CN104860646B - A kind of glazed tiles utilizing black earth to prepare - Google Patents
A kind of glazed tiles utilizing black earth to prepare Download PDFInfo
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- CN104860646B CN104860646B CN201510292856.5A CN201510292856A CN104860646B CN 104860646 B CN104860646 B CN 104860646B CN 201510292856 A CN201510292856 A CN 201510292856A CN 104860646 B CN104860646 B CN 104860646B
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000000758 substrate Substances 0.000 claims abstract description 27
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 25
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000011777 magnesium Substances 0.000 claims abstract description 18
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 18
- -1 magnesium aluminate Chemical class 0.000 claims abstract description 18
- 229910052596 spinel Inorganic materials 0.000 claims abstract description 18
- 239000011029 spinel Substances 0.000 claims abstract description 18
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 11
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 11
- 229910052581 Si3N4 Inorganic materials 0.000 claims abstract description 11
- 229920002472 Starch Polymers 0.000 claims abstract description 11
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 11
- 229910000428 cobalt oxide Inorganic materials 0.000 claims abstract description 11
- 239000010433 feldspar Substances 0.000 claims abstract description 11
- 239000000835 fiber Substances 0.000 claims abstract description 11
- 239000010903 husk Substances 0.000 claims abstract description 11
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims abstract description 11
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims abstract description 11
- 239000001095 magnesium carbonate Substances 0.000 claims abstract description 11
- 239000005011 phenolic resin Substances 0.000 claims abstract description 11
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 11
- 229950000845 politef Drugs 0.000 claims abstract description 11
- 239000000843 powder Substances 0.000 claims abstract description 11
- 239000010453 quartz Substances 0.000 claims abstract description 11
- 235000009566 rice Nutrition 0.000 claims abstract description 11
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000008107 starch Substances 0.000 claims abstract description 11
- 235000019698 starch Nutrition 0.000 claims abstract description 11
- 239000010959 steel Substances 0.000 claims abstract description 11
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 10
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000004917 carbon fiber Substances 0.000 claims abstract description 10
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 10
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims description 34
- 239000002994 raw material Substances 0.000 claims description 16
- 238000002156 mixing Methods 0.000 claims description 14
- 241000209094 Oryza Species 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 7
- 238000001354 calcination Methods 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 229910052681 coesite Inorganic materials 0.000 claims description 7
- 229910052593 corundum Inorganic materials 0.000 claims description 7
- 229910052906 cristobalite Inorganic materials 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 238000000465 moulding Methods 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- 239000000377 silicon dioxide Substances 0.000 claims description 7
- 229910052682 stishovite Inorganic materials 0.000 claims description 7
- 229910052905 tridymite Inorganic materials 0.000 claims description 7
- 238000010792 warming Methods 0.000 claims description 7
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 7
- 238000010521 absorption reaction Methods 0.000 abstract description 6
- 230000006835 compression Effects 0.000 abstract description 6
- 238000007906 compression Methods 0.000 abstract description 6
- 239000002253 acid Substances 0.000 abstract description 5
- 230000009970 fire resistant effect Effects 0.000 abstract description 5
- 230000035699 permeability Effects 0.000 abstract description 4
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 abstract description 2
- 240000007594 Oryza sativa Species 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 description 14
- 230000000694 effects Effects 0.000 description 4
- 239000010410 layer Substances 0.000 description 3
- 101100002917 Caenorhabditis elegans ash-2 gene Proteins 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910052925 anhydrite Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
Landscapes
- Finishing Walls (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Glass Compositions (AREA)
Abstract
The present invention relates to a kind of glazed tiles utilizing black earth to prepare, this glazed tiles base substrate is made up of black earth, magnesium aluminate spinel, potassium feldspar, quartz, magnesium carbonate, steel fibre, phenolic resin, starch and rice husk；This glazed tiles glaze is made up of iron oxide yellow, cobalt oxide, feldspar powder, nano zine oxide, silicon nitride, carbon fiber, tin ash, TEOS, politef, this glazed tiles smooth surface is clean and tidy, bright in colour beautiful, there is excellent resistance to compression, the fire-resistant and performance of acid and alkali-resistance, and light weight, water absorption rate is low, good permeability, low cost.
