CN104744703B - 一种含硅的桐油基醇酸树脂及其制备方法和应用 - Google Patents
一种含硅的桐油基醇酸树脂及其制备方法和应用 Download PDFInfo
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- CN104744703B CN104744703B CN201510091631.3A CN201510091631A CN104744703B CN 104744703 B CN104744703 B CN 104744703B CN 201510091631 A CN201510091631 A CN 201510091631A CN 104744703 B CN104744703 B CN 104744703B
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- verniciae fordii
- oleum verniciae
- maleic anhydride
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- 239000002383 tung oil Substances 0.000 title abstract 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title abstract 4
- 238000006243 chemical reaction Methods 0.000 claims abstract description 45
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 23
- -1 polydimethylsiloxanes Polymers 0.000 claims abstract description 20
- 238000010438 heat treatment Methods 0.000 claims abstract description 19
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- 125000000524 functional group Chemical group 0.000 claims description 3
- 238000000746 purification Methods 0.000 claims description 3
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 11
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- 235000019198 oils Nutrition 0.000 description 11
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- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 description 7
- 239000000047 product Substances 0.000 description 6
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- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
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- HBGPNLPABVUVKZ-POTXQNELSA-N (1r,3as,4s,5ar,5br,7r,7ar,11ar,11br,13as,13br)-4,7-dihydroxy-3a,5a,5b,8,8,11a-hexamethyl-1-prop-1-en-2-yl-2,3,4,5,6,7,7a,10,11,11b,12,13,13a,13b-tetradecahydro-1h-cyclopenta[a]chrysen-9-one Chemical compound C([C@@]12C)CC(=O)C(C)(C)[C@@H]1[C@H](O)C[C@]([C@]1(C)C[C@@H]3O)(C)[C@@H]2CC[C@H]1[C@@H]1[C@]3(C)CC[C@H]1C(=C)C HBGPNLPABVUVKZ-POTXQNELSA-N 0.000 description 1
- PFRGGOIBYLYVKM-UHFFFAOYSA-N 15alpha-hydroxylup-20(29)-en-3-one Natural products CC(=C)C1CCC2(C)CC(O)C3(C)C(CCC4C5(C)CCC(=O)C(C)(C)C5CCC34C)C12 PFRGGOIBYLYVKM-UHFFFAOYSA-N 0.000 description 1
- 238000005160 1H NMR spectroscopy Methods 0.000 description 1
- 238000005698 Diels-Alder reaction Methods 0.000 description 1
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- 240000002834 Paulownia tomentosa Species 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
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- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- SOKRNBGSNZXYIO-UHFFFAOYSA-N Resinone Natural products CC(=C)C1CCC2(C)C(O)CC3(C)C(CCC4C5(C)CCC(=O)C(C)(C)C5CCC34C)C12 SOKRNBGSNZXYIO-UHFFFAOYSA-N 0.000 description 1
- 229910018557 Si O Inorganic materials 0.000 description 1
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- 150000008065 acid anhydrides Chemical class 0.000 description 1
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- 150000002333 glycines Chemical class 0.000 description 1
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- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000007144 microwave assisted synthesis reaction Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
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- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000003961 organosilicon compounds Chemical group 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 125000005496 phosphonium group Chemical group 0.000 description 1
- 238000000016 photochemical curing Methods 0.000 description 1
- 239000010773 plant oil Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229950000845 politef Drugs 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000012643 polycondensation polymerization Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
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- 239000000057 synthetic resin Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 150000005671 trienes Chemical class 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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CN105418902B (zh) * | 2015-12-29 | 2017-07-18 | 中国林业科学研究院林产化学工业研究所 | 一种模塑料用桐油基不饱和共酯树脂及其合成方法和应用 |
CN107383270B (zh) * | 2017-07-25 | 2019-04-02 | 中国林业科学研究院林产化学工业研究所 | 一种环氧油脂基不饱和酯光固化树脂及其制备方法和应用 |
CN113897028B (zh) * | 2021-10-22 | 2024-04-16 | 中国林业科学研究院林产化学工业研究所 | 一种桐油基互穿网络型形状记忆聚合物及其制备方法 |
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CN103881075A (zh) * | 2014-02-28 | 2014-06-25 | 成都杰晟蜀邦新材料科技有限公司 | 一种改性醇酸树脂 |
CN104086761A (zh) * | 2014-06-05 | 2014-10-08 | 华南理工大学 | 一种水性有机硅改性醇酸树脂及其制备方法 |
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CN103881075A (zh) * | 2014-02-28 | 2014-06-25 | 成都杰晟蜀邦新材料科技有限公司 | 一种改性醇酸树脂 |
CN104086761A (zh) * | 2014-06-05 | 2014-10-08 | 华南理工大学 | 一种水性有机硅改性醇酸树脂及其制备方法 |
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