CN103570380A - Wear-resistant antiskid glaze and preparation method thereof as well as preparation method of wear-resistant antiskid tile - Google Patents
Wear-resistant antiskid glaze and preparation method thereof as well as preparation method of wear-resistant antiskid tile Download PDFInfo
- Publication number
- CN103570380A CN103570380A CN201310565409.3A CN201310565409A CN103570380A CN 103570380 A CN103570380 A CN 103570380A CN 201310565409 A CN201310565409 A CN 201310565409A CN 103570380 A CN103570380 A CN 103570380A
- Authority
- CN
- China
- Prior art keywords
- wear
- resisting
- glaze
- frit
- slip
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Abstract
The invention discloses a wear-resistant antiskid glaze and a preparation method thereof as well as a preparation method of a wear-resistant antiskid tile. The wear-resistant antiskid glaze comprises fused block glaze powder and Al2O3 with a corundum structure, and specifically comprises the following components in percentage by weight: 25-40% of SiO2, 40-60% of Al2O3, 1-5% of K2O+Na2O, 1-10% of CaO, 1-5% of MgO, 1-15% of BaO and 1-10% of ZnO. The wear-resistant antiskid glaze disclosed by the invention is simple to operate and the effect of the original decorative patterns is not influenced; by adopting the glaze produced by the preparation method to form a glaze layer on the surface of a ceramic tile body, after high-temperature firing, the tile has a good antifouling wear-resistant antiskid effect and a wide application range; wear-resistant antifouling antiskid glazes with different bases can be selected according to the firing temperature (1100-1230 DEG C) of ceramic tiles, and are matched with an original artwork design to produce wear-resistant antifouling antiskid tiles meeting requirements.
Description
Technical field
The present invention relates to a kind of wear-resisting on-slip ceramic tile glaze, in particular the preparation method of a kind of wear-resisting on-slip glaze and preparation method thereof and wear-resisting on-slip brick.
Background technology
Because building decoration class constantly improves, at present popular polished tile, throwing glazed brick and the brilliant brick of throwing etc. are used in public building (hotel, office building, station, sales field, apartment in a large number ...) ground, when beautifying vision, but ignored the security hidden trouble slipping in ground.When especially running into ground humidity, easily produce especially the phenomenon slipping.
At present the frictional coefficient maximum of polished tile can only reach 0.4, frictional coefficient minimum but only have 0.2, and the frictional coefficient minimum that safety standards requires both at home and abroad all will reach 0.5 and is just considered to safe.Existing polished tile, throwing glazed brick are also far not by far up to the mark with the safe frictional coefficient of throwing brilliant brick.
Therefore, prior art has yet to be improved and developed.
Summary of the invention
The object of the present invention is to provide the preparation method of a kind of wear-resisting on-slip glaze and preparation method thereof and wear-resisting on-slip brick, be intended to solve existing polished tile, throwing glazed brick and the safe frictional coefficient of the brilliant brick of throwing and do not reach requirement, cause the problem of potential safety hazard.
Technical scheme of the present invention is as follows: a kind of wear-resisting on-slip glaze, wherein, comprises frit powdered frit and the Al that possesses corundum structure
2o
3, concrete composition and weight percent thereof are:
SiO
2：
25~40%；
Al
2O
3： 40~60%；
K
2O+Na
2O： 1~5%；
CaO： 1~10%；
MgO： 1~5%；
BaO ： 1~15%；
ZnO： 1~10%。
Described wear-resisting on-slip glaze, wherein, described frit powdered frit and the Al that possesses corundum structure
2o
3weight ratio be 5/5～8/2.
