CN105802081A - 涂层高粘结力哑光聚氯乙烯数码打印片材基材料 - Google Patents

涂层高粘结力哑光聚氯乙烯数码打印片材基材料 Download PDF

Info

Publication number
CN105802081A
CN105802081A CN201610317733.7A CN201610317733A CN105802081A CN 105802081 A CN105802081 A CN 105802081A CN 201610317733 A CN201610317733 A CN 201610317733A CN 105802081 A CN105802081 A CN 105802081A
Authority
CN
China
Prior art keywords
digital printing
printing sheet
cohesive force
polrvinyl chloride
floor height
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610317733.7A
Other languages
English (en)
Inventor
孟永华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Hongkai Plastic Co Ltd
Original Assignee
Jiangsu Hongkai Plastic Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Hongkai Plastic Co Ltd filed Critical Jiangsu Hongkai Plastic Co Ltd
Priority to CN201610317733.7A priority Critical patent/CN105802081A/zh
Publication of CN105802081A publication Critical patent/CN105802081A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/22—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length
    • B29C43/24—Calendering
    • B29C43/245—Adjusting calender parameters, e.g. bank quantity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32—Component parts, details or accessories; Auxiliary operations
    • B29C43/44—Compression means for making articles of indefinite length
    • B29C43/46—Rollers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32—Component parts, details or accessories; Auxiliary operations
    • B29C43/52—Heating or cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/92—Measuring, controlling or regulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32—Component parts, details or accessories; Auxiliary operations
    • B29C43/44—Compression means for making articles of indefinite length
    • B29C43/46—Rollers
    • B29C2043/461—Rollers the rollers having specific surface features
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/92704—Temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2027/00—Use of polyvinylhalogenides or derivatives thereof as moulding material
    • B29K2027/06—PVC, i.e. polyvinylchloride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2007/00—Flat articles, e.g. films or sheets
    • B29L2007/002—Panels; Plates; Sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)

Abstract

本发明涉及涂层高粘结力哑光聚氯乙烯数码打印片材基材料，以聚氯乙烯为主料，加入氯乙烯‑醋酸乙烯树脂，其配方中各原料的重量份为：聚氯乙烯 60～70，氯乙烯‑醋酸乙烯树脂8～12，钛白粉 3～5，纳米碳酸钙 8～12%，加工助剂 1～2，增强剂 5～8，热稳定剂 1.2～1.8，润滑剂1～1.5。本发明生产的涂层用PVC片材基材料具有高粘结力，刚性，韧性好，涂层性能卓越等优点。

