CN103693994A - Color-changing glaze tile and production method thereof - Google Patents

Color-changing glaze tile and production method thereof Download PDF

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Publication number
CN103693994A
CN103693994A CN201310715354.XA CN201310715354A CN103693994A CN 103693994 A CN103693994 A CN 103693994A CN 201310715354 A CN201310715354 A CN 201310715354A CN 103693994 A CN103693994 A CN 103693994A
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ceramic tile
parts
glaze
weight
changing colour
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农韦健
阮付贤
贾艳桦
陶靖
梁剑
倪海明
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BINYANG MINGXIANG NEW MATERIAL SCIENCE & TECHNOLOGY Co Ltd
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BINYANG MINGXIANG NEW MATERIAL SCIENCE & TECHNOLOGY Co Ltd
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Abstract

The invention discloses a color-changing glaze tile and a production method thereof, belonging to the technical field of tiles. The color-changing glaze tile consists of a color-changing glaze face and a tile blank, and is obtained by the steps of: respectively burdening the color-changing glaze face and the tile blank as required, performing ball milling and screening, then spraying color-changing glaze onto the tile blank, and feeding the tile blank to a kiln for one-step firing. The color-changing glaze tile disclosed by the invention has the characteristic of taking on different colors under the irradiation of different light sources, is elegant and attractive, and can be widely applied to the field of construction; the color-changing glaze tile is stable in performance, strong in mechanical performance, excellent in quality, very good in practicability, simple in preparation process, low in investment and production cost, and convenient for implementation of industrialization as well as popularization and application, and can be produced by traditional equipment.

Description

A kind of changing colour enamal ceramic tile and production method thereof
Technical field
The invention belongs to ceramic tile technical field, be specifically related to a kind of changing colour enamal ceramic tile and production method thereof.
Background technology
Glaze is the mixture that several vitrifying oxide compounds (frit) and inorganic additives form; after thermal treatment; on adobe surface, form the vitreous layer of one deck very thin (0.15-1.00); make adobe surface possess good resistance to chemical corrosion, liquid and gas can not penetrate into adobe surface, have easy to clean; smooth surface; wear-resistant, shock resistance, the characteristic such as elegant in appearance.Glaze plays an important role, and not only gives the technical characterictic of adobe uniqueness, and gives adobe distinctive decorative effect.The glaze that is applied to ceramic tile must meet certain requirement, is mainly divided into two large classes.One is relevant to glaze preparation, it is two relevant to the application characteristic of product, for fear of adobe surface glaze, peels off and chaps, reduce surface tension with shrink uneven, between adobe and glaze, must possess good associativity, glaze is melt into uniform important composition raw material.It is, after multiple powder raw material is mixed, at frit, to melt, and various raw materials decompose, interact and be converted into sticking liquid, and after adopting water or gas quick cooling, the frit of granulation shape or glass sheet.When a kind of frit and other frit or with a certain amount of other former suspect mix after, then through frit synthetic with the raw material newly adding, form the different but new frit of uniform component of a kind of from initial frit characteristic.This specific character of frit, makes to utilize limited frit and raw material just can generate different types of glaze.The composition of mainly urging of frit comprises: silicon, aluminium, boron, basic metal, alkaline-earth metal, heavy metal oxide and other metal oxide (being mainly titanium, tin, zinc and zirconium).
Along with the raising of people's quality of life and the transformation of consumption idea, require material of construction ceramic tile should have practicality, there are again artistry and sight.And be practicality, artistry and the sight that improves ceramic tile, often need on glaze, make an effort, by adopting special glaze formula to make to there are the surperficial ceramic tiles of different colour developing, realize.
Changing colour enamal is a kind of special color glaze, can under Different Light is irradiated, present distinct colors.
Chinese patent (application number: 200910254659.9) disclose a kind of metalluster ceramic glaze with color changeable effect and preparation method thereof, it consists of underlying metal ground-coat enamel and variable color cover-coat enamel two portions, respectively underlying metal ground-coat enamel and variable color cover-coat enamel are prepared burden as requested, then add respectively and add respectively water after 0.2~1.2%CMC and carry out ball milling, controlling underlying metal ground-coat enamel fineness is 425mesh sieve all-pass mistake, controls variable color cover-coat enamel fineness 325mesh sieve all-pass mistake.First underlying metal ground-coat enamel is sprayed or watered and drench behind ceramic body surface, again variable color cover-coat enamel is covered on underlying metal ground-coat enamel with spraying or water pouring method, control between 0.1~1.2 millimeter of underlying metal ground-coat enamel glazing thickness, control between 0.1~0.6 millimeter of variable color cover-coat enamel glazing thickness.Dry after ceramic body, at 1150~1210 ℃ of once-firings.Resulting variable color metal glaze has color variation, and glaze quality is good, and mechanical property is strong, and chemical stability is high, has metal-like, under Different Light is irradiated, colour-change can occur.
