KR20160074513A - 혼합 매트릭스 중합 멤브레인들 - Google Patents
혼합 매트릭스 중합 멤브레인들 Download PDFInfo
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- KR20160074513A KR20160074513A KR1020167010919A KR20167010919A KR20160074513A KR 20160074513 A KR20160074513 A KR 20160074513A KR 1020167010919 A KR1020167010919 A KR 1020167010919A KR 20167010919 A KR20167010919 A KR 20167010919A KR 20160074513 A KR20160074513 A KR 20160074513A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/36—Pervaporation; Membrane distillation; Liquid permeation
- B01D61/362—Pervaporation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
- B01D63/02—Hollow fibre modules
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
- B01D63/06—Tubular membrane modules
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
- B01D63/08—Flat membrane modules
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
- B01D63/10—Spiral-wound membrane modules
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0079—Manufacture of membranes comprising organic and inorganic components
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0079—Manufacture of membranes comprising organic and inorganic components
- B01D67/00791—Different components in separate layers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/14—Dynamic membranes
- B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
- B01D69/1411—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes containing dispersed material in a continuous matrix
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/14—Dynamic membranes
- B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
- B01D69/142—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes with "carriers"
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/14—Dynamic membranes
- B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
- B01D69/148—Organic/inorganic mixed matrix membranes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/028—Molecular sieves
- B01D71/0281—Zeolites
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/58—Other polymers having nitrogen in the main chain, with or without oxygen or carbon only
- B01D71/62—Polycondensates having nitrogen-containing heterocyclic rings in the main chain
- B01D71/64—Polyimides; Polyamide-imides; Polyester-imides; Polyamide acids or similar polyimide precursors
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/144—Purification; Separation; Use of additives using membranes, e.g. selective permeation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/1067—Wholly aromatic polyimides, i.e. having both tetracarboxylic and diamino moieties aromatically bound
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/10—Nitrogen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/16—Hydrogen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/22—Carbon dioxide
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/24—Hydrocarbons
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/24—Hydrocarbons
- B01D2256/245—Methane
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/10—Single element gases other than halogens
- B01D2257/102—Nitrogen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/10—Single element gases other than halogens
- B01D2257/108—Hydrogen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/702—Hydrocarbons
- B01D2257/7022—Aliphatic hydrocarbons
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/702—Hydrocarbons
- B01D2257/7022—Aliphatic hydrocarbons
- B01D2257/7025—Methane
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/15—Use of additives
- B01D2323/218—Additive materials
