CN104822456A - 用于氢甲酰化乙烯的双齿配位体 - Google Patents

用于氢甲酰化乙烯的双齿配位体 Download PDF

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Publication number
CN104822456A
CN104822456A CN201380062320.3A CN201380062320A CN104822456A CN 104822456 A CN104822456 A CN 104822456A CN 201380062320 A CN201380062320 A CN 201380062320A CN 104822456 A CN104822456 A CN 104822456A
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ligand
group
independently
formula
unsubstituted
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Chinese (zh)
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O·迭博尔特
H·特瑞卡斯
P·W·N·M·万莱文
H·A·斯平尼
R·D·J·弗勒泽
M·A·布莱默
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Dow Technology Investments LLC
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Dow Technology Investments LLC
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B01J31/186—Mono- or diamide derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1865—Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
    • B01J31/187—Amide derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CN201380062320.3A 2012-12-04 2013-11-19 用于氢甲酰化乙烯的双齿配位体 Pending CN104822456A (zh)

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CN201811183222.6A CN109364997A (zh) 2012-12-04 2013-11-19 用于氢甲酰化乙烯的双齿配位体

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EP12382481.5A EP2740535A1 (en) 2012-12-04 2012-12-04 Bidentate ligands for hydroformylation of ethylene
EP12382481.5 2012-12-04
PCT/US2013/070753 WO2014088800A1 (en) 2012-12-04 2013-11-19 Bidentate ligands for hydroformylation of ethylene

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EP (1) EP2740535A1 (enExample)
JP (1) JP6360067B2 (enExample)
KR (1) KR102157915B1 (enExample)
CN (2) CN109364997A (enExample)
WO (1) WO2014088800A1 (enExample)
ZA (1) ZA201503184B (enExample)

Cited By (11)

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Publication number Priority date Publication date Assignee Title
CN108698962A (zh) * 2016-02-11 2018-10-23 陶氏技术投资有限责任公司 将烯烃转化成醇、醚或其组合的方法
CN109922882A (zh) * 2016-11-08 2019-06-21 陶氏技术投资有限责任公司 使失活的氢甲酰化催化剂溶液再生的方法
CN109937090A (zh) * 2016-11-08 2019-06-25 陶氏技术投资有限责任公司 处理加氢甲酰化催化剂溶液的方法
CN109963649A (zh) * 2016-11-08 2019-07-02 陶氏技术投资有限责任公司 使失活的加氢甲酰化催化剂溶液再生的方法
CN113583046A (zh) * 2021-09-02 2021-11-02 成都欣华源科技有限责任公司 双齿膦配体及其制备方法、应用
CN113713862A (zh) * 2020-05-26 2021-11-30 中国科学院大连化学物理研究所 烯烃氢甲酰化反应的Co基多相催化剂及制备和应用
CN114163476A (zh) * 2021-12-02 2022-03-11 万华化学集团股份有限公司 一种单齿膦型配体、氢甲酰化催化剂，一种烯烃氢甲酰化制备线性醛的方法
CN114736239A (zh) * 2022-05-26 2022-07-12 重庆理工大学 一种双齿膦配体及其制备方法、应用
CN115536695A (zh) * 2021-06-30 2022-12-30 中国石油化工股份有限公司 一种含有聚乙二醇氨基的非对称膦配体及其应用
CN115536698A (zh) * 2021-06-30 2022-12-30 中国石油化工股份有限公司 膦配体化合物、用于均相氢甲酰化反应的催化剂组合物及方法
CN115536697A (zh) * 2021-06-30 2022-12-30 中国石油化工股份有限公司 膦配体化合物、用于催化氢甲酰化制备醛的催化剂组合物及方法

