CN104918885B - 脱硼β沸石的后处理 - Google Patents
脱硼β沸石的后处理 Download PDFInfo
- Publication number
- CN104918885B CN104918885B CN201380066254.7A CN201380066254A CN104918885B CN 104918885 B CN104918885 B CN 104918885B CN 201380066254 A CN201380066254 A CN 201380066254A CN 104918885 B CN104918885 B CN 104918885B
- Authority
- CN
- China
- Prior art keywords
- zeolitic material
- iii
- water
- temperature
- methods according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000012805 post-processing Methods 0.000 title claims abstract description 12
- 229910052796 boron Inorganic materials 0.000 title claims description 34
- 239000010457 zeolite Substances 0.000 title description 35
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 title description 25
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title description 25
- 229910021536 Zeolite Inorganic materials 0.000 title description 23
- 239000000463 material Substances 0.000 claims abstract description 286
- 238000000034 method Methods 0.000 claims abstract description 177
- 239000007788 liquid Substances 0.000 claims abstract description 105
- 238000009432 framing Methods 0.000 claims abstract description 55
- 230000004907 flux Effects 0.000 claims abstract description 45
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 131
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 90
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 90
- 238000010521 absorption reaction Methods 0.000 claims description 88
- 230000008569 process Effects 0.000 claims description 86
- 239000000203 mixture Substances 0.000 claims description 64
- 239000003054 catalyst Substances 0.000 claims description 23
- 230000002085 persistent effect Effects 0.000 claims description 19
- 150000001875 compounds Chemical class 0.000 claims description 15
- 238000002329 infrared spectrum Methods 0.000 claims description 15
- 229910052710 silicon Inorganic materials 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 10
- 229910052782 aluminium Inorganic materials 0.000 claims description 9
- 238000010992 reflux Methods 0.000 claims description 8
- 229910052718 tin Inorganic materials 0.000 claims description 8
- 229910052719 titanium Inorganic materials 0.000 claims description 8
- 229910052726 zirconium Inorganic materials 0.000 claims description 8
- 229910052738 indium Inorganic materials 0.000 claims description 7
- 230000026676 system process Effects 0.000 claims description 7
- 229910052733 gallium Inorganic materials 0.000 claims description 6
- 229910052732 germanium Inorganic materials 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 150000005846 sugar alcohols Polymers 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 5
- 235000011187 glycerol Nutrition 0.000 claims description 5
- 238000002441 X-ray diffraction Methods 0.000 claims description 4
- 229960005150 glycerol Drugs 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 45
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 42
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 35
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 32
- 239000000377 silicon dioxide Substances 0.000 description 32
- 239000007789 gas Substances 0.000 description 28
- 238000005406 washing Methods 0.000 description 28
- 239000000725 suspension Substances 0.000 description 26
- 229910052681 coesite Inorganic materials 0.000 description 25
- 229910052906 cristobalite Inorganic materials 0.000 description 25
- 229910052682 stishovite Inorganic materials 0.000 description 25
- 229910052905 tridymite Inorganic materials 0.000 description 25
- 238000001914 filtration Methods 0.000 description 23
- 229910052757 nitrogen Inorganic materials 0.000 description 23
- 238000003756 stirring Methods 0.000 description 20
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 19
- 238000002425 crystallisation Methods 0.000 description 18
- 230000008025 crystallization Effects 0.000 description 17
- 229960004592 isopropanol Drugs 0.000 description 17
- 239000012065 filter cake Substances 0.000 description 16
- 238000010438 heat treatment Methods 0.000 description 15
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 14
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 12
- 230000008859 change Effects 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 12
- 239000002253 acid Substances 0.000 description 11
- 238000010306 acid treatment Methods 0.000 description 11
- 238000012545 processing Methods 0.000 description 11
- 239000000047 product Substances 0.000 description 11
- 238000000926 separation method Methods 0.000 description 11
- 125000005372 silanol group Chemical group 0.000 description 11
- 238000001694 spray drying Methods 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 9
- 239000007921 spray Substances 0.000 description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
- 238000001035 drying Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 8
- 238000001228 spectrum Methods 0.000 description 8
- 238000009835 boiling Methods 0.000 description 7
- 230000009467 reduction Effects 0.000 description 7
- 235000012239 silicon dioxide Nutrition 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 239000012298 atmosphere Substances 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 230000003595 spectral effect Effects 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 229960000583 acetic acid Drugs 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000007795 chemical reaction product Substances 0.000 description 5
- 230000018044 dehydration Effects 0.000 description 5
- 238000006297 dehydration reaction Methods 0.000 description 5
- 239000003599 detergent Substances 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 4
- 239000004115 Sodium Silicate Substances 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 4
- 235000011054 acetic acid Nutrition 0.000 description 4
- 238000013019 agitation Methods 0.000 description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 4
- 239000012153 distilled water Substances 0.000 description 4
- 235000019253 formic acid Nutrition 0.000 description 4
- DUWWHGPELOTTOE-UHFFFAOYSA-N n-(5-chloro-2,4-dimethoxyphenyl)-3-oxobutanamide Chemical compound COC1=CC(OC)=C(NC(=O)CC(C)=O)C=C1Cl DUWWHGPELOTTOE-UHFFFAOYSA-N 0.000 description 4
- 229910017604 nitric acid Inorganic materials 0.000 description 4
- 235000006408 oxalic acid Nutrition 0.000 description 4
- 235000011007 phosphoric acid Nutrition 0.000 description 4
- 235000019260 propionic acid Nutrition 0.000 description 4
- 229910052911 sodium silicate Inorganic materials 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 239000001117 sulphuric acid Substances 0.000 description 4
- 235000011149 sulphuric acid Nutrition 0.000 description 4
- 235000002906 tartaric acid Nutrition 0.000 description 4
- 239000011975 tartaric acid Substances 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 238000013459 approach Methods 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 3
- 239000004327 boric acid Substances 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000006555 catalytic reaction Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 150000007524 organic acids Chemical class 0.000 description 3
- 238000005325 percolation Methods 0.000 description 3
- 235000019353 potassium silicate Nutrition 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- 230000008929 regeneration Effects 0.000 description 3
- 238000011069 regeneration method Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- 238000000108 ultra-filtration Methods 0.000 description 3
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 2
- 229910008051 Si-OH Inorganic materials 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 229910006358 Si—OH Inorganic materials 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 2
- ZSIQJIWKELUFRJ-UHFFFAOYSA-N azepane Chemical compound C1CCCNCC1 ZSIQJIWKELUFRJ-UHFFFAOYSA-N 0.000 description 2
- 210000000988 bone and bone Anatomy 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 238000012937 correction Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000003795 desorption Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 239000002815 homogeneous catalyst Substances 0.000 description 2
- 239000002808 molecular sieve Substances 0.000 description 2
- 239000010413 mother solution Substances 0.000 description 2
- 150000003053 piperidines Chemical class 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229920000193 polymethacrylate Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 230000011218 segmentation Effects 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000010189 synthetic method Methods 0.000 description 2
- BWYYVSNVUCFQQN-UHFFFAOYSA-N 1,3-diphenylpropan-2-amine Chemical compound C=1C=CC=CC=1CC(N)CC1=CC=CC=C1 BWYYVSNVUCFQQN-UHFFFAOYSA-N 0.000 description 1
- XDWURHFOCYSDBT-UHFFFAOYSA-N 3,3-dibenzyl-1,4-diazabicyclo[2.2.2]octane Chemical compound C1N(CC2)CCN2C1(CC=1C=CC=CC=1)CC1=CC=CC=C1 XDWURHFOCYSDBT-UHFFFAOYSA-N 0.000 description 1
- 241001502050 Acis Species 0.000 description 1
- 241000208340 Araliaceae Species 0.000 description 1
- 208000003556 Dry Eye Syndromes Diseases 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000004111 Potassium silicate Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000012711 adhesive precursor Substances 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007850 degeneration Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- AVPRDNCYNYWMNB-UHFFFAOYSA-N ethanamine;hydrate Chemical compound [OH-].CC[NH3+] AVPRDNCYNYWMNB-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 238000001640 fractional crystallisation Methods 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 235000008434 ginseng Nutrition 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000010335 hydrothermal treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical group 0.000 description 1
- -1 methanol and ethanol Chemical compound 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- UIUXUFNYAYAMOE-UHFFFAOYSA-N methylsilane Chemical compound [SiH3]C UIUXUFNYAYAMOE-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000002572 peristaltic effect Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000909 polytetrahydrofuran Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920006316 polyvinylpyrrolidine Polymers 0.000 description 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- OLGONLPBKFPQNS-UHFFFAOYSA-M sodium 2-(4-phenylphenyl)butanoate Chemical compound [Na+].CCC(C([O-])=O)c1ccc(cc1)-c1ccccc1 OLGONLPBKFPQNS-UHFFFAOYSA-M 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229940073455 tetraethylammonium hydroxide Drugs 0.000 description 1
- LRGJRHZIDJQFCL-UHFFFAOYSA-M tetraethylazanium;hydroxide Chemical compound [OH-].CC[N+](CC)(CC)CC LRGJRHZIDJQFCL-UHFFFAOYSA-M 0.000 description 1
- AJSTXXYNEIHPMD-UHFFFAOYSA-N triethyl borate Chemical compound CCOB(OCC)OCC AJSTXXYNEIHPMD-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/026—After-treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7007—Zeolite Beta
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/38—Base treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Catalysts (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12189036.2 | 2012-10-18 | ||
| EP12189036 | 2012-10-18 | ||
| PCT/EP2013/071040 WO2014060259A1 (en) | 2012-10-18 | 2013-10-09 | Post-treatment of deboronated zeolite beta |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104918885A CN104918885A (zh) | 2015-09-16 |
| CN104918885B true CN104918885B (zh) | 2016-12-07 |
Family
ID=47073320
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201380066254.7A Active CN104918885B (zh) | 2012-10-18 | 2013-10-09 | 脱硼β沸石的后处理 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US10179741B2 (ko) |
| EP (1) | EP2909143B1 (ko) |
| JP (1) | JP6306029B2 (ko) |
| KR (1) | KR102149320B1 (ko) |
| CN (1) | CN104918885B (ko) |
| BR (1) | BR112015008629B1 (ko) |
| ES (1) | ES2713408T3 (ko) |
| MX (1) | MX357233B (ko) |
| MY (1) | MY185228A (ko) |
| RU (1) | RU2636724C2 (ko) |
| SG (1) | SG11201503031WA (ko) |
| WO (1) | WO2014060259A1 (ko) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2637021C2 (ru) | 2012-10-18 | 2017-11-29 | Басф Се | Последующая обработка цеолитного материала |
| EP3178788A1 (en) * | 2015-12-08 | 2017-06-14 | Basf Se | A tin-containing zeolitic material having a bea framework structure |
| ES2887554T3 (es) | 2017-02-28 | 2021-12-23 | Basf Se | Procedimiento de preparación de un alcohol insaturado |
| ES2962447T3 (es) | 2017-08-11 | 2024-03-19 | Basf Se | Proceso de recuperación de 3-metilbut-3-en-1-ol |
| CN113600231B (zh) * | 2021-08-06 | 2023-01-20 | 西北大学 | 一种乙醇两步法制1,3-丁二烯的催化剂的制备方法 |
| CN113663721B (zh) * | 2021-09-07 | 2023-10-17 | 陕西延长石油（集团）有限责任公司 | 一种乙醇制备1,3-丁二烯的催化剂的制备方法及其应用 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0690024A2 (en) * | 1994-06-30 | 1996-01-03 | ARCO Chemical Technology, L.P. | Dealumination of aluminosilicates |
| WO2002057181A2 (en) * | 2000-12-22 | 2002-07-25 | California Institute Of Technology | Synthesis of molecular sieves by hydrothermal treatment with acid |
| CN1469843A (zh) * | 2000-09-14 | 2004-01-21 | ���з� | 在大孔和超大孔的硼硅酸盐沸石中杂原子晶格取代的方法 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2445747A1 (fr) | 1979-01-05 | 1980-08-01 | Armines | Procede de fabrication de pieces en silicium nitrure |
| US5047141A (en) * | 1984-07-16 | 1991-09-10 | Mobil Oil Corporation | Larger pore molecular sieves of controlled activity |
| JPS61158811A (ja) * | 1985-09-11 | 1986-07-18 | ユニオン・カ−バイド・コ−ポレ−シヨン | 珪素置換ゼオライト組成物 |
| US5324702A (en) * | 1991-11-22 | 1994-06-28 | Amoco Corporation | Catalytic oxidation and oxidative dehydrogenation using metal-compound-loaded, deboronated hams-1b crystalline borosilicate molecular sieve compositions |
| GB2263669B (en) * | 1992-01-31 | 1995-07-05 | Takata Corp | Air bag device for the knees of an occupant |
| US5200168A (en) * | 1992-01-31 | 1993-04-06 | Mobil Oil Corp. | Process for the dealumination of zeolite Beta |
| DE4207745A1 (de) * | 1992-03-11 | 1993-09-16 | Basf Ag | Azofarbstoffe enthaltende molekularsiebe |
| US5723710A (en) * | 1996-07-12 | 1998-03-03 | Uop | Zeolite beta and its use in aromatic alkylation |
| CA2363798C (en) * | 1999-03-03 | 2007-10-16 | Pq Holding, Inc. | Process for preparing a modified zeolite |
| DE10061715A1 (de) * | 2000-12-12 | 2002-06-13 | Basf Ag | Verfahren zur Herstellung von Homo- und Copolymeren des Isobutens |
| US20090325790A1 (en) * | 2004-06-17 | 2009-12-31 | Yale University | Size-controllable transition metal clusters in mcm-41 for improving chemical catalysis |
| ES2249183B1 (es) * | 2004-09-15 | 2007-12-01 | Universidad Politecnica De Valencia | Uso de material cristalino microporoso de naturaleza zeolitica con estructura lta (itq-29) en procesos de adsorcion y separacion de compuestos organicos. |
| EP2025402A1 (en) | 2007-07-31 | 2009-02-18 | Total Petrochemicals Research Feluy | Phosphorus modified molecular sieves, their use in conversion of organics to olefins |
| FR2952379B1 (fr) * | 2009-11-10 | 2012-05-11 | Inst Francais Du Petrole | Procede d'hydrocraquage mettant en oeuvre une zeolithe modifiee par un traitement basique |
| US8637419B2 (en) * | 2009-12-06 | 2014-01-28 | Chevron U.S.A. Inc. | Method for making a hydroprocessing catalyst |
| KR101147669B1 (ko) * | 2010-07-05 | 2012-05-21 | 한국과학기술원 | 규칙적 또는 불규칙적으로 배열된 메조기공을 포함하는 제올라이트 또는 유사 제올라이트 물질 및 그의 제조 방법 |
| US8710271B2 (en) * | 2011-04-08 | 2014-04-29 | Basf Se | Process for the production of an acylation catalyst |
-
2013
- 2013-10-09 US US14/436,738 patent/US10179741B2/en active Active
- 2013-10-09 SG SG11201503031WA patent/SG11201503031WA/en unknown
- 2013-10-09 KR KR1020157013068A patent/KR102149320B1/ko active IP Right Grant
- 2013-10-09 EP EP13774182.3A patent/EP2909143B1/en active Active
- 2013-10-09 JP JP2015537191A patent/JP6306029B2/ja active Active
- 2013-10-09 CN CN201380066254.7A patent/CN104918885B/zh active Active
- 2013-10-09 BR BR112015008629-2A patent/BR112015008629B1/pt active IP Right Grant
- 2013-10-09 MX MX2015004945A patent/MX357233B/es active IP Right Grant
- 2013-10-09 ES ES13774182T patent/ES2713408T3/es active Active
- 2013-10-09 MY MYPI2015001014A patent/MY185228A/en unknown
- 2013-10-09 RU RU2015118229A patent/RU2636724C2/ru active
- 2013-10-09 WO PCT/EP2013/071040 patent/WO2014060259A1/en active Application Filing
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0690024A2 (en) * | 1994-06-30 | 1996-01-03 | ARCO Chemical Technology, L.P. | Dealumination of aluminosilicates |
| CN1469843A (zh) * | 2000-09-14 | 2004-01-21 | ���з� | 在大孔和超大孔的硼硅酸盐沸石中杂原子晶格取代的方法 |
| WO2002057181A2 (en) * | 2000-12-22 | 2002-07-25 | California Institute Of Technology | Synthesis of molecular sieves by hydrothermal treatment with acid |
Also Published As
| Publication number | Publication date |
|---|---|
| RU2015118229A (ru) | 2016-12-10 |
| BR112015008629A2 (pt) | 2017-08-08 |
| EP2909143B1 (en) | 2018-11-28 |
| US10179741B2 (en) | 2019-01-15 |
| WO2014060259A1 (en) | 2014-04-24 |
| MX357233B (es) | 2018-07-02 |
| JP2015536290A (ja) | 2015-12-21 |
| KR102149320B1 (ko) | 2020-08-28 |
| EP2909143A1 (en) | 2015-08-26 |
| CN104918885A (zh) | 2015-09-16 |
| MX2015004945A (es) | 2015-11-23 |
| ES2713408T3 (es) | 2019-05-21 |
| SG11201503031WA (en) | 2015-05-28 |
| US20150344317A1 (en) | 2015-12-03 |
| JP6306029B2 (ja) | 2018-04-04 |
| RU2636724C2 (ru) | 2017-11-27 |
| MY185228A (en) | 2021-04-30 |
| KR20150072446A (ko) | 2015-06-29 |
| BR112015008629B1 (pt) | 2022-03-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104918885B (zh) | 脱硼β沸石的后处理 | |
| CN105849043B (zh) | 用于气体分离的具有改进的扩散率的zsm-58晶体的合成 | |
| CN104854031B (zh) | 沸石材料的后处理 | |
| CN102218298B (zh) | 一种改性zif-8沸石咪唑酯骨架材料的制备方法 | |
| CN102712489A (zh) | β型沸石及其制造方法 | |
| JP2019502629A (ja) | Ｂｅａ骨格構造を有するスズ含有ゼオライト材料 | |
| EP2909141B1 (en) | Post-treatment of deboronated mww zeolite | |
| CN105324334B (zh) | β型沸石及其制造方法、气体吸附剂及一氧化氮除去方法 | |
| CN104028299B (zh) | 一种fcc再生烟气脱硝用铜基微孔复合分子筛基催化剂、制备方法及其用途 | |
| CN108101066A (zh) | 一种疏水性球形有序多级孔二氧化硅吸附剂的制备方法及其应用 | |
| JP2021511274A (ja) | Ｃｈａ型骨格構造を有するゼオライト材料の高速バッチ式製造方法 | |
| CN103964459B (zh) | 一种分子筛的改性方法 | |
| KR102582814B1 (ko) | 골격체형 cha를 갖고, 칼륨 및 세슘 중 하나 이상 및 전이 금속을 포함하는 제올라이트 물질 | |
| EP3625171B1 (en) | A process for preparing a zeolitic material having framework type aei | |
| CN114920258A (zh) | 一种用预吸附-干燥-原位晶化法合成分子筛整体材料的方法 | |
| CN109311684A (zh) | 高耐水热性菱沸石型沸石和其制造方法 | |
| CN108452828A (zh) | 一种含磷和稀土的超稳y型分子筛及其制备方法 | |
| CN108455625B (zh) | 一种高稳定性的改性y型分子筛及其制备方法 | |
| CN105929003A (zh) | 一种提高气敏元件选择性的催化滤膜的制备方法 | |
| CN104556086A (zh) | 一种利用有机季铵盐合成全硅分子筛的方法 | |
| CN117208927A (zh) | 一种在潮湿环境下高效捕集低浓度co2的高硅lta分子筛及其制备方法和应用 | |
| CN108452836A (zh) | 一种催化裂化催化剂 | |
| JP2000093946A (ja) | 浄水用吸着剤及び水の浄化方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |