CN104302395A - 用于芳香族化合物的羟基化的方法、羟基化催化剂以及用于制备羟基化催化剂的方法 - Google Patents

用于芳香族化合物的羟基化的方法、羟基化催化剂以及用于制备羟基化催化剂的方法 Download PDF

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Publication number
CN104302395A
CN104302395A CN201380009890.6A CN201380009890A CN104302395A CN 104302395 A CN104302395 A CN 104302395A CN 201380009890 A CN201380009890 A CN 201380009890A CN 104302395 A CN104302395 A CN 104302395A
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zeolite
hydroxylation
hours
formula
precursor
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Chinese (zh)
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T.科尔
B.阿尔贝拉
L.博纳维奥
L.加雷尔
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Centre National de la Recherche Scientifique CNRS
Rhodia Operations SAS
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Rhodia Operations SAS
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by oxidation reactions introducing directly hydroxy groups on a =CH-group belonging to a six-membered aromatic ring with the aid of other oxidants than molecular oxygen or their mixtures with molecular oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B01J35/77—Compounds characterised by their crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/065—Galloaluminosilicates; Group IVB- metalloaluminosilicates; Ferroaluminosilicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/58—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by oxidation reactions introducing directly hydroxy groups on a =CH-group belonging to a six-membered aromatic ring with the aid of molecular oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/10—Infrared [IR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
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    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/16—Pore diameter

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Dispersion Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
CN201380009890.6A 2012-02-17 2013-02-15 用于芳香族化合物的羟基化的方法、羟基化催化剂以及用于制备羟基化催化剂的方法 Pending CN104302395A (zh)

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Application Number Priority Date Filing Date Title
CN201810264001.5A CN108435247A (zh) 2012-02-17 2013-02-15 用于芳香族化合物的羟基化的方法、羟基化催化剂以及用于制备羟基化催化剂的方法

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1251496A FR2987046B1 (fr) 2012-02-17 2012-02-17 Procede d'hydroxylation de composes aromatiques, catalyseur d'hydroxylation et son procede de preparation
FR1251496 2012-02-17
PCT/EP2013/053054 WO2013120986A1 (fr) 2012-02-17 2013-02-15 Procede d'hydroxylation de composes aromatiques, catalyseur d'hydroxylation et son procede de preparation

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CN201810264001.5A Pending CN108435247A (zh) 2012-02-17 2013-02-15 用于芳香族化合物的羟基化的方法、羟基化催化剂以及用于制备羟基化催化剂的方法

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EP (1) EP2814606A1 (https=)
JP (2) JP6509561B2 (https=)
CN (2) CN104302395A (https=)
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112888658A (zh) * 2018-08-24 2021-06-01 罗地亚经营管理公司 微孔铝钛硅酸盐结晶沸石，其制备方法和应用

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
UA124030C2 (uk) 2017-01-09 2021-07-07 Евонік Оперейшнс Гмбх Спосіб одержання оксидів металів за допомогою розпилювального піролізу
EP3424883A1 (de) 2017-07-05 2019-01-09 Evonik Degussa GmbH Sprühverdampfung eines flüssigen rohstoffes zur herstellung von siliciumdioxid und metalloxiden
CN107597173B (zh) * 2017-10-11 2020-07-21 中国天辰工程有限公司 一种苯酚羟基化合成苯二酚的催化剂及其制备方法
EP3495321A1 (de) * 2017-12-07 2019-06-12 Evonik Degussa GmbH Herstellung von pulverförmigen, porösen kristallinen metallsilikaten mittels flammensprühpyrolyse
FR3075198B1 (fr) * 2017-12-15 2020-04-03 Rhodia Operations Procede d'hydroxylation d'un compose aromatique
WO2019182035A1 (ja) * 2018-03-23 2019-09-26 宇部興産株式会社 芳香族ヒドロキシ化合物の製造方法
WO2019225549A1 (ja) * 2018-05-21 2019-11-28 三井化学株式会社 変性アルミノシリケートの製造方法、変性アルミノシリケート及びそれを用いた芳香族ジヒドロキシ化合物の製造方法
EP3628642A1 (en) * 2018-09-25 2020-04-01 Evonik Operations GmbH Process for the manufacture of pulverulent, porous crystalline metal silicates employing flame spray pyrolysis
FR3095199B1 (fr) * 2019-04-19 2021-10-29 Ifp Energies Now Procédé de synthèse rapide d'une zeolithe de type structural AFX avec une source de faujasite
MX2021013340A (es) * 2019-04-29 2021-11-17 Basf Se Pieza moldeada que comprende un titanosilicato zeolitico tipo mfi y un aglutinante de silice, su proceso de preparacion y uso como catalizador.
JP7556686B2 (ja) * 2019-12-26 2024-09-26 日揮触媒化成株式会社 アルコキシ基を含む原料を使用しないチタノシリケートゼオライトの製造方法
CN112717998B (zh) * 2021-01-19 2022-03-11 中国科学院大连化学物理研究所 一种高活性苯酚羟基化钛硅分子筛催化剂及其制备方法
CN112871206B (zh) * 2021-01-19 2022-04-08 中国科学院大连化学物理研究所 一种低成本高活性苯酚羟基化钛硅分子筛催化剂的制备方法
CN114634404B (zh) * 2022-04-01 2023-09-15 北京化工大学 一种苯氧化制备苯酚的方法
JP2023160591A (ja) * 2022-04-22 2023-11-02 三井化学株式会社 変性アルミノシリケートの製造方法、変性アルミノシリケート及びそれを用いた芳香族ポリヒドロキシド化合物の製造方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2523575A1 (fr) * 1982-03-19 1983-09-23 Anic Spa Procede pour l'hydroxylation d'hydrocarbures aromatiques
US4410501A (en) * 1979-12-21 1983-10-18 Snamprogetti S.P.A. Preparation of porous crystalline synthetic material comprised of silicon and titanium oxides
EP0638362A1 (en) * 1993-08-11 1995-02-15 Mitsubishi Gas Chemical Company, Inc. Titanosilicate catalyst particle
CN1167082A (zh) * 1996-06-05 1997-12-10 中国石油化工总公司 一种钛硅分子筛(ts-1)的制备方法
CN101913620A (zh) * 2010-07-20 2010-12-15 大连理工大学 一种廉价体系中快速合成小晶粒钛硅分子筛的方法