Description
Technical field
The invention belongs to glazed tiles field, particularly to a kind of glazed tiles utilizing black earth to prepare.
Background technology
Glazed tiles are one ancient, traditional ceramic materials of China.Along with the development of tourist industry, people are for the demand of glazed tiles
Also it is more and more, is also more and more higher to its requirement.
Glazed tiles, material is firm, bright in luster, glaze colours is smooth, and always as the building object of Chinese tradition, it is through the successive dynasties
Development, the improvement of quality, owing to having multiple excellent function, and it is widely used in modern architecture.
Existing glazed tiles are the most all to use multiple pug mixed sintering to form, and its glaze layer is the thickest and produces stress, quality
Weight, is easily caused product glaze and be full of cracks occurs, collapse the defect of stripping.The most smooth, and pug is easily generated dirt in process of production
Dye, cost and energy consumption are high, and the quality of product is not sufficiently stable, and its glaze glossiness is inadequate, and colour generation is abundant not, stable, at gas
Wait and easily fade under changeable area or long sunlight irradiation.
Present invention mainly solves technical problem is that: for the deficiencies in the prior art, it is provided that a kind of glazed tiles utilizing black earth to prepare,
This glazed tiles smooth surface is clean and tidy, bright in colour beautiful, has excellent resistance to compression, the fire-resistant and performance of acid and alkali-resistance, and light weight,
Water absorption rate is low, good permeability, low cost.
Summary of the invention
It is an object of the invention to, for the problems referred to above, develop a kind of glazed tiles utilizing black earth to prepare, by optimizing coloured glaze unbaked tile
Body and the composition of glaze, improve the colouring effect of glazed tiles, resistance to compression, the fire-resistant and performance of acid and alkali-resistance and water absorption rate and breathe freely
The physical and chemical performances such as property.
A kind of glazed tiles utilizing black earth to prepare, this glazed tiles base substrate weight portion composition is as follows:
Black earth 90-150 part；Magnesium aluminate spinel 20-30 part；Potassium feldspar 8-10 part；Quartz 1-7 part；Magnesium carbonate 1-7 part；
Steel fibre 1-7 part；Phenolic resin 1-7 part；Starch 1-7 part；Rice husk 1-7 part；
This glazed tiles glaze weight portion composition is as follows:
Iron oxide yellow 40-50 part；Cobalt oxide 1-5 part；Feldspar powder 1-5 part；Nano zine oxide 1-5 part；Silicon nitride 1-5 part；
Carbon fiber 1-5 part；Tin ash 1-5 part；TEOS 1-5 part；Politef 1-5 part；
Its preparation method is as follows:
(1) batch mixing: glazed tiles blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 3 days；
(2) pressed compact molding, compressing under 60Mpa pressure, it is incubated 2 hours, the demoulding；
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, and during kiln discharge, base substrate water content is less than 1.2wt%；
(4) glazing: added water by glaze raw material and prepare glaze, and glazing, glaze thickness is 0.2mm；After glazing and 150
Dry 24 hours at DEG C；
(5) burn till: in calcining kiln, heating rate 80 DEG C/h, after being warming up to 1200 DEG C, be incubated 2 hours,
Utilize glazed tiles prepared by black earth.
As preferably, the chemical composition of black earth is: SiO2 45wt%, Al2O3 35wt%, CaO 10wt%, other compositions
10wt%.
As preferably, the particle diameter of magnesium aluminate spinel is less than 1 μm.
