CN106082670B - Foam glaze and the glaze paint foamed ceramic with its production - Google Patents
Foam glaze and the glaze paint foamed ceramic with its production Download PDFInfo
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- CN106082670B CN106082670B CN201610450805.5A CN201610450805A CN106082670B CN 106082670 B CN106082670 B CN 106082670B CN 201610450805 A CN201610450805 A CN 201610450805A CN 106082670 B CN106082670 B CN 106082670B
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
- C04B2235/963—Surface properties, e.g. surface roughness
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
- C04B2235/9669—Resistance against chemicals, e.g. against molten glass or molten salts
- C04B2235/9692—Acid, alkali or halogen resistance
Abstract
The present invention relates to a kind of foaming glaze and the glaze paint foamed ceramics made of it, belong to ceramic technology field.Foaming glaze includes the following component according to mass fraction meter: 38 ~ 42 parts of potassium feldspar, 13 ~ 16 parts of kaolin, 5 ~ 8 parts of zirconium silicate, 8 ~ 11 parts of barium carbonate, 7 ~ 12 parts of quartz, 7 ~ 9 parts of calcium carbonate, 2 ~ 5 parts of zinc oxide, 5 ~ 10 parts of talcum, 0.8 ~ 1.3 part of magnesium carbonate, 1 ~ 5 part of silicon carbide, 2 ~ 4 parts of neodymia, 8 ~ 11 parts of clay, 16 ~ 20 parts of borax, 0.2 ~ 0.5 part of manganese oxide, 0.2 ~ 0.4 part of iron oxide, 18 ~ 24 parts of glass powder, 15 ~ 21 parts of low temperature frit, wherein, the low temperature frit includes the following component according to mass fraction meter: 47 ~ 51 parts of borax, 38 ~ 41 parts of potassium feldspar, 11 ~ 13 parts of calcium carbonate, 6 ~ 9 parts of kaolin;With the method for the foaming glaze production glaze paint foamed ceramic, includes the following steps: grinding, the adjusting of glaze concentration, glazing, fire extruding, is cooling to get glaze paint foamed ceramic.The present invention, which provides one kind, has discoloration effect, meanwhile, the glaze paint foamed ceramic with very strong acid-fast alkali-proof and pressure-proof and snap-resistent performance.
Description
Technical field
The invention belongs to ceramic technology fields, and in particular to a kind of foaming glaze and the glaze paint foamed ceramic with its production.
Background technique
Glaze is the glassy thin layer for being covered on the billet surfaces such as ceramics, enamel, and raw material used in general glaze is raw mineral materials
Such as quartz, feldspar, kaolin and chemical addition agent mix according to a certain ratio, by grinding, glazing, firing
And it obtains.Glaze smooth surface is glossy, and has the waterproof performance for being not easy to stain, and the physics of ceramic body not only can be improved
Performance can also enhance the appearance of beautification ceramic.
The foaming fired foaming of glaze forms glaze paint foaming on ceramic, has very strong appreciating, and have and prevent
Fiery heat insulation effect, but the acid-fast alkali-proof of existing foaming glaze ceramics and pressure-proof and snap-resistent performance are not able to satisfy the demand of people.Application
Number Chinese patent for being 201210190895.0, discloses a kind of foamed ceramic material and preparation method thereof, adopts in cosolvent
It with calcirm-fluoride, is disagreed with society is advocated now environmental protection, in firing bulking step, heating rate is slow, when firing
Between it is long, be unfavorable for energy saving, and the composition of raw materials used is less, and the ceramic product produced can no longer meet social now
The vision of product is appreciated and is required.
Application No. is 200710055292.9 Chinese patents, disclose a kind of tuff glaze foam ceramic thermal insulation decoration
Cosolvent, foaming agent, antioxidant is added using the tufa stone of natural rich reserves as primary raw material in brick and method of manufacturing technology,
In 1050 DEG C ~ 1200 DEG C formation foamed ceramicses, wherein the rich reserves of raw material are easy to get, but in cooling procedure, are still needed to
To cool down according to certain temperature range, and control certain cooling rate.
