CN104261897A - Ceramic tile having antiskid effect and manufacturing method thereof - Google Patents
Ceramic tile having antiskid effect and manufacturing method thereof Download PDFInfo
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- CN104261897A CN104261897A CN201410497320.2A CN201410497320A CN104261897A CN 104261897 A CN104261897 A CN 104261897A CN 201410497320 A CN201410497320 A CN 201410497320A CN 104261897 A CN104261897 A CN 104261897A
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Abstract
The invention discloses a ceramic tile having an antiskid effect and a manufacturing method thereof. The ceramic tile is composed of a base body layer, a base glaze layer and a cover glaze layer from bottom to top; as improved, the ceramic tile further comprises an antiskid glaze layer which is located above the cover glaze layer. The manufacturing method of the ceramic tile is to form the antiskid glaze layer by printing an antiskid glaze slip by use of a flat silk screen, wherein the antiskid glaze layer is sprayed on the cover glaze layer of the ceramic tile and fused with the cover glaze layer by virtue of high-temperature calcination, and consequently, the ceramic tile is enabled to have a wet antiskid effect, and therefore, the usability of a ceramic glazed floor tile can be remarkably improved and the market application range of the ceramic glazed floor tile can be expanded. The manufacturing method of the ceramic tile is carried out according to a traditional production and manufacturing flow and does not need to be greatly modified in the basic process flow; besides, the manufacturing method is wide in application range, and capable of simultaneously adapting to ceramic products such as once-fired stoneware floor tiles, once-fired porcelain floor tiles and twice-fired ceramic glazed floor tiles.
Description
Technical field
The present invention relates to a kind of building ceramic decoration material and manufacture method thereof, particularly a kind of ceramic tile and manufacture method thereof with skidproof effect.
Background technology
Ceramic glaze floor tile is one of indispensable important materials of current construction and decoration, is that ground such as stone material, timber floor, hard floor paint of continuing use the another important component part of materials.Ceramic glaze floor tile is high with its intensity, wear resistance good, is widely used by human consumer without the need to advantages such as intensive cares.
Traditional Ceramic glaze floor tile uses in a large number in the functions/drying district of house or architecture indoor mostly, and the wet and slippery ground of the public arenas such as kitchen in average family, toilet and hotel, dining room, hospital, school dining room all can limit by use to a certain extent, major cause can be returned and be studied carefully for: traditional Ceramic glaze floor tile its non-skid property under the environment of wet water can significantly decline, therefore the generation of the safety hazards such as the as easy as rolling off a log personnel of causing slip, tumble injury.Researching and developing a kind of Ceramic glaze floor tile also possessing non-skid property under wet water surrounding is the better mode addressed this problem.
Known can make Ceramic glaze floor tile under the environment of wet water, have non-skid property manufacture method or post-processing method have:
A, utilization die design method are started with from product structure, ceramic green or biscuit surface are designed in advance the die face effect that also forming position height differs, product burns till rear surface through high temperature and produces rough coarse texture, finally makes product possess non-skid property.
B, utilization pottery three degree of burning technologies, frit dry granular has the even cloth of half tone of the patterns such as various Ma Saike or pebbles to be applied to brick face by pre-designed, after burning till through three degree, product surface forms in picturesque disorder mould effect, effectively improves the non-skid property of usual production, reaches skidproof effect.
C, cover-coat enamel formula by the traditional glazed floor tile of adjustment, improves the firing temperature of cover-coat enamel, is in slight raw burn state all the time after impelling the cover-coat enamel of high refractoriness to burn till, the decline of glaze paint slickness, surface presentation harsh hand, product thus reach skidproof effect.
D, utilization thicken half tone, and print additional the convex glaze of one deck effect on traditional glazed floor tile surface, convex glaze can stand on common cover-coat enamel after high temperature burns till, and swells separately, forms concavo-convex drop, reach skidproof effect with cover-coat enamel.
E, the mode passed through cutting, slot, destroy the surface of glazed floor tile, be processed into the anti-slip veins of different lines on demand, reach skidproof effect.
F, utilizing works slipproofing agent carry out construction in later period process to conventional ceramic glazed floor tile, and slipproofing agent can destroy the microtexture of product surface, form tiny convex-concave surface, reach skidproof effect.