Chinese patent (application number: 200910047570.5) disclose a kind of can be at the rare-earth ceramic glaze pigment of variable color under Different Light, the variable color neodymium red that is 17-29% by weight percent and the feldspar glaze of 83-71% form; Wherein the weight of variable color neodymium red consists of: SiO2 42-50%, Al2O3 16-24%, CaO 6%, ZnO 5%, B2O3 3%, Nd2O3 12-15%, Er2O35-8%.This rare earth neodymium red stain color glaze, is combined into changing colour enamal product by camouflage paint in glaze porcelain, and it shows distinct colors under Different Light is irradiated.As aobvious light blue under fluorescent light, aobvious lilac under natural light, the next aobvious light green of electricity-saving lamp.Rare earth neodymium red stain color glaze of the present invention also can alleviate the cracked property on glaze, improves glaze glossiness, improves intensity, chemical stability, hardness etc.
At present, variable color glaze has been widely used on the fields such as pottery, ceramic tile, but due to the formula factor such as unreasonable, variable color glaze exists the defects such as preparation cost is high, variable color is uncertain always.
Summary of the invention
The object of this invention is to provide a kind of changing colour enamal ceramic tile, and the preparation method of this ceramic tile.
Concrete, technical scheme of the present invention is:
A changing colour enamal ceramic tile, is comprised of variable color glaze and ceramic tile blank, and its key is, described variable color glaze is comprised of 10-20 weight part camouflage paint and 80-90 weight part basis glaze; Wherein, described camouflage paint comprises that the raw material of following parts by weight forms: SiO 235-45 part; Al 2o 315-25 part; CaO1-10 part; ZnO1-10 part; TiO 21-10 part; B 2o 51-10 part; Nd 2o 55-20 part; Er 2o 31-10 part; Pr 2o 31-10 part; CeO 21-10 part; Y 2o 31-10 part; Described basic glaze comprises that the raw material of following parts by weight forms: potassium felspar sand 15-35 part; Albite 15-35 part; Attapulgite 1-10 part; Kaolin 1-10 part; Calcite 1-10 part; Quartzy 1-10 part; Magnesiumcarbonate powder 1-10 part; Calcium carbonate powders 1-10 part; Described changing colour enamal face thickness is controlled between 0.3-1.5mm, first sprays the methyl aqueous solution that one deck concentration is 0.3-0.8% before glazing on ceramic tile base base.
As further illustrating of such scheme, described ceramic tile blank is comprised of the raw material of following parts by weight: feldspar 30-100 part; Kaolin 15-30 part; Rhombspar 10-20 part; Quartz sand 20-50 part; Talcum powder 5-15 part; Wilkinite 5-15 part; Attapulgite 5-10 part.
As further illustrating of such scheme, described feldspar comprises albite, potassium felspar sand, lithium feldspar.
A production method for changing colour enamal ceramic tile, comprises following concrete production stage:
(1) camouflage paint is prepared by above-mentioned raw materials, added the tackiness agent methylol fiber sodium CMC of camouflage paint gross weight 0.5-1.0%, mix, carry out wet ball grinding, control camouflage paint fineness between 350-500 order;
(2) just basic glaze is prepared by above-mentioned raw materials, adds the tackiness agent methylol fiber sodium CMC of basic glaze gross weight 0.3-0.8%, mixes, and carries out wet ball grinding, controls basic glaze fineness between 350-500 order;
(3) raw material that mixing step (1), (2) obtain by weight ratio, obtains variable color glaze;
(4) before glazing, on ceramic tile blank, first spray the methyl aqueous solution that one deck concentration is 0.3-0.8%, then variable color glaze is executed on ceramic tile blank, control changing colour enamal face thickness between 0.3-1.5mm;
(5) ceramic tile blank of step (4) having been executed to glaze is sent into kiln, burns till ceramic tile work in-process through kiln 1150-1300 ℃ next time, after polishing edging, obtains finished product.
As further illustrating of such scheme, described ceramic tile blank is to mix by above-mentioned raw materials, add the tackiness agent methylol fiber sodium CMC of raw material gross weight 0.5-1.5% and the whipping agent powdered sodium carbonate of 0-1%, then carry out wet ball grinding, control fineness more than 80 orders, on drying tower, powder is made in spraying, utilizes dry press to be squeezed into the ceramic tile blank of certain specification under normal temperature condition.
As further illustrating of such scheme, the kiln firing time of step (5) is 20-120min.
The invention has the beneficial effects as follows:
(1) changing colour enamal ceramic tile of the present invention has the characteristic that presents different colours under Different Light is irradiated, generous attractive in appearance, can be widely used in building field.
(2) changing colour enamal ceramic tile of the present invention stable performance, mechanical property is strong, and Functionality, quality and appealing design possesses good practicality.
(3) to become vitreous brick preparation technology simple in the present invention, uses legacy equipment, less investment, and production cost is low, is convenient to implement industrialization and applies.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in further detail, the present embodiment is only that the present invention is done to clearer explanation, rather than limitation of the present invention.
Embodiment 1
A changing colour enamal ceramic tile, is comprised of variable color glaze and ceramic tile blank, and described variable color glaze is comprised of 15 weight part camouflage paints and 85 weight parts basis glaze; Wherein, described camouflage paint comprises that the raw material of following parts by weight forms: SiO 240 parts; Al 2o 320 parts; CaO4 part; ZnO4 part; TiO 24 parts; B 2o 55 parts; Nd 2o 58 parts; Er 2o 32 parts; Pr 2o 35 parts; CeO 25 parts; Y 2o 33 parts; Described basic glaze comprises that the raw material of following parts by weight forms: 35 parts of potassium felspar sands; 25 parts of albites; 5 parts of attapulgites; 5 parts of kaolin; 7 parts, calcite; Quartzy 8 parts; 7 parts, magnesiumcarbonate powder; 8 parts of calcium carbonate powderss; Described ceramic tile blank is comprised of the raw material of following parts by weight: 30 parts of albites; 45 parts of potassium felspar sands; 15 parts of lithium feldspars; 20 parts of kaolin; 15 parts of rhombspars; 35 parts of quartz sands; 15 parts of talcum powder; 15 parts of wilkinites; 10 parts of attapulgites.
Embodiment 2
A changing colour enamal ceramic tile, is comprised of variable color glaze and ceramic tile blank, and described variable color glaze is comprised of 20 weight part camouflage paints and 80 weight parts basis glaze; Wherein, described camouflage paint comprises that the raw material of following parts by weight forms: SiO 230 parts; Al 2o 325 parts; CaO8 part; ZnO5 part; TiO 24 parts; B 2o 55 parts; Nd 2o 52 parts; Er 2o 38 parts; Pr 2o 33 parts; CeO 25 parts; Y 2o 35 parts; Described basic glaze comprises that the raw material of following parts by weight forms: 20 parts of potassium felspar sands; 35 parts of albites; 10 parts of attapulgites; 10 parts of kaolin; 5 parts, calcite; Quartzy 8 parts; 6 parts, magnesiumcarbonate powder; 6 parts of calcium carbonate powderss; Described ceramic tile blank is comprised of the raw material of following parts by weight: 45 parts of albites; 30 parts of potassium felspar sands; 10 parts of lithium feldspars; 10 parts of kaolin; 10 parts of rhombspars; 50 parts of quartz sands; 10 parts of talcum powder; 15 parts of wilkinites; 10 parts of attapulgites.
Embodiment 3
A changing colour enamal ceramic tile, is comprised of variable color glaze and ceramic tile blank, and described variable color glaze is comprised of 10 weight part camouflage paints and 90 weight parts basis glaze; Wherein, described camouflage paint comprises that the raw material of following parts by weight forms: SiO 230 parts; Al 2o 325 parts; CaO8 part; ZnO5 part; TiO 24 parts; B 2o 55 parts; Nd 2o 52 parts; Er 2o 38 parts; Pr 2o 33 parts; CeO 25 parts; Y 2o 35 parts; Described basic glaze comprises that the raw material of following parts by weight forms: 30 parts of potassium felspar sands; 30 parts of albites; 5 parts of attapulgites; 5 parts of kaolin; 4 parts, calcite; Quartzy 8 parts; 8 parts, magnesiumcarbonate powder; 10 parts of calcium carbonate powderss; Described ceramic tile blank is comprised of the raw material of following parts by weight: 45 parts of albites; 45 parts of potassium felspar sands; 10 parts of lithium feldspars; 15 parts of kaolin; 20 parts of rhombspars; 45 parts of quartz sands; 10 parts of talcum powder; 10 parts of wilkinites; 5 parts of attapulgites.
