CN105593203B - 制备甲基丙烯酸化二苯甲酮的方法 - Google Patents
制备甲基丙烯酸化二苯甲酮的方法 Download PDFInfo
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- CN105593203B CN105593203B CN201480054472.3A CN201480054472A CN105593203B CN 105593203 B CN105593203 B CN 105593203B CN 201480054472 A CN201480054472 A CN 201480054472A CN 105593203 B CN105593203 B CN 105593203B
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- China
- Prior art keywords
- methyl
- benzophenone
- amount
- anhydride
- acrylate
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0209—Esters of carboxylic or carbonic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/62—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/017—Esters of hydroxy compounds having the esterified hydroxy group bound to a carbon atom of a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
- C08F22/10—Esters
- C08F22/12—Esters of phenols or saturated alcohols
- C08F22/14—Esters having no free carboxylic acid groups
Abstract
Description
反应时间 | MAA | MAAH | 羟基二苯甲酮 | 4-(甲基丙烯酰氧基)二苯甲酮 |
1h | 16.69 | 6.47 | 4.66 | 69.72 |
2h | 18.03 | 4.39 | 2.83 | 72.07 |
3h | 18.95 | 3.46 | 1.21 | 73.96 |
4h | 17.69 | 2.96 | 1.25 | 74.88 |
Claims (10)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102013220127.3 | 2013-10-04 | ||
DE201310220127 DE102013220127A1 (de) | 2013-10-04 | 2013-10-04 | Verfahren zur Herstellung von methacrylierten Benzophenonen |
PCT/EP2014/070787 WO2015049200A1 (de) | 2013-10-04 | 2014-09-29 | Verfahren zur herstellung von methacrylierten benzophenonen |
Publications (2)
Publication Number | Publication Date |
---|---|
CN105593203A CN105593203A (zh) | 2016-05-18 |
CN105593203B true CN105593203B (zh) | 2018-05-25 |
Family
ID=51628124
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201480054472.3A Active CN105593203B (zh) | 2013-10-04 | 2014-09-29 | 制备甲基丙烯酸化二苯甲酮的方法 |
Country Status (9)
Country | Link |
---|---|
US (1) | US9656941B2 (zh) |
EP (1) | EP3052467B1 (zh) |
JP (1) | JP6530384B2 (zh) |
KR (1) | KR102254784B1 (zh) |
CN (1) | CN105593203B (zh) |
DE (1) | DE102013220127A1 (zh) |
ES (1) | ES2769580T3 (zh) |
TW (1) | TWI654176B (zh) |
WO (1) | WO2015049200A1 (zh) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
MX2020012421A (es) * | 2018-05-23 | 2021-02-09 | Evonik Operations Gmbh | Procedimiento de preparacion de (met)acrilatos aromaticos ceto-funcionalizados. |
MX2021000530A (es) | 2018-07-17 | 2021-06-08 | Evonik Operations Gmbh | Procedimiento de preparacion de (met)acrilatos acidos c-h. |
EP3599232A1 (de) | 2018-07-26 | 2020-01-29 | Evonik Operations GmbH | Verfahren zur herstellung von n-methyl(meth)acrylamid |
KR20230065268A (ko) * | 2020-09-10 | 2023-05-11 | 에보닉 오퍼레이션스 게엠베하 | 바닐린 (메트)아크릴레이트의 제조 방법 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003261506A (ja) * | 2002-03-06 | 2003-09-19 | Mitsubishi Rayon Co Ltd | (メタ)アクリロイルオキシベンゾフェノン類の製造方法 |
CN102203048A (zh) * | 2008-12-15 | 2011-09-28 | 赢创罗姆有限公司 | 制备甲基丙烯酸化的二苯甲酮的方法 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1720603C3 (de) | 1967-01-18 | 1975-06-12 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung von wäßrigen Dispersionen lichtvernetzbarer Polymerisate |
