CN104910920A - Tobacco stem charcoal soil conditioner of acidic tobacco planting soil, and processing method thereof - Google Patents
Tobacco stem charcoal soil conditioner of acidic tobacco planting soil, and processing method thereof Download PDFInfo
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- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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Abstract
The invention relates to a tobacco stem charcoal soil conditioner of acidic tobacco planting soil, and a processing method thereof. The chitosan thin film layer of the conditioner is wrapped outside a core layer, and the wrapping thickness of the chitosan thin film layer is 0.6-0.8mm; and the core layer is mainly composed of tobacco stem charcoal, calcium nitrate, magnesium nitrate, zinc oxide, borax and phosphate dissolving bacteria. The processing method of the conditioner mainly comprises the following steps: preparing tobacco stem charcoal from waste tobacco stems; crushing the tobacco stem charcoal; uniformly mixing all components of the core layer; sprinkling the phosphate dissolving bacteria; sprinkling a binder, and granulating; and dressing by using chitosan. In the invention, the tobacco stem charcoal has extremely strong water absorption and water retention abilities, an extremely high specific surface area and a loose physical structure, can effectively improve the content of organic carbon in soil, improves the soil nitrogen retention ability and potassium supply ability, improves the nutrients needed by the growth of tobacco, increases the mineralization release of effective phosphorus in soil, and can effectively improve the southern acidic tobacco planting soil.
Description
Technical field
The invention belongs to soil improvement agent technical field, relate to a kind of charcoal type soil improvement agent and working method thereof of acid tobacco-growing soil, be specially adapted to the improvement of acid tobacco-growing soil.
Background technology
Charcoal be agricultural crop straw, xyloid material, fowl and animal excrement or other organic materialss under low-oxygen environment, the class obtained through high temperature (300 DEG C-700 DEG C) pyrolysis has that specific surface area is large, hole is many, the height aromatize carbon rich material matter of absorption and the feature such as stability is strong.In recent years, charcoal causes extensive concern as the application of a kind of functional materials in the many research fields of agricultural, environment and the energy, and it presents considerable potentiality in soil tilth improvement, fertility lifting, reduction of greenhouse gas discharge and pollution amelioration etc.
Since the middle and later periods nineties 20th century, charcoal is increasing as the research of soil improvement agent and solid carbon agent, large quantity research shows that charcoal can significantly improve soil organic carbon after imposing on soil, be beneficial to the formation of soil agreegate and reduce the soil weight, improve acid soil pH, improve fertilizer nutrient utilization, strengthen guarantor's accumulation of energy power of soil available N and P potassium nutrition.And having good interaction due to charcoal and nitrogenous fertilizer, major part test proves that charcoal can promote seed germination, plant-growth improve crop yield and quality.
Yunnan Province cultivation cigarette is with a long history, and quality of tobacco has long enjoyed a good reputation, and is one of the whole nation and even foremost tobacco leaf main producing region, the world.But Crop Diseases in Yunnan pattern of farming development imbalances in recent years, in addition long-term unreasonable fertilising makes the field edatope of much planting tobacco run down, fertility declines, nutrient supply is unbalanced, harden serious, unit weight continues to increase, and cause cigarette strain retarded growth, larger fluctuation appears in quality of tobacco.
At present, charcoal applied research has carried out some research in wheat, corn, paddy rice and Soybean and Other Crops, but research on tobacco is also fewer, also not for the charcoal type soil improvement agent of typical cigarette district, south acid soil.To charcoal physico-chemical property quality standard, the preparation method of suitable tobacco, to rational formula, the amount of application of charcoal type soil improvement agent, and to the improved effect of soil and promote that the investigation and application of the aspects such as tobacco growth lacks the research of long-term field.
Summary of the invention
The present invention is directed in prior art the means lacking permanently effective stable lifting vega soil quality, lack product charcoal technology be applied in the improvement of tobacco planting field, particularly lack the situation of discarded cigarette stalk processing cigarette stalk charcoal soil improvement agent technology, a kind of cigarette stalk charcoal soil improvement agent and working method thereof of acid tobacco-growing soil are provided.
