CN104262288B - 一种橡胶硫化促进剂dm的生产方法 - Google Patents
一种橡胶硫化促进剂dm的生产方法 Download PDFInfo
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- CN104262288B CN104262288B CN201410467697.3A CN201410467697A CN104262288B CN 104262288 B CN104262288 B CN 104262288B CN 201410467697 A CN201410467697 A CN 201410467697A CN 104262288 B CN104262288 B CN 104262288B
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- Prior art keywords
- reaction
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- production method
- vulcanization accelerator
- rubber vulcanization
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 23
- 238000013040 rubber vulcanization Methods 0.000 title claims abstract description 15
- 238000006243 chemical reaction Methods 0.000 claims abstract description 21
- 239000000463 material Substances 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 claims abstract description 14
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000003756 stirring Methods 0.000 claims abstract description 14
- 238000010792 warming Methods 0.000 claims abstract description 14
- 230000001590 oxidative effect Effects 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 10
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims abstract description 9
- 238000007664 blowing Methods 0.000 claims abstract description 9
- 230000035484 reaction time Effects 0.000 claims abstract description 9
- 239000001632 sodium acetate Substances 0.000 claims abstract description 9
- 235000017281 sodium acetate Nutrition 0.000 claims abstract description 9
- LHEFLUZWISWYSQ-CVBJKYQLSA-L cobalt(2+);(z)-octadec-9-enoate Chemical compound [Co+2].CCCCCCCC\C=C/CCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCC([O-])=O LHEFLUZWISWYSQ-CVBJKYQLSA-L 0.000 claims abstract description 8
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- 238000004806 packaging method and process Methods 0.000 claims abstract description 7
- 230000003647 oxidation Effects 0.000 claims description 15
- 238000007254 oxidation reaction Methods 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 6
- 230000000694 effects Effects 0.000 claims description 4
- 238000001035 drying Methods 0.000 abstract description 6
- 238000005406 washing Methods 0.000 abstract description 5
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000000243 solution Substances 0.000 description 5
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000002161 passivation Methods 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 235000010288 sodium nitrite Nutrition 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical group CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
- C07D277/60—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings condensed with carbocyclic rings or ring systems
- C07D277/62—Benzothiazoles
- C07D277/68—Benzothiazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
- C07D277/70—Sulfur atoms
- C07D277/76—Sulfur atoms attached to a second hetero atom
- C07D277/78—Sulfur atoms attached to a second hetero atom to a second sulphur atom
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201410467697.3A CN104262288B (zh) | 2014-09-15 | 2014-09-15 | 一种橡胶硫化促进剂dm的生产方法 |
Applications Claiming Priority (1)
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CN201410467697.3A CN104262288B (zh) | 2014-09-15 | 2014-09-15 | 一种橡胶硫化促进剂dm的生产方法 |
Publications (2)
Publication Number | Publication Date |
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CN104262288A CN104262288A (zh) | 2015-01-07 |
CN104262288B true CN104262288B (zh) | 2019-03-08 |
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CN201410467697.3A Active CN104262288B (zh) | 2014-09-15 | 2014-09-15 | 一种橡胶硫化促进剂dm的生产方法 |
Country Status (1)
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CN (1) | CN104262288B (zh) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105949148B (zh) * | 2016-05-24 | 2018-06-26 | 山东尚舜化工有限公司 | 一种橡胶硫化促进剂dm的生产工艺 |
CN110776477B (zh) * | 2019-11-27 | 2023-03-10 | 山东省化工研究院 | 一种双氧水氧化m制备dm的方法 |
CN112063373A (zh) * | 2020-09-01 | 2020-12-11 | 武汉思越化学技术有限公司 | 一种钻井液用降滤失剂性能促进剂 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101463018A (zh) * | 2008-12-16 | 2009-06-24 | 濮阳蔚林化工股份有限公司 | 一种橡胶硫化促进剂二硫化二苯并噻唑的制备方法 |
CN101899019A (zh) * | 2010-03-22 | 2010-12-01 | 天津市科迈化工有限公司 | 以双氧水为氧化剂生产医药原料dm的方法 |
CN102030720A (zh) * | 2010-12-08 | 2011-04-27 | 河南省开仑化工有限责任公司 | 一种橡胶硫化促进剂dm的生产新工艺 |
CN102838558A (zh) * | 2012-09-25 | 2012-12-26 | 科迈化工股份有限公司 | 以粗品2-硫醇基苯并噻唑为原料生产橡胶促进剂dm的方法 |
CN103709121A (zh) * | 2013-11-18 | 2014-04-09 | 朝阳天铭工贸有限公司 | 医药级2-硫醇基苯并噻唑及其衍生物dm的制备方法 |
-
2014
- 2014-09-15 CN CN201410467697.3A patent/CN104262288B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101463018A (zh) * | 2008-12-16 | 2009-06-24 | 濮阳蔚林化工股份有限公司 | 一种橡胶硫化促进剂二硫化二苯并噻唑的制备方法 |
CN101899019A (zh) * | 2010-03-22 | 2010-12-01 | 天津市科迈化工有限公司 | 以双氧水为氧化剂生产医药原料dm的方法 |
CN102030720A (zh) * | 2010-12-08 | 2011-04-27 | 河南省开仑化工有限责任公司 | 一种橡胶硫化促进剂dm的生产新工艺 |
CN102838558A (zh) * | 2012-09-25 | 2012-12-26 | 科迈化工股份有限公司 | 以粗品2-硫醇基苯并噻唑为原料生产橡胶促进剂dm的方法 |
CN103709121A (zh) * | 2013-11-18 | 2014-04-09 | 朝阳天铭工贸有限公司 | 医药级2-硫醇基苯并噻唑及其衍生物dm的制备方法 |
Non-Patent Citations (1)
Title |
---|
橡胶促进剂DM的合成工艺;陈学玺,等;《精细石油化工进展》;20060930;第7卷(第9期);第35-39页 |
Also Published As
Publication number | Publication date |
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CN104262288A (zh) | 2015-01-07 |
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Denomination of invention: A production method of rubber vulcanization accelerator DM Effective date of registration: 20210120 Granted publication date: 20190308 Pledgee: Bank of China Limited Anyang Branch Pledgor: HENAN KAILUN CHEMICAL Co.,Ltd. Registration number: Y2021980000537 |
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Denomination of invention: A production method of rubber vulcanization accelerator DM Effective date of registration: 20220218 Granted publication date: 20190308 Pledgee: Bank of China Limited Anyang Branch Pledgor: HENAN KAILUN CHEMICAL Co.,Ltd. Registration number: Y2022980001689 |
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Date of cancellation: 20230131 Granted publication date: 20190308 Pledgee: Bank of China Limited Anyang Branch Pledgor: HENAN KAILUN CHEMICAL Co.,Ltd. Registration number: Y2022980001689 |
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Denomination of invention: A production method of rubber vulcanization accelerator DM Effective date of registration: 20230202 Granted publication date: 20190308 Pledgee: Bank of China Limited Anyang Branch Pledgor: HENAN KAILUN CHEMICAL Co.,Ltd. Registration number: Y2023980031973 |
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