Described wear-resisting on-slip glaze, wherein, when wear-resisting on-slip glaze is the wear-resisting on-slip glaze of little floor tile series, comprises frit powdered frit and the Al that possesses corundum structure
2o
3, concrete composition and weight percent thereof are:
SiO
2：
25~40%；
Al
2O
3： 40~60%；
K
2O+Na
2O： 1~5%；
CaO： 1~10%；
MgO： 1~5%；
BaO ： 1~10%；
ZnO： 1~10%。
Described wear-resisting on-slip glaze, wherein, when wear-resisting on-slip glaze is the wear-resisting on-slip glaze of Antique Imitation Tiles series, comprises frit powdered frit and the Al that possesses corundum structure
2o
3, concrete composition and weight percent thereof are:
SiO
2：
25~40%；
Al
2O
3： 40~60%；
K
2O+Na
2O： 1~5%；
CaO： 1~5%；
MgO： 1~5%；
BaO ： 5~15%；
ZnO： 1~5%。
A preparation method for wear-resisting on-slip glaze as described in above-mentioned any one, is characterized in that, specifically comprises the following steps:
Steps A 00: prepare frit: found after the desired formula composition of the component that starting material are comprised by frit and weight percent thereof configures and mixes, glass melting temperature is 1500 ℃ ~ 1600 ℃, melting time is 1.5 ~ 8 hours, and then quenching to normal temperature becomes frit rapidly;
Step B00: preparation printing powdered frit: utilize ball mill wet grinding to passing through standard sieves more than 200 orders frit, form slurry, beat powder after slurry is dried, obtain printing powdered frit;
Step C00: the Al that possesses corundum structure
2o
3starting material are through washing drying and processing;
Step D00: hybrid packed: by the printing powdered frit making and the Al that possesses corundum structure
2o
3starting material are packed after requiring evenly to mix according to formulation ratio, obtain wear-resisting on-slip glaze.
Wear-resisting on-slip glaze as described in above-mentioned any one carries out a preparation method for the wear-resisting on-slip brick of print surface, it is characterized in that, specifically comprises the following steps:
Step a00: prepare wear-resisting on-slip glaze and ceramic tile brick body;
Step b00: stamp-pad ink is proportionally added in wear-resisting on-slip glaze;
Step c00: utilize screen printing mode glazing in ceramic tile brick surface, obtain work in-process brick body;
Steps d 00: work in-process brick body, through 1100 ℃ ~ 1230 ℃ fire, is obtained to wear-resisting on-slip brick.
The preparation method of described wear-resisting on-slip brick, wherein, in described step b00, the ratio of wear-resisting on-slip glaze and stamp-pad ink is 1:1～1:1.5.
The preparation method of described wear-resisting on-slip brick, wherein, in described steps d 00, the firing time of work in-process brick body is 45-65 minute.
Beneficial effect of the present invention: the present invention is by the preparation method of a kind of wear-resisting on-slip glaze and preparation method thereof and wear-resisting on-slip brick is provided, and the preparation of this wear-resisting on-slip glaze does not simply affect original decorative design effects; The glaze that adopts this preparation method to produce, in ceramic embryo brick surface, form glaze layer, after high-temperature firing, antifouling wear-resisting anti-slip effect is good, through ceramic certification authority of country, detecting its glazed tile wear resistance measures and can reach 4 grade 12000 and turn, Mohs' hardness mensuration mean value is that the static friction coefficient determination dry and wet way of 6, GB/T4100-2006 appendix M all can reach 1.3, and meets the code requirement of ceramic tile GB/T 3810-2006; Applied range, can select different basic wear-resisting antifouling on-slip glaze according to the firing temperature (1100 ~ 1230 ℃) of ceramic tile, and original picture proof design of arranging in pairs or groups can be produced into the wear-resisting antifouling on-slip brick that meets demand.
Accompanying drawing explanation
Fig. 1 is the surperficial enlarged view of general frit under microscope in the present invention.
Fig. 2 is the surperficial enlarged view of raw material glaze under microscope in the present invention.
Fig. 3 is the surperficial enlarged view of wear-resisting on-slip glaze under microscope in the present invention.
Embodiment
For making object of the present invention, technical scheme and advantage clearer, clear and definite, referring to accompanying drawing, developing simultaneously, the present invention is described in more detail for embodiment.
In the present invention, wear-resisting on-slip glaze comprises frit powdered frit and possesses the Al of corundum structure
2o
3, concrete composition and weight percent thereof are:
SiO
2：
25~40%；
Al
2O
3： 40~60%；
K
2O+Na
2O： 1~5%；
CaO： 1~10%；
MgO： 1~5%；
BaO ： 1~15%；
ZnO： 1~10%。
As known in Fig. 1-3 contrast, above-mentioned wear-resisting on-slip glaze, after 1100 ~ 1230 ℃ of high temperature burn till, has the hard projection of needle-like, compared with general frit and raw material glaze, can effectively in dry type and wet condition, be issued to anti-slip effect, and also can possess wear-resisting antifouling effect through overtesting adjustment.
Wherein, described frit powdered frit and the Al that possesses corundum structure
2o
3weight ratio can be different according to different ceramic tile series, both weight ratios (frit: the Al that possesses corundum structure
2o
3) between 5/5～8/2.
Particularly, when the wear-resisting on-slip glaze of basis is specifically applied in to little floor tile series (firing temperature: 1100 ~ 1160 ℃) wear-resisting on-slip glaze and Antique Imitation Tiles series (firing temperature: 1180 ~ 1230 ℃) wear-resisting on-slip glaze, composition and weight percent thereof that it comprises are specific as follows:
When wear-resisting on-slip glaze is the wear-resisting on-slip glaze of little floor tile series, comprise frit powdered frit and the Al that possesses corundum structure
2o
3, concrete composition and weight percent thereof are:
SiO
2：
25~40%；
Al
2O
3： 40~60%；
K
2O+Na
2O： 1~5%；
CaO： 1~10%；
MgO： 1~5%；
BaO ： 1~10%；
ZnO： 1~10%。
When wear-resisting on-slip glaze is the wear-resisting on-slip glaze of little floor tile series, composition and weight percent thereof that described frit powdered frit comprises are:
Na
2O： 1.0%；
K
2O： 5.0%；
MgO： 2.0%；
CaO： 8.0%；
ZnO： 9.5%；
BaO： 10.0%；
Al
2O
3：10.0%；
SiO
2: 54.5%。
When wear-resisting on-slip glaze is the wear-resisting on-slip glaze of Antique Imitation Tiles series, comprise frit powdered frit and the Al that possesses corundum structure
2o
3, concrete composition and weight percent thereof are:
SiO
2：
25~40%；
Al
2O
3： 40~60%；
K
2O+Na
2O： 1~5%；
CaO： 1~5%；
MgO： 1~5%；
BaO ： 5~15%；
ZnO： 1~5%。
When wear-resisting on-slip glaze is the wear-resisting on-slip glaze of Antique Imitation Tiles series, composition and weight percent thereof that described frit powdered frit comprises are:
Na
2O： 1.5%；
K
2O： 6.0%；
MgO： 2.4%；
CaO： 3.5%；
ZnO： 4.4%；
BaO： 22.4%；
Al
2O
3： 10.5%；
SiO
2: 49.3%。
Oxide component and weight percent thereof contained in described wear-resisting on-slip glaze can be provided according to proportioning by different starting material, and the proportioning of the wear-resisting on-slip glaze that different ceramic tile requires is also different, according to ratio requirement, selects suitable starting material to carry out proportioning.
The preparation method of wear-resisting on-slip glaze, specifically comprise the following steps:
Steps A 00: prepare frit powdered frit: found after the desired formula composition of the component that starting material are comprised by frit and weight percent thereof configures and mixes, glass melting temperature is 1500 ℃ ~ 1600 ℃, melting time is 1.5 ~ 8 hours, and then quenching to normal temperature becomes frit powdered frit rapidly;
Step B00: preparation printing powdered frit: utilize ball mill wet grinding to passing through standard sieves more than 200 orders frit powdered frit, form slurry, beat powder after slurry is dried, obtain printing powdered frit;
Step C00: the Al that possesses corundum structure
2o
3starting material are through washing drying and processing;
Step D00: hybrid packed: by the printing powdered frit making and the Al that possesses corundum structure
2o
3starting material are packed after requiring evenly to mix according to formulation ratio, obtain wear-resisting on-slip glaze.
Wear-resisting on-slip glaze as described above carries out a preparation method for the wear-resisting on-slip brick of print surface, specifically comprises the following steps:
Step a00: prepare wear-resisting on-slip glaze and ceramic tile brick body;
Step b00: stamp-pad ink is proportionally added in wear-resisting on-slip glaze;
Step c00: utilize screen printing mode glazing in ceramic tile brick surface, obtain work in-process brick body;
Steps d 00: work in-process brick body, through 1100 ℃ ~ 1230 ℃ fire, is obtained to wear-resisting on-slip brick.
In described step b00, the ratio of wear-resisting on-slip glaze and stamp-pad ink can be determined according to actual requirement, and in the present embodiment, the ratio of described wear-resisting on-slip glaze and stamp-pad ink is 1:1～1:1.5.
In described step c00, the specification of silk screen can be determined according to actual requirement, and in the present embodiment, described silk screen is 32T half tone silk screen.
Particularly, in described steps d 00, the firing time of work in-process brick body is 45-65 minute.