As preferably, this glazed tiles base substrate weight portion composition is as follows:
110 parts of black earth；Magnesium aluminate spinel 25 parts；Potassium feldspar 9 parts；4 parts of quartz；Magnesium carbonate 4 parts；Steel fibre 4 parts；
4 parts of phenolic resin；Starch 4 parts；4 parts of rice husk.
As preferably, this glazed tiles glaze weight portion composition is as follows:
Iron oxide yellow 45 parts；Cobalt oxide 4 parts；Feldspar powder 4 parts；Nano zine oxide 4 parts；Silicon nitride 4 parts；Carbon fiber 4
Part；Tin ash 4 parts；TEOS 4 parts；Politef 4 parts.
Beneficial effects of the present invention:
(1) generally speaking, by optimizing glazed tiles base substrate and the composition of glaze, improve the colouring effect of glazed tiles, resistance to compression,
The performance of fire-resistant and acid and alkali-resistance and the physical and chemical performance such as water absorption rate and breathability；This glazed tiles smooth surface is clean and tidy, bright in colour bright
Beautiful, there is excellent resistance to compression, the fire-resistant and performance of acid and alkali-resistance, and light weight, water absorption rate is low, good permeability, low cost.Should
The water absorption rate of glazed tiles is less than 5.4%, and comprcssive strength is more than 56Mpa.
(2) in base substrate dispensing, being the first primary raw material with black earth, magnesium aluminate spinel is the second primary raw material, and assists potassium
Anhydrite, quartz, magnesium carbonate, steel fibre, phenolic resin, starch and rice husk, and form by optimizing the weight portion of each component,
The resistance to compression of customer service black earth is strong, the imperfect deficiency of stability, and optimizes water suction and the permeability of base substrate.And due to black
Soil has preferable viscosity, and preferable with the combination of glaze layer, therefore, glaze layer can be the thinnest, such that it is able to prevent glaze from going out
Now chap, collapse the defect of stripping.Meanwhile, black earth carries color, also the colour brightness that glazed tiles are overall can be produced material impact.
(3) by with the addition of cobalt oxide and silicon nitride in glaze, the toughness of surface layer can be improved, and nano zine oxide,
The automatically cleaning effect of glazed tiles can be played；And feldspar powder can play the effect of sintering aid；And TEOS and politef
Interpolation, effective surface protection can be carried out for glazed tiles, improve the smooth degree on surface.Prepared by the application out
Glazed tiles smooth surface is clean and tidy, bright in colour beautiful, and has preferable stability.
Detailed description of the invention
Below in conjunction with specific embodiment, and with reference to data, the present invention is described in further detail.Should be understood that these
The embodiment present invention solely for the purpose of illustration, rather than limit the scope of the present invention by any way.
Embodiment 1:
A kind of glazed tiles utilizing black earth to prepare,
This glazed tiles base substrate weight portion composition is as follows:
110 parts of black earth；Magnesium aluminate spinel 25 parts；Potassium feldspar 9 parts；4 parts of quartz；Magnesium carbonate 4 parts；
Steel fibre 4 parts；4 parts of phenolic resin；Starch 4 parts；4 parts of rice husk；
This glazed tiles glaze weight portion composition is as follows,
Iron oxide yellow 45 parts；Cobalt oxide 4 parts；Feldspar powder 4 parts；Nano zine oxide 4 parts；Silicon nitride 4 parts；
4 parts of carbon fiber；Tin ash 4 parts；TEOS 4 parts；Politef 4 parts；
The chemical composition of black earth is: SiO2 45wt%, Al2O3 35wt%, CaO 10wt%, other compositions
10wt%.
The particle diameter of magnesium aluminate spinel is less than 1 μm.