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CN105683142B (zh) 2013-10-28 2018-11-13 罗门哈斯公司 用于分离甲基丙烯醛的方法
RU2619951C1 (ru) * 2016-06-21 2017-05-22 ФЕДЕРАЛЬНОЕ ГОСУДАРСТВЕННОЕ БЮДЖЕТНОЕ УЧРЕЖДЕНИЕ НАУКИ ИНСТИТУТ ОРГАНИЧЕСКОЙ ХИМИИ им. Н.Д. ЗЕЛИНСКОГО РОССИЙСКОЙ АКАДЕМИИ НАУК (ИОХ РАН) Двухстадийный способ получения пропионового альдегида
US10183899B2 (en) 2016-11-10 2019-01-22 Chevron Phillips Chemical Company Lp Normal alpha olefin synthesis using metathesis and dehydroformylation
KR102131788B1 (ko) 2017-05-29 2020-07-09 주식회사 엘지화학 히드로포밀화 반응용 촉매 조성물 및 이를 이용한 알데히드 제조방법
WO2018221830A1 (ko) * 2017-05-29 2018-12-06 (주) 엘지화학 히드로포밀화 반응용 촉매 조성물 및 이를 이용한 알데히드 제조방법
US11123723B2 (en) 2018-02-26 2021-09-21 The Regents Of The University Of California Oxidative dehydroxymethylation of alcohols to produce olefins
US10723672B2 (en) 2018-02-26 2020-07-28 Chervon Phillips Chemical Company Lp Normal alpha olefin synthesis using dehydroformylation or dehydroxymethylation
CN110327975B (zh) * 2019-06-06 2020-05-19 浙江新和成股份有限公司 氢甲酰化催化剂及其制备方法和应用
US11370737B2 (en) 2020-09-25 2022-06-28 Lyondell Chemical Technology, L.P. Co-feeding ethylene with allyl alcohol in hydroformylation to make 1,4-butanediol and n-propanol
CN113385236B (zh) * 2021-06-16 2023-02-03 上海华谊（集团）公司 烯烃氢甲酰化催化剂组合物和氢甲酰化方法
US12151993B2 (en) 2021-09-10 2024-11-26 Chevron Phillips Chemical Company Lp Selective 1-hexene/1-octene production with 1-decene
CN118019747A (zh) 2021-10-06 2024-05-10 陶氏环球技术有限责任公司 丙基亚胺官能化有机硅化合物和伯氨基丙基官能化有机硅化合物的制备
JP2024536286A (ja) 2021-10-06 2024-10-04 ダウ グローバル テクノロジーズ エルエルシー プロピルイミン官能性有機ケイ素化合物及び一級アミノプロピル官能性有機ケイ素化合物の調製

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Cited By (19)

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CN108698962A (zh) * 2016-02-11 2018-10-23 陶氏技术投资有限责任公司 将烯烃转化成醇、醚或其组合的方法
CN108698962B (zh) * 2016-02-11 2022-02-25 陶氏技术投资有限责任公司 将烯烃转化成醇、醚或其组合的方法
CN109963649A (zh) * 2016-11-08 2019-07-02 陶氏技术投资有限责任公司 使失活的加氢甲酰化催化剂溶液再生的方法
CN109963649B (zh) * 2016-11-08 2023-01-03 陶氏技术投资有限责任公司 使失活的加氢甲酰化催化剂溶液再生的方法
CN109937090A (zh) * 2016-11-08 2019-06-25 陶氏技术投资有限责任公司 处理加氢甲酰化催化剂溶液的方法
CN109922882A (zh) * 2016-11-08 2019-06-21 陶氏技术投资有限责任公司 使失活的氢甲酰化催化剂溶液再生的方法
CN109937090B (zh) * 2016-11-08 2022-12-20 陶氏技术投资有限责任公司 处理加氢甲酰化催化剂溶液的方法
CN113713862A (zh) * 2020-05-26 2021-11-30 中国科学院大连化学物理研究所 烯烃氢甲酰化反应的Co基多相催化剂及制备和应用
CN113713862B (zh) * 2020-05-26 2023-04-11 中国科学院大连化学物理研究所 烯烃氢甲酰化反应的Co基多相催化剂及制备和应用
CN115536695B (zh) * 2021-06-30 2025-10-14 中国石油化工股份有限公司 一种含有聚乙二醇氨基的非对称膦配体及其应用
CN115536695A (zh) * 2021-06-30 2022-12-30 中国石油化工股份有限公司 一种含有聚乙二醇氨基的非对称膦配体及其应用
CN115536698A (zh) * 2021-06-30 2022-12-30 中国石油化工股份有限公司 膦配体化合物、用于均相氢甲酰化反应的催化剂组合物及方法
CN115536697A (zh) * 2021-06-30 2022-12-30 中国石油化工股份有限公司 膦配体化合物、用于催化氢甲酰化制备醛的催化剂组合物及方法
CN113583046A (zh) * 2021-09-02 2021-11-02 成都欣华源科技有限责任公司 双齿膦配体及其制备方法、应用
CN113583046B (zh) * 2021-09-02 2023-08-25 成都欣华源科技有限责任公司 双齿膦配体及其制备方法、应用
CN114163476B (zh) * 2021-12-02 2023-09-19 万华化学集团股份有限公司 一种单齿膦型配体、氢甲酰化催化剂，一种烯烃氢甲酰化制备线性醛的方法
CN114163476A (zh) * 2021-12-02 2022-03-11 万华化学集团股份有限公司 一种单齿膦型配体、氢甲酰化催化剂，一种烯烃氢甲酰化制备线性醛的方法
CN114736239A (zh) * 2022-05-26 2022-07-12 重庆理工大学 一种双齿膦配体及其制备方法、应用
CN114736239B (zh) * 2022-05-26 2024-01-16 重庆理工大学 一种双齿膦配体及其制备方法、应用

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JP6360067B2 (ja) 2018-07-18
KR102157915B1 (ko) 2020-09-21
ZA201503184B (en) 2017-07-26
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CN109364997A (zh) 2019-02-22
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