CN108147786A - A kind of heat-preserving decorating wall material and preparation method thereof - Google Patents

A kind of heat-preserving decorating wall material and preparation method thereof Download PDF

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Publication number
CN108147786A
CN108147786A CN201810013106.3A CN201810013106A CN108147786A CN 108147786 A CN108147786 A CN 108147786A CN 201810013106 A CN201810013106 A CN 201810013106A CN 108147786 A CN108147786 A CN 108147786A
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CN
China
Prior art keywords
heat
insulating layer
finish coat
decorating wall
raw material
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Pending
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CN201810013106.3A
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Chinese (zh)
Inventor
马腾
杜国炜
陈莹锐
江龙明
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Hangzhou Stephen Perot Environmental Technology Co Ltd
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Hangzhou Stephen Perot Environmental Technology Co Ltd
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Priority to CN201810013106.3A priority Critical patent/CN108147786A/en
Publication of CN108147786A publication Critical patent/CN108147786A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/1324Recycled material, e.g. tile dust, stone waste, spent refractory material
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/02Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by adding chemical blowing agents
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/0875Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having a basic insulating layer and at least one covering layer
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

Abstract

The invention discloses a kind of heat-preserving decorating wall materials and preparation method thereof.The heat-preserving decorating wall material includes insulating layer and finish coat, and the insulating layer and finish coat are combined into integral material by layered arrangement powder raw material in a mold and to the powder raw material high-temperature heat treatment.Present invention process is simple, production efficiency is high, improve the aesthetic measure of product, avoid the problem of heat-preserving decorating wall material comes off after long-term use, improve product quality and service life, and solve the problems, such as waste material of buildings can not effective recycling, reduce production cost, can obtain that good heat insulating, compression strength is high, the ideal heat-preserving decorating wall material of humidity resistance.