Its preparation method is as follows:
(1) batch mixing: glazed tiles blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 3 days；
(2) pressed compact molding, compressing under 60Mpa pressure, it is incubated 2 hours, the demoulding；
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, and during kiln discharge, base substrate water content is less than 1.2wt
%；
(4) glazing: added water by glaze raw material and prepare glaze, and glazing, glaze thickness is 0.2mm；Glazing
Afterwards and dry 24 hours at 150 DEG C；
(5) burn till: in calcining kiln, heating rate 80 DEG C/h, after being warming up to 1200 DEG C, be incubated 2
Hour, utilize glazed tiles prepared by black earth.
Embodiment 2:
A kind of glazed tiles utilizing black earth to prepare,
This glazed tiles base substrate weight portion composition is as follows:
112 parts of black earth；Magnesium aluminate spinel 26 parts；Potassium feldspar 8 parts；4 parts of quartz；Magnesium carbonate 4 parts；
Steel fibre 4 parts；4 parts of phenolic resin；Starch 4 parts；4 parts of rice husk；
This glazed tiles glaze weight portion composition is as follows,
Iron oxide yellow 46 parts；Cobalt oxide 4 parts；Feldspar powder 2 parts；Nano zine oxide 2 parts；Silicon nitride 4 parts；
4 parts of carbon fiber；Tin ash 2 parts；TEOS 4 parts；Politef 4 parts；
The chemical composition of black earth is: SiO2 45wt%, Al2O3 35wt%, CaO 10wt%, other compositions
10wt%.
The particle diameter of magnesium aluminate spinel is less than 1 μm.
Its preparation method is as follows:
(1) batch mixing: glazed tiles blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 3 days；
(2) pressed compact molding, compressing under 60Mpa pressure, it is incubated 2 hours, the demoulding；
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, and during kiln discharge, base substrate water content is less than 1.2wt
%；
(4) glazing: added water by glaze raw material and prepare glaze, and glazing, glaze thickness is 0.2mm；Glazing
Afterwards and dry 24 hours at 150 DEG C；
(5) burn till: in calcining kiln, heating rate 80 DEG C/h, after being warming up to 1200 DEG C, be incubated 2
Hour, utilize glazed tiles prepared by black earth.
Embodiment 3:
A kind of glazed tiles utilizing black earth to prepare,
This glazed tiles base substrate weight portion composition is as follows:
109 parts of black earth；Magnesium aluminate spinel 22 parts；Potassium feldspar 9 parts；5 parts of quartz；Magnesium carbonate 5 parts；
Steel fibre 5 parts；5 parts of phenolic resin；Starch 5 parts；5 parts of rice husk；
This glazed tiles glaze weight portion composition is as follows,
Iron oxide yellow 42 parts；Cobalt oxide 4 parts；Feldspar powder 2 parts；Nano zine oxide 2 parts；Silicon nitride 2 parts；
4 parts of carbon fiber；Tin ash 4 parts；TEOS2 part；Politef 2 parts；
The chemical composition of black earth is: SiO2 45wt%, Al2O3 35wt%, CaO 10wt%, other compositions
10wt%.
The particle diameter of magnesium aluminate spinel is less than 1 μm.
Its preparation method is as follows:
(1) batch mixing: glazed tiles blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 3 days；
(2) pressed compact molding, compressing under 60Mpa pressure, it is incubated 2 hours, the demoulding；
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, and during kiln discharge, base substrate water content is less than 1.2wt
%；
(4) glazing: added water by glaze raw material and prepare glaze, and glazing, glaze thickness is 0.2mm；Glazing
Afterwards and dry 24 hours at 150 DEG C；
(5) burn till: in calcining kiln, heating rate 80 DEG C/h, after being warming up to 1200 DEG C, be incubated 2
Hour, utilize glazed tiles prepared by black earth.