Embodiment 4
A changing colour enamal ceramic tile, is comprised of variable color glaze and ceramic tile blank, and described variable color glaze is comprised of 15 weight part camouflage paints and 85 weight parts basis glaze; Wherein, described camouflage paint comprises that the raw material of following parts by weight forms: SiO 240 parts; Al 2o 322 parts; CaO5 part; ZnO3 part; TiO 22 parts; B 2o 55 parts; Nd 2o 52 parts; Er 2o 38 parts; Pr 2o 33 parts; CeO 25 parts; Y 2o 35 parts; Described basic glaze comprises that the raw material of following parts by weight forms: 35 parts of potassium felspar sands; 15 parts of albites; 10 parts of attapulgites; 10 parts of kaolin; 10 parts, calcite; Quartzy 8 parts; 6 parts, magnesiumcarbonate powder; 6 parts of calcium carbonate powderss; Described ceramic tile blank is comprised of the raw material of following parts by weight: 30 parts of albites; 30 parts of potassium felspar sands; 40 parts of lithium feldspars; 20 parts of kaolin; 15 parts of rhombspars; 30 parts of quartz sands; 15 parts of talcum powder; 15 parts of wilkinites; 5 parts of attapulgites.
Embodiment 5
A changing colour enamal ceramic tile, is comprised of variable color glaze and ceramic tile blank, and described variable color glaze is comprised of 15 weight part camouflage paints and 85 weight parts basis glaze; Wherein, described camouflage paint comprises that the raw material of following parts by weight forms: SiO 235 parts; Al 2o 330 parts; CaO3 part; ZnO4 part; TiO 25 parts; B 2o 53 parts; Nd 2o 55 parts; Er 2o 35 parts; Pr 2o 34 parts; CeO 23 parts; Y 2o 33 parts; Described basic glaze comprises that the raw material of following parts by weight forms: 15 parts of potassium felspar sands; 35 parts of albites; 8 parts of attapulgites; 8 parts of kaolin; 10 parts, calcite; Quartzy 8 parts; 8 parts, magnesiumcarbonate powder; 8 parts of calcium carbonate powderss; Described ceramic tile blank is comprised of the raw material of following parts by weight: 25 parts of albites; 30 parts of potassium felspar sands; 25 parts of lithium feldspars; 30 parts of kaolin; 20 parts of rhombspars; 45 parts of quartz sands; 15 parts of talcum powder; 5 parts of wilkinites; 5 parts of attapulgites.
Following examples 6-10 is respectively the preparation method of variable color glaze described in corresponding embodiment 1-5, therefore for feed composition, is no longer described.
Embodiment 6
A production method for changing colour enamal ceramic tile, comprises following concrete production stage:
(1) camouflage paint is prepared by above-mentioned raw materials, added the tackiness agent methylol fiber sodium CMC of camouflage paint gross weight 0.8%, mix, carry out wet ball grinding, control camouflage paint fineness between 400 orders;
(2) just basic glaze is prepared by above-mentioned raw materials, adds the tackiness agent methylol fiber sodium CMC of basic glaze gross weight 0.5%, mixes, and carries out wet ball grinding, controls basic glaze fineness between 500 orders;
(3) raw material that mixing step (1), (2) obtain by weight ratio, obtains variable color glaze;
(4) constitutive material described in ceramic tile blank is mixed, add the tackiness agent methylol fiber sodium CMC of raw material gross weight 1.0% and 0.3% whipping agent powdered sodium carbonate, then carry out wet ball grinding, control fineness more than 80 orders, on drying tower, powder is made in spraying, utilizes dry press to be squeezed into the ceramic tile blank of certain specification under normal temperature condition.