But above-mentioned several method all deposits deficiency in some aspects, specific as follows:
A method: the thinking introducing die design changes the formal structure of product, and on the one hand due to the certainty that the groove of mould exists, groove location is as easy as rolling off a log shelters evil people and countenance evil practices, cause hygienic cleaning difficulty large, routine use is not easy to clean.On the other hand, compare common plane floor tile, the probability meeting obviously increase that mould product is damaged in the processes such as production, packaging and transport, comprehensive cost is high.
B method: use three degree to burn and pile the anti-skidding problem that frit Technology solves traditional glazed floor tile, its manufacturing cost is quite high, and terminal price is high, therefore interior use is restricted on a large scale.In addition, due to be subject to surface mosaic or pebbles shape impact, the pattern texture under frit dry granular cannot enrich and manifest, and causes Integral decoration effect single, change and diversity not strong.
C method: by the firing temperature of adjusting range glaze formula, it is made to be in raw burn state, thus reduce the slickness burning till rear glaze paint, the as easy as rolling off a log soil pick-up problem causing glaze paint of the method, because the glaze paint density of raw burn declines, trickle pore is easy to adsorb the spot in life and rubbish, and cleaning difficulty is large, uses that to affect ground attractive in appearance for a long time.
D method: maximum deficiency is poor stability, convex glaze is applied on cover-coat enamel by half tone cloth, the angle of doctor and degree of wear change, the permeable membrane amount change of half tone, the factors such as the running speed change of glaze line belt all can cause convex glaze cloth to be coated with the difference of weight, thus cannot realize the unification of concave-convex effect.Secondly, the height that the fluctuation of kiln firing temperature also easily produces convex glaze protuberance is inconsistent, and finally cause the fluctuation of the skidproof effect of product, the stability of product can not be guaranteed.
E method: because the means such as later stage cutting, fluting need increase extra labour cost, therefore its comprehensive cost is high, in addition, easily produces the breakage of product and scraps, increasing product loss in the process of cutting.In addition, the modes such as cutting, fluting can destroy the continuity of the design and color texture of product surface, expose end base, thus affect the aesthetics of product.
F method: the microstructure being destroyed product surface by engineering post-processed means, thus improve the non-skid property of product, there is the weakness and deficiency that engineering cost is high, work-ing life is not grown in the method simultaneously.
Summary of the invention
The object of the invention is to analyze the existing Ceramic glaze floor tile that can realize under wet water surrounding, also possess the method for manufacturing of skidproof effect or the reality of post-processing method, overcome these methods in many-sided deficiencies such as Technology, manufacturing process, cost and product effects, thus provide that a kind of cost is low, the original performance of stable manufacturing process, product and pattern decorative effect substantially impregnable, and under wet water surrounding, also possess the Ceramic glaze ground brick producing process of non-skid property.
The object of the invention is to be achieved through the following technical solutions:
There is ceramic tile and the manufacture method thereof of skidproof effect, this manufacture method and technical process as follows: picking of raw material → electronic proportioning → ball milling → deironing → spray pulverization → compression moulding → biscuiting → biscuit → pouring ground-coat enamel → pouring cover-coat enamel → spray ink Printing decalcomania → screen printing specialty printing anti-skidding glaze → glaze firing → edging → sorting → packaging → warehouse-in.
Be made up of end base layer, ground glaze layer, cover coat from top to bottom the ceramic tile obtained above, its improvement is, also comprises an anti-skidding glaze layer, and described anti-skidding glaze layer is positioned on described cover coat.
The mass percent of the base substrate powder composition of base layer of the described end is: quartz 30 ~ 40%, feldspar 15 ~ 20%, flint clay 5 ~ 10%, fat clay 20 ~ 30%, lime powder 15 ~ 20%.
The base substrate powder fineness of base layer of the described end is 250 mesh screen residues: 2.0% ± 0.1%, and the massfraction that the moisture in this base substrate powder accounts for this base substrate powder is: 4% ~ 5%, and the blank forming pressure of this end base layer is: 320 ± 1bar.
The mass percent of described anti-skidding glaze layer material composition is: the specialty printing material 50 ~ 60% containing the anti-skidding factor, print cream 30 ~ 40%, thinner 10 ~ 20%.
The moiety mass percent of the described specialty printing material containing the anti-skidding factor is: SiO
2: 30% ~ 31.5%, Al
2o
3: 48% ~ 49.5%, Fe
2o
3:≤0.1%, TiO
2:≤0.1%, CaO:4.5% ~ 6%, MgO:0.5% ~ 1.0%, K
2o:2.5% ~ 3.5%, Na
2o:0.5% ~ 1.0%, ZnO:5% ~ 7%, BaO:5% ~ 7%, B
2o
3:≤2%.
