CN106866103B - Nanometer fireproof decorative panel and its manufacturing method - Google Patents
Nanometer fireproof decorative panel and its manufacturing method Download PDFInfo
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- CN106866103B CN106866103B CN201710101833.0A CN201710101833A CN106866103B CN 106866103 B CN106866103 B CN 106866103B CN 201710101833 A CN201710101833 A CN 201710101833A CN 106866103 B CN106866103 B CN 106866103B
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/30—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
- C04B28/32—Magnesium oxychloride cements, e.g. Sorel cement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/52—Producing shaped prefabricated articles from the material specially adapted for producing articles from mixtures containing fibres, e.g. asbestos cement
- B28B1/525—Producing shaped prefabricated articles from the material specially adapted for producing articles from mixtures containing fibres, e.g. asbestos cement containing organic fibres, e.g. wood fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B3/00—Producing shaped articles from the material by using presses; Presses specially adapted therefor
- B28B3/12—Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein one or more rollers exert pressure on the material
- B28B3/123—Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein one or more rollers exert pressure on the material on material in moulds or on moulding surfaces moving continuously underneath or between the rollers, e.g. on an endless belt
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention discloses a kind of nanometer fireproof decorative panel and its manufacturing method, which is calculated with parts by weight, including following component：24 parts of 26 parts of diatomite, 13 parts of waterglass, 0.1 1 parts of nano silicon dioxide, 0.1 1 parts of zinc oxide, 5 15 parts of titanium dioxide powder, 10 30 parts of magnesium chloride, 10 30 parts of magnesia and modifying agent.Nano silicon dioxide has the characteristics that absorption property is strong, prevents fires, is heat-insulated, heat safe；Diatomite in powder has unique pore structure, and weight is light and soft, and porosity is big, the strong feature of absorption property；Nanometer titanium dioxide titanium valve has uvioresistant, antibacterial, sterilization, anti-aging performance；Zinc oxide has high-strength, bloom, high abrasion, anti-aging special function.By the combination of each functional material, does not burn, prevents fires completely to reach fireproof decoration plate, is moisture-proof, nontoxic, sterilization, drive roach, drive ant and recyclable regeneration, environment friendly and pollution-free function, the performance of existing fireproof decoration plate can be optimized significantly.
Description
Technical field
The present invention relates to the technical field of building materials more particularly to a kind of nanometer fireproof decorative panel and its manufacturing methods.
Background technology
Currently, house, office space indoor and outdoor decorative material for wall surface mostly use coating, ceramic tile, marble, artificial marble
The materials such as stone, solid wood board, aluminium-plastic panel, wallpaper, traditional material cost of manufacture is high, needs to produce in a large amount of artificial, production processes
Raw a large amount of rubbish especially return Nan Tian's metope humidity, and wallpaper, the service life of plank are short, once it makes moist, be squeezed, high/low temperature
It is poor to be easy for cracking greatly, deform, is mouldy, it grows bacterium, attract cockroach, mosquito, fly, ant, therefore, invention one kind is manufactured into
This cheap nanometer fireproof decorative panel replaces traditional product, has profound historical significance and market value.
Invention content
Shortcoming present in view of the above technology, the present invention provide a kind of recyclable regeneration, environment friendly and pollution-free
Nanometer fireproof decorative panel and its manufacturing method.
In order to achieve the above object, a kind of nanometer fireproof decorative panel of the present invention, is calculated with parts by weight, including below at
Point：
2-6 parts of diatomite；
1-3 parts of waterglass；
0.1-1 parts of nano silicon dioxide；
0.1-1 parts of zinc oxide；
5-15 parts of titanium dioxide powder；
10-30 parts of magnesium chloride；
10-30 parts of magnesia；
And 2-4 parts of modifying agent.
Wherein, which further includes 2-4 parts of Folium Artemisiae Argyi powder, 1-3 parts of Herba Menthae powder, 1-3 parts of leaf of Cortex cinnamomi camphorae powder and drives
1-3 parts of mosquito grass meal.
Wherein, which further includes 0.1-1 parts of lemon powder, 0.1-1 parts of lavender powder, 0.1-1 parts of ginger powder, ice
1-2 parts of 0.1-1 parts of piece powder, 0.1-1 parts of borax powder and sea salt powder.
