CN105636671A - 混合基质聚合物膜 - Google Patents

混合基质聚合物膜 Download PDF

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Publication number
CN105636671A
CN105636671A CN201480057237.1A CN201480057237A CN105636671A CN 105636671 A CN105636671 A CN 105636671A CN 201480057237 A CN201480057237 A CN 201480057237A CN 105636671 A CN105636671 A CN 105636671A
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Prior art keywords
membrane
mixed matrix
mof
matrix polymer
zif
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CN201480057237.1A
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Chinese (zh)
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伊哈卜·N·乌达
刘云阳
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SABIC Global Technologies BV
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SABIC Global Technologies BV
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/36—Pervaporation; Membrane distillation; Liquid permeation
    • B01D61/362—Pervaporation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02—Hollow fibre modules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/06—Tubular membrane modules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/08—Flat membrane modules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/10—Spiral-wound membrane modules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0079—Manufacture of membranes comprising organic and inorganic components
    • B01D67/00791—Different components in separate layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/14—Dynamic membranes
    • B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
    • B01D69/1411—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes containing dispersed material in a continuous matrix
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/14—Dynamic membranes
    • B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
    • B01D69/142—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes with "carriers"
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/14—Dynamic membranes
    • B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
    • B01D69/148—Organic/inorganic mixed matrix membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/028—Molecular sieves
    • B01D71/0281—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/58—Other polymers having nitrogen in the main chain, with or without oxygen or carbon only
    • B01D71/62—Polycondensates having nitrogen-containing heterocyclic rings in the main chain
    • B01D71/64—Polyimides; Polyamide-imides; Polyester-imides; Polyamide acids or similar polyimide precursors
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/144—Purification; Separation; Use of additives using membranes, e.g. selective permeation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1067—Wholly aromatic polyimides, i.e. having both tetracarboxylic and diamino moieties aromatically bound
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/10—Nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/16—Hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/22—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/24—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/24—Hydrocarbons
    • B01D2256/245—Methane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/10—Single element gases other than halogens
    • B01D2257/102—Nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/10—Single element gases other than halogens
    • B01D2257/108—Hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702—Hydrocarbons
    • B01D2257/7022—Aliphatic hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702—Hydrocarbons
    • B01D2257/7022—Aliphatic hydrocarbons
    • B01D2257/7025—Methane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/15—Use of additives
    • B01D2323/218—Additive materials
    • B01D2323/2189—Metal-organic compounds or complexes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/20—Capture or disposal of greenhouse gases of methane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
CN201480057237.1A 2013-10-16 2014-10-07 混合基质聚合物膜 Pending CN105636671A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201361891774P 2013-10-16 2013-10-16
US61/891,774 2013-10-16
PCT/US2014/059549 WO2015057429A1 (en) 2013-10-16 2014-10-07 Mixed matrix polymeric membranes

Publications (1)

Publication Number Publication Date
CN105636671A true CN105636671A (zh) 2016-06-01

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Country Status (6)

Country Link
US (1) US20150101986A1 (enExample)
EP (1) EP3057681A1 (enExample)
JP (1) JP2017500204A (enExample)
KR (1) KR20160074513A (enExample)
CN (1) CN105636671A (enExample)
WO (1) WO2015057429A1 (enExample)

Cited By (12)

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Publication number Priority date Publication date Assignee Title
CN107051398A (zh) * 2017-04-26 2017-08-18 浙江大学 一种制备丝蛋白纳米纤维－金属有机框架复合薄膜的方法
CN107469643A (zh) * 2017-07-26 2017-12-15 华南理工大学 一种高性能金属有机骨架膜及其在丙烯与丙烷高效分离中的应用
CN107890752A (zh) * 2017-10-31 2018-04-10 郑州大学 高度定向金属有机骨架分子筛膜及其制备方法和应用
CN110280153A (zh) * 2019-07-03 2019-09-27 郑州大学 一种用于丙烯/丙烷高效分离的混合基质膜及其制备方法
CN111450716A (zh) * 2019-01-18 2020-07-28 南开大学 一类共价交联的高分子-金属-有机笼复合膜的制备
CN112867556A (zh) * 2018-10-22 2021-05-28 日东电工株式会社 分离膜及膜分离方法
CN113209839A (zh) * 2021-05-11 2021-08-06 天津工业大学 一种具有高耐酸性能的甲烷/氮气分离的混合基质膜及制备方法和应用
CN114941591A (zh) * 2021-02-16 2022-08-26 通用汽车环球科技运作有限责任公司 用于内燃发动机的进气系统的蒸汽捕获元件
CN115463561A (zh) * 2021-12-13 2022-12-13 中国科学院福建物质结构研究所 一种共混基质气体分离膜及其制备方法
CN116764462A (zh) * 2023-07-17 2023-09-19 理工清科(重庆)先进材料研究院有限公司 一种混合基质膜及其制备方法与应用
CN117771976A (zh) * 2023-12-28 2024-03-29 天津工业大学 一种Zr-基金属-有机骨架基混合基质膜的制备方法
CN118615889A (zh) * 2024-08-01 2024-09-10 山东汇海膜材料科技有限公司 一种聚酰亚胺脱硫脱碳膜及其制备方法

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WO2015095044A1 (en) 2013-12-16 2015-06-25 Sabic Global Technologies B.V. Treated mixed matrix polymeric membranes
WO2015183831A1 (en) * 2014-05-24 2015-12-03 Georgia Tech Research Corporation Mixed matrix hollow fiber membranes
US20170252720A1 (en) * 2015-07-01 2017-09-07 Ihab N. Odeh Modification of zeolitic imidazolate frameworks and azide cross-linked mixed-matrix membranes made therefrom
US11110405B2 (en) * 2015-11-16 2021-09-07 The Regents Of The University Of California Adsorption-enhanced and plasticization resistant composite membranes
CN105536574B (zh) * 2015-12-15 2019-12-03 中能科泰（北京）科技有限公司 过滤膜及其制备方法和用途
EP3251742A1 (en) * 2016-05-31 2017-12-06 ETH Zurich Self-supporting mof membranes
CN107042067B (zh) * 2017-05-24 2019-11-08 天津大学 聚硅氧烷-金属有机框架材料杂化渗透蒸发复合膜及其制备与应用
JP2019018178A (ja) * 2017-07-20 2019-02-07 旭化成株式会社 分離膜
JPWO2019078171A1 (ja) * 2017-10-16 2020-11-19 国立大学法人京都大学 ポリマー化合物の濃縮もしくは分離方法
KR102050597B1 (ko) * 2018-01-02 2019-12-03 재단법인대구경북과학기술원 이온성 고분자 내의 확산 조절을 통한 금속-유기 구조체의 인-시츄 제조방법
US11827647B2 (en) * 2018-06-11 2023-11-28 Massachusetts Institute Of Technology Branched metal-organic framework nanoparticles in mixed-matrix membranes and associated methods
KR102172958B1 (ko) * 2018-06-11 2020-11-02 인천대학교 산학협력단 금속-유기 골격체를 포함하는 습도 감지용 트랜지스터 및 수분흡착 특성을 갖는 유기 반도체 조성물
CN108822544B (zh) * 2018-07-09 2020-11-03 陕西科技大学 一种聚酰亚胺/金属有机骨架复合薄膜的制备方法
CN109260967B (zh) * 2018-09-29 2021-11-19 浙江工业大学 一种金属有机骨架复合膜及其制备方法和应用
US11484845B2 (en) * 2018-10-23 2022-11-01 Sogang University Research & Business Development Foundation Hybrid membrane comprising zeolitic imidazolate framework nanoparticles and method of gas separation using the same
CN109647234B (zh) * 2018-12-21 2021-08-20 北京工业大学 一种mof/聚合物复合膜制备方法及其应用
US11103827B2 (en) * 2019-02-05 2021-08-31 Generon Igs, Inc. Two-stage gas separation unit contained within a single housing
KR102201876B1 (ko) * 2019-03-25 2021-01-12 한국화학연구원 메탄 선택적 작용기가 도입된 유무기 복합 다공체를 포함하는 메탄 선택성 복합 분리막, 이의 용도 및 이의 제조방법
CN111821812B (zh) * 2019-04-23 2021-09-03 中国石油大学(北京) 一种co2的吸收剂及其合成与应用
US20230112816A1 (en) * 2020-02-06 2023-04-13 Nitto Denko Corporation Separation membrane and metal organic framework
US20230130077A1 (en) * 2020-03-25 2023-04-27 Nitto Denko Corporation Separation membrane
CN111672330B (zh) * 2020-06-16 2022-04-08 北京工业大学 一种采用热退火后合成技术制备mof纳滤膜的方法
CN113713639B (zh) * 2021-07-07 2022-09-02 中国石油大学(北京) 一种zif-8/6fda-bi：dam(1:1)杂化膜及其制备方法和应用
CN113637216B (zh) * 2021-09-01 2023-06-20 大同共聚(西安)科技有限公司 一种表面修饰zif-8的低介电聚酰亚胺及其制备方法
KR20240067781A (ko) 2022-11-08 2024-05-17 국민대학교산학협력단 하이브리드 마이크로 가스 크로마토그래피 컬럼
CN119281124B (zh) * 2024-09-09 2025-09-23 湖南大学 一种基于原位mof凝胶混合基质膜的制备方法和应用

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US20150101986A1 (en) 2015-04-16

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