After burned biscuit spoons ground-coat enamel and cover-coat enamel, the anti-skidding glaze slip utilizing flat bed screen printing to modulate forms an anti-skidding glaze layer, this anti-skidding glaze layer is sprayed on the cover coat of ceramic tile, through high-temperature calcination and described cover coat generation frit reaction, makes described ceramic tile have the anti-skidding effect of wet water.
High-temperature calcination temperature after described anti-skidding glaze layer spraying is 1100 ± 5 DEG C.
The high-temperature calcination time after described anti-skidding glaze layer spraying is 55 ± 1min.
The described flat bed screen printing anti-skidding glaze glaze that this has in preparation technology's flow process of the ceramic tile of anti-skidding glaze is: utilize flat bed screen as printing carrier, based on containing the specialty printing material of the anti-skidding factor, be aided with print cream and a small amount of thinner is the anti-skidding glaze printed medium that formula is formed.
The good order number of half tone of described flat bed screen is: 40 ~ 80 orders.
The good print thickness of described screen printing specialty printing anti-skidding glaze is 8 ~ 12 grams/piece of bricks, and the specification of every tile is 300 × 300mm.
The present invention is a kind of, and to have the beneficial effect that the ceramic tile of anti-skidding glaze and manufacture method thereof can reach as follows:
1, product possesses stronger non-skid property, and anti-slip stable is high.The present invention has used the special type formula glaze including the anti-skidding factor to directly act on cover-coat enamel, react through high-temperature calcination and cover-coat enamel generation high-temperature fusion, cover-coat enamel is impelled to burn till reconfiguring of microtexture and arrange, the effect that the glaze paint of otherwise smooth is possessed wet water is anti-skidding.In addition, owing to this process employs effective combination of anti-skidding glaze and normal cover-coat enamel, make it the part becoming product glaze composition, skidproof effect is defined with former cover-coat enamel acting in conjunction, therefore improve traditional convex glaze that utilizes and burn till the drawback of swelling and reaching the poor stability of skidproof effect, the anti-slip stable of the method is significantly improved.
2, product quality is unaffected, and product comprehensive cost is low.The present invention has continued to use the manufacturing flow process of ordinary porcelain brick product substantially, and production line is without doing large adjustment and variation, and the extra-expense that the processing, process etc. without the need to carrying out the later stage produces, comprehensive cost is low.In addition, the present invention does not need to carry out special technique adjustment to brick face, and the performance, work-ing life, quality etc. of product are substantially unaffected.
3, good product effect.Mode of printing of the present invention is various, and the mode of printings such as silk screen, roller and spray ink Printing are all applicable, and color pattern and color texture all can embody well and apply, good product effect.Substantially do not destroy former technical process due to the present invention and affect, the richness of product effect and pattern can effectively ensure.
Embodiment
Main experimental of the present invention, by screen mesh printing plate printing specialty printing anti-skidding glaze, is piled up the difference of printing weight (i.e. print thickness), thus is obtained the product of different skidproof effect in brick face, in addition, also by changing different ratios of raw materials test skidproof effect.Different printing weight controls primarily of the order number of screen mesh printing plate.Below in conjunction with concrete embodiment, the present invention is described in further detail:
Embodiment 1:
Embodiment 1 is most preferred embodiment, the quartz of 35% weight part and the feldspar of 15% weight part, the flint clay of 5% weight part are joined in the fat clay of 25% weight part, stir, the lime powder adding 20% weight part again mixes, then ball milling deironing, fineness reaches 250 mesh screen residues: 2.0%.Then the operation such as spray-dried forms the powder of water ratio 4 ~ 5%, and the press-molding being 320bar through excess pressure enters biscuit kiln biscuiting.Biscuit after biscuiting completes is stand-by.Use the specialty printing material including the anti-skidding factor of 50% weight part, the print cream of 30% weight part and the thinner of 20% weight part, make specialty printing anti-skidding glaze through high-speed grinder grinding for subsequent use.