Technical scheme of the present invention is: a kind of cigarette stalk charcoal soil improvement agent of acid tobacco-growing soil and working method thereof, the cigarette stalk charcoal soil improvement agent of acid tobacco-growing soil mainly includes sandwich layer and chitosan film layer composition, chitosan film layer is wrapped in outside sandwich layer, and the Jacket thickness of chitosan film layer is 0.6mm-0.8mm; Calculate by weight, sandwich layer is made up of following ingredients, cigarette stalk charcoal 900-1000 part, nitrocalcite 50-60 part, magnesium nitrate 8-12 part, zinc oxide 8-12 part, borax 25-35 part.
The cigarette stalk charcoal soil improvement agent of acid tobacco-growing soil is obtained by following methods:
(1) cigarette stalk charcoal is prepared: the cigarette stalk staying field after being gathered in the crops by tobacco leaf dries and collects, the bar section that length is less than 10cm is chopped into stock cutter, put into charring furnace to carbonize, under anaerobic environment, control charing in-furnace temperature at 450 DEG C, cigarette stalk is carbonized gradually;
(2) obtained cigarette stalk charcoal is ground into the particle of particle diameter 2mm ± 0.5mm, for subsequent use;
(3) by each composition of sandwich layer, take and send into stirrer in right amount, stir; Spray phosphate solubilizing bacteria stoste thereon, in stoste, living bacteria count is no less than 25,000,000,000/mL, and the amount of sprinkling controls to be no less than 2.5 hundred million containing phosphate solubilizing bacteria living bacteria count in every gram of material, leaves standstill 6 hours;
(4) spray binding agent at material, the composition of binding agent is Xylo-Mucine, again stirs material, the wet stock mixed is sent into Squeezinggranulator granulation, naturally dries after granulation;
(5) adopt chitosan to carry out dressing to the particulate materials after oven dry, naturally dry after dressing, after dressing, the thickness of chitosan film is 0.6mm-0.8mm, is left standstill by material bagging and obtains finished product.
Cigarette stalk charcoal in above-mentioned working method after charing, all technical is:
Index | Value range | Index | Value range |
Water ratio (%) | 6.5±3.0 | Available phosphorus (mgkg -1) | 227.4±8.0 |
Carbon content (%) | 62.7±5.0 | Effective potassium (%) | 1.3±0.2 |
Ash content (%) | 18.3±2.5 | Cl content (%) | 0.06±0.02 |
Specific surface area (m 2·g -1) | 6.0±0.2 | Sulphur content (%) | 0.9±0.1 |
pH | 9.4±0.2 | Zn content (mgkg -1) | 40.5±4.0 |
Total nitrogen content (%) | 3.4±0.2 | Boron contents (mgkg -1) | 14.5±1.0 |
Alkali-hydrolyzable nitrogen (mgkg -1) | 42.5±3.0 | C/N | 20.0-30.0 |
Beneficial effect of the present invention is:
1, take full advantage of agriculture waste cigarette stalk resource, protect environment, production technique is simple, and cost is low.
2, this invention product pH is strong basicity, effectively can improve the soil of the pH, particularly pH<5 of southern acid tobacco-growing soil, to make its suitable tobacco cultivation.
3, main material cigarette stalk charcoal has extremely strong water suction and water-holding power, and the present invention, under the condition of not adding any water-holding agent, effectively can promote retention capacity of soil, reduces Arid Meteorology to the loss of tobacco leaf production.
4, main material cigarette stalk charcoal has high specific surface area and loose physical structure, can regulate soil tilth, significantly reduce the soil weight, effectively promotes that tobacco growing is grown.
5, main material cigarette stalk charcoal effectively can improve the content of soil organic matter, strengthens soil fertility.
6, main material cigarette stalk charcoal contains effective potassium element of high content, and coordinate the chitosan sustained-release layer of parcel, the guarantor that effectively can improve soil potassium stores and long run supply ability, promotes tobacco leaf product quality.
7, because tobacco is the crop liking nitric nitrogen, inclusion nitrocalcite of the present invention, magnesium nitrate, zinc oxide and borax, enhance the validity of soil nitrate nitrogen, and calcium, magnesium, zinc, boron deliverability, and the slow-release capability of nitrogen, calcium, magnesium, zinc, boron is improve by chitosan sustained-release layer, ensure tobacco production stable yields, suitable product.