Description

涂层高粘结力哑光聚氯乙烯数码打印片材基材料
技术领域
本发明涉及PVC硬质片材技术领域，具体涉及一种数码打印用的涂层高粘结力哑光聚氯乙烯片材基材料及其制备方法。
背景技术
随着科学技术的不断进步及新技术的不断应用，各类数码打印，喷绘材料的使用得到了飞速发展，应用领域也越来越广泛，制作各类数码打印，喷绘材料的基材料除具有一般PVC硬质片材的特殊性外，对涂层与PVC片材基材料的粘结力、打印色彩方面均具有较高要求，目前国内外各PVC硬质片材基材料，涂层与PVC片材基材料之间的粘结力、打印效果还存在不足，影响打印效果。
发明内容
本发明所要解决的技术问题是针对上述现有技术提供一种涂层高粘结力哑光聚氯乙烯数码打印片材基材料，提高涂层与PVC硬质片材间的粘结力，改善数码打印效果，本发明的另一目的是提供该PVC片材基材料的制备方法。
本发明解决上述问题所采用的技术方案为：一种涂层高粘结力哑光聚氯乙烯数码打印片材基材料，加入氯乙烯-醋酸乙烯树脂，其配方中各原料的重量份为：
聚氯乙烯60～70，
氯乙烯-醋酸乙烯树脂8～12，
钛白粉3～5，
纳米碳酸钙8～12%，
加工助剂1～2，
增强剂5～8，
热稳定剂1.2～1.8，
润滑剂1～1.5。
本发明氯乙烯-醋酸乙烯树脂中醋酸乙烯的质量含量为16%。
本发明加工助剂为丙烯酸酯类改性剂。
本发明增强剂是甲基丙烯酸甲酯与丁二烯和苯乙烯的共聚物。
本发明热稳定剂是硫醇甲基锡。
本发明润滑剂是硬脂酸。
本发明涂层高粘结力哑光聚氯乙烯数码打印片材基材料的制备方法，包括如下步骤：
步骤一、搅拌熔融物料按配比将各种原料混合，充分搅拌均匀，并搅拌至料温100～110℃；
步骤二、搅拌冷却物料降低搅拌速度，保持搅拌，使料温降至40～45℃；
步骤三、挤出机塑化把冷却好的物料均匀送入行星挤出机塑化，行星挤出机加热温度控制在145～160℃；
步骤四、压延机压延经行星挤出机塑化好熔融物料均匀地送入压延机压延成片材，压延辊辊面温度控制在165～195℃，所述压延辊辊面进行喷砂处理，使辊轮表面粗糙度Ra值1.8～2.0μm；
步骤五、引离片材由引离冷却系统中的引离辊把所形成之片材从压延辊上剥离，引离辊辊面温度控制在110～90℃；
步骤六、冷却定型由引离冷却系统中的冷却辊对所形成之片材冷却定型，冷却辊辊面温度控制在80～40℃，冷却辊温度设定从高到低，最后一组冷却辊辊面温度设定为40℃；
步骤七、收卷经冷却定型的片材由中心收卷机收卷、包装。
本发明通过对压延机辊轮进行喷砂处理，使压延辊表面粗糙，通过喷砂压延机辊轮生产出来的数码打印片材基材料表面哑光，并存在一定的毛细孔型粗糙度，通过这种工艺生产出的涂层用片材具有更好的涂层粘结力。
加入纳米碳酸钙，利用纳米材料在力学性能方面的卓越性能，增加了填充料，使生产出来的涂层用片材具有很好的刚性，但其低温脆性不变；加入氯乙烯-醋酸乙烯树脂改性聚氯乙烯树脂，进一步增强了涂层与PVC片材基材料的粘结力。
本发明的PVC数码打印片材基材料是以聚氯乙烯为主料加入氯乙烯-醋酸乙烯共混树脂，用于增强基材料与涂层的粘结力，同时压延机出片辊轮用100目金刚砂进行喷砂工艺，使辊轮表面产生粗糙度，使产品表面具有毛细孔状粗糙度，使涂层与基材料间的结合力得到进一步增强。
通过上述配方调配和工艺改进，使本发明生产的涂层用PVC片材基材料具有高粘结力，刚性，韧性好，涂层性能卓越等优点。
具体实施方式
以下结合实施例对本发明作进一步详细描述。
实施1：生产涂层高粘结力哑光聚氯乙烯数码打印片材
一、备料
称取聚录乙烯660Kg，钛白粉35Kg，纳米碳酸钙90Kg，氯乙烯-醋酸乙烯树脂100Kg，增强剂65Kg，热稳定剂15Kg，和润滑剂15Kg，加工助剂20Kg。
二、加工工艺步骤：
1、高速搅拌熔融物料将上述计量好的原料放入高速搅拌机，充分搅拌混合均匀，并搅拌至料温100～110℃；
2、低速搅拌冷却物料把高速搅拌好的物料排放至低速冷却搅拌机冷却搅拌，搅拌使料温降至40～45℃；
3、挤出机塑化把冷却好的物料均匀输入行星挤出机塑化，行星挤出机温度控制在145～160℃，物料的塑化温度为160～180℃；
4、压延经行星挤出机塑化好熔融物料均匀地送人五辊压延机压延，辊轮表面粗糙度Ra值1.8～2.0μm，根据客户所需材料厚度控制好辊轮间隙，同时压延辊辊面温度控制在165～195℃；
5、引离片材由引离冷却系统中的引离辊把所形成之片材从压延辊剥离，引离辊温度控制在110～90℃，压延辊压力调正4Kg/cm2；
6、经冷却辊冷却定型，冷却辊温度控制在80～40℃，辊轮温度设定从高到低，最后一组冷却辊辊面的冷却温度设定为40℃；
7、由自动测厚装置在线检测产品厚度，如发现所检出厚度超标，自动测厚装置会反馈至压延机，自动调节辊轮间隙至符合产品厚度。
8、收卷经冷却定型的片材由中心收卷机收卷、包装。
实施例2：
实施例2和实施例1的不同之处仅在于各原料的配比不同：聚氯乙烯650Kg，钛白粉35Kg，纳米碳酸钙90Kg，氯乙烯-醋酸乙烯树脂110Kg，增强剂65Kg，热稳定剂15Kg，和润滑剂15Kg，加工助剂20Kg。
其余同实施例1。
实施例3：
实施例3和实施例1的不同之处仅在于各原料的配比不同：聚氯乙烯650Kg，钛白粉35Kg，纳米碳酸钙100Kg，氯乙烯-醋酸乙烯树脂100Kg，增强剂65Kg，热稳定剂15Kg，和润滑剂15Kg，加工助剂20Kg。
其中氯乙烯-醋酸乙烯树脂中醋酸乙烯含量16%。增强剂为甲基丙烯酸甲酯与丁二烯和苯乙烯的共聚物，代号为MBS。热稳定剂是硫醇甲基锡。润滑剂是硬脂酸。纳米碳酸钙细度为80纳米，加工助剂为ACR丙烯酸酯类改性剂。
上述实施例所对应的PVC半哑光片材的物理机械性能测试数据如下表：
指标名称 指 标 实测数据
光泽度% 60° ≤20 17
粗糙度Ra(um) 0.7～1.3 1.0
拉伸强度 Mpa ≥44 46
维卡软化点℃ 75±2℃ 76
密度 g/cm3 1.4±0.05 1.4
弯曲 次 ≥1000 3000
扭曲 次 ≥1000 3000
加热收缩率100℃ 5分钟 纵向≥-8%，横向≤-3% 纵向-5%，横向+2%
表面张力 达因/cm ≥36 38
厚度（mm） 公差≤±4% ≤±4%