Summary of the invention
The purpose of the present invention is overcome the deficiencies of the prior art and provide it is a kind of foaming glaze and with its production glaze paint foaming pottery
Porcelain, wherein raw material used in the present invention easily obtains and is environmental protection material, has discoloration effect, meanwhile, have very strong resistance to
Sour alkaline-resisting and pressure-proof and snap-resistent performance.
The present invention can be achieved through the following technical solutions:
A kind of foaming glaze, including the following component according to mass fraction meter: 38 ~ 42 parts of potassium feldspar, 13 ~ 16 parts of kaolin,
5 ~ 8 parts of zirconium silicate, 8 ~ 11 parts of barium carbonate, 7 ~ 12 parts of quartz, 7 ~ 9 parts of calcium carbonate, 2 ~ 5 parts of zinc oxide, 5 ~ 10 parts of talcum, magnesium carbonate
0.8 ~ 1.3 part, 1 ~ 5 part of silicon carbide, 2 ~ 4 parts of neodymia, 8 ~ 11 parts of clay, 16 ~ 20 parts of borax, 0.2 ~ 0.5 part of manganese oxide, oxidation
0.2 ~ 0.4 part of iron, 18 ~ 24 parts of glass powder, 15 ~ 21 parts of low temperature frit, wherein the low temperature frit includes according to mass fraction meter
Following component: 47 ~ 51 parts of borax, 38 ~ 41 parts of potassium feldspar, 11 ~ 13 parts of calcium carbonate, 6 ~ 9 parts of kaolin.
Further, including the following component according to mass fraction meter: 40 parts of potassium feldspar, 15 parts of kaolin, zirconium silicate 7
Part, 10 parts of barium carbonate, 9 parts of quartz, 8 parts of calcium carbonate, 2 parts of zinc oxide, 8 parts of talcum, 1 part of magnesium carbonate, 1.6 parts of silicon carbide, oxidation
3 parts of neodymium, 9 parts of clay, 19 parts of borax, 0.2 part of manganese oxide, 0.2 part of iron oxide, 20 parts of glass powder, 19 parts of low temperature frit.
Further, the low temperature frit includes the following component according to mass fraction meter: 48 parts of borax, potassium feldspar 29
Part, 12 parts of calcium carbonate, 8 parts of kaolin.
With the method for the foaming glaze production glaze paint foamed ceramic, include the following steps:
Step 1, grinding:
According to the mass ratio, after each raw material component is mixed, the water that total mass of raw material 70% ~ 85% is added is ground,
Ball-milling Time is 40 ~ 45h, crosses sieve, obtains ball milling material;
Step 2, glaze concentration are adjusted:
Water is added in the resulting ball milling material of step 1, is adjusted to 46 ~ 49 Baume degrees, obtains glaze slurry;
Step 3, glazing:
Using glaze method, the ceramic idiosome baked is immersed into glaze slurry obtained by step 2, must foam glaze ceramics after dry
Semi-finished product;
Step 4 fires extruding:
Foaming glaze ceramic semi-finished product obtained by step 3 is fired, specific firing is as follows: with the heating of 20 ~ 35 DEG C/min
Speed is warming up to 800 DEG C, is warming up to 1100 DEG C with the heating rate of 15 ~ 18 DEG C/min, with the heating rate liter of 7 ~ 13 DEG C/min
For temperature to 1200 ~ 1280 DEG C, constant temperature fires natural cooling after 70 ~ 90min, obtains glaze paint foamed ceramic.
Further, in step 1, the revolving speed when ball milling is 400 ~ 450r/min, and sieve is 200 mesh screens.
Further, in step 3, the drying is carried out in the environment that humidity is 50% in temperature 60 C, and drying time is
6h。
Further, in the firing puffing process, specific firing is as follows: being warming up to the heating rate of 26 DEG C/min
800 DEG C, 1100 DEG C are warming up to the heating rate of 17 DEG C/min, is warming up to 1200 ~ 1280 DEG C with the heating rate of 8 DEG C/min,
Constant temperature fires natural cooling after 70 ~ 90min, obtains glaze paint foamed ceramic.
Compared with prior art, the present invention has the advantages that:
Foaming glaze of the invention and the glaze paint foamed ceramic made of it, the raw material of use easily obtain and are environmentally friendly material
Material.Wherein, it joined rare-earth oxidation neodymium, the unique optical property of rare earth be utilized, keeps ceramic product beautiful in colour, soft and moist, hair
It steeps glaze and neodymia is added, since neodymia has discoloration effect, make the color multiplicity of glaze paint foamed ceramic, product is more appreciated
Property;Moreover, the product produced has excellent performance, wherein its acid resistance reaches 99%, and fastness to alkali reaches 98%, pressure resistance
Degree reaches 20MPa, and flexural strength reaches 20MPa;Meanwhile in the production process, simple process, it is easily controllable, after the completion of firing
Natural cooling is only needed, it is energy saving, it is suitble to popularity.
Specific embodiment
Below by specific embodiment, invention is further described in detail, but those skilled in the art will manage
Solution, the following example is merely to illustrate the present invention, and should not be taken as limiting the scope of the invention.
Embodiment 1
A kind of foaming glaze, including the following component according to mass fraction meter: 38 parts of potassium feldspar, 13 parts of kaolin, zirconium silicate 5
Part, 8 parts of barium carbonate, 7 parts of quartz, 7 parts of calcium carbonate, 2 parts of zinc oxide, 5 parts of talcum, 0.8 part of magnesium carbonate, 1 part of silicon carbide, neodymia
2 parts, 8 parts of clay, 16 parts of borax, 0.2 part of manganese oxide, 0.2 part of iron oxide, 18 parts of glass powder, 15 parts of low temperature frit, wherein institute
Stating low temperature frit includes the following component according to mass fraction meter: 47 parts of borax, 38 parts of potassium feldspar, and 11 parts of calcium carbonate, kaolin 6
Part.
With the method for the foaming glaze production glaze paint foamed ceramic, include the following steps:
Step 1, grinding:
According to the mass ratio, after each raw material component is mixed, the water that total mass of raw material 70% is added is ground, ball milling
When revolving speed be 400r/min, Ball-milling Time 40h, cross 200 mesh screens, obtain ball milling material;
Step 2, glaze concentration are adjusted:
Water is added in the resulting ball milling material of step 1, is adjusted to 46 Baume degrees, obtains glaze slurry;
Step 3, glazing:
Using glaze method, the ceramic idiosome baked is immersed into glaze slurry obtained by step 2, in temperature 60 C, humidity is
It is dried in 50% environment, drying time 6h, must foam glaze ceramic semi-finished product;
Step 4 fires extruding:
Foaming glaze ceramic semi-finished product obtained by step 3 is fired, specific firing is as follows: with the heating speed of 20 DEG C/min
Degree is warming up to 800 DEG C, then is warming up to 1100 DEG C with the heating rate of 15 DEG C/min, is finally heated up with the heating rate of 7 DEG C/min
To 1200 DEG C, constant temperature fires natural cooling after 70min, obtains glaze paint foamed ceramic.
Embodiment 2
A kind of foaming glaze, including the following component according to mass fraction meter: 40 parts of potassium feldspar, 15 parts of kaolin, zirconium silicate 7
Part, 10 parts of barium carbonate, 9 parts of quartz, 8 parts of calcium carbonate, 2 parts of zinc oxide, 8 parts of talcum, 1 part of magnesium carbonate, 1.6 parts of silicon carbide, oxidation
3 parts of neodymium, 9 parts of clay, 19 parts of borax, 0.2 part of manganese oxide, 0.2 part of iron oxide, 20 parts of glass powder, 19 parts of low temperature frit.Wherein,
The low temperature frit includes the following component according to mass fraction meter: 48 parts of borax, 29 parts of potassium feldspar, and 12 parts of calcium carbonate, kaolinite
8 parts of soil.
With the method for the foaming glaze production glaze paint foamed ceramic, include the following steps:
Step 1, grinding:
According to the mass ratio, after each raw material component is mixed, the water that total mass of raw material 80% is added is ground, ball milling
When revolving speed be 430r/min, Ball-milling Time 42h, cross 200 mesh screens, obtain ball milling material;
Step 2, glaze concentration are adjusted:
Water is added in the resulting ball milling material of step 1, is adjusted to 48 Baume degrees, obtains glaze slurry;
Step 3, glazing:
Using glaze method, the ceramic idiosome baked is immersed into glaze slurry obtained by step 2, in temperature 60 C, humidity is
It is dried in 50% environment, drying time 6h, must foam glaze ceramic semi-finished product;
Step 4 fires extruding:
Foaming glaze ceramic semi-finished product obtained by step 3 is fired, specific firing is as follows: with the heating speed of 26 DEG C/min
Degree is warming up to 800 DEG C, then is warming up to 1100 DEG C with the heating rate of 17 DEG C/min, is finally heated up with the heating rate of 8 DEG C/min
To 1200 DEG C, constant temperature fires natural cooling after 70min, obtains glaze paint foamed ceramic.
Embodiment 3
A kind of foaming glaze, including the following component according to mass fraction meter: 40 parts of potassium feldspar, 15 parts of kaolin, zirconium silicate 7
Part, 10 parts of barium carbonate, 9 parts of quartz, 8 parts of calcium carbonate, 2 parts of zinc oxide, 8 parts of talcum, 1 part of magnesium carbonate, 1.6 parts of silicon carbide, oxidation
3 parts of neodymium, 9 parts of clay, 19 parts of borax, 0.2 part of manganese oxide, 0.2 part of iron oxide, 20 parts of glass powder, 19 parts of low temperature frit.Wherein,
The low temperature frit includes the following component according to mass fraction meter: 48 parts of borax, 29 parts of potassium feldspar, and 12 parts of calcium carbonate, kaolinite
8 parts of soil.
With the method for the foaming glaze production glaze paint foamed ceramic, include the following steps:
Step 1, grinding:
According to the mass ratio, after each raw material component is mixed, the water that total mass of raw material 80% is added is ground, ball milling
When revolving speed be 430r/min, Ball-milling Time 42h, cross 200 mesh screens, obtain ball milling material;
Step 2, glaze concentration are adjusted:
Water is added in the resulting ball milling material of step 1, is adjusted to 48 Baume degrees, obtains glaze slurry;
Step 3, glazing:
Using glaze method, the ceramic idiosome baked is immersed into glaze slurry obtained by step 2, in temperature 60 C, humidity is
It is dried in 50% environment, drying time 6h, must foam glaze ceramic semi-finished product;
Step 4 fires extruding:
Foaming glaze ceramic semi-finished product obtained by step 3 is fired, specific firing is as follows: with the heating speed of 26 DEG C/min
Degree is warming up to 800 DEG C, then is warming up to 1100 DEG C with the heating rate of 17 DEG C/min, is finally heated up with the heating rate of 8 DEG C/min
To 1200 DEG C, constant temperature fires natural cooling after 70min, obtains glaze paint foamed ceramic.
The present invention is detected according to glaze paint foamed ceramic obtained by embodiment 1, embodiment 2 and embodiment 3, as a result
It is as shown in table 1 below:
1 test result of table
The above is a preferred embodiment of the present invention, it is noted that for those skilled in the art
For, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also considered as
Protection scope of the present invention.
Claims (7)
1. a kind of foaming glaze, which is characterized in that including the following component according to mass fraction meter: 38 ~ 42 parts of potassium feldspar, kaolin
13 ~ 16 parts, 5 ~ 8 parts of zirconium silicate, 8 ~ 11 parts of barium carbonate, 7 ~ 12 parts of quartz, 7 ~ 9 parts of calcium carbonate, 2 ~ 5 parts of zinc oxide, talcum 5 ~ 10
Part, 0.8 ~ 1.3 part of magnesium carbonate, 1 ~ 5 part of silicon carbide, 2 ~ 4 parts of neodymia, 8 ~ 11 parts of clay, 16 ~ 20 parts of borax, manganese oxide 0.2 ~
0.5 part, 0.2 ~ 0.4 part of iron oxide, 18 ~ 24 parts of glass powder, 15 ~ 21 parts of low temperature frit, wherein the low temperature frit include according to
The following component of mass fraction meter: 47 ~ 51 parts of borax, 38 ~ 41 parts of potassium feldspar, 11 ~ 13 parts of calcium carbonate, 6 ~ 9 parts of kaolin.