With the biscuit water spray 1 ~ 2 gram of 300 × 300mm, drench ground-coat enamel 60 grams/piece, drench cover-coat enamel 120 grams/piece, carry out the printing of pattern and color through ink-jet printer, then the specialty printing anti-skidding glaze will made, its specialty printing materials chemistry containing the anti-skidding factor consists of: SiO
2: 30%, Al
2o
3: 49%, Fe
2o
3: 0.1%, TiO
2: 0.1%, CaO:4.5%, MgO:0.5%, K
2o:3.0%, Na
2o:1.0%, ZnO:5.0%, BaO:5.0%, B
2o
3: 1.8%.Print through 40 object screen mesh printing plates, printing weight is 12 grams/piece, and then through glaze firing, temperature of glaze firing is 1100 DEG C, and firing time is 55min.Product after glaze firing completes is to be checked.Detect through anti-skidding tester, the anti-skidding static coefficient of this product is 1.2, and anti-skidding grade is R13, is extreme safe condition.
Embodiment 2:
On the basis of embodiment 1, change brick face and pile up printing weight, namely the use content of anti-skidding glaze is changed, the quartz of 35% weight part and the feldspar of 15% weight part, the flint clay of 5% weight part are joined in the fat clay of 25% weight part, stir, the lime powder adding 20% weight part again mixes, then ball milling deironing, and fineness reaches 250 mesh screen residues: 2.0%.Then the operation such as spray-dried forms the powder of water ratio 4 ~ 5%, and the press-molding being 320bar through excess pressure enters biscuit kiln biscuiting.Biscuit after biscuiting completes is stand-by.Use the specialty printing material including the anti-skidding factor of 50% weight part, the print cream of 30% weight part and the thinner of 20% weight part, make specialty printing anti-skidding glaze through high-speed grinder grinding for subsequent use.
With the biscuit water spray 1 ~ 2 gram of 300 × 300mm, drench ground-coat enamel 60 grams/piece, drench cover-coat enamel 120 grams/piece, carry out the printing of pattern and color through ink-jet printer, then the specialty printing anti-skidding glaze will made, its specialty printing materials chemistry containing the anti-skidding factor consists of: SiO
2: 30%, Al
2o
3: 49%, Fe
2o
3: 0.1%, TiO
2: 0.1%, CaO:4.5%, MgO:0.5%, K
2o:3.0%, Na
2o:1.0%, ZnO:5.0%, BaO:5.0%, B
2o
3: 1.8%.Print through 60 object screen mesh printing plates, printing weight is 10 grams/piece, and then through glaze firing, temperature of glaze firing is 1100 DEG C, and firing time is 55min.Product after glaze firing completes is to be checked.Detect through anti-skidding tester, the anti-skidding static coefficient of this product is 0.9, and anti-skidding grade is R12, is unusual safe condition.
Embodiment 3:
On the basis of embodiment 1 and 2, change brick face again and pile up printing weight, the quartz of 35% weight part and the feldspar of 15% weight part, the flint clay of 5% weight part are joined in the fat clay of 25% weight part, stir, the lime powder adding 20% weight part again mixes, then ball milling deironing, fineness reaches 250 mesh screen residues: 2.0%.Then the operation such as spray-dried forms the powder of water ratio 4 ~ 5%, and the press-molding being 320bar through excess pressure enters biscuit kiln biscuiting.Biscuit after biscuiting completes is stand-by.Use the specialty printing material including the anti-skidding factor of 50% weight part, the print cream of 30% weight part and the thinner of 20% weight part, make specialty printing anti-skidding glaze through high-speed grinder grinding for subsequent use.
With the biscuit water spray 1 ~ 2 gram of 300 × 300mm, drench ground-coat enamel 60 grams/piece, drench cover-coat enamel 120 grams/piece, carry out the printing of pattern and color through ink-jet printer, then the specialty printing anti-skidding glaze will made, its specialty printing materials chemistry containing the anti-skidding factor consists of: SiO
2: 30%, Al
2o
3: 49%, Fe
2o
3: 0.1%, TiO
2: 0.1%, CaO:4.5%, MgO:0.5%, K
2o:3.0%, Na
2o:1.0%, ZnO:5.0%, BaO:5.0%, B
2o
3: 1.8%.Print through 80 object screen mesh printing plates, printing weight is 8 grams/piece, and then through glaze firing, temperature of glaze firing is 1100 DEG C, and firing time is 55min.Product after glaze firing completes is to be checked.Detect through anti-skidding tester, the anti-skidding static coefficient of this product is 0.6, and anti-skidding grade is R11, is comparatively safe state.
Find out from above three embodiments, along with successively decreasing gradually of anti-skidding glaze content on brick face, its skidproof effect also declines to some extent, illustrates that its anti-skidding glaze can improve the skidproof effect in brick face really.