Description

A kind of heat-preserving decorating wall material and preparation method thereof
Technical field
The present invention relates to building material fields more particularly to a kind of heat-preserving decorating wall material and preparation method thereof.
Background technology
With the gradual scarcity of world energy sources, China has formulated the basic principle of " energy saving, to realize sustainable development ", Therefore building energy conservation also becomes an emphasis of current Chinese architecture career development.The main means of building energy conservation are outer at present Wall heat preservation technology, external-wall heat-insulation material can effectively solve China's two season of summer in winter indoor/outdoor temperature-difference and caused by energy loss ask Topic.
Thermal insulation material involved by exterior wall heat-preserving system includes two major class of organic insulation material and inorganic heat insulation material.It is organic Thermal insulation material such as thermoplastic material EPS, XPS, thermosets polyurethane, phenolic aldehyde etc., although organic insulation material has preferably Heat insulation effect, but its poor fire, and be difficult to degrade and with toxicity, environment can be adversely affected.Rock wool, expansion The inorganic heat insulation materials such as perlite, foam cement, foamed glass, mineral wool are environmental-friendly since fire protecting performance is preferable, are produced into This is relatively low, thus has obtained being widely applied further in recent years.
However, although inorganic heat insulation material has many advantages, such as energy conservation and environmental protection, safe and reliable, color is single, beautiful Degree is not ideal enough, in practical applications, usually also needs in one layer of finishing material of inorganic heat insulation material incrustation.
The prior art generally selects manufacture heat preservation and decorating wall material, and by it by way of anchoring or being bonded respectively It is connected as entirety.Therefore, the heat-preserving decorating wall material not only complex process, and easily coming off of the prior art, makes for a long time Aesthetic measure is not only influenced after, more brings security risk.
Invention content
To overcome defect and deficiency in the prior art, the invention discloses a kind of heat-preserving decorating wall material and its Preparation method.
The invention is realized by the following technical scheme:
A kind of heat-preserving decorating wall material, including insulating layer and finish coat, the insulating layer and finish coat pass through in mold Middle layered arrangement powder raw material and integral material is combined into the powder raw material high-temperature heat treatment.
Further, it is (60-70) that the raw material of the insulating layer, which includes mass percent,:(25-35):The backheat of (2-5) Material, ceramic batch and foaming agent;In mortar of the backheat material selected from building recycling, brick, concrete, ceramic cutting waste material It is at least one;The ceramic batch is selected from least one of bentonite, talcum, kaolin and small red soil.
Further, the ceramic batch includes 5%-10%, 4%- for accounting for the raw material gross mass of the insulating layer successively 10%th, the bentonite of 13%-16% and 4%-10%, talcum, kaolin and small red soil.
Further, it is (90-98) that the raw material of the finish coat, which includes mass percent,:The building stones mineral powder of (2-10) and Foaming agent.
Further, the raw material of the finish coat includes matter building stones mineral powder;The building stones mineral powder is selected from lime stone, big At least one of reason stone, granite, sandstone, flag.
Further, the thermal conductivity factor of the insulating layer is 0.065w/ (m.k) -0.1w/ (m.k).
Further, the compression strength of the insulating layer is 2.0MPa-10MPa.
Further, the water absorption rate of the insulating layer is less than or equal to 2.
A kind of preparation method of heat-preserving decorating wall material, includes the following steps:
(1) raw material of the raw material of the insulating layer and finish coat with water is mixed respectively and ground uniformly, protected respectively Warm layer slurry material and finish coat slurry material;
(2) insulating layer slurry material and finish coat slurry material are squeezed into respectively in spray tower and are dried, drying passes through after coming off Sieve detaches, and obtains insulating layer granular powder and finish coat granular powder respectively;
(3) the uniform place mat of finish coat granular powder is uniformly spread the insulating layer granular powder in mold bottom Pad is on the finish coat granular powder;
(4) mold is sent into kiln, preheats 30-40min within the temperature range of 600-700 DEG C first, then 30-40min is kept the temperature within the temperature range of being warming up to 1100-1200 DEG C;
(5) it demoulds, cut after the mold is cooled down in kiln, obtain the heat-preserving decorating wall material.
Further, the grain fineness of the insulating layer slurry material and finish coat slurry material is less than or equal to 100 mesh.
The advantage of the invention is that:
The present invention is prepared for protecting by layered arrangement powder raw material in a mold and to the powder raw material high-temperature heat treatment Warm layer and finish coat are combined into the heat-preserving decorating wall material of integral material, simple for process, and production efficiency is high, improves product Aesthetic measure avoids the problem of heat-preserving decorating wall material comes off after long-term use, improves product quality and using the longevity Life;