2. foaming glaze according to claim 1, which is characterized in that including the following component according to mass fraction meter: potassium is long
40 parts of stone, 15 parts of kaolin, 7 parts of zirconium silicate, 10 parts of barium carbonate, 9 parts of quartz, 8 parts of calcium carbonate, 2 parts of zinc oxide, 8 parts of talcum, carbon
1 part of sour magnesium, 1.6 parts of silicon carbide, 3 parts of neodymia, 9 parts of clay, 19 parts of borax, 0.2 part of manganese oxide, 0.2 part of iron oxide, glass powder
20 parts, 19 parts of low temperature frit.
3. foaming glaze according to claim 1, which is characterized in that the low temperature frit include according to mass fraction meter as
Lower component: 48 parts of borax, 29 parts of potassium feldspar, 12 parts of calcium carbonate, 8 parts of kaolin.
4. with the method for foaming glaze production glaze paint foamed ceramic according to claim 1, which is characterized in that including walking as follows
It is rapid:
Step 1, grinding:
According to the mass ratio, after each raw material component is mixed, the water that total mass of raw material 70% ~ 85% is added is ground, ball milling
Time is 40 ~ 45h, crosses sieve, obtains ball milling material;
Step 2, glaze concentration are adjusted:
Water is added in the resulting ball milling material of step 1, is adjusted to 46 ~ 49 Baume degrees, obtains glaze slurry;
Step 3, glazing:
Using glaze method, the ceramic idiosome baked is immersed into glaze slurry obtained by step 2, the glaze that must foam after dry it is ceramic partly at
Product;
Step 4 fires extruding:
Foaming glaze ceramic semi-finished product obtained by step 3 is fired, specific firing is as follows: with the heating rate of 20 ~ 35 DEG C/min
800 DEG C are warming up to, 1100 DEG C is warming up to the heating rate of 15 ~ 18 DEG C/min, is warming up to the heating rate of 7 ~ 13 DEG C/min
1200 ~ 1280 DEG C, constant temperature fires natural cooling after 70 ~ 90min, obtains glaze paint foamed ceramic.
5. the method according to claim 4 with foaming glaze production foaming glaze ceramics, which is characterized in that described in step 1
Revolving speed when ball milling is 400 ~ 450r/min, and sieve is 200 mesh screens.
6. the method according to claim 4 with foaming glaze production glaze paint foamed ceramic, which is characterized in that institute in step 3
It states drying to carry out in temperature 60 C, the environment that humidity is 50%, drying time 6h.
7. the method according to claim 4 with foaming glaze production glaze paint foamed ceramic, which is characterized in that institute in step 4
It states and fires in puffing process, specific firing is as follows: 800 DEG C is warming up to the heating rate of 26 DEG C/min, with the liter of 17 DEG C/min
Warm speed is warming up to 1100 DEG C, is warming up to 1200 ~ 1280 DEG C with the heating rate of 8 DEG C/min, constant temperature fire after 70 ~ 90min from
It is so cooling, obtain glaze paint foamed ceramic.
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CN105601110A (en) * | 2016-01-14 | 2016-05-25 | 福建省泉州得盛集团有限公司 | Black silver drop reduced transmutation glaze, black silver drop reduced transmutation glaze ceramic product prepared using same and preparation method |
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KR900001543B1 (en) * | 1986-09-04 | 1990-03-12 | 최학천 | Compositions of glaze |
CN1609061A (en) * | 2003-10-24 | 2005-04-27 | 蔡日馨 | Nanometer glaze with far infrared radiating function and its application |
CN102557753A (en) * | 2011-12-14 | 2012-07-11 | 陈新基 | Glaze for fine bone china |
CN102557749A (en) * | 2011-12-14 | 2012-07-11 | 谢健城 | Formula of high-grade pottery matt glaze |
CN105218164A (en) * | 2015-10-19 | 2016-01-06 | 福建省德化县华茂陶瓷有限公司 | Copper red furnace transmutation glaze and by its copper red furnace transmutation glaze ceramic prepared and preparation method |
CN105601110A (en) * | 2016-01-14 | 2016-05-25 | 福建省泉州得盛集团有限公司 | Black silver drop reduced transmutation glaze, black silver drop reduced transmutation glaze ceramic product prepared using same and preparation method |
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