Embodiment 4:
Most preferably fill a prescription on basis in embodiment 1, change ceramic tile blank to become to be grouped into, the quartz of 30% weight part and the feldspar of 20% weight part, the flint clay of 7% weight part are joined in the fat clay of 23% weight part, stir, the lime powder adding 20% weight part again mixes, then ball milling deironing, fineness reaches 250 mesh screen residues: 2.0%.Then the operation such as spray-dried forms the powder of water ratio 4 ~ 5%, and the press-molding being 320bar through excess pressure enters biscuit kiln biscuiting.Biscuit after biscuiting completes is stand-by.Use the specialty printing material including the anti-skidding factor of 50% weight part, the print cream of 30% weight part and the thinner of 20% weight part, make specialty printing anti-skidding glaze through high-speed grinder grinding for subsequent use.
With the biscuit water spray 1 ~ 2 gram of 300 × 300mm, drench ground-coat enamel 60 grams/piece, drench cover-coat enamel 120 grams/piece, carry out the printing of pattern and color through ink-jet printer, then the specialty printing anti-skidding glaze will made, its specialty printing materials chemistry containing the anti-skidding factor consists of: SiO
2: 30%, Al
2o
3: 49%, Fe
2o
3: 0.1%, TiO
2: 0.1%, CaO:4.5%, MgO:0.5%, K
2o:3.0%, Na
2o:1.0%, ZnO:5.0%, BaO:5.0%, B
2o
3: 1.8%.Print through 40 object screen mesh printing plates, printing weight is 12 grams/piece, and then through glaze firing, temperature of glaze firing is 1100 DEG C, and firing time is 55min.Product after glaze firing completes is to be checked.Detect through anti-skidding tester, the anti-skidding static coefficient of this product is 1.2.
Embodiment 5:
Most preferably fill a prescription on basis in embodiment 1, change ceramic tile blank to become to be grouped into, the quartz of 37% weight part and the feldspar of 15% weight part, the flint clay of 7% weight part are joined in the fat clay of 20% weight part, stir, the lime powder adding 21% weight part again mixes, then ball milling deironing, fineness reaches 250 mesh screen residues: 2.0%.Then the operation such as spray-dried forms the powder of water ratio 4 ~ 5%, and the press-molding being 320bar through excess pressure enters biscuit kiln biscuiting.Biscuit after biscuiting completes is stand-by.Use the specialty printing material including the anti-skidding factor of 50% weight part, the print cream of 30% weight part and the thinner of 20% weight part, make specialty printing anti-skidding glaze through high-speed grinder grinding for subsequent use.
With the biscuit water spray 1 ~ 2 gram of 300 × 300mm, drench ground-coat enamel 60 grams/piece, drench cover-coat enamel 120 grams/piece, carry out the printing of pattern and color through ink-jet printer, then the specialty printing anti-skidding glaze will made, its specialty printing materials chemistry containing the anti-skidding factor consists of: SiO
2: 30%, Al
2o
3: 49%, Fe
2o
3: 0.1%, TiO
2: 0.1%, CaO:4.5%, MgO:0.5%, K
2o:3.0%, Na
2o:1.0%, ZnO:5.0%, BaO:5.0%, B
2o
3: 1.8%.Print through 40 object screen mesh printing plates, printing weight is 12 grams/piece, and then through glaze firing, temperature of glaze firing is 1100 DEG C, and firing time is 55min.Product after glaze firing completes is to be checked.Detect through anti-skidding tester, the anti-skidding static coefficient of this product is 1.2.
Known by above two embodiments, change the moiety of ceramic tile blank, anti-skidding glaze component concentration is constant, and constant containing the specialty printing materials chemistry component of the anti-skidding factor, and printing weight is constant, on skidproof effect substantially without impact.
Embodiment 6:
Most preferably fill a prescription on basis in embodiment 1, change specialty printing material, print cream, thinner per distribution ratio, the quartz of 35% weight part and the feldspar of 15% weight part, the flint clay of 5% weight part are joined in the fat clay of 25% weight part, stir, the lime powder adding 20% weight part again mixes, then ball milling deironing, fineness reaches 250 mesh screen residues: 2.0%.Then the operation such as spray-dried forms the powder of water ratio 4 ~ 5%, and the press-molding being 320bar through excess pressure enters biscuit kiln biscuiting.Biscuit after biscuiting completes is stand-by.Use: the specialty printing material including the anti-skidding factor of 55% weight part, the print cream of 35% weight part and the thinner of 10% weight part, make specialty printing anti-skidding glaze through high-speed grinder grinding for subsequent use.