The present invention is by using building salvage material as raw material, and environmentally protective, solving waste material of buildings can not effectively return The problem of utilizing is received, while reduces production cost;
The ceramic batch of present invention addition special ratios obtains low thermal conductivity factor, good heat insulating, resistance to compression as raw material Intensity is high, water absorption rate is low, the ideal heat-preserving decorating wall material of humidity resistance.
Specific embodiment
In the description of this specification, reference term " one embodiment ", " some embodiments ", " some embodiments ", The description of " illustrative examples ", " example ", " specific example " or " some examples " etc. means that combining the embodiment or example retouches The particular features, structures, materials, or characteristics stated are contained at least one embodiment or example of the utility model.In this theory In bright book, schematic expression of the above terms may not refer to the same embodiment or example.Moreover, the specific spy of description Sign, structure, material or feature can in an appropriate manner combine in any one or more embodiments or example.
In implementation below, the foundation of heat-preserving decorating wall material properties test is as follows:The test method ginseng of thermal conductivity According to《Technology of Steady State Thermal Resistance of Thermal Insulating Material and one Guarded hot plate of measure in relation to characteristic》(GB/T10294-2008);The survey of compression strength Method for testing reference《Foam glass insulating product》(JC/T647-2005);The test method reference of unit weight and water absorption rate《Porous pottery Porcelain performance test methods》(GB/T1966-1996);《Exterior insulation heat-insulation system》Standard requirement (Q/ZZD002- 2012)。
The present invention provides a kind of heat-preserving decorating wall materials and preparation method thereof.
An embodiment of the present invention provides a kind of heat-preserving decorating wall material, the heat-preserving decorating wall material includes insulating layer And finish coat, the insulating layer and finish coat are warmed by layered arrangement powder raw material in a mold and to the powder raw material height Processing is combined into integral material.
The material quality percentage of the insulating layer and finish coat is (80-90):(10-20).
In some embodiments of the present invention, the material quality percentage of the insulating layer and finish coat is (86-88): (12-14)。
In some embodiments of the present invention, it is (60-70) that the raw material of the insulating layer, which includes mass percent,:(25- 35):Backheat material, ceramic batch and the foaming agent of (2-5);The backheat material be selected from building recycling mortar, brick, concrete, At least one of ceramic cutting waste material;The ceramic batch in bentonite, talcum, kaolin and small red soil at least one Kind.
In some embodiments of the present invention, it is (64-66) that the raw material of the insulating layer, which includes mass percent,:(28- 32):Backheat material, ceramic batch and the foaming agent of (3-4).
In some embodiments of the present invention, the ceramic batch includes accounting for the raw material gross mass of the insulating layer successively 5%-10%, 4%-10%, 13%-16% and 4%-10% bentonite, talcum, kaolin and small red soil.
In some embodiments of the present invention, it is (90-98) that the raw material of the finish coat, which includes mass percent,:(2- 10) building stones mineral powder and foaming agent.
In some embodiments of the present invention, it is (95-98) that the raw material of the finish coat, which includes mass percent,:(2- 5) building stones mineral powder and foaming agent.
The present invention some embodiments in, the building stones mineral powder be selected from lime stone, marble, granite, sandstone, At least one of flag.
In some embodiments of the present invention, it is (90-92) that the raw material of the finish coat, which includes mass percent,:(2- 4):(2-4):(2-4):Building stones mineral powder, foaming agent, cosolvent, stabilizer and the colorant of (2-4).
In some embodiments of the present invention, the foaming agent included in the raw material of the finish coat is selected from expanded pearlite At least one of rock, silicon carbide, silica, calcium carbonate, carbon dust, polystyrene.
In some embodiments of the present invention, the foaming agent included in the raw material of the finish coat includes mass percent For (10-15):(20-25):(20-25):Expanded perlite, silicon carbide, silica and the calcium carbonate of (40-45).
In some embodiments of the present invention, the foaming agent included in the raw material of the finish coat includes mass percent For (20-30):(20-30):(20-30):Silica, calcium carbonate, carbon dust and the polystyrene of (20-30).
In some embodiments of the present invention, the cosolvent is in potassium feldspar, albite, calcite, fluorite It is at least one.
In some embodiments of the present invention, it is (10-15) that the cosolvent, which includes mass percent,:(20-25): (20-25):Potassium feldspar, albite, calcite and the fluorite of (40-50).
In some embodiments of the present invention, the stabilizer is selected from least one of cerium oxide, yttrium oxide.
In some embodiments of the present invention, it is (30-40) that the stabilizer, which includes mass percent,:(60-70's) Cerium oxide and yttrium oxide.
In some embodiments of the present invention, the colorant is selected from erbium oxide, ytterbium oxide, praseodymium oxide, samarium oxide, oxygen Change at least one of europium, thulium oxide, neodymia.