Claims (8)

1.一种涂层高粘结力哑光聚氯乙烯数码打印片材基材料，其特征在于：以聚氯乙烯为主料，加入氯乙烯-醋酸乙烯树脂，其配方中各原料的重量份为：
聚氯乙烯60～70，
氯乙烯-醋酸乙烯树脂8～12，
钛白粉3～5，
纳米碳酸钙8～12%，
加工助剂1～2，
增强剂5～8，
热稳定剂1.2～1.8，
润滑剂1～1.5。
2.根据权利要求1所述的涂层高粘结力哑光聚氯乙烯数码打印片材基材料，其特征在于：所述氯乙烯-醋酸乙烯树脂中醋酸乙烯的质量含量为16%。
3.根据权利要求1所述的涂层高粘结力哑光聚氯乙烯数码打印片材基材料，其特征在于：所述加工助剂为丙烯酸酯类改性剂。
4.根据权利要求1所述的涂层高粘结力哑光聚氯乙烯数码打印片材基材料，其特征在于：所述增强剂是甲基丙烯酸甲酯与丁二烯和苯乙烯的共聚物。
5.根据权利要求1所述的涂层高粘结力哑光聚氯乙烯数码打印片材基材料，其特征在于：所述热稳定剂是硫醇甲基锡。
6.根据权利要求1所述的涂层高粘结力哑光聚氯乙烯数码打印片材基材料，其特征在于：所述润滑剂是硬脂酸。
7.一种制备权利要求1所述涂层高粘结力哑光聚氯乙烯数码打印片材基材料的方法，其特征在于：包括如下步骤
步骤一、搅拌熔融物料按配比将各种原料混合，充分搅拌均匀，并搅拌至料温100～110℃；
步骤二、搅拌冷却物料降低搅拌速度，保持搅拌，使料温降至40～45℃；
步骤三、挤出机塑化把冷却好的物料均匀送入行星挤出机塑化，行星挤出机加热温度控制在145～160℃；
步骤四、压延机压延经行星挤出机塑化好熔融物料均匀地送入压延机压延成片材，压延辊辊面温度控制在165～195℃，所述压延辊辊面进行喷砂处理，使辊轮表面粗糙度Ra值1.8～2.0μm；
步骤五、引离片材由引离冷却系统中的引离辊把所形成之片材从压延辊上剥离，引离辊辊面温度控制在110～90℃；
步骤六、冷却定型由引离冷却系统中的冷却辊对所形成之片材冷却定型，冷却辊辊面温度控制在80～40℃，冷却辊温度设定从高到低，最后一组冷却辊辊面温度设定为40℃；
步骤七、收卷经冷却定型的片材由中心收卷机收卷、包装。
8.根据权利要求7所述的涂层高粘结力哑光聚氯乙烯数码打印片材基材料的制备方法，其特征在于：所述步骤四的压延辊辊面经过100目金刚砂喷砂。
CN201610317733.7A 2016-05-14 2016-05-14 涂层高粘结力哑光聚氯乙烯数码打印片材基材料 Pending CN105802081A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610317733.7A CN105802081A (zh) 2016-05-14 2016-05-14 涂层高粘结力哑光聚氯乙烯数码打印片材基材料

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610317733.7A CN105802081A (zh) 2016-05-14 2016-05-14 涂层高粘结力哑光聚氯乙烯数码打印片材基材料

Publications (1)

Publication Number Publication Date
CN105802081A true CN105802081A (zh) 2016-07-27

Family

ID=56456110

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610317733.7A Pending CN105802081A (zh) 2016-05-14 2016-05-14 涂层高粘结力哑光聚氯乙烯数码打印片材基材料

Country Status (1)