With the biscuit water spray 1 ~ 2 gram of 300 × 300mm, drench ground-coat enamel 60 grams/piece, drench cover-coat enamel 120 grams/piece, carry out the printing of pattern and color through ink-jet printer, then the specialty printing anti-skidding glaze will made, its specialty printing materials chemistry containing the anti-skidding factor consists of: SiO
2: 30%, Al
2o
3: 49%, Fe
2o
3: 0.1%, TiO
2: 0.1%, CaO:4.5%, MgO:0.5%, K
2o:3.0%, Na
2o:1.0%, ZnO:5.0%, BaO:5.0%, B
2o
3: 1.8%.Print through 40 object screen mesh printing plates, printing weight is 12 grams/piece, and then through glaze firing, temperature of glaze firing is 1100 DEG C, and firing time is 55min.Product after glaze firing completes is to be checked.Detect through anti-skidding tester, the anti-skidding static coefficient of this product is 0.9.
Embodiment 7:
Most preferably fill a prescription on basis in embodiment 1, change specialty printing material, print cream, thinner per distribution ratio, the quartz of 35% weight part and the feldspar of 15% weight part, the flint clay of 5% weight part are joined in the fat clay of 25% weight part, stir, the lime powder adding 20% weight part again mixes, then ball milling deironing, fineness reaches 250 mesh screen residues: 2.0%.Then the operation such as spray-dried forms the powder of water ratio 4 ~ 5%, and the press-molding being 320bar through excess pressure enters biscuit kiln biscuiting.Biscuit after biscuiting completes is stand-by.Use: the specialty printing material including the anti-skidding factor of 60% weight part, the print cream of 30% weight part and the thinner of 10% weight part, make specialty printing anti-skidding glaze through high-speed grinder grinding for subsequent use.
With the biscuit water spray 1 ~ 2 gram of 300 × 300mm, drench ground-coat enamel 60 grams/piece, drench cover-coat enamel 120 grams/piece, carry out the printing of pattern and color through ink-jet printer, then the specialty printing anti-skidding glaze will made, its specialty printing materials chemistry containing the anti-skidding factor consists of: SiO
2: 30%, Al
2o
3: 49%, Fe
2o
3: 0.1%, TiO
2: 0.1%, CaO:4.5%, MgO:0.5%, K
2o:3.0%, Na
2o:1.0%, ZnO:5.0%, BaO:5.0%, B
2o
3: 1.8%.Print through 40 object screen mesh printing plates, printing weight is 12 grams/piece, and then through glaze firing, temperature of glaze firing is 1100 DEG C, and firing time is 55min.Product after glaze firing completes is to be checked.Detect through anti-skidding tester, the anti-skidding static coefficient of this product is 0.7.
Known by above two embodiments, change specialty printing material, print cream, thinner per distribution ratio have impact to skidproof effect, its interact relation nonlinear specialty printing material content is more high better, its three at a suitable per distribution ratio, the good skidproof effect of competence exertion.
Embodiment 8:
Embodiment 1 is most preferred embodiment, the specialty printing materials chemistry changed containing the anti-skidding factor forms, the quartz of 35% weight part and the feldspar of 15% weight part, the flint clay of 5% weight part are joined in the fat clay of 25% weight part, stir, the lime powder adding 20% weight part again mixes, then ball milling deironing, fineness reaches 250 mesh screen residues: 2.0%.Then the operation such as spray-dried forms the powder of water ratio 4 ~ 5%, and the press-molding being 320bar through excess pressure enters biscuit kiln biscuiting.Biscuit after biscuiting completes is stand-by.Use the specialty printing material including the anti-skidding factor of 50% weight part, the print cream of 30% weight part and the thinner of 20% weight part, make specialty printing anti-skidding glaze through high-speed grinder grinding for subsequent use.
With the biscuit water spray 1 ~ 2 gram of 300 × 300mm, drench ground-coat enamel 60 grams/piece, drench cover-coat enamel 120 grams/piece, carry out the printing of pattern and color through ink-jet printer, then the specialty printing anti-skidding glaze will made, its specialty printing materials chemistry containing the anti-skidding factor consists of: SiO
2: 31%, Al
2o
3: 48%, Fe
2o
3: 0.1%, TiO
2: 0.1%, CaO:5.0%, MgO:0.7%, K
2o:2.5%, Na
2o:0.7%, ZnO:6.0%, BaO:5.0%, B
2o
3: 0.9%.Print through 40 object screen mesh printing plates, printing weight is 12 grams/piece, and then through glaze firing, temperature of glaze firing is 1100 DEG C, and firing time is 55min.Product after glaze firing completes is to be checked.Detect through anti-skidding tester, the anti-skidding static coefficient of this product is 1.0.
