FR3095199B1 - Procédé de synthèse rapide d'une zeolithe de type structural AFX avec une source de faujasite - Google Patents

Procédé de synthèse rapide d'une zeolithe de type structural AFX avec une source de faujasite Download PDF

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Publication number
FR3095199B1
FR3095199B1 FR1904196A FR1904196A FR3095199B1 FR 3095199 B1 FR3095199 B1 FR 3095199B1 FR 1904196 A FR1904196 A FR 1904196A FR 1904196 A FR1904196 A FR 1904196A FR 3095199 B1 FR3095199 B1 FR 3095199B1
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Prior art keywords
fau
sio2
al2o3
zeolite
structural
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FR1904196A
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English (en)
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FR3095199A1 (fr
Inventor
Franco Raquel Martinez
Bogdan Harbuzaru
Eric Llido
David Berthout
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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Priority to FR1904196A priority Critical patent/FR3095199B1/fr
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to JP2021561937A priority patent/JP2022529174A/ja
Priority to PCT/EP2020/060476 priority patent/WO2020212356A1/fr
Priority to CN202080029881.3A priority patent/CN113748087A/zh
Priority to US17/604,238 priority patent/US11851338B2/en
Priority to EP20717887.2A priority patent/EP3956264A1/fr
Priority to KR1020217033843A priority patent/KR20210153626A/ko
Publication of FR3095199A1 publication Critical patent/FR3095199A1/fr
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Publication of FR3095199B1 publication Critical patent/FR3095199B1/fr
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/065—Galloaluminosilicates; Group IVB- metalloaluminosilicates; Ferroaluminosilicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

La présente invention concerne un procédé de synthèse rapide d'une zéolithe de type structural AFX comprenant au moins :i) le mélange en milieu aqueux, d’une zéolithe de type structural FAU ayant un ratio molaire SiO2 (FAU)/Al2O3 (FAU) compris entre 2,00 et 100, d’un composé organique azoté R, d’au moins une source d'au moins un métal alcalin et/ou alcalino-terreux M de valence n, avec la composition molaire suivante : (SiO2 (FAU))/(Al2O3 (FAU)) compris entre 2,00 et 100, H2O/(SiO2 (FAU)) compris entre 1 et 100, R/(SiO2 (FAU)) compris entre 0,01 à 0,6, M2/nO/(SiO2 (FAU)) compris entre 0,005 à 0,45, dans laquelle SiO2 (FAU) désigne la quantité de SiO2 apportée par la zéolithe FAU, et Al2O3 (FAU) désigne la quantité de Al2O3 apportée par la zéolithe FAU, jusqu’à l’obtention d’un gel précurseur homogène ; ii) le traitement hydrothermal dudit gel précurseur obtenu à l’issue de l’étape i) sous pression autogène à une température comprise entre 120°C et 250°C, pendant 4 à 12 heures. Figure 1 à publier
FR1904196A 2019-04-19 2019-04-19 Procédé de synthèse rapide d'une zeolithe de type structural AFX avec une source de faujasite Active FR3095199B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR1904196A FR3095199B1 (fr) 2019-04-19 2019-04-19 Procédé de synthèse rapide d'une zeolithe de type structural AFX avec une source de faujasite
PCT/EP2020/060476 WO2020212356A1 (fr) 2019-04-19 2020-04-14 Procede de synthese rapide d'une zeolithe de type structural afx avec une source de faujasite
CN202080029881.3A CN113748087A (zh) 2019-04-19 2020-04-14 用八面沸石源快速合成afx结构沸石的方法
US17/604,238 US11851338B2 (en) 2019-04-19 2020-04-14 Method for fast synthesis of an AFX-structure zeolite with a FAUjasite source
JP2021561937A JP2022529174A (ja) 2019-04-19 2020-04-14 フォージャサイト供給源を有するａｆｘ構造ゼオライトの高速合成方法
EP20717887.2A EP3956264A1 (fr) 2019-04-19 2020-04-14 Procede de synthese rapide d'une zeolithe de type structural afx avec une source de faujasite
KR1020217033843A KR20210153626A (ko) 2019-04-19 2020-04-14 포우저사이트 소스로 afx-구조 제올라이트의 빠른 합성 방법

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1904196A FR3095199B1 (fr) 2019-04-19 2019-04-19 Procédé de synthèse rapide d'une zeolithe de type structural AFX avec une source de faujasite
FR1904196 2019-04-19

Publications (2)

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FR3095199A1 FR3095199A1 (fr) 2020-10-23
FR3095199B1 true FR3095199B1 (fr) 2021-10-29

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FR1904196A Active FR3095199B1 (fr) 2019-04-19 2019-04-19 Procédé de synthèse rapide d'une zeolithe de type structural AFX avec une source de faujasite

