KR20160074513A - 혼합 매트릭스 중합 멤브레인들 - Google Patents
혼합 매트릭스 중합 멤브레인들 Download PDFInfo
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- KR20160074513A KR20160074513A KR1020167010919A KR20167010919A KR20160074513A KR 20160074513 A KR20160074513 A KR 20160074513A KR 1020167010919 A KR1020167010919 A KR 1020167010919A KR 20167010919 A KR20167010919 A KR 20167010919A KR 20160074513 A KR20160074513 A KR 20160074513A
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Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
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| KR20190082648A (ko) * | 2018-01-02 | 2019-07-10 | 재단법인대구경북과학기술원 | 코어-쉘 구조를 갖는 이온성 고분자 내 금속-유기 구조체의 인-시츄 제조방법 |
| KR20190140388A (ko) * | 2018-06-11 | 2019-12-19 | 인천대학교 산학협력단 | 금속-유기 골격체를 포함하는 습도 감지용 트랜지스터 및 수분흡착 특성을 갖는 유기 반도체 조성물 |
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| CN119281124B (zh) * | 2024-09-09 | 2025-09-23 | 湖南大学 | 一种基于原位mof凝胶混合基质膜的制备方法和应用 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008140788A1 (en) | 2007-05-11 | 2008-11-20 | The Regents Of The University Of California | Adsorptive gas separation of multi-component gases |
| US20100186588A1 (en) | 2007-07-17 | 2010-07-29 | The Regents Of The University Of California | Preparation of functionalized zeolitic frameworks |
| WO2012112122A1 (en) | 2011-02-14 | 2012-08-23 | National University Of Singapore | Preparation of zeolitic imidazolate frameworks (zifs) - polybenzimidazole mixed-matrix composite and application for gas and vapor separation |
| WO2012159224A1 (en) | 2011-05-25 | 2012-11-29 | Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences | Membranes |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070022877A1 (en) * | 2002-04-10 | 2007-02-01 | Eva Marand | Ordered mesopore silica mixed matrix membranes, and production methods for making ordered mesopore silica mixed matric membranes |
| US7637983B1 (en) * | 2006-06-30 | 2009-12-29 | Uop Llc | Metal organic framework—polymer mixed matrix membranes |
| CN101959577A (zh) * | 2007-06-01 | 2011-01-26 | 环球油品公司 | Uv交联的聚合物官能化分子筛/聚合物混合基质膜 |
| US20090149565A1 (en) * | 2007-12-11 | 2009-06-11 | Chunqing Liu | Method for Making High Performance Mixed Matrix Membranes |
| WO2010088629A1 (en) * | 2009-02-02 | 2010-08-05 | The Regents Of The University Of California | Reversible ethylene oxide capture in porous frameworks |
| US20110138999A1 (en) * | 2009-12-15 | 2011-06-16 | Uop Llc | Metal organic framework polymer mixed matrix membranes |
| WO2011100501A1 (en) * | 2010-02-12 | 2011-08-18 | Dow Global Technologies Llc | Metal organic framework filled polymer based membranes |
| US9527872B2 (en) * | 2012-01-30 | 2016-12-27 | Georgia Tech Research Corporation | Hybrid zeolitic imidazolate frameworks: controlling framework porosity and functionality by a mixed-ligand synthetic approach |
-
2014
- 2014-10-07 WO PCT/US2014/059549 patent/WO2015057429A1/en not_active Ceased
- 2014-10-07 JP JP2016549017A patent/JP2017500204A/ja not_active Withdrawn
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- 2014-10-07 KR KR1020167010919A patent/KR20160074513A/ko not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008140788A1 (en) | 2007-05-11 | 2008-11-20 | The Regents Of The University Of California | Adsorptive gas separation of multi-component gases |
| US20100186588A1 (en) | 2007-07-17 | 2010-07-29 | The Regents Of The University Of California | Preparation of functionalized zeolitic frameworks |
| WO2012112122A1 (en) | 2011-02-14 | 2012-08-23 | National University Of Singapore | Preparation of zeolitic imidazolate frameworks (zifs) - polybenzimidazole mixed-matrix composite and application for gas and vapor separation |
| WO2012159224A1 (en) | 2011-05-25 | 2012-11-29 | Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences | Membranes |
Non-Patent Citations (24)
| Title |
|---|
| Aaron & Tsouris, Sep Sci Technol. 40:321-348, 2005. |
| Askari & Chung, Journal of Membrane Science. 444:173-183, 2013. |
| Banerjee, et al., J Am Chem Soc. 131:3875-3877, 2009. |
| Banerjee, et al., Science. 319:939-943, 2008. |
| Chung, et al., Prog Polym Sci. 32:483-507, 2007. |
| Hayashi, et al., Nature Mater. 6:501-506, 2007. |
| Hillock et al., Journal of Membrane Science. 314:193-199, 2008. |
| Koros & Mahajan, J Membr Sci. 175:181, 2000. |
| Mahajan, et al., J Appl Polym Sci. 86:881, 2002. |
| Mersmann, et al., Chem Eng Technol. 23:937-944, 2000. |
| Moore, et al., AIChE J. 50:311, 2004. |
| Morris, et al., J J Am Chem Soc. 130:12626-12627, 2008 |
| Pan, et al., Journal of Membrane Science. 390-391:93-98, 2012 |
| Pan, et al., Journal of Membrane Science. 421-422:292-298, 2012b. |
| Park, et al., PNAS. 103:10186-10191, 2006. |
| Robeson, J Membr Sci. 320:390-400, 2008. |
| Robeson, J Membr Sci. 62:165, 1991. |
| Rosi, et al., J Am Chem Soc. 127(5):1504-18, 2005. |
| Thompson, et al., Chem Mater. 24:1930, 2012. |
| Venna & Carreon, J Am Chem Soc. 132:76-78, 2010. |
| Wang & Cohen, Chem Soc Rev. 38(5):1315-29, 2009. |
| Zhang, et al., Journal of Membrane Science. 389:34-42, 2012. |
| 미국특허출원 번호 US 4,933,132. |
| 하기 참조문헌들은, 본 출원에서 설정된 내용에 대하여, 예시 절차 또는 다른 상세한 보충을 제공하는 정도로, 참조로서 구체적으로 본 출원에 포함되었다. |
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| Publication number | Publication date |
|---|---|
| JP2017500204A (ja) | 2017-01-05 |
| CN105636671A (zh) | 2016-06-01 |
| EP3057681A1 (en) | 2016-08-24 |
| WO2015057429A1 (en) | 2015-04-23 |
| US20150101986A1 (en) | 2015-04-16 |
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