Embodiment 9:
Embodiment 1 is most preferred embodiment, the specialty printing materials chemistry changed containing the anti-skidding factor forms, the quartz of 35% weight part and the feldspar of 15% weight part, the flint clay of 5% weight part are joined in the fat clay of 25% weight part, stir, the lime powder adding 20% weight part again mixes, then ball milling deironing, fineness reaches 250 mesh screen residues: 2.0%.Then the operation such as spray-dried forms the powder of water ratio 4 ~ 5%, and the press-molding being 320bar through excess pressure enters biscuit kiln biscuiting.Biscuit after biscuiting completes is stand-by.Use the specialty printing material including the anti-skidding factor of 50% weight part, the print cream of 30% weight part and the thinner of 20% weight part, make specialty printing anti-skidding glaze through high-speed grinder grinding for subsequent use.
With the biscuit water spray 1 ~ 2 gram of 300 × 300mm, drench ground-coat enamel 60 grams/piece, drench cover-coat enamel 120 grams/piece, carry out the printing of pattern and color through ink-jet printer, then the specialty printing anti-skidding glaze will made, its specialty printing materials chemistry containing the anti-skidding factor consists of: SiO
2: 30%, Al
2o
3: 48%, Fe
2o
3: 0.05%, TiO
2: 0.05%, CaO:5.0%, MgO:0.8%, K
2o:3.0%, Na
2o:0.5%, ZnO:6.0%, BaO:6.0%, B
2o
3: 0.6%.Print through 40 object screen mesh printing plates, printing weight is 12 grams/piece, and then through glaze firing, temperature of glaze firing is 1100 DEG C, and firing time is 55min.Product after glaze firing completes is to be checked.Detect through anti-skidding tester, the anti-skidding static coefficient of this product is 0.9.
Known by above two embodiments, its composition of specialty printing materials chemistry containing the anti-skidding factor also has certain influence to skidproof effect, exists and preferably forms content proportioning.
Claims (10)
1. have a ceramic tile for skidproof effect, this ceramic tile is made up of end base layer, ground glaze layer, cover coat from top to bottom, it is characterized in that, also comprises an anti-skidding glaze layer, and described anti-skidding glaze layer is positioned on described cover coat.
2. a kind of ceramic tile with skidproof effect as claimed in claim 1, is characterized in that, the mass percent of described anti-skidding glaze layer material composition is: the specialty printing material 50 ~ 60% containing the anti-skidding factor, print cream 30 ~ 40%, thinner 10 ~ 20%.
3. a kind of ceramic tile with skidproof effect as claimed in claim 2, is characterized in that, the moiety mass percent of the described specialty printing material containing the anti-skidding factor is: SiO
2: 30% ~ 31.5%, Al
2o
3: 48% ~ 49.5%, Fe
2o
3:≤0.1%, TiO
2:≤0.1%, CaO:4.5% ~ 6%, MgO:0.5% ~ 1.0%, K
2o:2.5% ~ 3.5%, Na
2o:0.5% ~ 1.0%, ZnO:5% ~ 7%, BaO:5% ~ 7%, B
2o
3:≤2%.
4. one kind has the manufacture method of the ceramic tile of skidproof effect, this ceramic tile is made up of end base layer, ground glaze layer, cover coat from top to bottom, it is characterized in that, comprise the steps: that flat bed screen prints anti-skidding glaze slip and forms an anti-skidding glaze layer, this anti-skidding glaze layer is sprayed on described cover coat, through high-temperature calcination and described cover coat generation frit reaction, described ceramic tile is made to have the anti-skidding effect of wet water.
5. a kind of manufacture method with the ceramic tile of skidproof effect as claimed in claim 4, it is characterized in that, the mass percent of described anti-skidding glaze layer material composition is: the specialty printing material 50 ~ 60% containing the anti-skidding factor, print cream 30 ~ 40%, thinner 10 ~ 20%.