Country Status (7)

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US (1) US11851338B2 (fr)
EP (1) EP3956264A1 (fr)
JP (1) JP2022529174A (fr)
KR (1) KR20210153626A (fr)
CN (1) CN113748087A (fr)
FR (1) FR3095199B1 (fr)
WO (1) WO2020212356A1 (fr)

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4508837A (en) 1982-09-28 1985-04-02 Chevron Research Company Zeolite SSZ-16
US5194235A (en) 1992-08-27 1993-03-16 Chevron Research And Technology Company Synthesis of SSZ-16 zeolite catalyst
JP2010126397A (ja) * 2008-11-27 2010-06-10 Jgc Catalysts & Chemicals Ltd ペンタシル型ゼオライトの合成方法
JP2012051782A (ja) * 2010-08-06 2012-03-15 Jgc Catalysts & Chemicals Ltd 結晶性シリカアルミノフォスフェートおよびその合成方法
JP6173185B2 (ja) * 2013-11-25 2017-08-02 日揮触媒化成株式会社 チャバサイト型ゼオライトの合成方法
US9802831B2 (en) * 2014-07-23 2017-10-31 Chevron U.S.A. Inc. Synthesis of high silica zeolite via interzeolite transformation without OSDAs
US10173211B2 (en) * 2014-10-14 2019-01-08 California Institute Of Technology Organic-free synthesis of small pore zeolite catalysts
US20160137518A1 (en) * 2014-11-14 2016-05-19 Johnson Matthey Public Limited Company Afx zeolite
JP6672849B2 (ja) * 2015-02-05 2020-03-25 東ソー株式会社 新規ゼオライト
JP6430303B2 (ja) 2015-03-16 2018-11-28 国立大学法人横浜国立大学 Ａｆｘ型ゼオライトの製法
US10744449B2 (en) 2015-11-16 2020-08-18 Exxonmobil Upstream Research Company Adsorbent materials and methods of adsorbing carbon dioxide
JP6759596B2 (ja) * 2016-01-18 2020-09-23 東ソー株式会社 Ａｆｘ型ゼオライト及びその製造方法
GB2551623A (en) * 2016-04-22 2017-12-27 Johnson Matthey Plc Methods of producing SAPO-56, an AFX-containing molecular sieve
US9868643B2 (en) 2016-05-20 2018-01-16 Chevron U.S.A. Inc. Synthesis of zeolite SSZ-16
BR112018070992A2 (pt) 2016-05-24 2019-01-29 Exxonmobil Chemical Patents Inc zeólita sintética compreendendo um metal catalítico
JP6835873B2 (ja) * 2016-06-07 2021-02-24 シェブロン ユー．エス．エー． インコーポレイテッド 高シリカａｆｘフレームワーク型ゼオライト
WO2018064265A1 (fr) 2016-09-30 2018-04-05 Johnson Matthey Public Limited Company Synthèse de zéolite afx
US10500573B2 (en) 2016-09-30 2019-12-10 Johnson Matthey Public Limited Company Zeolite synthesis with alkaline earth metal
FR3064262B1 (fr) * 2017-03-24 2019-03-22 IFP Energies Nouvelles Procede de synthese de la zeolithe izm-2 en presence d'un structurant dibromure de 1,6-bis(methylpiperidinium)hexane
FR3064261B1 (fr) * 2017-03-24 2019-03-22 IFP Energies Nouvelles Procede de synthese de la zeolithe izm-2 en presence d'un structurant dihydroxyde de 1,6-bis(methylpiperidinium)hexane
US10053368B1 (en) * 2017-09-07 2018-08-21 Chevron U.S.A. Inc. Synthesis of AFX framework type molecular sieves
FR3081347B1 (fr) 2018-05-24 2023-07-28 Ifp Energies Now Procede de preparation d'une zeolithe de type structural afx de haute purete avec un structurant organique azote
FR3081348B1 (fr) 2018-05-24 2023-11-10 Ifp Energies Now Catalyseur comprenant une zeolithe de type structural afx de tres haute purete et au moins un metal de transition pour la reduction selective de nox
FR3081345B1 (fr) 2018-05-24 2023-11-10 Ifp Energies Now Procede de synthese d'une zeolithe de type structural afx de tres haute purete en presence d'un structurant organique azote

Also Published As

Publication number Publication date
CN113748087A (zh) 2021-12-03
KR20210153626A (ko) 2021-12-17
US11851338B2 (en) 2023-12-26
FR3095199A1 (fr) 2020-10-23
US20220194805A1 (en) 2022-06-23
JP2022529174A (ja) 2022-06-17
EP3956264A1 (fr) 2022-02-23
WO2020212356A1 (fr) 2020-10-22

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