Especially, the preparation method of above-mentioned wear-resisting on-slip brick is specifically applied in to little floor tile series and Antique Imitation Tiles series, concrete Application Example is as follows:
Embodiment 1: be applied in little floor tile series
Composition and weight percent thereof that in the wear-resisting on-slip glaze of described little floor tile series, frit powdered frit comprises are: Na2O:1.0%, K
2o:5.0%, MgO:2.0%, CaO:8.0%, ZnO:9.5%, BaO:10.0%, Al
2o
3: 10.0%, SiO
2: 54.5%.
The oxide component that above-mentioned frit powdered frit comprises and weight percent thereof can be provided by proportioning by following starting material, concrete raw-material formula and weight percent thereof are: barium carbonate: 11.5%, potassium felspar sand: 34.0%, salt of wormwood: 1.5%, silica sand: 19.1%, Wingdale: 5.0%, rhombspar: 8.4%, kaolin: 7.7%, zinc white: 8.4%, wollastonite: 4.4%.
In the oxide component that above-mentioned starting material are comprised according to frit powdered frit, desired formula composition is founded after configuring and mixing, glass melting temperature is 1560 ℃, hold temperature 2 hours, after having melted, pour into rapidly in normal-temperature water and carry out quenching, obtain frit powdered frit; Utilize ball mill wet grinding to passing through standard sieves more than 200 orders frit powdered frit, form slurry, after slurry is dried, beat powder, obtain printing powdered frit; The Al that possesses corundum structure
2o
3starting material are through washing drying and processing; By the printing powdered frit making (account for wear-resisting on-slip glaze gross weight 70%) and the Al that possesses corundum structure
2o
3starting material (account for wear-resisting on-slip glaze gross weight 30%) require evenly to mix according to formula, obtain the wear-resisting on-slip glaze of little floor tile series.
By the wear-resisting on-slip glaze of little floor tile series configuring with print cream powder oil in proportion 1:1～1:1.5 be uniformly mixed, with the mode of printing glazing of 32T half tone silk screen in the ceramic tile brick surface preparing, and burn till in tunnel furnace, firing period 45～60 minutes, 1100～1160 ℃ of firing temperatures, be fired into glaze, can obtain the wear-resisting on-slip brick of little floor tile series.
Embodiment 2: be applied in Antique Imitation Tiles series
Composition and weight percent thereof that in the wear-resisting on-slip glaze of described Antique Imitation Tiles series, frit powdered frit comprises are: Na
2o:1.5%, K
2o:6.0%, MgO:2.4%, CaO:3.5%, ZnO:4.4%, BaO:22.4%, Al
2o
3: 10.5%, SiO
2: 49.3%.
The oxide component that above-mentioned frit powdered frit comprises and weight percent thereof can be provided by proportioning by following starting material, concrete raw-material formula and weight percent thereof are: barium carbonate: 24.9%, potassium felspar sand: 30.0 %, salt of wormwood: 3.2 %, silica sand: 17.2%, sodium carbonate: 0.8%, rhombspar: 9.8%, kaolin: 10.3%, zinc white: 3.8%.
In the oxide component that above-mentioned starting material are comprised according to frit powdered frit, desired formula composition is founded after configuring and mixing, glass melting temperature is 1560 ℃, hold temperature 2 hours, after having melted, pour into rapidly in normal-temperature water and carry out quenching, obtain frit powdered frit; Utilize ball mill wet grinding to passing through standard sieves more than 200 orders frit powdered frit, form slurry, after slurry is dried, beat powder, obtain printing powdered frit; The Al that possesses corundum structure
2o
3starting material are through washing drying and processing; By the printing powdered frit making (account for wear-resisting on-slip glaze gross weight 60%) and the Al that possesses corundum structure
2o
3starting material (account for wear-resisting on-slip glaze gross weight 40%) require evenly to mix according to formula, obtain the wear-resisting on-slip glaze of Antique Imitation Tiles series.
By the wear-resisting on-slip glaze of Antique Imitation Tiles series configuring with print cream powder oil in proportion 1:1～1:1.5 be uniformly mixed, with the mode of printing glazing of 32T half tone silk screen in the ceramic tile brick surface preparing, and burn till in tunnel furnace, firing period 52～65 minutes, 1180～1230 ℃ of firing temperatures, be fired into glaze, can obtain the wear-resisting on-slip brick of Antique Imitation Tiles series.
After tested, the wear-resisting on-slip brick that uses this wear-resisting on-slip glaze to fire has following performance:
1. non-skid property: according to the mensuration of State Standard of the People's Republic of China GB/T 4100-2006 appendix M[ceramic tile appendix M frictional coefficient] carry out the mensuration of coefficient of friction, under the condition of dry method, detecting static friction coefficient is 1.34; Under the condition of wet method, detecting static friction coefficient is 1.31, and anti-slip effect is good.