In some embodiments of the present invention, it is (20-50) that the colorant, which includes mass percent,:(50-80's) Erbium oxide and europium oxide.
In some embodiments of the present invention, it is (30-40) that the colorant, which includes mass percent,:(60-70's) Praseodymium oxide and neodymia.
In some embodiments of the present invention, it is (20-30) that the colorant, which includes mass percent,:(20-30): (20-30):Ytterbium oxide, samarium oxide, thulium oxide and the erbium oxide of (20-30).
Heat-preserving decorating wall material provided in an embodiment of the present invention is made up of following steps:
(1) raw material of the raw material of the insulating layer and finish coat with water is mixed respectively and ground uniformly, protected respectively Warm layer slurry material and finish coat slurry material;
(2) insulating layer slurry material and finish coat slurry material are squeezed into respectively in spray tower and are dried, drying passes through after coming off Sieve detaches, and obtains insulating layer granular powder and finish coat granular powder respectively;
(3) the uniform place mat of finish coat granular powder is uniformly spread the insulating layer granular powder in mold bottom Pad is on the finish coat granular powder;
(4) mold is sent into kiln, preheats 30-40min within the temperature range of 600-700 DEG C first, then 30-40min is kept the temperature within the temperature range of being warming up to 1100-1200 DEG C;
(5) it demoulds, cut after the mold is cooled down in kiln, obtain the heat-preserving decorating wall material.
In some embodiments of the present invention, the grain fineness of the insulating layer slurry material and finish coat slurry material is less than Equal to 100 mesh.
In some embodiments of the present invention, during implementation steps (4), the mold is sent into kiln, is existed first 30-40min is preheated within the temperature range of 640-660 DEG C, 30- is kept the temperature within the temperature range of then raising temperature to 1140-1160 DEG C 40min。
It is described in detail below in conjunction with embodiment.
The heat-preserving decorating wall material described in embodiment 1-11 is prepared with the following method.
According to backheat material ceramic blank in the insulating layer raw material described in table 1 and the mass ratio of finish coat raw material, insulating layer raw material Material and the mass ratio of foaming agent, the component of ceramic batch and each component account for the percentage of insulating layer raw material gross mass, weigh original Material.Wherein, the backheat material includes building the mortar of recycling, brick, concrete, ceramic cutting waste material.The group of finish coat raw material Divide and the content of each component is listed in table 2, the building stones mineral powder is selected from lime stone, marble, granite, sandstone, flag.
After the completion of raw material weighs, the raw material of the raw material of the insulating layer and finish coat with water is mixed respectively and is ground It is even, insulating layer slurry material and finish coat slurry material are obtained respectively;Insulating layer slurry material and finish coat slurry material are squeezed into spray respectively It being dried in tower, drying is detached after coming off by sieve, obtains insulating layer granular powder and finish coat granular powder respectively, In, powder detection is aqueous to have to≤0.08;By the uniform place mat of finish coat granular powder in mold bottom, by the heat preservation The layer uniform place mat of granular powder is on the finish coat granular powder;The mold is sent into kiln, according to described in table 3 Preheating temperature and time and holding temperature and time handle raw material held for some time after preheating first then heats up, Wherein heating rate is 4-8 DEG C/min;It demoulds, cut after the mold is cooled down in kiln, obtain the heat-preserving decorative wall Body material.
Wherein, the raw material of the raw material of the insulating layer and finish coat with water is mixed respectively and grinds uniform method and be: Each raw material is weighed to be packed into ball mill jointly, mill ball, raw material and water according to quality with:Ball:Material:Water is 1.5:1:0.8 ratio Example is milled, and 0.5% stabilizer is added in mill processes, is milled to the mesh of fineness≤100.
Table 4 lists each to performance parameter of the heat-preserving decorating wall material of embodiment 1-11 acquisitions.As shown in Table 4, originally In the heat-preserving decorating wall material that inventive embodiments obtain, the thermal conductivity factor of the insulating layer is 0.065w/ (m.k) -0.1w/ (m.k), the compression strength of the insulating layer is 2.0MPa-10MPa, and the water absorption rate of the insulating layer is less than or equal to 2.
Table 1:The composition of insulating layer raw material and the ratio of insulating layer raw material and finish coat raw material in embodiment 1-11
Table 2:The composition and ratio of finish coat raw material are protected in embodiment 1-11
The temperature and time of preheating and the heat preservation of 3 embodiment 1-11 of table
Embodiment Preheating temperature Preheating time Holding temperature Soaking time
Embodiment 1 600℃ 40min 1100℃ 40min
Embodiment 2 640℃ 40min 114℃ 40min
Embodiment 3 660℃ 30min 1160℃ 30min
Embodiment 4 700℃ 30min 1200℃ 30min
Embodiment 5 600℃ 40min 1100℃ 40min
Embodiment 6 640℃ 40min 114℃ 40min
Embodiment 7 660℃ 30min 1160℃ 30min
Embodiment 8 700℃ 30min 1200℃ 30min
Embodiment 9 600℃ 35min 1100℃ 35min
Embodiment 10 700℃ 40min 1150℃ 30min
Embodiment 11 700℃ 40min 1150℃ 30min
4 embodiment 1-11 of table obtains the performance parameter of product
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.