6. a kind of manufacture method with the ceramic tile of skidproof effect as claimed in claim 5, is characterized in that, the moiety mass percent of the described specialty printing material containing the anti-skidding factor is: SiO
2: 30% ~ 31.5%, Al
2o
3: 48% ~ 49.5%, Fe
2o
3:≤0.1%, TiO
2:≤0.1%, CaO:4.5% ~ 6%, MgO:0.5% ~ 1.0%, K
2o:2.5% ~ 3.5%, Na
2o:0.5% ~ 1.0%, ZnO:5% ~ 7%, BaO:5% ~ 7%, B
2o
3:≤2%.
7. a kind of manufacture method with the ceramic tile of skidproof effect as claimed in claim 6, is characterized in that, the high-temperature calcination temperature after described anti-skidding glaze layer spraying is 1100 ± 5 DEG C.
8. a kind of manufacture method with the ceramic tile of skidproof effect as claimed in claim 7, is characterized in that, the high-temperature calcination time after described anti-skidding glaze layer spraying is 55 ± 1min.
9. a kind of manufacture method with the ceramic tile of skidproof effect as claimed in claim 8, it is characterized in that, the half tone order number of described flat bed screen is: 40 ~ 80 orders.
10. a kind of manufacture method with the ceramic tile of skidproof effect as claimed in claim 9, it is characterized in that, the print thickness of described anti-skidding glaze layer is 8 ~ 12 grams/piece of bricks, and the specification of every tile is 300 × 300mm.
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| CN201410497320.2A CN104261897B (en) | 2014-09-25 | 2014-09-25 | A kind of ceramic tile and manufacture method thereof with skidproof effect |
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| CN105967524A (en) * | 2016-06-30 | 2016-09-28 | 安徽省德邦瓷业有限公司 | Nonslip ceramic glaze and preparation method thereof |
| CN106830682A (en) * | 2017-01-17 | 2017-06-13 | 四川新高峰瓷业有限公司 | A kind of skid-resistance ceramic glaze, anti-skidding Dali stone ceramic tile and preparation method thereof |
| CN107265861A (en) * | 2017-07-21 | 2017-10-20 | 广东金意陶陶瓷集团有限公司 | The preparation method of the easy clean Ceramic Tiles of anti-skid wearable |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102491789A (en) * | 2011-11-14 | 2012-06-13 | 星谊精密陶瓷科技（昆山）有限公司 | Anti-skid printing glaze and preparation method and application thereof |
| CN103570380A (en) * | 2013-11-14 | 2014-02-12 | 广东三水大鸿制釉有限公司 | Wear-resistant antiskid glaze and preparation method thereof as well as preparation method of wear-resistant antiskid tile |
-
2014
- 2014-09-25 CN CN201410497320.2A patent/CN104261897B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102491789A (en) * | 2011-11-14 | 2012-06-13 | 星谊精密陶瓷科技（昆山）有限公司 | Anti-skid printing glaze and preparation method and application thereof |
| CN103570380A (en) * | 2013-11-14 | 2014-02-12 | 广东三水大鸿制釉有限公司 | Wear-resistant antiskid glaze and preparation method thereof as well as preparation method of wear-resistant antiskid tile |
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Effective date of registration: 20170420 Address after: 528061 Guangdong city of Foshan province Baini town Sanshui District Central Industrial Development Zone Co-patentee after: Guangdong Xinmingzhu Ceramic Group Co., Ltd. Patentee after: Foshan Sanshui Newpearl Building Ceramics Industrial Co., Ltd. Co-patentee after: Jiangxi New Mingzhu Building Material Co.,Ltd. Address before: 528061 Guangdong city of Foshan province Baini town Sanshui District Central Industrial Development Zone Co-patentee before: Guangdong Xinmingzhu Ceramic Group Co., Ltd. Patentee before: Foshan Sanshui Newpearl Building Ceramics Industrial Co., Ltd. |
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Address after: 528061 Central Industrial Development Zone, Foshan, Sanshui District, Guangdong Patentee after: FOSHAN SANSHUI NEW PEARL CONSTRUCTION CERAMICS INDUSTRIAL Co.,Ltd. Patentee after: New Pearl Group Co.,Ltd. Patentee after: Jiangxi Xinmingzhu Building Materials Co.,Ltd. Address before: 528061 Central Industrial Development Zone, Foshan, Sanshui District, Guangdong Patentee before: FOSHAN SANSHUI NEW PEARL CONSTRUCTION CERAMICS INDUSTRIAL Co.,Ltd. Patentee before: GUANGDONG NEWPEARL CERAMIC GROUP Co.,Ltd. Patentee before: Jiangxi Xinmingzhu Building Materials Co.,Ltd. |