(5) on ceramic tile blank, first spraying one deck concentration before glazing is 0.5% the methyl aqueous solution, then variable color glaze is executed on ceramic tile blank, controls changing colour enamal face thickness between 0.9mm;
(6) ceramic tile blank of step (5) having been executed to glaze is sent into kiln, through 1220 ℃ of kilns, burns till (time be 30 quick) ceramic tile work in-process next time, after polishing edging, obtains finished product.
Embodiment 7
A production method for changing colour enamal ceramic tile, comprises following concrete production stage:
(1) camouflage paint is prepared by above-mentioned raw materials, added the tackiness agent methylol fiber sodium CMC of camouflage paint gross weight 0.3%, mix, carry out wet ball grinding, control camouflage paint fineness between 450 orders;
(2) just basic glaze is prepared by above-mentioned raw materials, adds the tackiness agent methylol fiber sodium CMC of basic glaze gross weight 0.5%, mixes, and carries out wet ball grinding, controls basic glaze fineness between 500 orders;
(3) raw material that mixing step (1), (2) obtain by weight ratio, obtains variable color glaze;
(4) constitutive material described in ceramic tile blank is mixed, add the tackiness agent methylol fiber sodium CMC of raw material gross weight 1.2% and 0.5% whipping agent powdered sodium carbonate, then carry out wet ball grinding, control fineness more than 100 orders, on drying tower, powder is made in spraying, utilizes dry press to be squeezed into the ceramic tile blank of certain specification under normal temperature condition.
(5) on ceramic tile blank, first spraying one deck concentration before glazing is 0.4% the methyl aqueous solution, then variable color glaze is executed on ceramic tile blank, controls changing colour enamal face thickness between 0.5mm;
(6) ceramic tile blank of step (5) having been executed to glaze is sent into kiln, through 1200 ℃ of kilns, burns till (time be 40 quick) ceramic tile work in-process next time, after polishing edging, obtains finished product.
Embodiment 8
A production method for changing colour enamal ceramic tile, comprises following concrete production stage:
(1) camouflage paint is prepared by above-mentioned raw materials, added the tackiness agent methylol fiber sodium CMC of camouflage paint gross weight 1.0%, mix, carry out wet ball grinding, control camouflage paint fineness between 350 orders;
(2) just basic glaze is prepared by above-mentioned raw materials, adds the tackiness agent methylol fiber sodium CMC of basic glaze gross weight 0.3%, mixes, and carries out wet ball grinding, controls basic glaze fineness between 450 orders;
(3) raw material that mixing step (1), (2) obtain by weight ratio, obtains variable color glaze;
(4) constitutive material described in ceramic tile blank is mixed, add the tackiness agent methylol fiber sodium CMC of raw material gross weight 0.6% and 0.6% whipping agent powdered sodium carbonate, then carry out wet ball grinding, more than controlling fineness 100 orders, on drying tower, powder is made in spraying, utilizes dry press to be squeezed into the ceramic tile blank of certain specification under normal temperature condition.
(5) on ceramic tile blank, first spraying one deck concentration before glazing is 0.5% the methyl aqueous solution, then variable color glaze is executed on ceramic tile blank, controls changing colour enamal face thickness between 0.8mm;
(6) ceramic tile blank of step (5) having been executed to glaze is sent into kiln, through 1280 ℃ of kilns, burns till (time is 20min) ceramic tile work in-process next time, after polishing edging, obtains finished product.
Embodiment 9
A production method for changing colour enamal ceramic tile, comprises following concrete production stage:
(1) camouflage paint is prepared by above-mentioned raw materials, added the tackiness agent methylol fiber sodium CMC of camouflage paint gross weight 0.5%, mix, carry out wet ball grinding, control camouflage paint fineness between 500 orders;
(2) just basic glaze is prepared by above-mentioned raw materials, adds the tackiness agent methylol fiber sodium CMC of basic glaze gross weight 0.5%, mixes, and carries out wet ball grinding, controls basic glaze fineness between 350 orders;
(3) raw material that mixing step (1), (2) obtain by weight ratio, obtains variable color glaze;
(4) constitutive material described in ceramic tile blank is mixed, add the tackiness agent methylol fiber sodium CMC of raw material gross weight 0.5% and 0.2% whipping agent powdered sodium carbonate, then carry out wet ball grinding, control fineness more than 150 orders, on drying tower, powder is made in spraying, utilizes dry press to be squeezed into the ceramic tile blank of certain specification under normal temperature condition.
(5) on ceramic tile blank, first spraying one deck concentration before glazing is 0.3% the methyl aqueous solution, then variable color glaze is executed on ceramic tile blank, controls changing colour enamal face thickness between 0.5mm;
(6) ceramic tile blank of step (5) having been executed to glaze is sent into kiln, through 1150 ℃ of kilns, burns till (time is 60min) ceramic tile work in-process next time, after polishing edging, obtains finished product.
Embodiment 10
A production method for changing colour enamal ceramic tile, comprises following concrete production stage:
(1) camouflage paint is prepared by above-mentioned raw materials, added the tackiness agent methylol fiber sodium CMC of camouflage paint gross weight 0.7%, mix, carry out wet ball grinding, control camouflage paint fineness between 450 orders;
(2) just basic glaze is prepared by above-mentioned raw materials, adds the tackiness agent methylol fiber sodium CMC of basic glaze gross weight 0.5%, mixes, and carries out wet ball grinding, controls basic glaze fineness between 500 orders;
(3) raw material that mixing step (1), (2) obtain by weight ratio, obtains variable color glaze;
(4) by above-mentioned raw materials, mix, add the tackiness agent methylol fiber sodium CMC of raw material gross weight 1.0% and 0.5% whipping agent powdered sodium carbonate, then carry out wet ball grinding, control fineness more than 150 orders, on drying tower, powder is made in spraying, utilizes dry press to be squeezed into the ceramic tile blank of certain specification under normal temperature condition.
(5) on ceramic tile blank, first spraying one deck concentration before glazing is 0.5% the methyl aqueous solution, then variable color glaze is executed on ceramic tile blank, controls changing colour enamal face thickness between 1.0mm;
(6) ceramic tile blank of step (5) having been executed to glaze is sent into kiln, through 1200 ℃ of kilns, burns till (time is 30min) ceramic tile work in-process next time, after polishing edging, obtains finished product.

Claims (6)

1. a changing colour enamal ceramic tile, is comprised of variable color glaze and ceramic tile blank, it is characterized in that, described variable color glaze is comprised of 10-20 weight part camouflage paint and 80-90 weight part basis glaze; Wherein,
Described camouflage paint comprises that the raw material of following parts by weight forms: SiO 235-45 part; Al 2o 315-25 part; CaO1-10 part; ZnO1-10 part; TiO 21-10 part; B 2o 51-10 part; Nd 2o 55-20 part; Er 2o 31-10 part; Pr 2o 31-10 part; CeO 21-10 part; Y 2o 31-10 part;
Described basic glaze comprises that the raw material of following parts by weight forms: potassium felspar sand 15-35 part; Albite 15-35 part; Attapulgite 1-10 part; Kaolin 1-10 part; Calcite 1-10 part; Quartzy 1-10 part; Magnesiumcarbonate powder 1-10 part; Calcium carbonate powders 1-10 part;
Described changing colour enamal face thickness is controlled between 0.3-1.5mm, first sprays the methyl aqueous solution that one deck concentration is 0.3-0.8% before glazing on ceramic tile base base.
2. changing colour enamal ceramic tile according to claim 1, is characterized in that, described ceramic tile blank is comprised of the raw material of following parts by weight: feldspar 30-100 part; Kaolin 15-30 part; Rhombspar 10-20 part; Quartz sand 20-50 part; Talcum powder 5-15 part; Wilkinite 5-15 part; Attapulgite 5-10 part.
3. changing colour enamal ceramic tile according to claim 2, it is also just, described feldspar comprises albite, potassium felspar sand, lithium feldspar.
4. the production method of the changing colour enamal ceramic tile as described in as arbitrary in claim 1-3, is characterized in that, the method comprises following concrete production stage:
(1) camouflage paint is prepared by above-mentioned raw materials, added the tackiness agent methylol fiber sodium CMC of camouflage paint gross weight 0.5-1.0%, mix, carry out wet ball grinding, control camouflage paint fineness between 350-500 order;
(2) just basic glaze is prepared by above-mentioned raw materials, adds the tackiness agent methylol fiber sodium CMC of basic glaze gross weight 0.3-0.8%, mixes, and carries out wet ball grinding, controls basic glaze fineness between 350-500 order;
(3) raw material that mixing step (1), (2) obtain by weight ratio, obtains variable color glaze;
(4) before glazing, on ceramic tile blank, first spray the methyl aqueous solution that one deck concentration is 0.3-0.8%, then variable color glaze is executed on ceramic tile blank, control changing colour enamal face thickness between 0.3-1.5mm;
(5) ceramic tile blank of step (4) having been executed to glaze is sent into kiln, burns till ceramic tile work in-process through kiln 1150-1300 ℃ next time, after polishing edging, obtains finished product.
5. the production method of changing colour enamal ceramic tile according to claim 4, it is characterized in that, described ceramic tile blank is to mix by above-mentioned raw materials, add the tackiness agent methylol fiber sodium CMC of raw material gross weight 0.5-1.5% and the whipping agent powdered sodium carbonate of 0-1%, then carry out wet ball grinding, control fineness more than 80 orders, on drying tower, powder is made in spraying, utilizes dry press to be squeezed into the ceramic tile blank of certain specification under normal temperature condition.
6. according to the production method of the changing colour enamal ceramic tile described in claim 4 or 5, it is characterized in that, the kiln firing time of step (5) is 20-120min.
CN201310715354.XA 2013-12-23 2013-12-23 Color-changing glaze tile and production method thereof Pending CN103693994A (en)

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CN114907101A (en) * 2021-02-08 2022-08-16 Oppo广东移动通信有限公司 Shell assembly, preparation method and electronic equipment
CN114907094A (en) * 2022-05-23 2022-08-16 吴佘斌 Ceramic tile for realizing superfine gap and production process thereof

Cited By (18)

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CN105565901A (en) * 2014-10-08 2016-05-11 陈能谟 Red glaze and preparation process thereof
CN107827432A (en) * 2017-11-09 2018-03-23 佛山恒泰红狮陶瓷有限公司 A kind of preparation technology of the homogeneous transmutation brick of transmutation effect
CN107827432B (en) * 2017-11-09 2018-10-19 佛山恒泰红狮陶瓷有限公司 A kind of preparation process for the transmutation brick that transmutation effect is uniform
CN109336391A (en) * 2018-12-25 2019-02-15 佛山科学技术学院 A kind of rare earth color-change ceramic glaze and preparation method thereof
CN110436936A (en) * 2019-08-09 2019-11-12 东莞市唯美陶瓷工业园有限公司 A kind of photochromic Ceramic Tiles of decorative pattern and preparation method thereof
CN110436936B (en) * 2019-08-09 2022-01-11 东莞市唯美陶瓷工业园有限公司 Photochromic ceramic tile with decorative patterns and preparation method thereof
CN111170638A (en) * 2020-01-20 2020-05-19 陈漫霞 Super stain-resistant ceramic tile color-preserving glaze, stain-resistant ceramic tile and preparation process thereof
CN111499194A (en) * 2020-04-23 2020-08-07 潮州市智信新材料科技有限公司 Preparation method of pearlescent colorful refractive antibacterial ceramic product
CN111943728A (en) * 2020-08-19 2020-11-17 佛山欧神诺陶瓷有限公司 Pattern-penetrating glaze and preparation method thereof, pattern-penetrating glazed brick and preparation method thereof
CN111943728B (en) * 2020-08-19 2023-01-13 佛山欧神诺陶瓷有限公司 Pattern-penetrating glaze and preparation method thereof, pattern-penetrating glazed brick and preparation method thereof
CN114907101A (en) * 2021-02-08 2022-08-16 Oppo广东移动通信有限公司 Shell assembly, preparation method and electronic equipment
CN113773114A (en) * 2021-09-24 2021-12-10 童心笛 Glaze color painted ceramic tile with shadow effect and preparation method thereof
CN113800952B (en) * 2021-09-24 2022-12-23 童心笛 Glazed tile with artistic effect and preparation method thereof
CN113800952A (en) * 2021-09-24 2021-12-17 童心笛 Glazed tile with artistic effect and preparation method thereof
CN113979723A (en) * 2021-12-09 2022-01-28 马伟忠 Method for making multifunctional far infrared humidity-regulating building material
CN114907013A (en) * 2022-04-21 2022-08-16 景德镇陶瓷大学 Preparation and application method of once-fired black-and-white ink glaze
CN114907013B (en) * 2022-04-21 2024-01-12 景德镇陶瓷大学 Preparation and application method of one-time firing black-white interphase ink glaze
CN114907094A (en) * 2022-05-23 2022-08-16 吴佘斌 Ceramic tile for realizing superfine gap and production process thereof

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