DE3601098C1 (de) | 1986-01-16 | 1987-03-26 | Maizena Gmbh | Verfahren zur Herstellung peracetylierter Zuckeralkohole mit mindestens vier C-Atomen |
US4737559A (en) * | 1986-05-19 | 1988-04-12 | Minnesota Mining And Manufacturing Co. | Pressure-sensitive adhesive crosslinked by copolymerizable aromatic ketone monomers |
DE3820463A1 (de) | 1988-06-16 | 1989-12-21 | Basf Ag | Strahlungsempfindliche, ethylenisch ungesaettigte, copolymerisierbare verbindungen und verfahren zu deren herstellung |
JP2000191590A (ja) * | 1998-12-24 | 2000-07-11 | Nof Corp | (メタ)アクリル酸フェニルエステルの製造方法 |
JP4261112B2 (ja) * | 2002-03-06 | 2009-04-30 | 三菱レイヨン株式会社 | (メタ)アクリル酸エステルの製造方法 |
JP5702048B2 (ja) * | 2008-11-28 | 2015-04-15 | 三菱レイヨン株式会社 | (メタ)アクリル酸ナフチルエステルの製造方法 |
CN103755558B (zh) * | 2009-02-05 | 2016-06-22 | 三菱丽阳株式会社 | (甲基)丙烯酸酯的制造方法 |
-
2013
- 2013-10-04 DE DE201310220127 patent/DE102013220127A1/de not_active Withdrawn
-
2014
- 2014-09-29 ES ES14777311T patent/ES2769580T3/es active Active
- 2014-09-29 KR KR1020167011836A patent/KR102254784B1/ko active IP Right Grant
- 2014-09-29 CN CN201480054472.3A patent/CN105593203B/zh active Active
- 2014-09-29 EP EP14777311.3A patent/EP3052467B1/de active Active
- 2014-09-29 JP JP2016520000A patent/JP6530384B2/ja active Active
- 2014-09-29 US US15/026,861 patent/US9656941B2/en active Active
- 2014-09-29 WO PCT/EP2014/070787 patent/WO2015049200A1/de active Application Filing
- 2014-10-01 TW TW103134250A patent/TWI654176B/zh active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003261506A (ja) * | 2002-03-06 | 2003-09-19 | Mitsubishi Rayon Co Ltd | (メタ)アクリロイルオキシベンゾフェノン類の製造方法 |
CN102203048A (zh) * | 2008-12-15 | 2011-09-28 | 赢创罗姆有限公司 | 制备甲基丙烯酸化的二苯甲酮的方法 |
Non-Patent Citations (1)
Title |
---|
Improved Thin‐layer Chromatography Bioautographic Assay for the Detection of Actylcho -linesterase Inhibitors in Plants;Zhong-Duo Yangdeng;《Phytochem. Anal.》;20110324;第22卷;第509-515页 * |
Also Published As
Publication number | Publication date |
---|---|
US20160297738A1 (en) | 2016-10-13 |
KR102254784B1 (ko) | 2021-05-21 |
EP3052467A1 (de) | 2016-08-10 |
KR20160067929A (ko) | 2016-06-14 |
JP6530384B2 (ja) | 2019-06-12 |
TWI654176B (zh) | 2019-03-21 |
US9656941B2 (en) | 2017-05-23 |
EP3052467B1 (de) | 2019-12-18 |
CN105593203A (zh) | 2016-05-18 |
ES2769580T3 (es) | 2020-06-26 |
JP2016539913A (ja) | 2016-12-22 |
TW201527273A (zh) | 2015-07-16 |
DE102013220127A1 (de) | 2015-04-09 |
WO2015049200A1 (de) | 2015-04-09 |
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Address after: Darmstadt Patentee after: Roma Chemical Co.,Ltd. Address before: Darmstadt Patentee before: EVONIK ROHM GmbH Address after: Essen, Germany Patentee after: Evonik Operations Ltd. Address before: Essen, Germany Patentee before: EVONIK DEGUSSA GmbH |
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Effective date of registration: 20201102 Address after: Essen, Germany Patentee after: EVONIK DEGUSSA GmbH Address before: Darmstadt Patentee before: EVONIK ROHMAX ADDITIVES GmbH Effective date of registration: 20201102 Address after: Darmstadt Patentee after: EVONIK ROHMAX ADDITIVES GmbH Address before: Darmstadt Patentee before: Roma Chemical Co.,Ltd. |
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