CN105591177B - 用于金属-空气电池的水增强离子液体电解质 - Google Patents
用于金属-空气电池的水增强离子液体电解质 Download PDFInfo
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- CN105591177B CN105591177B CN201510660850.9A CN201510660850A CN105591177B CN 105591177 B CN105591177 B CN 105591177B CN 201510660850 A CN201510660850 A CN 201510660850A CN 105591177 B CN105591177 B CN 105591177B
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- 239000006185 dispersion Substances 0.000 claims abstract description 24
- -1 Cation cation Chemical class 0.000 claims description 24
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- QSZMZKBZAYQGRS-UHFFFAOYSA-N lithium;bis(trifluoromethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F QSZMZKBZAYQGRS-UHFFFAOYSA-N 0.000 claims description 4
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- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- AMWRITDGCCNYAT-UHFFFAOYSA-L manganese oxide Inorganic materials [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- PPNAOCWZXJOHFK-UHFFFAOYSA-N manganese(2+);oxygen(2-) Chemical class [O-2].[Mn+2] PPNAOCWZXJOHFK-UHFFFAOYSA-N 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 150000002892 organic cations Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 150000003053 piperidines Chemical class 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 150000003235 pyrrolidines Chemical class 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 239000012088 reference solution Substances 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000003115 supporting electrolyte Substances 0.000 description 1
- 230000008685 targeting Effects 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/04—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
- H01M12/06—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/08—Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/02—Details
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8605—Porous electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0068—Solid electrolytes inorganic
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/381—Alkaline or alkaline earth metals elements
- H01M4/382—Lithium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Hybrid Cells (AREA)
- Inert Electrodes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14/538,290 | 2014-11-11 | ||
| US14/538,290 US9941559B2 (en) | 2014-11-11 | 2014-11-11 | Water enhanced ionic liquid electrolytes for metal-air batteries |
Publications (2)
| Publication Number | Publication Date |
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| CN105591177A CN105591177A (zh) | 2016-05-18 |
| CN105591177B true CN105591177B (zh) | 2019-11-19 |
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| US (1) | US9941559B2 (enExample) |
| JP (1) | JP6723728B2 (enExample) |
| CN (1) | CN105591177B (enExample) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10868332B2 (en) | 2016-04-01 | 2020-12-15 | NOHMs Technologies, Inc. | Modified ionic liquids containing phosphorus |
| FR3052598B1 (fr) * | 2016-06-10 | 2018-06-01 | Universite De Rennes 1 | Utilisation de liquides ioniques comme adjuvant en electrochimie |
| US10177427B2 (en) * | 2017-02-10 | 2019-01-08 | General Electric Company | Electrochemical cell for use in high temperature metal-air battery |
| US10826145B2 (en) | 2017-02-10 | 2020-11-03 | General Electric Company | Electrochemical cell for use in high temperature metal-air battery |
| DE102017205339A1 (de) * | 2017-03-29 | 2018-10-04 | Forschungszentrum Jülich GmbH | Chemisch beständiger, oxidischer Elektrokatalysator für die Sauerstoffentwicklung während der alkalischen Wasserelektrolyse basierend auf BaCoO3-delta, Verfahren zu seiner Herstellung und ihn umfassende Anode sowie katalytisch aktives und chemisch stabiles Reaktionsprodukt davon |
| JP6491258B2 (ja) * | 2017-04-17 | 2019-03-27 | 冨士色素株式会社 | 金属空気電池 |