8, phosphate solubilizing bacteria is FZB42 bacillus amyloliquefaciens, is present in vigor in soil extremely strong, and the present invention utilizes this bacterial strain to enhance the quantity of profitable strain in soil, adds the mineralising release of soil available phosphorus, facilitates the lifting of tobacco production and value amount.
Accompanying drawing explanation
Fig. 1 is the schematic diagram that in contrast experiment one, soil improvement agent affects soil organic matter and component concentration thereof.
Fig. 2 is that in contrast experiment one, soil improvement agent affects schematic diagram to the yield of tobacco output value.
Fig. 3 is the schematic diagram that in contrast experiment two, soil improvement agent affects soil organic matter and component concentration thereof.
Fig. 4 is that in contrast experiment two, soil improvement agent affects schematic diagram to the yield of tobacco output value.
Embodiment
Embodiment one: a kind of cigarette stalk charcoal soil improvement agent of acid tobacco-growing soil, mainly include sandwich layer and chitosan film layer composition, chitosan film layer is wrapped in outside sandwich layer, and the Jacket thickness of chitosan film layer is 0.8mm; Calculate by weight, sandwich layer is made up of following ingredients, cigarette stalk charcoal 1000 parts, 60 parts, nitrocalcite, magnesium nitrate 12 parts, 12 parts, zinc oxide, borax 35 parts.
The cigarette stalk charcoal soil improvement agent of acid tobacco-growing soil is obtained by following methods:
(1) cigarette stalk charcoal is prepared: the cigarette stalk staying field after being gathered in the crops by tobacco leaf dries and collects, the bar section that length is less than 10cm is chopped into stock cutter, put into charring furnace to carbonize, under anaerobic environment, control charing in-furnace temperature at 450 DEG C, cigarette stalk is carbonized gradually;
(2) obtained cigarette stalk charcoal is ground into the particle of particle diameter 2.5mm, for subsequent use;
(3) press the formula of sandwich layer, take and send into stirrer in right amount, stir; Spray phosphate solubilizing bacteria stoste thereon, in stoste, living bacteria count is no less than 25,000,000,000/mL, and the amount of sprinkling controls to be no less than 2.5 hundred million containing phosphate solubilizing bacteria living bacteria count in every gram of material, leaves standstill 6 hours;
(4) spray binding agent at material, the composition of binding agent is Xylo-Mucine, again stirs material, the wet stock mixed is sent into Squeezinggranulator granulation, naturally dries after granulation;
(5) adopt chitosan to carry out dressing to the particulate materials after oven dry, naturally dry after dressing, after dressing, the thickness of chitosan film is 0.8mm, is left standstill by material bagging and obtains finished product.
Cigarette stalk charcoal in above-mentioned working method after charing, all technical is:
Index | Value range | Index | Value range |
Water ratio (%) | 6.5±3.0 | Available phosphorus (mgkg -1) | 227.4±8.0 |
Carbon content (%) | 62.7±5.0 | Effective potassium (%) | 1.3±0.2 |
Ash content (%) | 18.3±2.5 | Cl content (%) | 0.06±0.02 |
Specific surface area (m 2·g -1) | 6.0±0.2 | Sulphur content (%) | 0.9±0.1 |
pH | 9.4±0.2 | Zn content (mgkg -1) | 40.5±4.0 |
Total nitrogen content (%) | 3.4±0.2 | Boron contents (mgkg -1) | 14.5±1.0 |
Alkali-hydrolyzable nitrogen (mgkg -1) | 42.5±3.0 | C/N | 20.0-30.0 |
Embodiment two: a kind of cigarette stalk charcoal soil improvement agent of acid tobacco-growing soil and working method thereof, the cigarette stalk charcoal soil improvement agent of acid tobacco-growing soil mainly includes sandwich layer and chitosan film layer composition, chitosan film layer is wrapped in outside sandwich layer, and the Jacket thickness of chitosan film layer is 0.6mm; Calculate by weight, sandwich layer is made up of following ingredients, cigarette stalk charcoal 900 parts, 50 parts, nitrocalcite, magnesium nitrate 8 parts, 8 parts, zinc oxide, borax 25 parts.