Wherein, the waterglass, nano silicon dioxide, zinc oxide, Folium Artemisiae Argyi powder, Herba Menthae powder, leaf of Cortex cinnamomi camphorae powder, Mozzie buster
Powder, lemon powder, lavender powder, ginger powder, borneol powder, borax powder and sea salt powder are received by grinding and mechanical milling process formation
Rice flour last current state.
Wherein, which further includes 15-20 parts of leaf of Cortex cinnamomi camphorae powder or stalk.
The invention also discloses a kind of manufacturing methods of nanometer fireproof decorative panel, include the following steps：
S1, raw material mixing：By 2-6 parts of diatomite, 1-3 parts of waterglass, 0.1-1 parts of nano silicon dioxide, 0.1-1
Part zinc oxide, 5-15 parts of titanium dioxide powder, 10-30 parts of magnesium chloride, 10-30 parts of magnesia, 2-4 parts of modifying agent with
And 15-20 parts of leaf of Cortex cinnamomi camphorae powder or stalk is added in batch mixer according to sequencing and carries out raw material and be sufficiently mixed；
S2, material tube is poured into：Mixed material in batch mixer is transported in the medium mold to be implanted of material tube；
S3, roll-forming：Mixed material is injected into mold, it is automatically that material roll-in is smooth using roller；
S4, surface polishing：Pressed sheet is cut according to the size of adjustment, and product is placed in by grinding machine according to specification
Surface polishing is carried out, keeps surface smooth.
Wherein, in S1 first by 1-3 parts of waterglass, 0.1-1 parts of nano silicon dioxide, 0.1-1 parts of zinc oxide,
1-3 parts of Herba Menthae powder, 1-3 parts of leaf of Cortex cinnamomi camphorae powder, 1-3 parts of mosquito repellent grass meal, 0.1-1 parts of lemon powder, 0.1-1 parts smoke clothing
Grass meal, 0.1-1 parts of ginger powder, 0.1-1 parts of borneol powder, 0.1-1 parts of borax powder and 0.1-1 parts of sea salt powder pass through powder
The process of broken, grinding and ball milling forms nanometer powder, and the above nanometer powder and 2-6 parts of diatomite are poured into blender
It is mixed, and mixture is toasted in the environment of 80-100 DEG C, so that nanometer powder is filled into diatomaceous gap,
The mixing of remaining material in S1 is carried out again.
Wherein, further include spraying to take off on mold before mixed material injects mold during the roll-forming of S3
Mould agent, and enclose the process of layer of glass.
Wherein, in the surface polishing process of S4, after pressed sheet is cut, the plank of forming is placed in material frame
Upper feeding thermostatic chamber carries out 12 hours thermostatic curings, then carries out polishing processing.
Wherein, which further includes the plate surface maintenance processes of S5, and smooth product uses environment-protecting and non-poisonous
Ink carries out color, wood grain, the printing of marble grain pattern on four color printers of high speed；Ultraviolet light is carried out in plate surface
Processing, enhances anti-aging function and wearing coefficient.
The beneficial effects of the invention are as follows：
Compared with prior art, nanometer fireproof decorative panel of the invention, nano silicon dioxide have absorption property strong, anti-
Fiery, heat-insulated, heat safe feature；Diatomite in powder has unique pore structure, and weight is light and soft, and porosity is big, and absorption property is strong
The characteristics of；Nanometer titanium dioxide titanium valve has uvioresistant, antibacterial, sterilization, anti-aging performance；Waterglass primarily serve bonding with
Fireproof acts on；Zinc oxide has high-strength, bloom, high abrasion, anti-aging special function；Modifying agent has cladding crystal and guarantor
The effect for protecting crystal is the solvent that must be added when magnesium chloride, magnesia and water react.By the combination of each functional material, from
And fireproof decoration plate is reached and has not burnt, prevents fires completely, is moisture-proof, is nontoxic, sterilization, drive roach, drive ant and recyclable regeneration, ring
Free of contamination function is protected, the performance of existing fireproof decoration plate can be optimized significantly, is had profound historical significance and market value.
The fireproof decoration plate manufacturing approach craft flow of the present invention is simple, requires that equipment is low and operability is strong, can be widely available and push away
Wide application.
Description of the drawings
Fig. 1 is the flow chart of the manufacturing method of nanometer fireproof decorative panel of the present invention.
Specific implementation mode
In order to more clearly state the present invention, the present invention is further described below in conjunction with the accompanying drawings.
Refering to fig. 1, the invention discloses a kind of manufacturing method of nanometer fireproof decorative panel, include the following steps：
S1, raw material mixing：First by 1-3 parts of waterglass, 0.1-1 parts of nano silicon dioxide, 0.1-1 parts of oxidation
Zinc, 1-3 parts of Herba Menthae powder, 1-3 parts of leaf of Cortex cinnamomi camphorae powder, 1-3 parts of mosquito repellent grass meal, 0.1-1 parts of lemon powder, 0.1-1 parts
Lavender powder, 0.1-1 parts of ginger powder, 0.1-1 parts of borneol powder, 0.1-1 parts of borax powder and 0.1-1 parts of sea salt powder warp
The process for crossing crushing, grinding and ball milling forms nanometer powder, and the above nanometer powder and 2-6 parts of diatomite are poured into stirring
It is mixed in machine, and mixture is toasted in the environment of 80-100 DEG C, so that nanometer powder is filled into diatomaceous sky
In gap, then by diatomaceous mixture, 5-15 parts of titanium dioxide powder, 10-30 parts of magnesium chloride, 10-30 parts of magnesia, 2-
The leaf of Cortex cinnamomi camphorae powder or stalk of 4 parts of modifying agent and 15-20 part are added in batch mixer according to sequencing and carry out filling for raw material
Divide mixing；
S2, material tube is poured into：Mixed material in batch mixer is transported in the medium mold to be implanted of material tube；
S3, roll-forming：Releasing agent is sprayed on mold, and encloses layer of glass, and mixture is injected into mold
Material, it is automatically that material roll-in is smooth using roller；
S4, surface polishing：Pressed sheet is cut according to the size of adjustment, the plank of forming is placed on material frame
It is sent into thermostatic chamber and carries out 12 hours thermostatic curings, and product is placed in sander according to specification and carries out polishing processing, make surface
It is smooth.
S5, plate surface maintenance：Smooth product is carried out using environment-protecting and non-poisonous ink on four color printers of high speed
Color, wood grain, the printing of marble grain pattern；Ultraviolet light processing is carried out in plate surface；And use edge banding machine by plank four
Week carries out edge sealing with batten.
Waterglass：Waterglass is a kind of water-soluble silicate, and aqueous solution is commonly called as waterglass, is a kind of mine binder.Its
Chemical formula is R2OnSiO2, and R2O is alkali metal oxide in formula, and n is the ratio of silica and alkali metal oxide molal quantity
Value, the referred to as number that rubs of waterglass.
Diatomite：It is a kind of biogenic siliceous sedimentary rock, it is mainly made of the remains of ancient times diatom.Its chemistry
Ingredient can indicate that mineralogical composition is opal and its mutation based on SiO2 with SiO2 nH2O.Kieselguhr wall material is to moisture
Absorption and release can generate waterfall effect, by water-molecule dissociation at negative ions.Due to hydrone be wrapped, formed it is positive and negative from
Subgroup is swum everywhere in air then using hydrone as carrier, possesses sterilizing ability.That swims everywhere in air is positive and negative
Cluster ion encounters the harmful substances such as allergin and other bacteriums, mould, can be surrounded and is isolated immediately.So
Afterwards, the most active hydroxide ion of performance carries out violent chemical reaction with these harmful substances in negative ions group, finally will
They are completely decomposed into the harmless objects such as hydrone.
Titanium dioxide：It was verified that the dichloride in anatase type TiO2 with 0.1mg/cm3 concentration can thoroughly kill HeLa cell,
The killing rate of hay bacillus, Pseudomonas aeruginosa, Escherichia coli, gold-coloured staphylococci, salmonella, tooth branch bacterium and Aspergillus is reached
98% or more, under the action of fluorescent lamp or ultraviolet, so that TiO2 is activated and generate the free radical with high catalytic activity, energy
Very strong photooxidation and reducing power are generated, can be catalyzed, photodissociation is attached to the organic matters such as the various formaldehyde of body surface, inorganic
Object can play the role of purifying the air of a room.