| US10446875B2 (en) | 2017-05-26 | 2019-10-15 | Toyota Motor Engineering & Manufacturing North America, Inc. | Phosphonium-based ionic liquids for lithium metal-based batteries |
| EP4087005A1 (en) | 2017-07-17 | 2022-11-09 | Nohms Technologies, Inc. | Phosphorus-containing electrolytes |
| JP7125023B2 (ja) * | 2017-10-26 | 2022-08-24 | 国立大学法人東京農工大学 | 混合エントロピー電池及び発電方法 |
| JP6911774B2 (ja) | 2018-01-09 | 2021-07-28 | トヨタ自動車株式会社 | 水系電解液及び水系リチウムイオン二次電池 |
| JP2019155349A (ja) * | 2018-03-12 | 2019-09-19 | 国立大学法人群馬大学 | 酸素還元触媒用炭素系複合体ならびにその製造方法および用途 |
| WO2019176511A1 (ja) * | 2018-03-12 | 2019-09-19 | 国立大学法人群馬大学 | 酸素還元触媒用炭素系複合体ならびにその製造方法および用途 |
| DE102018114146A1 (de) | 2018-06-13 | 2019-12-19 | Forschungszentrum Jülich GmbH | Hybrider Elektrolyt für wässrige Lithium-Ionen-Batterien |
| WO2019245929A1 (en) * | 2018-06-15 | 2019-12-26 | Massachusetts Institute Of Technology | Perovskites for catalyzing oxygen evolution |
| US12057559B2 (en) * | 2018-10-26 | 2024-08-06 | National University Of Singapore | Lithium ion battery materials recycling method |
| CN110011001A (zh) * | 2019-04-10 | 2019-07-12 | 南开大学 | 一种基于有机羰基聚合物负极的水系空气电池及其制备方法 |
| CN112447986B (zh) * | 2020-11-24 | 2022-03-22 | 四川大学 | 一种稀土金属有机框架衍生双功能催化剂及其用途 |
| CN115189076B (zh) * | 2022-05-16 | 2024-09-10 | 吉林大学 | 一种宽温固态金属空气电池及其制备方法 |
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| US7167353B2 (en) * | 2002-04-24 | 2007-01-23 | Nisshinbo Industries, Inc. | Ionic liquid, method of dehydration, electrical double layer capacitor, and secondary battery |
| CN102157763A (zh) * | 2011-03-09 | 2011-08-17 | 哈尔滨工业大学 | 锂/空气电池 |
| CN102487155A (zh) * | 2010-12-06 | 2012-06-06 | 中国电子科技集团公司第十八研究所 | 多层电解质锂空气电池 |
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| US4377623A (en) | 1980-07-29 | 1983-03-22 | Anumin Pty. Ltd. | Electro-chemical cells |
| US6797437B2 (en) | 2001-12-28 | 2004-09-28 | Quallion Llc | Electrolyte system and energy storage device using same |
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| US9786944B2 (en) | 2008-06-12 | 2017-10-10 | Massachusetts Institute Of Technology | High energy density redox flow device |
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| JP2011134595A (ja) * | 2009-12-24 | 2011-07-07 | Toyota Motor Corp | 金属空気電池 |
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| CN102971904B (zh) * | 2010-05-12 | 2016-06-08 | 亚利桑那董事会代表亚利桑那大学 | 具有性能增强添加剂的金属-空气电池 |
| WO2011159391A1 (en) | 2010-06-15 | 2011-12-22 | Fluidic, Inc. | Metal-air cell with tuned hydrophobicity |
| WO2011161822A1 (ja) * | 2010-06-25 | 2011-12-29 | 株式会社 東芝 | 空気電池 |
| US20130202974A1 (en) * | 2010-08-23 | 2013-08-08 | Fuminori Mizuno | Air cathode, metal-air battery and method for producing air cathode for metal-air battery |
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| JP5556618B2 (ja) * | 2010-11-24 | 2014-07-23 | トヨタ自動車株式会社 | リチウム空気電池 |
| CN103688400A (zh) | 2011-04-27 | 2014-03-26 | 联邦科学与工业研究组织 | 锂储能装置 |
| IL221252A (en) | 2011-08-02 | 2017-04-30 | Phinergy Ltd | Electrolyte system for metal-air batteries and methods for using it |
| JP5621745B2 (ja) * | 2011-10-07 | 2014-11-12 | トヨタ自動車株式会社 | 空気電池用電解液 |
-
2014
- 2014-11-11 US US14/538,290 patent/US9941559B2/en active Active
-
2015
- 2015-10-14 CN CN201510660850.9A patent/CN105591177B/zh active Active
- 2015-11-10 JP JP2015220254A patent/JP6723728B2/ja active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US7167353B2 (en) * | 2002-04-24 | 2007-01-23 | Nisshinbo Industries, Inc. | Ionic liquid, method of dehydration, electrical double layer capacitor, and secondary battery |
| CN102487155A (zh) * | 2010-12-06 | 2012-06-06 | 中国电子科技集团公司第十八研究所 | 多层电解质锂空气电池 |
| CN102157763A (zh) * | 2011-03-09 | 2011-08-17 | 哈尔滨工业大学 | 锂/空气电池 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2016096141A (ja) | 2016-05-26 |
| CN105591177A (zh) | 2016-05-18 |
| US20160134002A1 (en) | 2016-05-12 |
| US9941559B2 (en) | 2018-04-10 |
| JP6723728B2 (ja) | 2020-07-15 |
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