Claims (10)

1. a kind of heat-preserving decorating wall material, it is characterised in that:Including insulating layer and finish coat, the insulating layer and finish coat lead to It crosses layered arrangement powder raw material in a mold and integral material is combined into the powder raw material high-temperature heat treatment.
2. heat-preserving decorating wall material according to claim 1, it is characterised in that:The raw material of the insulating layer includes quality Percentage is (60-70): (25-35): backheat material, ceramic batch and the foaming agent of (2-5);The backheat material is selected from building and recycles Mortar, brick, concrete, at least one of ceramic cutting waste material;The ceramic batch is selected from bentonite, talcum, kaolinite At least one of native and small red soil.
3. heat-preserving decorating wall material according to claim 2, it is characterised in that:The ceramic batch includes accounting for institute successively State the bentonite, talcum, kaolinite of 5%-10%, 4%-10%, 13%-16% and 4%-10% of the raw material gross mass of insulating layer Native and small red soil.
4. heat-preserving decorating wall material according to claim 1, it is characterised in that:The raw material of the finish coat includes quality Percentage is (90-98): the building stones mineral powder and foaming agent of (2-10).
5. heat-preserving decorating wall material according to claim 1, it is characterised in that:The raw material of the finish coat includes matter stone Expect mineral powder;The building stones mineral powder is selected from least one of lime stone, marble, granite, sandstone, flag.
6. the heat-preserving decorating wall material according to any one in claim 1-4, it is characterised in that:The insulating layer Thermal conductivity factor is 0.065w/ (m.k) -0.1w/ (m.k).
7. the heat-preserving decorating wall material according to any one in claim 1-4, it is characterised in that:The insulating layer Compression strength is 2.0MPa-10MPa.
8. the heat-preserving decorating wall material according to any one in claim 1-4, it is characterised in that:The insulating layer Water absorption rate is less than or equal to 2.
9. a kind of preparation method of the heat-preserving decorating wall material in 1-8 such as claim as described in any one, it is characterised in that Include the following steps:
(1) raw material of the raw material of the insulating layer and finish coat with water is mixed respectively and ground uniformly, obtain insulating layer respectively Slurry material and finish coat slurry material;
(2) insulating layer slurry material and finish coat slurry material are squeezed into respectively in spray tower and are dried, drying passes through sieve after coming off Separation obtains insulating layer granular powder and finish coat granular powder respectively;
(3) the uniform place mat of finish coat granular powder is existed the uniform place mat of insulating layer granular powder in mold bottom On the finish coat granular powder;
(4) mold is sent into kiln, preheats 30-40min within the temperature range of 600-700 DEG C first, then heated up 30-40min is kept the temperature within the temperature range of to 1100-1200 DEG C;
(5) it demoulds, cut after the mold is cooled down in kiln, obtain the heat-preserving decorating wall material.
10. a kind of preparation method of heat-preserving decorating wall material as claimed in claim 9, it is characterised in that:The insulating layer The grain fineness of slurry material and finish coat slurry material is less than or equal to 100 mesh.
CN201810013106.3A 2018-01-05 2018-01-05 A kind of heat-preserving decorating wall material and preparation method thereof Pending CN108147786A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111926990A (en) * 2020-08-10 2020-11-13 浩华环境科学有限责任公司 Exterior wall heat insulation building block and manufacturing method thereof
CN112341247A (en) * 2020-11-10 2021-02-09 中钢集团马鞍山矿山研究总院股份有限公司 Method for preparing heat-preservation and decoration integrated wall material by utilizing solid wastes
CN113024272A (en) * 2021-03-10 2021-06-25 江苏泽建环境科技有限公司 One-time fired ceramic foaming heat preservation device integrated plate and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5761665A (en) * 1980-09-27 1982-04-14 Shinichi Takeda Sandstone ceramic wall material
CN102877614A (en) * 2012-09-07 2013-01-16 佛山市溶洲建筑陶瓷二厂有限公司 Heat insulating and preserving ceramic composite plate with decorative properties
CN106478130A (en) * 2016-10-25 2017-03-08 杭州珀泉环境技术有限公司 A kind of fire prevention, heat-preserving wall section bar and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5761665A (en) * 1980-09-27 1982-04-14 Shinichi Takeda Sandstone ceramic wall material
CN102877614A (en) * 2012-09-07 2013-01-16 佛山市溶洲建筑陶瓷二厂有限公司 Heat insulating and preserving ceramic composite plate with decorative properties
CN106478130A (en) * 2016-10-25 2017-03-08 杭州珀泉环境技术有限公司 A kind of fire prevention, heat-preserving wall section bar and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111926990A (en) * 2020-08-10 2020-11-13 浩华环境科学有限责任公司 Exterior wall heat insulation building block and manufacturing method thereof
CN111926990B (en) * 2020-08-10 2021-07-02 浩华环境科学有限责任公司 Exterior wall heat insulation building block and manufacturing method thereof
CN112341247A (en) * 2020-11-10 2021-02-09 中钢集团马鞍山矿山研究总院股份有限公司 Method for preparing heat-preservation and decoration integrated wall material by utilizing solid wastes
CN112341247B (en) * 2020-11-10 2023-01-20 中钢集团马鞍山矿山研究总院股份有限公司 Method for preparing heat-preservation and decoration integrated wall material by utilizing solid wastes
CN113024272A (en) * 2021-03-10 2021-06-25 江苏泽建环境科技有限公司 One-time fired ceramic foaming heat preservation device integrated plate and preparation method thereof

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Application publication date: 20180612