Leaf of Cortex cinnamomi camphorae powder or stalk：Not only using expelling parasite but also it can mitigate the weight of plank as packing material.
First embodiment
A kind of nanometer fireproof decorative panel of the present invention, is calculated, including following component with parts by weight：
4 parts of diatomite, 2 parts of waterglass, 0.5 part of nano silicon dioxide, 0.5 part of zinc oxide, 3 parts of Folium Artemisiae Argyi powder, Herba Menthae powder 2
Part, 2 parts of leaf of Cortex cinnamomi camphorae powder, 2 parts of mosquito repellent grass meal, 0.5 part of lemon powder, 0.5 part of lavender powder, 0.5 part of ginger powder, borneol powder 0.5
Part, 0.5 part of borax powder, 1.5 parts of sea salt powder, 10 parts of nanometer titanium dioxide titanium valve, 20 parts of magnesium chloride, 20 parts of magnesia and modification
17 parts of 3 parts of agent, leaf of Cortex cinnamomi camphorae powder or stalk.
Second embodiment
A kind of nanometer fireproof decorative panel of the present invention, is calculated, including following component with parts by weight：
2 parts of diatomite, 1 part of waterglass, 0.1 part of nano silicon dioxide, 0.1 part of zinc oxide, 2 parts of Folium Artemisiae Argyi powder, Herba Menthae powder 1
Part, 1 part of leaf of Cortex cinnamomi camphorae powder, 1 part of mosquito repellent grass meal, 0.1 part of lemon powder, 0.1 part of lavender powder, 0.1 part of ginger powder, borneol powder 0.1
Part, 0.1 part of borax powder, 1 part of sea salt powder, 5 parts of nanometer titanium dioxide titanium valve, 10 parts of magnesium chloride, 10 parts of magnesia and modifying agent 2
15 parts of part, leaf of Cortex cinnamomi camphorae powder or stalk.
3rd embodiment
A kind of nanometer fireproof decorative panel of the present invention, is calculated, including following component with parts by weight：
6 parts of diatomite, 3 parts of waterglass, 1 part of nano silicon dioxide, 1 part of zinc oxide, 4 parts of Folium Artemisiae Argyi powder, 3 parts of Herba Menthae powder, perfume
3 parts of camphortree leaf powder, 3 parts of mosquito repellent grass meal, 1 part of lemon powder, 1 part of lavender powder, 1 part of ginger powder, 1 part of borneol powder, 1 part of borax powder,
2 parts of sea salt powder, 30 parts of nano diatomite, 15 parts of nanometer titanium dioxide titanium valve, 30 parts of magnesium chloride, 30 parts of magnesia and modifying agent 4
20 parts of part, leaf of Cortex cinnamomi camphorae powder or stalk.
Disclosed above is only several specific embodiments of the present invention, but the present invention is not limited to this, any ability
What the technical staff in domain can think variation should all fall into protection scope of the present invention.
Claims (5)
1. a kind of nanometer fireproof decorative panel, which is characterized in that calculated with parts by weight, including following component：
2-6 parts of diatomite；
1-3 parts of waterglass；
0.1-1 parts of nano silicon dioxide；
0.1-1 parts of zinc oxide；
5-15 parts of titanium dioxide powder；
10-30 parts of magnesium chloride；
10-30 parts of magnesia；
And 2-4 parts of modifying agent；
The fireproof decoration plate further include 2-4 parts of Folium Artemisiae Argyi powder, 1-3 parts of Herba Menthae powder, 1-3 parts of leaf of Cortex cinnamomi camphorae powder, 1-3 parts of mosquito repellent grass meal,
0.1-1 parts of lemon powder, 0.1-1 parts of lavender powder, 0.1-1 parts of ginger powder, 0.1-1 parts of borneol powder, 0.1-1 parts of borax powder and sea
1-2 parts of salt fines；
The waterglass, nano silicon dioxide, zinc oxide, Folium Artemisiae Argyi powder, Herba Menthae powder, leaf of Cortex cinnamomi camphorae powder, mosquito repellent grass meal, lemon powder,
Lavender powder, ginger powder, borneol powder, borax powder and sea salt powder form nanometer powder shape by grinding and mechanical milling process
State.
2. a kind of manufacturing method of nanometer fireproof decorative panel, which is characterized in that calculated, included the following steps with parts by weight：
S1, first by 1-3 parts of waterglass, 0.1-1 parts of nano silicon dioxide, 0.1-1 parts of zinc oxide, 1-3 parts of peppermint
Powder, 1-3 parts of leaf of Cortex cinnamomi camphorae powder, 1-3 parts of mosquito repellent grass meal, 0.1-1 parts of lemon powder, 0.1-1 parts of lavender powder, 0.1-1
Part ginger powder, 0.1-1 part of borneol powder, the sea salt powder process crushing of 0.1-1 part of borax powder and 0.1-1 part, grinding with
And the process of ball milling forms nanometer powder, and the above nanometer powder and 2-6 parts of diatomite are poured into stirrer for mixing stirring,
And toast mixture in the environment of 80-100 DEG C, so that nanometer powder is filled into diatomaceous gap, then by diatom
Soil mixture, 5-15 parts of titanium dioxide powder, 10-30 parts of magnesium chloride, 10-30 parts of magnesia, 2-4 parts of modifying agent with
And 15-20 parts of leaf of Cortex cinnamomi camphorae powder or stalk is added in batch mixer according to sequencing and carries out raw material and be sufficiently mixed；
S2, material tube is poured into：Mixed material in batch mixer is transported in the medium mold to be implanted of material tube；
S3, roll-forming：Mixed material is injected into mold, it is automatically that material roll-in is smooth using roller；
S4, surface polishing：Pressed sheet is cut according to the size of adjustment, and product is placed in by grinding machine according to specification and is carried out
Surface polishes, and keeps surface smooth.
3. the manufacturing method of nanometer fireproof decorative panel according to claim 2, which is characterized in that in the roll-forming mistake of S3
Cheng Zhong further includes the mistake for spraying releasing agent on mold, and enclosing layer of glass before mixed material injects mold
Journey.
4. the manufacturing method of nanometer fireproof decorative panel according to claim 2, which is characterized in that polished on the surface of S4
The plank of forming after cutting pressed sheet, is placed in feeding thermostatic chamber 12 hours constant temperature of progress on material frame and supported by Cheng Zhong
Shield, then carry out polishing processing.
5. the manufacturing method of nanometer fireproof decorative panel according to claim 2, which is characterized in that the manufacturing method further includes
The plate surface maintenance processes of S5, smooth product carry out face using environment-protecting and non-poisonous ink on four color printers of high speed
Color, wood grain, the printing of marble grain pattern；Ultraviolet light processing is carried out in plate surface, enhances anti-aging function and wear-resisting system
Number.
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| CN201610999189 | 2016-11-14 | ||
| CN2016109991899 | 2016-11-14 |
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| CN106866103B true CN106866103B (en) | 2018-08-21 |
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| CN109267686A (en) * | 2017-07-18 | 2019-01-25 | 上海前引科技有限公司 | A kind of fireproof mould-proof antibacterial anionic furred ceiling |
| CN110683825A (en) * | 2018-07-06 | 2020-01-14 | 江苏吉福新材料股份有限公司 | Decorative plate and manufacturing method thereof |
| CN110683824A (en) * | 2018-07-06 | 2020-01-14 | 江苏吉福新材料股份有限公司 | Decorative plate and manufacturing method thereof |
| CN110423091A (en) * | 2019-09-02 | 2019-11-08 | 范斌 | A kind of preparation method of alkali magnesium cement fire prevention cockroach proof humidity conditioning function wardrobe plate |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104310942A (en) * | 2014-10-14 | 2015-01-28 | 武汉大学 | Formaldehyde-free carbon dioxide absorption functional composite plate and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104310942A (en) * | 2014-10-14 | 2015-01-28 | 武汉大学 | Formaldehyde-free carbon dioxide absorption functional composite plate and preparation method thereof |
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Address after: 430000 Poly Plaza, No. 99 South Central Road, Wuchang District, Hubei, China Applicant after: He Xinqiao Applicant after: He Shan Address before: 518107 Guangdong province Shenzhen Guangming New District Gongming Yong King City 12B1301 Applicant before: He Xinqiao Applicant before: He Shan |
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