Embodiment 4:
A kind of glazed tiles utilizing black earth to prepare,
This glazed tiles base substrate weight portion composition is as follows:
119 parts of black earth；Magnesium aluminate spinel 27 parts；Potassium feldspar 9 parts；2 parts of quartz；Magnesium carbonate 5 parts；
Steel fibre 2 parts；2 parts of phenolic resin；Starch 2 parts；5 parts of rice husk；
This glazed tiles glaze weight portion composition is as follows,
Iron oxide yellow 47 parts；Cobalt oxide 4 parts；Feldspar powder 2 parts；Nano zine oxide 2 parts；Silicon nitride 2 parts；
2 parts of carbon fiber；Tin ash 2 parts；TEOS2 part；Politef 2 parts；
The chemical composition of black earth is: SiO2 45wt%, Al2O3 35wt%, CaO 10wt%, other compositions
10wt%.
The particle diameter of magnesium aluminate spinel is less than 1 μm.
Its preparation method is as follows:
(1) batch mixing: glazed tiles blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 3 days；
(2) pressed compact molding, compressing under 60Mpa pressure, it is incubated 2 hours, the demoulding；
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, and during kiln discharge, base substrate water content is less than 1.2wt
%；
(4) glazing: added water by glaze raw material and prepare glaze, and glazing, glaze thickness is 0.2mm；Glazing
Afterwards and dry 24 hours at 150 DEG C；
(5) burn till: in calcining kiln, heating rate 80 DEG C/h, after being warming up to 1200 DEG C, be incubated 2
Hour, utilize glazed tiles prepared by black earth.
Embodiment 5:
A kind of glazed tiles utilizing black earth to prepare,
This glazed tiles base substrate weight portion composition is as follows:
100 parts of black earth；Magnesium aluminate spinel 20 parts；Potassium feldspar 9 parts；3 parts of quartz；Magnesium carbonate 5 parts；
Steel fibre 4 parts；5 parts of phenolic resin；Starch 4 parts；5 parts of rice husk；
This glazed tiles glaze weight portion composition is as follows,
Iron oxide yellow 50 parts；Cobalt oxide 4 parts；Feldspar powder 2 parts；Nano zine oxide 2 parts；Silicon nitride 2 parts；
2 parts of carbon fiber；Tin ash 4 parts；TEOS2 part；Politef 2 parts；
The chemical composition of black earth is: SiO2 45wt%, Al2O3 35wt%, CaO 10wt%, other compositions
10wt%.
The particle diameter of magnesium aluminate spinel is less than 1 μm.
Its preparation method is as follows:
(1) batch mixing: glazed tiles blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 3 days；
(2) pressed compact molding, compressing under 60Mpa pressure, it is incubated 2 hours, the demoulding；
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, and during kiln discharge, base substrate water content is less than 1.2wt
%；
(4) glazing: added water by glaze raw material and prepare glaze, and glazing, glaze thickness is 0.2mm；Glazing
Afterwards and dry 24 hours at 150 DEG C；
(5) burn till: in calcining kiln, heating rate 80 DEG C/h, after being warming up to 1200 DEG C, be incubated 2
Hour, utilize glazed tiles prepared by black earth.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and
And without departing from the spirit or essential characteristics of the present invention, it is possible to realize this in other specific forms
Bright.Therefore, no matter from the point of view of which point, embodiment all should be regarded as exemplary, and be non-limiting
, the scope of the present invention is limited by claims rather than described above, wants it is intended that will fall in right
All changes in the implication of the equivalency asked and scope are included in the present invention.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, but the most each embodiment party
Formula only comprises an independent technical scheme, and this narrating mode of description is only for clarity sake, ability
Field technique personnel should be using description as an entirety, and the technical scheme in each embodiment can also be through suitable group
Close, form other embodiments that it will be appreciated by those skilled in the art that.
Claims (5)
1. the glazed tiles utilizing black earth to prepare, it is characterised in that:
This glazed tiles base substrate weight portion composition is as follows:
Black earth 90-150 part；Magnesium aluminate spinel 20-30 part；Potassium feldspar 8-10 part；Quartz 1-7 part；Magnesium carbonate 1-7 part；Steel fibre 1-7 part；Phenolic resin 1-7 part；Starch 1-7 part；Rice husk 1-7 part；
This glazed tiles glaze weight portion composition is as follows:
Iron oxide yellow 40-50 part；Cobalt oxide 1-5 part；Feldspar powder 1-5 part；Nano zine oxide 1-5 part；Silicon nitride 1-5 part；Carbon fiber 1-5 part；Tin ash 1-5 part；TEOS 1-5 part；Politef 1-5 part；
Its preparation method is as follows:
(1) batch mixing: glazed tiles blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 3 days；
(2) pressed compact molding, compressing under 60Mpa pressure, it is incubated 2 hours, the demoulding；
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, and during kiln discharge, base substrate water content is less than 1.2wt%；
(4) glazing: added water by glaze raw material and prepare glaze, and glazing, glaze thickness is 0.2mm；Dry 24 hours after glazing and at 150 DEG C；
(5) burn till: in calcining kiln, heating rate 80 DEG C/h, after being warming up to 1200 DEG C, be incubated 2 hours, utilize glazed tiles prepared by black earth.
2. one kind utilizes glazed tiles prepared by black earth as claimed in claim 1, it is characterised in that the chemical composition of black earth is: SiO2 45wt%, Al2O335wt%, CaO 10wt%, other compositions 10wt%.
3. one kind utilizes glazed tiles prepared by black earth as claimed in claim 1 or 2, it is characterised in that the particle diameter of magnesium aluminate spinel is less than 1 μm.
4. one kind utilizes glazed tiles prepared by black earth as claimed in claim 1, it is characterised in that this glazed tiles base substrate weight portion composition is as follows:
110 parts of black earth；Magnesium aluminate spinel 25 parts；Potassium feldspar 9 parts；4 parts of quartz；Magnesium carbonate 4 parts；Steel fibre 4 parts；4 parts of phenolic resin；Starch 4 parts；4 parts of rice husk.
5. one kind utilizes glazed tiles prepared by black earth as claimed in claim 1, it is characterised in that this glazed tiles glaze weight portion composition is as follows:
Iron oxide yellow 45 parts；Cobalt oxide 4 parts；Feldspar powder 4 parts；Nano zine oxide 4 parts；Silicon nitride 4 parts；4 parts of carbon fiber；Tin ash 4 parts；TEOS 4 parts；Politef 4 parts.
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| CN106116467B (en) * | 2016-06-22 | 2018-11-13 | 嵊州市森汇知识产权运营有限公司 | A method of preparing low fever's glazed tiles using black earth |
| CN106116463A (en) * | 2016-06-22 | 2016-11-16 | 徐晓 | The preparation method of low grade fever's glazed tiles additive |
| CN106242275A (en) * | 2016-08-08 | 2016-12-21 | 太仓市科教新城琉璃艺术策划中心 | The preparation technology of colored drawing coloured glaze |
| CN107417254A (en) * | 2017-06-28 | 2017-12-01 | 常州市沃兰特电子有限公司 | A kind of easy fired antique glazed tile and preparation method thereof |
| CN107265851A (en) * | 2017-07-24 | 2017-10-20 | 太仓市科教新城琉璃艺术策划中心 | A kind of coloured glaze containing black earth composition |
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| CN103538141B (en) * | 2013-10-15 | 2015-08-26 | 常熟大象建陶有限公司 | The preparation method of colored glaze ceramic tile and the method shaped device used |
| CN103693993A (en) * | 2013-12-23 | 2014-04-02 | 宾阳县明翔新材料科技有限公司 | Ceramic tile with heat-preservation and heat-insulation functions and production method of same |
| CN103833325B (en) * | 2014-01-04 | 2015-05-27 | 安徽省含山瓷业股份有限公司 | Low-cost domestic ceramic containing laterite |
| CN104860644A (en) * | 2015-05-29 | 2015-08-26 | 苏州拓科仪器设备有限公司 | Underglaze blue and underglaze red glaze ceramic |
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