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2071464A5 (https=) 1969-12-30 1971-09-17 Rhone Poulenc Sa
IT1207519B (it) * 1985-12-19 1989-05-25 Eniricerche Spa Materiale sintetico cristallino poroso contenetne ossidi di silicio titanio e alluminio.
IT1222868B (it) 1987-10-12 1990-09-12 Montedipe Spa Metodo per la preparazione di titanio silicaliti
JP2866715B2 (ja) * 1990-07-04 1999-03-08 三井化学株式会社 芳香族ヒドロキシ化合物の製造法
DE4419195A1 (de) * 1993-07-12 1995-01-19 Degussa Strukturierter Katalysator, bestehend aus mikroporösen Oxiden von Silicium, Aluminium und Titan
JPH07100387A (ja) * 1993-08-11 1995-04-18 Mitsubishi Gas Chem Co Inc 改良されたチタノシリケート触媒、その製造方法及びこれを触媒として使用する過酸化水素を利用した有機合成反応
JP3697737B2 (ja) 1995-03-14 2005-09-21 東ソー株式会社 合成ゼオライト物質
CN1063106C (zh) * 1996-10-22 2001-03-14 中国石油化工总公司上海石油化工研究院 钛硅分子筛的合成方法
FR2784672B1 (fr) * 1998-10-19 2000-12-29 Rhodia Chimie Sa Procede de preparation d'une silicalite de titane de type mel, produit obtenu et ses applications en catalyse
CN1076724C (zh) * 1999-03-30 2001-12-26 中国石油化工集团公司 一种苯酚羟基化的方法
EP1129991A1 (de) * 2000-03-02 2001-09-05 Degussa AG Verfahren zur Herstellung eines titanhaltigen Zeolithen
EP1195368A3 (en) * 2000-09-25 2002-05-15 Haldor Topsoe A/S Process for the catalytic selective oxidation of a hydrocarbon compound in presence of mesoporous zeolite
US7211239B2 (en) * 2005-04-22 2007-05-01 Basf Aktiengesellschaft Process for preparing a nanosized zeolitic material
DE102007049743A1 (de) * 2007-10-16 2009-04-23 Evonik Degussa Gmbh Silicium-Titan-Mischoxidpulver, Dispersion hiervon und daraus hergestellter titanhaltiger Zeolith
CN101612586B (zh) * 2008-06-25 2011-06-29 中国科学院大连化学物理研究所 一种分子筛催化剂及其制备和应用
US8124555B2 (en) 2010-02-01 2012-02-28 Lyondell Chemical Technology L.P. Process for making titanium-MWW zeolite

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4410501A (en) * 1979-12-21 1983-10-18 Snamprogetti S.P.A. Preparation of porous crystalline synthetic material comprised of silicon and titanium oxides
FR2523575A1 (fr) * 1982-03-19 1983-09-23 Anic Spa Procede pour l'hydroxylation d'hydrocarbures aromatiques
EP0638362A1 (en) * 1993-08-11 1995-02-15 Mitsubishi Gas Chemical Company, Inc. Titanosilicate catalyst particle
CN1167082A (zh) * 1996-06-05 1997-12-10 中国石油化工总公司 一种钛硅分子筛(ts-1)的制备方法
CN101913620A (zh) * 2010-07-20 2010-12-15 大连理工大学 一种廉价体系中快速合成小晶粒钛硅分子筛的方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
A.J.H.P. VAN DER POL 等: "Why are some titanium silicalite-1 samples active and others not ?", 《APPLIED CATALYSIS A：GENERAL》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112888658A (zh) * 2018-08-24 2021-06-01 罗地亚经营管理公司 微孔铝钛硅酸盐结晶沸石，其制备方法和应用
CN112888658B (zh) * 2018-08-24 2024-04-16 罗地亚经营管理公司 微孔铝钛硅酸盐结晶沸石，其制备方法和应用

Also Published As

Publication number Publication date
CN108435247A (zh) 2018-08-24
FR2987046B1 (fr) 2014-03-21
US20170253547A1 (en) 2017-09-07
FR2987046A1 (fr) 2013-08-23
WO2013120986A1 (fr) 2013-08-22
JP6509561B2 (ja) 2019-05-08
US9682909B2 (en) 2017-06-20
JP2019001711A (ja) 2019-01-10
US20150299076A1 (en) 2015-10-22
JP2015511945A (ja) 2015-04-23
US10173954B2 (en) 2019-01-08
EP2814606A1 (fr) 2014-12-24

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Application publication date: 20150121