The cigarette stalk charcoal soil improvement agent of acid tobacco-growing soil is obtained by following methods:
(1) cigarette stalk charcoal is prepared: the cigarette stalk staying field after being gathered in the crops by tobacco leaf dries and collects, the bar section that length is less than 10cm is chopped into stock cutter, put into charring furnace to carbonize, under anaerobic environment, control charing in-furnace temperature at 450 DEG C, cigarette stalk is carbonized gradually;
(2) obtained cigarette stalk charcoal is ground into the particle of particle diameter 1.5mm, for subsequent use;
(3) by each composition of sandwich layer, take and send into stirrer in right amount, stir; Spray phosphate solubilizing bacteria stoste thereon, in stoste, living bacteria count is no less than 25,000,000,000/mL, and the amount of sprinkling controls to be no less than 2.5 hundred million containing phosphate solubilizing bacteria living bacteria count in every gram of material, leaves standstill 6 hours;
(4) spray binding agent at material, the composition of binding agent is Xylo-Mucine, again stirs material, the wet stock mixed is sent into Squeezinggranulator granulation, naturally dries after granulation;
(5) adopt chitosan to carry out dressing to the particulate materials after oven dry, naturally dry after dressing, after dressing, the thickness of chitosan film is 0.6mm, is left standstill by material bagging and obtains finished product.
Cigarette stalk charcoal in above-mentioned working method after charing, all technical is:
Index | Value range | Index | Value range |
Water ratio (%) | 6.5±3.0 | Available phosphorus (mgkg -1) | 227.4±8.0 |
Carbon content (%) | 62.7±5.0 | Effective potassium (%) | 1.3±0.2 |
Ash content (%) | 18.3±2.5 | Cl content (%) | 0.06±0.02 |
Specific surface area (m 2·g -1) | 6.0±0.2 | Sulphur content (%) | 0.9±0.1 |
pH | 9.4±0.2 | Zn content (mgkg -1) | 40.5±4.0 |
Total nitrogen content (%) | 3.4±0.2 | Boron contents (mgkg -1) | 14.5±1.0 |
Alkali-hydrolyzable nitrogen (mgkg -1) | 42.5±3.0 | C/N | 20.0-30.0 |
effect contrast experiment
Contrast experiment one
1.1 materials and methods
Test is located at test point, Yuxi Hongta District of Yunnan Province, and terrestrial coordinates 24o17 ' 24 " N, 102o35 ' 24 " E, the situations such as this soil fertility is lower, and soil compaction is heavier, initial soil physicochemical character see the following form.Be " flue-cured tobacco---rape---flue-cured tobacco " cultivation mode before on-test, this test flue-cured tobacco cultivation kind is K326.
Choose three process of Yuxi Hongta District of Yunnan Province low fertility soil, be respectively H C0: conventional fertilizer application does not use this soil improvement agent, HC1: conventional fertilizer application also uses this soil improvement agent 15t
.hm
-2, HC2: conventional fertilizer application also uses this soil improvement agent 30t
.hm
-2, this soil improvement agent is used once by design quantity for 1 year.3 repetitions are all established in each process, and each repetition area is 666.7m
2, each community random alignment.Test for long term experiment, started after flue-cured tobacco results from 2010, to flue-cured tobacco results in 2014 only, and the cultivation mode of unified employing test site in " flue-cured tobacco---let a piece of farmland go to waste---flue-cured tobacco ".
This soil improvement agent application process is spread fertilizer over the fields before plowing, and turns over, and fully mixes with topsoil 20cm soil.Other cultivations and conventional fertilizer application mode perform with reference to Yuxi high-quality tobacco comprehensive standard.Flue-cured tobacco transplanting carried out in annual 20-25 day in April, adopted roasting end annual 1-5 day in September.
1.2 results and analysis
(1) Figure of description 1 is shown in the impact of long-term application soil improvement agent of the present invention on soil organic matter and component concentration thereof.
in fig. 1:different lowercase represents that between contemporaneity different treatment, difference reaches conspicuous level (P < 0.05), and different capitalization represents that same process different times difference reaches conspicuous level (P < 0.05).
in fig. 1:use soil improvement agent of the present invention in whole trial period and significantly improve topsoil soils (0-20cm) total content of organic carbon (P < 0.05).During to off-test, HC1 and HC2 process soil total content of organic carbon comparatively its contrast adds 73.2% and 77.7% respectively.
After using soil improvement agent of the present invention, oPOM state organic carbon content increases sharply, and be the major cause that total content of organic carbon increases, fPOM state content also significantly increases.