- B01D2323/2189—Metal-organic compounds or complexes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/20—Capture or disposal of greenhouse gases of methane
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361891774P | 2013-10-16 | 2013-10-16 | |
| US61/891,774 | 2013-10-16 | ||
| PCT/US2014/059549 WO2015057429A1 (en) | 2013-10-16 | 2014-10-07 | Mixed matrix polymeric membranes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20160074513A true KR20160074513A (ko) | 2016-06-28 |
Family
ID=51794969
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020167010919A Withdrawn KR20160074513A (ko) | 2013-10-16 | 2014-10-07 | 혼합 매트릭스 중합 멤브레인들 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20150101986A1 (enExample) |
| EP (1) | EP3057681A1 (enExample) |
| JP (1) | JP2017500204A (enExample) |
| KR (1) | KR20160074513A (enExample) |
| CN (1) | CN105636671A (enExample) |
| WO (1) | WO2015057429A1 (enExample) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20190082648A (ko) * | 2018-01-02 | 2019-07-10 | 재단법인대구경북과학기술원 | 코어-쉘 구조를 갖는 이온성 고분자 내 금속-유기 구조체의 인-시츄 제조방법 |
| KR20190140388A (ko) * | 2018-06-11 | 2019-12-19 | 인천대학교 산학협력단 | 금속-유기 골격체를 포함하는 습도 감지용 트랜지스터 및 수분흡착 특성을 갖는 유기 반도체 조성물 |
| KR20210018913A (ko) * | 2018-06-11 | 2021-02-18 | 메사추세츠 인스티튜트 오브 테크놀로지 | 혼합-기질 막에서의 분지형 금속-유기 골격체 나노입자 및 연관된 방법 |
| KR20240067781A (ko) | 2022-11-08 | 2024-05-17 | 국민대학교산학협력단 | 하이브리드 마이크로 가스 크로마토그래피 컬럼 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9522364B2 (en) | 2013-12-16 | 2016-12-20 | Sabic Global Technologies B.V. | Treated mixed matrix polymeric membranes |
| WO2015183831A1 (en) * | 2014-05-24 | 2015-12-03 | Georgia Tech Research Corporation | Mixed matrix hollow fiber membranes |
| US20170252720A1 (en) * | 2015-07-01 | 2017-09-07 | Ihab N. Odeh | Modification of zeolitic imidazolate frameworks and azide cross-linked mixed-matrix membranes made therefrom |
| WO2017087422A1 (en) * | 2015-11-16 | 2017-05-26 | The Regents Of The University Of California | Adsorption-enhanced and plasticization resistant composite membranes |
| CN105536574B (zh) * | 2015-12-15 | 2019-12-03 | 中能科泰(北京)科技有限公司 | 过滤膜及其制备方法和用途 |
| EP3251742A1 (en) * | 2016-05-31 | 2017-12-06 | ETH Zurich | Self-supporting mof membranes |
| CN107051398B (zh) * | 2017-04-26 | 2020-01-14 | 浙江大学 | 一种制备丝蛋白纳米纤维-金属有机框架复合薄膜的方法 |
| CN107042067B (zh) * | 2017-05-24 | 2019-11-08 | 天津大学 | 聚硅氧烷-金属有机框架材料杂化渗透蒸发复合膜及其制备与应用 |
| JP2019018178A (ja) * | 2017-07-20 | 2019-02-07 | 旭化成株式会社 | 分離膜 |
| CN107469643B (zh) * | 2017-07-26 | 2021-03-30 | 华南理工大学 | 一种高性能金属有机骨架膜及其在丙烯与丙烷高效分离中的应用 |
| JPWO2019078171A1 (ja) * | 2017-10-16 | 2020-11-19 | 国立大学法人京都大学 | ポリマー化合物の濃縮もしくは分離方法 |
| CN107890752B (zh) * | 2017-10-31 | 2020-05-22 | 郑州大学 | 高度定向金属有机骨架分子筛膜及其制备方法和应用 |
| CN108822544B (zh) * | 2018-07-09 | 2020-11-03 | 陕西科技大学 | 一种聚酰亚胺/金属有机骨架复合薄膜的制备方法 |
| CN109260967B (zh) * | 2018-09-29 | 2021-11-19 | 浙江工业大学 | 一种金属有机骨架复合膜及其制备方法和应用 |
| CN112867556A (zh) * | 2018-10-22 | 2021-05-28 | 日东电工株式会社 | 分离膜及膜分离方法 |
| US11484845B2 (en) * | 2018-10-23 | 2022-11-01 | Sogang University Research & Business Development Foundation | Hybrid membrane comprising zeolitic imidazolate framework nanoparticles and method of gas separation using the same |
| CN109647234B (zh) * | 2018-12-21 | 2021-08-20 | 北京工业大学 | 一种mof/聚合物复合膜制备方法及其应用 |
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| US11103827B2 (en) * | 2019-02-05 | 2021-08-31 | Generon Igs, Inc. | Two-stage gas separation unit contained within a single housing |
| KR102201876B1 (ko) * | 2019-03-25 | 2021-01-12 | 한국화학연구원 | 메탄 선택적 작용기가 도입된 유무기 복합 다공체를 포함하는 메탄 선택성 복합 분리막, 이의 용도 및 이의 제조방법 |
| CN111821812B (zh) * | 2019-04-23 | 2021-09-03 | 中国石油大学(北京) | 一种co2的吸收剂及其合成与应用 |
| CN110280153B (zh) * | 2019-07-03 | 2021-10-08 | 郑州大学 | 一种用于丙烯/丙烷高效分离的混合基质膜及其制备方法 |
| CN115087495A (zh) * | 2020-02-06 | 2022-09-20 | 日东电工株式会社 | 分离膜及金属有机结构体 |
| WO2021192745A1 (ja) * | 2020-03-25 | 2021-09-30 | 日東電工株式会社 | 分離膜 |
| CN111672330B (zh) * | 2020-06-16 | 2022-04-08 | 北京工业大学 | 一种采用热退火后合成技术制备mof纳滤膜的方法 |
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| CN113209839B (zh) * | 2021-05-11 | 2022-03-08 | 天津工业大学 | 一种具有高耐酸性能的甲烷/氮气分离的混合基质膜及制备方法和应用 |
| CN113713639B (zh) * | 2021-07-07 | 2022-09-02 | 中国石油大学(北京) | 一种zif-8/6fda-bi:dam(1:1)杂化膜及其制备方法和应用 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008140788A1 (en) | 2007-05-11 | 2008-11-20 | The Regents Of The University Of California | Adsorptive gas separation of multi-component gases |
| US20100186588A1 (en) | 2007-07-17 | 2010-07-29 | The Regents Of The University Of California | Preparation of functionalized zeolitic frameworks |
| WO2012112122A1 (en) | 2011-02-14 | 2012-08-23 | National University Of Singapore | Preparation of zeolitic imidazolate frameworks (zifs) - polybenzimidazole mixed-matrix composite and application for gas and vapor separation |
| WO2012159224A1 (en) | 2011-05-25 | 2012-11-29 | Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences | Membranes |
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| US20070022877A1 (en) * | 2002-04-10 | 2007-02-01 | Eva Marand | Ordered mesopore silica mixed matrix membranes, and production methods for making ordered mesopore silica mixed matric membranes |
| US7637983B1 (en) * | 2006-06-30 | 2009-12-29 | Uop Llc | Metal organic framework—polymer mixed matrix membranes |
| CN101959577A (zh) * | 2007-06-01 | 2011-01-26 | 环球油品公司 | Uv交联的聚合物官能化分子筛/聚合物混合基质膜 |
| US20090149565A1 (en) * | 2007-12-11 | 2009-06-11 | Chunqing Liu | Method for Making High Performance Mixed Matrix Membranes |
| EP2384237A1 (en) * | 2009-02-02 | 2011-11-09 | The Regents of The University of California | Reversible ethylene oxide capture in porous frameworks |
| US20110138999A1 (en) * | 2009-12-15 | 2011-06-16 | Uop Llc | Metal organic framework polymer mixed matrix membranes |
| CA2789563A1 (en) * | 2010-02-12 | 2011-08-18 | Scott T. Matteucci | Metal organic framework filled polymer based membranes |
| US9527872B2 (en) * | 2012-01-30 | 2016-12-27 | Georgia Tech Research Corporation | Hybrid zeolitic imidazolate frameworks: controlling framework porosity and functionality by a mixed-ligand synthetic approach |
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2014
- 2014-10-07 JP JP2016549017A patent/JP2017500204A/ja not_active Withdrawn
- 2014-10-07 WO PCT/US2014/059549 patent/WO2015057429A1/en not_active Ceased
- 2014-10-07 US US14/508,848 patent/US20150101986A1/en not_active Abandoned
- 2014-10-07 KR KR1020167010919A patent/KR20160074513A/ko not_active Withdrawn
- 2014-10-07 CN CN201480057237.1A patent/CN105636671A/zh active Pending
- 2014-10-07 EP EP14789457.0A patent/EP3057681A1/en not_active Withdrawn
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20190082648A (ko) * | 2018-01-02 | 2019-07-10 | 재단법인대구경북과학기술원 | 코어-쉘 구조를 갖는 이온성 고분자 내 금속-유기 구조체의 인-시츄 제조방법 |
| KR20190140388A (ko) * | 2018-06-11 | 2019-12-19 | 인천대학교 산학협력단 | 금속-유기 골격체를 포함하는 습도 감지용 트랜지스터 및 수분흡착 특성을 갖는 유기 반도체 조성물 |
| KR20210018913A (ko) * | 2018-06-11 | 2021-02-18 | 메사추세츠 인스티튜트 오브 테크놀로지 | 혼합-기질 막에서의 분지형 금속-유기 골격체 나노입자 및 연관된 방법 |
| KR20240067781A (ko) | 2022-11-08 | 2024-05-17 | 국민대학교산학협력단 | 하이브리드 마이크로 가스 크로마토그래피 컬럼 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2017500204A (ja) | 2017-01-05 |
| CN105636671A (zh) | 2016-06-01 |
| WO2015057429A1 (en) | 2015-04-23 |
| EP3057681A1 (en) | 2016-08-24 |
| US20150101986A1 (en) | 2015-04-16 |
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