infrared powder material is the far-infrared powder material of zr element, and its ratio accounts for 0.5～30% of glaze content.
F. nano material can be the composition of elements such as silver, silicon, aluminium, sodium, potassium, magnesium, calcium, titanium, iron, lithium, or its oxide compound, and its ratio accounts for 0.5～10% of glaze content.
According to this, after being about to aforementioned flux, fusing assistant, flame-proofing agent, glutinous agent, far-infrared ray material and nano material and mixing according to proper proportion, add the water that is equivalent to 0.6～1.5 times of glaze amount again and filled a part grinding, it is 350 ± 20g/200cc that all material abrasive lapping is become concentration, and fineness is 200～325 purpose glaze.
According to this, the glaze of being finished 1 is when actual applying, promptly can be coated in the surface of ceramic green embryo or plain embryo B, as shown in Figure 2, and together with ceramic stock with 1120 ℃～1350 ℃ temperature sinter into have the far-infrared radiation effect and have nano-meter characteristic as drinking vessel, filter material, building materials, the bathroom apparatus, ceramic such as oil product activator even, make this ceramic when reality is used, be able to can not allow fully dust via the characteristic of nano material, pollutents such as oil stain adhere to, and can often protect the bright and clean of this ceramic surface, attractive in appearance, and generation has the bacterium of preventing, virus is adhered to the anti-microbial effect that grows, and be applied in as toilet; the closet of urinating bucket; grow; the existing sterilization of its anti-microbial effect is positive with the germ that avoids mixing in making movement, and can effectively prevent the diffusion of transmissible disease.
And can be via the far-infrared radiation function of this ceramic, activation institute's splendid attire or the molecular characterization by material, and promoted the function of this material, and use zr element as the raw material of far-infrared powder material not only color can variation and emissivity increase, i.e. effect that reaction times is kept to 1～3 second, and confirm that through the expert far infrared rays has following characteristic:
1. the radiation form is a radiation wave, need not be by air conduction.
2. can be the directly dark intelligent's body subcutis of seepage force is directly from the inner health of strengthening of skin.
3. the wavelength close (4-50um) of the far infrared rays that the form of sympathetic response, absorption is distributed because of the wavelength may command and the needed by human body of far infrared rays, behind the object exposure, interior molecules can produce resonance sympathetic response effect, is beneficial to absorption of human body, promotes the physical function activation.
And it has directly been benefited human body:
1. enhance metabolism: improve poor circulation, stabilizing blood pressure, mediation neural system, discharge deleteriously accumulate thing for a long time, away from disease.
2. the prevention cancer cells is grown: " thermotherapy " for far infrared rays medically to a contribution greatly of human body, effectively suppress and kill cancer cells.
3. prevent and delaying retrogradation: behind the cell activation, inner metabolism is normal, and the external skin pore is difficult for residual makeup or airborne dust and dirt.
4. promote cell regeneration power: the active cells regeneration power, clear the head, promote immunizing power, and then reproductive performance is also had suitable help.
Again, glaze of the present invention has the actual finished product that has a fling at, and wherein, when being applied in drinking vessel, pouring tea or wine in test ceramic glaze cup and conventional ceramic cup, under the time effect in one to three second, can obviously feel different change of water quality.
And when the filtrate that is applied in cigaratte filter uses, under the situation of cigarette lighter and smoking immediately, can feel the difference of smoke at once, and find that this filter material can tar adsorption because of the far infrared rays effect, so tar can't be adsorbed on the filter material, and tar is residued in the filter tip of cigarette, human body can not suck too much tar content yet certainly.
Again, use-testing ceramic glaze teacup is tested with pencil and salad oil respectively, and the surface of pencil in test ceramic glaze teacup scratched back and forth, but at all loses the vestige of pencil-lead, or salad oil poured in the test ceramic glaze teacup in right amount, then can not be attached to fully on the test ceramic glaze teacup glaze.
And advantageous characteristic so antibiotic, anti-soil, the applicant also entrusts Taiwan Test Technology Co., Ltd. (SGS) to do test:
Test one: respectively splash into several pollutant (Sucus Vitis viniferaes at the sample surfaces externally and internally, wet tea bag, coffee, lipstick), with 23 ℃ of sample dwell temperature, in relative humidity 50% environment 16 hours, use general rag speckling with on the surface of pollutant, the strength that imposes on normal hand wiping 20 times back and forth, the residual situation of record wiping rear surface pollutant, its test result: surperficial noresidue.
Concrete test case is as follows:
Sample title: riceization far-infrared ray ceramic how
Product narration: antibiotic, anti-soil
Supplier: along boat Industrial Co., Ltd
Datereceived: on August 20th, 2003
TestDate: on August 22nd, 2003
Test event and method:
The anti-soil test is with reference to ANSIZ124.6
1, at each number of sample surfaces externally and internally pollutant
2, with 23 ℃ of sample dwell temperature, in relative humidity 50% environment 16
Hour
3, use general rag speckling with on the surface of pollutant, impose on normal
The wiping 20 times back and forth of the strength of hand
4, the residual situation of record wiping rear surface pollutant
Test result:
Pollutant
Test result
Sucus Vitis viniferae surface noresidue
Wet tea bag surface noresidue
Coffee surface noresidue
Lipstick surface noresidue
Test two: at streptococcus aureus and colibacillary antibacterial test, its result all less than 10 test limits, makes the antibacterial effect of this product of proof splendid.
Concrete test case is as follows:
The sample title: riceization far-infrared ray ceramic how
The product narration: antibiotic, anti-soil
The supplier: along boat Industrial Co., Ltd
Datereceived: on August 20th, 2003
Survey date: on August 26th, 2003
September 02,09,19,23 in 2003
Test event and method:
Antibacterial test: with reference to U.S.Pharmacopeia 24 NF 19 Microbiological
Tests(51)Antimicrobial?Effectiveness?Testing.
Test result:
Strain name
The former bacterium amount that connects
Action time
9/02 9/09 9/19 9/23
Staphyloccocus aureus (CFU/ diameter 4.5*4.5cm) 1.4*10
5＜10＜10＜10＜10
Intestinal bacteria (CFU/ diameter 4.5*4.5cm) 1.9*10
5＜10＜10＜10＜10
Especially, glaze of the present invention is to be sintered into complete ceramic simultaneously with ceramic green embryo or plain embryo surface, so its far-infrared radiation function and nano-meter characteristic are long-acting existence, can not fail because of long-time the use.
As mentioned above, the present invention's " nanometer glaze of a kind of tool far-infrared radiation effect ", it when actual embodiment the surface that can be coated in ceramic green embryo or plain embryo, and sinter the glaze of ceramic that have a far-infrared radiation effect and the tool nano-meter characteristic into together with ceramic stock, make normal effect the in this ceramic surface keep bright and clean, attractive in appearance, and produce to have and prevent that bacterium, virus from adhering to the anti-microbial effect that grows, and long-acting activation institute's splendid attire or the molecular characterization by material, to promote the function of this material, so offer application for a patent for invention in accordance with the law; But, above implementation and graphic shown in, be one of preferred embodiment of the present invention, be not to limit to the present invention with this, therefore, approximate with structure of the present invention, device, feature etc. or identical mutually such as, of the present invention founding within purpose and the claim all should be belonged to.
Claims (11)
1. the nanometer glaze of tool far-infrared radiation effect is characterized in that:
This nanometer glaze comprises:
35～65% flux, 1～35% fusing assistant, 0～25% flame-proofing agent, 0.1～5% glutinous agent, 0.5～30% far-infrared powder material and 0.5～10% nano material, all percentage ratios are weight percentage.
2. the nanometer glaze of a kind of tool far-infrared radiation as claimed in claim 1 effect, wherein, this flux is a kind of in feldspar, boron, boric acid, borax, borosilicate and the silica powder or several.
3. the nanometer glaze of a kind of tool far-infrared radiation as claimed in claim 2 effect, wherein, this boron can be obtained in the compound by boric acid, borax, borosilicate or boron.
4. the nanometer glaze of a kind of tool far-infrared radiation as claimed in claim 1 effect, wherein, this fusing assistant is a kind of in lime carbonate, barium carbonate, Quilonum Retard, magnesiumcarbonate, zinc oxide and the talcum powder or several.
5. the nanometer glaze of a kind of tool far-infrared radiation as claimed in claim 1 effect, wherein, this flame-proofing agent is one or both in kaolin and the frog order soil.
6. the nanometer glaze of a kind of tool far-infrared radiation as claimed in claim 1 effect, wherein, this glutinous agent is made of silicon-dioxide, magnesium oxide, aluminium sesquioxide, ferric oxide, calcium oxide, sodium oxide, potassium oxide, Lithium Oxide 98min and inorganic resin.
7. the nanometer glaze of a kind of tool far-infrared radiation as claimed in claim 1 effect, wherein, this glutinous agent is made of 38.42% silicon-dioxide, 17.13% magnesium oxide, 0.69% aluminium sesquioxide, 0.11% ferric oxide, 3.25% calcium oxide, 4.96% sodium oxide, 0.07% potassium oxide, 0.72% Lithium Oxide 98min and 24.84% inorganic resin.
8. the nanometer glaze of a kind of tool far-infrared radiation as claimed in claim 1 effect, wherein, this far-infrared powder material is a zr element.
9. the nanometer glaze of a kind of tool far-infrared radiation as claimed in claim 1 effect, wherein, this nano material is the composition of silver, silicon, aluminium, sodium, potassium, magnesium, calcium, titanium, iron, elemental lithium, perhaps is the oxide compound of silver, silicon, aluminium, sodium, potassium, magnesium, calcium, titanium, iron, elemental lithium composition.
10. the method for application such as described any nanometer glaze of claim 1 to 9 is characterized in that:
Should mixed nanometer glaze adding water, to grind to form concentration be 350 ± 20g/200cc, fineness is 200～325 purpose glaze, and when actual applying, be the surface that is coated in ceramic green embryo or plain embryo, sinter the ceramic that has the far-infrared radiation effect and have nano-meter characteristic into 1120 ℃～1350 ℃ temperature.
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| CNB2003101016846A CN1297519C (en) | 2003-10-24 | 2003-10-24 | Nanometer glaze with far infrared radiating function and its application |
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| CN1609061A true CN1609061A (en) | 2005-04-27 |
| CN1297519C CN1297519C (en) | 2007-01-31 |
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| CN101353227B (en) * | 2007-07-23 | 2011-05-11 | 珠海天睿生物科技有限公司 | Far infrared composite powder |
| CN102391017A (en) * | 2011-08-09 | 2012-03-28 | 武汉钢铁(集团)公司 | High-temperature infrared radiation glaze and preparation method thereof |
| CN102391018A (en) * | 2011-08-10 | 2012-03-28 | 刘冬青 | Method for making archaistic semimatte thin glaze for Ru porcelain |
| WO2013139257A1 (en) * | 2012-03-19 | 2013-09-26 | 东莞市海格瑞化工有限公司 | Burn-free colored glaze material |
| CN104829120A (en) * | 2015-04-15 | 2015-08-12 | 涡阳县鸿运玻璃制品有限公司 | Glass clarification flux and preparation method thereof |
| CN104876438A (en) * | 2015-04-15 | 2015-09-02 | 涡阳县鸿运玻璃制品有限公司 | Glass fluxing agent containing barium peroxide and preparation method thereof |
| CN106082670A (en) * | 2016-06-22 | 2016-11-09 | 德化县太阳鸟工艺品有限公司 | Foaming glaze and the glaze foamed ceramic made of it |
| CN106336117A (en) * | 2016-08-26 | 2017-01-18 | 佛山市高明区明城镇新能源新材料产业技术创新中心 | Preparation method of waterproof coating of fused quartz ceramic |
| CN107447591A (en) * | 2017-08-22 | 2017-12-08 | 江苏众立生包装科技有限公司 | A kind of production method of tobacco package far infrared paper |
| CN111333430A (en) * | 2020-05-19 | 2020-06-26 | 佛山市东鹏陶瓷发展有限公司 | Deodorizing glaze and preparation method of glazed tile using same |
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| US5830812A (en) * | 1996-04-01 | 1998-11-03 | Ppg Industries, Inc. | Infrared and ultraviolet radiation absorbing green glass composition |
| CN1174938C (en) * | 2001-08-30 | 2004-11-10 | 武汉大学 | Photocatalystic self-cleaning TiO2 ceramic and its prepn. |
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| CN101353227B (en) * | 2007-07-23 | 2011-05-11 | 珠海天睿生物科技有限公司 | Far infrared composite powder |
| CN102391017A (en) * | 2011-08-09 | 2012-03-28 | 武汉钢铁(集团)公司 | High-temperature infrared radiation glaze and preparation method thereof |
| CN102391017B (en) * | 2011-08-09 | 2013-07-31 | 武汉钢铁(集团)公司 | High-temperature infrared radiation glaze and preparation method thereof |
| CN102391018A (en) * | 2011-08-10 | 2012-03-28 | 刘冬青 | Method for making archaistic semimatte thin glaze for Ru porcelain |
| WO2013139257A1 (en) * | 2012-03-19 | 2013-09-26 | 东莞市海格瑞化工有限公司 | Burn-free colored glaze material |
| CN104876438A (en) * | 2015-04-15 | 2015-09-02 | 涡阳县鸿运玻璃制品有限公司 | Glass fluxing agent containing barium peroxide and preparation method thereof |
| CN104829120A (en) * | 2015-04-15 | 2015-08-12 | 涡阳县鸿运玻璃制品有限公司 | Glass clarification flux and preparation method thereof |
| CN106082670A (en) * | 2016-06-22 | 2016-11-09 | 德化县太阳鸟工艺品有限公司 | Foaming glaze and the glaze foamed ceramic made of it |
| CN106082670B (en) * | 2016-06-22 | 2018-12-11 | 德化县太阳鸟工艺品有限公司 | Foam glaze and the glaze paint foamed ceramic with its production |
| CN106336117A (en) * | 2016-08-26 | 2017-01-18 | 佛山市高明区明城镇新能源新材料产业技术创新中心 | Preparation method of waterproof coating of fused quartz ceramic |
| CN106336117B (en) * | 2016-08-26 | 2019-02-12 | 佛山市高明区明城镇新能源新材料产业技术创新中心 | A kind of preparation method of the waterproof coating of fused quartz ceramic |
| CN107447591A (en) * | 2017-08-22 | 2017-12-08 | 江苏众立生包装科技有限公司 | A kind of production method of tobacco package far infrared paper |
| CN111333430A (en) * | 2020-05-19 | 2020-06-26 | 佛山市东鹏陶瓷发展有限公司 | Deodorizing glaze and preparation method of glazed tile using same |
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| CN1297519C (en) | 2007-01-31 |
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Granted publication date: 20070131 Termination date: 20191024 |