The rising of organic carbon content illustrates that soil improvement agent of the present invention facilitates the soil organism and formed; MOM, oPOM and fPOM component stability declines successively, transformation period reduces gradually, show that the soil organic matter character applying soil improvement agent of the present invention formation is comparatively stable, can exist for a long time in soil and progressively transform, add the higher fPOM content of plant utilization rate at this season again simultaneously, show positive Effects on Soil Amendments.
(2) impact of long-term application soil improvement agent of the present invention on soil Main Nutrients and physical behavior sees the following form:
Note: different lowercase represents that between contemporaneity different treatment, difference reaches conspicuous level (P < 0.05).
It is generally acknowledged that soil weight reduction characterizes soil physics structure and improves, contribute to improving soil fertilizer feeder capability.Test-results as shown above, this test discovery is used soil improvement agent of the present invention and is significantly reduced the soil weight, improve soil pH, within whole trial period, we find to use the content that soil improvement agent of the present invention can significantly improve soil alkali-hydrolyzable nitrogen, available phosphorus and effective potassium, strengthen soil nutrient deliverability.
(3) Figure of description 2 is shown in the impact of long-term application soil improvement agent of the present invention on the yield of tobacco output value.
In Figure of description 2: different lowercase represents that between contemporaneity different treatment, difference reaches conspicuous level (P < 0.05).
Shown in Figure of description 2, the process of using soil improvement agent of the present invention comparatively contrasts and significantly improves yield of tobacco.The first two years yield of tobacco increases along with soil improvement agent consumption of the present invention and increases, and in the rear effect embodying stable yields for 2 years.During to off-test, HC1 and HC2 process yield of tobacco reaches 2465kg respectively
.hm
-2and 2337kg
.hm
-2, comparatively contrast and add 12.9% and 7.1% respectively.Survey product and show that using the roasting rear product of soil improvement agent tobacco leaf of the present invention is slightly better than contrast mutually, improve the average price of tobacco leaf, the variation tendency of the tobacco leaf output value is close with yield of tobacco generally.During to off-test, HC1 and the HC2 process tobacco leaf output value reaches 71150Yuan respectively
.hm
-2and 70344Yuan
.hm
-2, comparatively its contrast adds 19.7% and 18.4% respectively.
Contrast experiment two
2.1 materials and methods
Test " N, the 102o46 ' 23 " E that is located at Yuxi Tonghai County, Yunnan Province, terrestrial coordinates 24o11 ' 42, soil fertility is higher, and soil compaction is heavier, and be " flue-cured tobacco---vegetables---flue-cured tobacco " cultivation mode before on-test, this test flue-cured tobacco cultivation kind is K326.Three somes TC0, TC1, TC2. are chosen in test
Test Treatment Design and trial with embodiment 1, wherein: T C0: conventional fertilizer application does not use this soil improvement agent, TC1: conventional fertilizer application also uses this soil improvement agent 15t
.hm
-2, TC2: conventional fertilizer application also uses this soil improvement agent 30t
.hm
-2.
2.2 results and analysis
(1) Figure of description 3 is shown in the impact of long-term application soil improvement agent of the present invention on soil organic matter and component concentration thereof.
In Figure of description 3: different lowercase represents that between contemporaneity different treatment, difference reaches conspicuous level (P < 0.05), and different capitalization represents that same process different times difference reaches conspicuous level (P < 0.05).
In Figure of description 3: use soil improvement agent of the present invention in whole trial period and significantly improve topsoil soils (0-20cm) total content of organic carbon (P < 0.05).During to off-test, TC1 and TC2 process soil total content of organic carbon comparatively its contrast adds 45.7% and 46.7% respectively.
After using soil improvement agent of the present invention, oPOM state organic carbon content increases sharply, and be the major cause that total content of organic carbon increases, fPOM state content also significantly increases.
Facilitate the soil organism with the bright soil improvement agent of the present invention of sample test card to be formed; Improve the stability of soil organic matter character; Add the higher fPOM content of plant utilization rate at this season again simultaneously; Show positive Effects on Soil Amendments.
(2) long-term application soil improvement agent of the present invention is on the impact of soil Main Nutrients and physical behavior
Note: different lowercase represents that between contemporaneity different treatment, difference reaches conspicuous level (P < 0.05).
It is generally acknowledged that soil weight reduction characterizes soil physics structure and improves, contribute to improving soil fertilizer feeder capability.As shown above, this test discovery is used soil improvement agent of the present invention and is significantly reduced the soil weight, improve soil pH, within whole trial period, we find to use the content that soil improvement agent of the present invention can significantly improve soil alkali-hydrolyzable nitrogen, available phosphorus and effective potassium, strengthen soil nutrient deliverability.
(3) Figure of description 4 is shown in the impact of long-term application soil improvement agent of the present invention on the yield of tobacco output value.
In Figure of description 4: different lowercase represents that between contemporaneity different treatment, difference reaches conspicuous level (P < 0.05).
In Figure of description 4: the process of using soil improvement agent of the present invention comparatively contrasts and significantly improves yield of tobacco.From test Second Year, yield of tobacco increases along with soil improvement agent consumption of the present invention and increases, in the rear effect embodying stable yields for 2 years of test.During to off-test, TC1 and TC2 process yield of tobacco reaches 2591kg respectively
.hm
-2and 2555kg
.hm
-2, comparatively contrast and add 6.5% and 5.1% respectively.Survey product and show that using the roasting rear product of soil improvement agent tobacco leaf of the present invention is slightly better than contrast mutually, improve the average price of tobacco leaf, the variation tendency of the tobacco leaf output value is close with yield of tobacco generally.During to off-test, TC1 and the TC2 process tobacco leaf output value reaches 74995Yuan respectively
.hm
-2and 76686Yuan
.hm
-2, comparatively its contrast adds 12.6% and 15.1% respectively.
Claims (3)
1. the cigarette stalk charcoal soil improvement agent of acid tobacco-growing soil, is characterized in that: mainly include sandwich layer and chitosan film layer composition, chitosan film layer is wrapped in outside sandwich layer, and the Jacket thickness of chitosan film layer is 0.6mm-0.8mm; Calculate by weight, sandwich layer is made up of following ingredients, cigarette stalk charcoal 900-1000 part, nitrocalcite 50-60 part, magnesium nitrate 10 parts, 10 parts, zinc oxide, borax 30 parts.
2. the working method of the cigarette stalk charcoal soil improvement agent of acid tobacco-growing soil as claimed in claim 1, is characterized in that:
(1) cigarette stalk charcoal is prepared: the cigarette stalk staying field after being gathered in the crops by tobacco leaf dries and collects, the bar section that length is less than 10cm is chopped into stock cutter, put into charring furnace to carbonize, under anaerobic environment, control charing in-furnace temperature at 450 DEG C, cigarette stalk is carbonized gradually;
(2) obtained cigarette stalk charcoal is ground into the particle of particle diameter 2mm ± 0.5mm, for subsequent use;
(3) by the sandwich layer composition determined in claim 1, take and send into stirrer in right amount, stir; Spray phosphate solubilizing bacteria stoste thereon, in stoste, living bacteria count is no less than 25,000,000,000/mL, and the amount of sprinkling controls to be no less than 2.5 hundred million containing phosphate solubilizing bacteria living bacteria count in every gram of material, leaves standstill 6 hours;
(4) spray binding agent at material, the composition of binding agent is Xylo-Mucine, again stirs material, the wet stock mixed is sent into Squeezinggranulator granulation, naturally dries after granulation;
(5) adopt chitosan to carry out dressing to the particulate materials after oven dry, naturally dry after dressing, after dressing, the thickness of chitosan film is 0.6mm-0.8mm, is left standstill by material bagging and obtains finished product.
3. the working method of the cigarette stalk charcoal soil improvement agent of acid tobacco-growing soil according to claim 2, it is characterized in that: the cigarette stalk charcoal after charing, all technical is:
。
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CN107011913A (en) * | 2017-04-18 | 2017-08-04 | 广东丰康生物科技有限公司 | A kind of acid soil improving agent |
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CN111203143A (en) * | 2020-01-14 | 2020-05-29 | 南京万德斯环保科技股份有限公司 | Soil conditioner preparation system of living beings charcoal coupling microorganism |
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CN111269724B (en) * | 2020-03-10 | 2021-12-24 | 中国科学院合肥物质科学研究院 | Preparation method of acidic soil remediation agent, prepared soil remediation agent and application |
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