Country Link
CN (1) CN105802081A (zh)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107312272A (zh) * 2017-08-09 2017-11-03 江阴宏凯塑胶有限公司 聚氯乙烯/氯醋树脂共混半哑光热收缩膜及其制备方法
CN108503974A (zh) * 2018-03-22 2018-09-07 台州久通塑胶有限公司 耐寒的pvc片材
CN109810433A (zh) * 2019-03-01 2019-05-28 苏州华盖信息科技有限公司 一种可降低产品表面光亮度的哑光pvc装饰薄膜
CN110724467A (zh) * 2019-10-22 2020-01-24 江苏名阳高分子新材料有限公司 一种pvc伪装贴膜及其制备方法
CN109971083B (zh) * 2017-12-28 2021-09-03 广州宏信塑胶工业有限公司 信用卡面料层、信用卡及其制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1858106A (zh) * 2006-06-05 2006-11-08 上海达凯塑胶有限公司 一种用于激光打印面层的压延基材及其制备方法
CN105273336A (zh) * 2015-11-06 2016-01-27 江阴宏凯塑胶有限公司 一种抗菌、防霉灯饰用pvc半哑光片材及其制备方法
CN105482288A (zh) * 2014-10-17 2016-04-13 常州百佳薄膜科技有限公司 一种用于免背胶喷绘的硬质pvc材料及其生产工艺和用途

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1858106A (zh) * 2006-06-05 2006-11-08 上海达凯塑胶有限公司 一种用于激光打印面层的压延基材及其制备方法
CN105482288A (zh) * 2014-10-17 2016-04-13 常州百佳薄膜科技有限公司 一种用于免背胶喷绘的硬质pvc材料及其生产工艺和用途
CN105273336A (zh) * 2015-11-06 2016-01-27 江阴宏凯塑胶有限公司 一种抗菌、防霉灯饰用pvc半哑光片材及其制备方法

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107312272A (zh) * 2017-08-09 2017-11-03 江阴宏凯塑胶有限公司 聚氯乙烯/氯醋树脂共混半哑光热收缩膜及其制备方法
CN109971083B (zh) * 2017-12-28 2021-09-03 广州宏信塑胶工业有限公司 信用卡面料层、信用卡及其制备方法
CN108503974A (zh) * 2018-03-22 2018-09-07 台州久通塑胶有限公司 耐寒的pvc片材
CN109810433A (zh) * 2019-03-01 2019-05-28 苏州华盖信息科技有限公司 一种可降低产品表面光亮度的哑光pvc装饰薄膜
CN110724467A (zh) * 2019-10-22 2020-01-24 江苏名阳高分子新材料有限公司 一种pvc伪装贴膜及其制备方法

Similar Documents

Publication Publication Date Title
CN105802081A (zh) 涂层高粘结力哑光聚氯乙烯数码打印片材基材料
US10363701B2 (en) Method for producing inorganic substance powder highly-oriented thin film sheet
CN105273336B (zh) 一种抗菌、防霉灯饰用pvc半哑光片材及其制备方法
CN1313531C (zh) 抗静电、耐候灯饰用pvc哑光片材及其制备方法
CN101463170B (zh) 一种宽幅聚氯乙烯收缩膜及其生产设备、制造工艺
CN105924828B (zh) 抗紫外、耐磨、耐刮伤信用卡面层及其制备方法
CN102492244B (zh) 聚氯乙烯自由发泡板材及其制备方法
TW201500210A (zh) 聚酯薄膜及其製造方法
CN103057220A (zh) 一种用于家具贴面的环保石头纸及其制备方法
CN109591419B (zh) Pvc发泡耐折板及其制备方法
CN1288202C (zh) 制作非接触ic卡用聚氯乙烯卡基材料及其制备方法
CN112793268B (zh) 一种复合石晶地板及其制造方法
WO2014169454A1 (zh) 用于家具贴面的环保石头纸及其制备方法
JP4259980B2 (ja) 五層共押出二軸延伸ポリプロピレンパール光沢合成紙及びその製造法
US10569519B2 (en) Low cost surface covering tiles and the process for their manufacture
CN107116741A (zh) 压纹非硅离型材料的制备方法
CN104448507B (zh) 一种用聚丙烯纤维增强高填充环保纸的方法
CN100374498C (zh) 用于低维卡接触式、非接触智能卡的压延基材及制备方法
JP2968773B2 (ja) 高光沢度と印刷速乾性を有する二軸延伸ポリプロピレン合成紙の製造方法
CN107722858A (zh) 一种耐热高强度易拉胶带及其制备方法
CN108349184A (zh) 用于在保持良好切削光滑性的同时实现改进的滚筒粘着性的lvt配方和滚筒表面
CN107266830A (zh) Sim卡激光打码用pvc/abs共混哑光片材及其制备方法
CN109233152B (zh) 一种表面处理碳酸钙补强pvc地板砖生产工艺
CN106905644A (zh) 一种压延pvc易撕硬质透明胶片
CN107312272A (zh) 聚氯乙烯/氯醋树脂共混半哑光热收缩膜及其制备方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20160727

WD01 Invention patent application deemed withdrawn after publication