2. abrasion resistance test: carry out the mensuration of glazed tile surface abrasion resistance according to EN ISO 10545-7 1998, test result is 12000 to turn at the rotating speed of wearing and tearing visible marks, and wear resistance rank is 4 grades, and wear resisting property is good.
3. Mohs' hardness test: carry out the mensuration of Mohs' hardness according to BS 6431:Part 13 1986, test result Mohs' hardness mean value is 6, and the more general ceramic tile of hardness is good.
4. meet the every code requirement of ceramic tile GB/T 3810-2006.
5. the radioactive material nucleic that the meets national building standard GB 6566-2010 requirement of limiting the quantity of.
The preparation of this wear-resisting on-slip glaze does not simply affect original decorative design effects; The glaze that adopts this preparation method to produce, forms glaze layer in ceramic embryo brick surface, after high-temperature firing, antifouling wear-resisting anti-slip effect is good; Applied range, can select different basic wear-resisting antifouling on-slip glaze according to the firing temperature (1100 ~ 1230 ℃) of ceramic tile, and original picture proof design of arranging in pairs or groups can be produced into the wear-resisting antifouling on-slip brick that meets demand.
Should be understood that, application of the present invention is not limited to above-mentioned giving an example, and for those of ordinary skills, can be improved according to the above description or convert, and all these improvement and conversion all should belong to the protection domain of claims of the present invention.
Claims (8)
1. a wear-resisting on-slip glaze, is characterized in that, comprises frit powdered frit and the Al that possesses corundum structure
2o
3, concrete composition and weight percent thereof are:
SiO
2：
25~40%；
Al
2O
3： 40~60%；
K
2O+Na
2O： 1~5%；
CaO： 1~10%；
MgO： 1~5%；
BaO ： 1~15%；
ZnO： 1~10%。
2. wear-resisting on-slip glaze according to claim 1, is characterized in that, described frit powdered frit and the Al that possesses corundum structure
2o
3weight ratio be 5/5～8/2.
3. wear-resisting on-slip glaze according to claim 2, is characterized in that, when wear-resisting on-slip glaze is the wear-resisting on-slip glaze of little floor tile series, comprises frit powdered frit and the Al that possesses corundum structure
2o
3, concrete composition and weight percent thereof are:
SiO
2：
25~40%；
Al
2O
3： 40~60%；
K
2O+Na
2O： 1~5%；
CaO： 1~10%；
MgO： 1~5%；
BaO ： 1~10%；
ZnO： 1~10%。
4. wear-resisting on-slip glaze according to claim 2, is characterized in that, when wear-resisting on-slip glaze is the wear-resisting on-slip glaze of Antique Imitation Tiles series, comprises frit powdered frit and the Al that possesses corundum structure
2o
3, concrete composition and weight percent thereof are:
SiO
2：
25~40%；
Al
2O
3： 40~60%；
K
2O+Na
2O： 1~5%；
CaO： 1~5%；
MgO： 1~5%；
BaO ： 5~15%；
ZnO： 1~5%。
5. a preparation method for the wear-resisting on-slip glaze as described in claim 1-4 any one, is characterized in that, specifically comprises the following steps:
Steps A 00: prepare frit: found after the desired formula composition of the component that starting material are comprised by frit and weight percent thereof configures and mixes, glass melting temperature is 1500 ℃ ~ 1600 ℃, melting time is 1.5 ~ 8 hours, and then quenching to normal temperature becomes frit rapidly;
Step B00: preparation printing powdered frit: utilize ball mill wet grinding to passing through standard sieves more than 200 orders frit, form slurry, beat powder after slurry is dried, obtain printing powdered frit;
Step C00: the Al that possesses corundum structure
2o
3starting material are through washing drying and processing;
Step D00: hybrid packed: by the printing powdered frit making and the Al that possesses corundum structure
2o
3starting material are packed after requiring evenly to mix according to formulation ratio, obtain wear-resisting on-slip glaze.
6. the wear-resisting on-slip glaze of utilization as described in claim 1-4 any one carries out a preparation method for the wear-resisting on-slip brick of print surface, it is characterized in that, specifically comprises the following steps:
Step a00: prepare wear-resisting on-slip glaze and ceramic tile brick body;
Step b00: stamp-pad ink is proportionally added in wear-resisting on-slip glaze;
Step c00: utilize screen printing mode glazing in ceramic tile brick surface, obtain work in-process brick body;
Steps d 00: work in-process brick body, through 1100 ℃ ~ 1230 ℃ fire, is obtained to wear-resisting on-slip brick.
7. the preparation method of wear-resisting on-slip brick according to claim 6, is characterized in that, in described step b00, the ratio of wear-resisting on-slip glaze and stamp-pad ink is 1:1～1:1.5.
8. the preparation method of wear-resisting on-slip brick according to claim 7, is characterized in that, in described steps d 00, the firing time of work in-process brick body is 45-65 minute.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310565409.3A CN103570380B (en) | 2013-11-14 | 2013-11-14 | Wear-resistant antiskid glaze and preparation method thereof as well as preparation method of wear-resistant antiskid tile |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310565409.3A CN103570380B (en) | 2013-11-14 | 2013-11-14 | Wear-resistant antiskid glaze and preparation method thereof as well as preparation method of wear-resistant antiskid tile |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103570380A true CN103570380A (en) | 2014-02-12 |
| CN103570380B CN103570380B (en) | 2014-10-01 |
Family
ID=50043179
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310565409.3A Active CN103570380B (en) | 2013-11-14 | 2013-11-14 | Wear-resistant antiskid glaze and preparation method thereof as well as preparation method of wear-resistant antiskid tile |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103570380B (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103951398A (en) * | 2014-04-08 | 2014-07-30 | 安徽省亚欧陶瓷有限责任公司 | High-wear-resistant ceramic tile and preparation method thereof |
| CN104261897A (en) * | 2014-09-25 | 2015-01-07 | 佛山市三水新明珠建陶工业有限公司 | Ceramic tile having antiskid effect and manufacturing method thereof |
| CN104261801A (en) * | 2014-09-18 | 2015-01-07 | 湖南嘉盛电陶新材料股份有限公司 | Ceramic bearing platter for microwave oven and preparation method of ceramic bearing platter |
| CN105271753A (en) * | 2015-10-30 | 2016-01-27 | 淄博金狮王科技陶瓷有限公司 | Anti-skid and antibacterial ceramic tile and preparation process thereof |
| CN106698950A (en) * | 2016-11-28 | 2017-05-24 | 尹念党 | Diamond microcrystalline material and a preparation method and application thereof |
| CN106830682A (en) * | 2017-01-17 | 2017-06-13 | 四川新高峰瓷业有限公司 | A kind of skid-resistance ceramic glaze, anti-skidding Dali stone ceramic tile and preparation method thereof |
| CN107540345A (en) * | 2017-09-30 | 2018-01-05 | 福建德胜新建材有限公司 | A kind of ultra-fine dry granular porcelain glazed brick |
| CN109608207A (en) * | 2019-01-24 | 2019-04-12 | 信益陶瓷(中国)有限公司 | A kind of entire body is without glaze Dali stone ceramic tile and its manufacturing method |
| CN110054412A (en) * | 2019-05-21 | 2019-07-26 | 南顺芝 | A kind of super abrasive diamond glaze formula and production technology |
| CN111004038A (en) * | 2020-01-02 | 2020-04-14 | 杭州诺贝尔陶瓷有限公司 | Ultra-large specification thin porcelain plate with electric heating function and production method thereof |
| CN111233333A (en) * | 2020-03-13 | 2020-06-05 | 东莞市唯美陶瓷工业园有限公司 | Anti-slip glaze, anti-slip ceramic tile and preparation method thereof |
| CN111362728A (en) * | 2020-04-20 | 2020-07-03 | 广东家美陶瓷有限公司 | Digital anti-skid ink-jet ink, preparation method thereof and preparation method of digital anti-skid ceramic tile |
| CN112939465A (en) * | 2021-03-31 | 2021-06-11 | 江西太阳陶瓷有限公司 | Anti-slip glaze and processing method of anti-slip glazed brick |
| CN113955942A (en) * | 2021-12-22 | 2022-01-21 | 广东简一(集团)陶瓷有限公司 | High-hardness glaze and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1075308A (en) * | 1992-02-13 | 1993-08-18 | 瑞士隆萨股份公司 | The hard particles, its production method and the application that on matrix of oxide, cover with beramic color |
| CN1151385A (en) * | 1995-11-24 | 1997-06-11 | 李建国 | Tech. for mfg. of diamond-like glazed floor tile |
| CN1830690A (en) * | 2005-03-11 | 2006-09-13 | 杨德宁 | Three-dimensional diamond and its manufacturing method |
| CN1887812A (en) * | 2006-07-18 | 2007-01-03 | 广东三水大鸿制釉有限公司 | Decoration glaze for inner wall tile and its prepn and detection method |
| CN102491789A (en) * | 2011-11-14 | 2012-06-13 | 星谊精密陶瓷科技（昆山）有限公司 | Anti-skid printing glaze and preparation method and application thereof |
-
2013
- 2013-11-14 CN CN201310565409.3A patent/CN103570380B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1075308A (en) * | 1992-02-13 | 1993-08-18 | 瑞士隆萨股份公司 | The hard particles, its production method and the application that on matrix of oxide, cover with beramic color |
| CN1151385A (en) * | 1995-11-24 | 1997-06-11 | 李建国 | Tech. for mfg. of diamond-like glazed floor tile |
| CN1830690A (en) * | 2005-03-11 | 2006-09-13 | 杨德宁 | Three-dimensional diamond and its manufacturing method |
| CN1887812A (en) * | 2006-07-18 | 2007-01-03 | 广东三水大鸿制釉有限公司 | Decoration glaze for inner wall tile and its prepn and detection method |
| CN102491789A (en) * | 2011-11-14 | 2012-06-13 | 星谊精密陶瓷科技（昆山）有限公司 | Anti-skid printing glaze and preparation method and application thereof |
Non-Patent Citations (5)
| Title |
|---|
| 侯旭晨等: "瓷质砖低成本耐磨釉的研制", 《佛山陶瓷》, vol. 14, no. 7, 31 July 2004 (2004-07-31) * |
| 陈建忠等: "超耐磨高硬度全抛釉的制备研究", 《中国陶瓷》, vol. 48, no. 9, 30 September 2012 (2012-09-30) * |
| 陈爱芬: "提高陶瓷釉面耐磨性和耐久性的几个途径", 《中国陶瓷工业》, no. 3, 30 June 1997 (1997-06-30) * |
| 陈舰等: "刚玉对陶瓷地砖釉面耐磨性能影响的研究", 《东莞理工学院学报》, vol. 14, no. 5, 31 May 2007 (2007-05-31), pages 1 - 1 * |
| 马光华等: "抛釉砖耐磨釉面的研究", 《中国陶瓷工业》, vol. 7, no. 4, 31 December 2000 (2000-12-31) * |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103951398A (en) * | 2014-04-08 | 2014-07-30 | 安徽省亚欧陶瓷有限责任公司 | High-wear-resistant ceramic tile and preparation method thereof |
| CN103951398B (en) * | 2014-04-08 | 2015-04-01 | 安徽省亚欧陶瓷有限责任公司 | High-wear-resistant ceramic tile and preparation method thereof |
| CN104261801A (en) * | 2014-09-18 | 2015-01-07 | 湖南嘉盛电陶新材料股份有限公司 | Ceramic bearing platter for microwave oven and preparation method of ceramic bearing platter |
| CN104261801B (en) * | 2014-09-18 | 2015-10-14 | 湖南嘉盛电陶新材料股份有限公司 | Pottery carrying tray of a kind of microwave oven and preparation method thereof |
| CN104261897A (en) * | 2014-09-25 | 2015-01-07 | 佛山市三水新明珠建陶工业有限公司 | Ceramic tile having antiskid effect and manufacturing method thereof |
| CN104261897B (en) * | 2014-09-25 | 2015-12-02 | 佛山市三水新明珠建陶工业有限公司 | A kind of ceramic tile and manufacture method thereof with skidproof effect |
| CN105271753A (en) * | 2015-10-30 | 2016-01-27 | 淄博金狮王科技陶瓷有限公司 | Anti-skid and antibacterial ceramic tile and preparation process thereof |
| CN105271753B (en) * | 2015-10-30 | 2017-03-15 | 淄博金狮王科技陶瓷集团有限公司 | Anti-skidding antibiotic ceramic tile and its preparation technology |
| CN106698950A (en) * | 2016-11-28 | 2017-05-24 | 尹念党 | Diamond microcrystalline material and a preparation method and application thereof |
| CN106830682A (en) * | 2017-01-17 | 2017-06-13 | 四川新高峰瓷业有限公司 | A kind of skid-resistance ceramic glaze, anti-skidding Dali stone ceramic tile and preparation method thereof |
| CN107540345A (en) * | 2017-09-30 | 2018-01-05 | 福建德胜新建材有限公司 | A kind of ultra-fine dry granular porcelain glazed brick |
| CN107540345B (en) * | 2017-09-30 | 2020-01-10 | 福建德胜新建材有限公司 | Superfine dry particle ceramic glazed tile |
| CN109608207A (en) * | 2019-01-24 | 2019-04-12 | 信益陶瓷(中国)有限公司 | A kind of entire body is without glaze Dali stone ceramic tile and its manufacturing method |
| CN110054412A (en) * | 2019-05-21 | 2019-07-26 | 南顺芝 | A kind of super abrasive diamond glaze formula and production technology |
| CN111004038A (en) * | 2020-01-02 | 2020-04-14 | 杭州诺贝尔陶瓷有限公司 | Ultra-large specification thin porcelain plate with electric heating function and production method thereof |
| CN111004038B (en) * | 2020-01-02 | 2022-05-03 | 杭州诺贝尔陶瓷有限公司 | Super-large-specification thin porcelain plate with electrothermal function and production method thereof |
| CN111233333A (en) * | 2020-03-13 | 2020-06-05 | 东莞市唯美陶瓷工业园有限公司 | Anti-slip glaze, anti-slip ceramic tile and preparation method thereof |
| CN111362728A (en) * | 2020-04-20 | 2020-07-03 | 广东家美陶瓷有限公司 | Digital anti-skid ink-jet ink, preparation method thereof and preparation method of digital anti-skid ceramic tile |
| CN112939465A (en) * | 2021-03-31 | 2021-06-11 | 江西太阳陶瓷有限公司 | Anti-slip glaze and processing method of anti-slip glazed brick |
| CN113955942A (en) * | 2021-12-22 | 2022-01-21 | 广东简一(集团)陶瓷有限公司 | High-hardness glaze and preparation method thereof |
| CN113955942B (en) * | 2021-12-22 | 2022-03-15 | 广东简一(集团)陶瓷有限公司 | High-hardness glaze and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103570380B (en) | 2014-10-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103570380B (en) | Wear-resistant antiskid glaze and preparation method thereof as well as preparation method of wear-resistant antiskid tile | |
| CN110683767B (en) | High-performance wear-resistant glaze and preparation method thereof | |
| CN103964900B (en) | A kind of sky blue furnace transmutation glaze formula and preparation method thereof | |
| CN100372813C (en) | Glaze material for surface of ceramic tile | |
| CN106746651A (en) | A kind of dry granular glaze with diamond luster effect | |
| CN102731169A (en) | Fully glazed ceramic chip and preparation method thereof | |
| CN105130378B (en) | A kind of artificial color sand colouring agent, artificial color sand and preparation method using the colouring agent | |
| CN106278387B (en) | There is the glazed tile and preparation method thereof of gold decorative effect on surface | |
| CN104140297A (en) | Glaze and preparation of embossment phantom glazed brick | |
| CN101898887A (en) | Semitransparent ceramic material, imitation jadeite ceramic sheet and preparation thereof | |
| WO2016038447A1 (en) | Glaze composition for treating ceramics, method of glazing ceramic articles and glazed ceramic articles | |
| CN102001864A (en) | Heat-resistant porcelain glaze | |
| CN103183529B (en) | Production process of superflat full polished glazed brick added with transparent microcrystal fine powder | |
| US11807577B2 (en) | Super-wear-resistant diamond glaze, ceramic tile and preparation method thereof | |
| CN108484114A (en) | A kind of glaze Imitation Rock Porcelain Tiles of high additive polished waste material and preparation method thereof | |
| CN107601880A (en) | A kind of ceramic opaque glaze and preparation method thereof | |
| WO2020234676A1 (en) | Producing composite glaze ceramic tiles | |
| CN114853346B (en) | Wear-resistant antifouling protective glaze, matt ceramic tile and preparation method thereof | |
| CN104860646B (en) | A kind of glazed tiles utilizing black earth to prepare | |
| JP2014201477A (en) | Low melting point leadless glass composition for ceramics | |
| CN114573233A (en) | Preparation method of wear-resistant color-assisting frit for wear-resistant glaze, super wear-resistant glaze and ceramic tile | |
| CN107573017A (en) | A kind of technique for manufacturing stealthy decorative pattern ceramic | |
| CN101851119A (en) | Glazing resintering technology of unglazed ancient colored glaze components | |
| CN102219382B (en) | Frit for full polish and preparation method thereof | |
| CN112608029B (en) | Dazzling archaized brick and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |