CN104944907B - A kind of glazed tiles utilizing Suzhou soil to prepare - Google Patents

A kind of glazed tiles utilizing Suzhou soil to prepare Download PDF

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CN104944907B
CN104944907B CN201510289465.8A CN201510289465A CN104944907B CN 104944907 B CN104944907 B CN 104944907B CN 201510289465 A CN201510289465 A CN 201510289465A CN 104944907 B CN104944907 B CN 104944907B
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parts
glazed tiles
suzhou soil
glaze
base substrate
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CN104944907A (en
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张锋超
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Zhejiang Jiayuan Horticultural Landscape Co ltd
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Abstract

The present invention relates to a kind of glazed tiles utilizing Suzhou soil to prepare, this glazed tiles base substrate is made up of Suzhou soil, schmigel, albite, quartz, fused magnesite, organic fiber, phenolic resin, starch and rice husk;This glazed tiles glaze is made up of iron oxide yellow, yttrium stable zirconium oxide, feldspar powder, nano zine oxide, carborundum, carbon fiber, tin ash, TEOS, politef, this glazed tiles smooth surface is clean and tidy, bright in colour beautiful, there is excellent resistance to compression, the fire-resistant and performance of acid and alkali-resistance, and light weight, water absorption rate is low, good permeability, low cost.

Description

A kind of glazed tiles utilizing Suzhou soil to prepare
Technical field
The invention belongs to glazed tiles field, particularly to a kind of glazed tiles utilizing Suzhou soil to prepare.
Background technology
Glazed tiles are one ancient, traditional ceramic materials of China.Along with the development of tourist industry, people are for the demand of glazed tiles Also it is more and more, is also more and more higher to its requirement.
Glazed tiles, material is firm, bright in luster, glaze colours is smooth, and always as the building object of Chinese tradition, it is through the successive dynasties Development, the improvement of quality, owing to having multiple excellent function, and it is widely used in modern architecture.
Existing glazed tiles are the most all to use multiple pug mixed sintering to form, and its glaze layer is the thickest and produces stress, quality Weight, is easily caused product glaze and be full of cracks occurs, collapse the defect of stripping.The most smooth, and pug is easily generated dirt in process of production Dye, cost and energy consumption are high, and the quality of product is not sufficiently stable, and its glaze glossiness is inadequate, and colour generation is abundant not, stable, at gas Wait and easily fade under changeable area or long sunlight irradiation.
Present invention mainly solves technical problem is that: for the deficiencies in the prior art, it is provided that a kind of coloured glaze utilizing Suzhou soil to prepare Watt, this glazed tiles smooth surface is clean and tidy, bright in colour beautiful, has excellent resistance to compression, the fire-resistant and performance of acid and alkali-resistance, and matter Amount is light, and water absorption rate is low, good permeability, low cost.
Summary of the invention
It is an object of the invention to, for the problems referred to above, develop a kind of glazed tiles utilizing Suzhou soil to prepare, by optimizing glazed tiles Base substrate and the composition of glaze, improve the colouring effect of glazed tiles, resistance to compression, the fire-resistant and performance of acid and alkali-resistance and water absorption rate and thoroughly The physical and chemical performances such as gas.
A kind of glazed tiles utilizing Suzhou soil to prepare, this glazed tiles base substrate weight portion composition is as follows:
Suzhou soil 90-140 part;Schmigel 20-30 part;Albite 8-10 part;Quartz 1-6 part;Fused magnesite 1-6 part; Organic fiber 1-6 part;Phenolic resin 1-6 part;Starch 1-6 part;Rice husk 1-6 part;
This glazed tiles glaze weight portion composition is as follows:
Iron oxide yellow 40-50 part;Yttrium stable zirconium oxide 1-6 part;Feldspar powder 1-6 part;Nano zine oxide 1-6 part;Carborundum 1-6 part;Carbon fiber 1-6 part;Tin ash 1-6 part;TEOS 1-6 part;Politef 1-6 part;
Its preparation method is as follows:
(1) batch mixing: glazed tiles blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 2 days;
(2) pressed compact molding, compressing under 50MPa pressure, it is incubated 2 hours, the demoulding;
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, and during kiln discharge, base substrate water content is less than 1.2wt%;
(4) glazing: added water by glaze raw material and prepare glaze, and glazing, glaze thickness is 0.2mm;After glazing and 150 Dry 24 hours at DEG C;
(5) burn till: in calcining kiln, heating rate 60 DEG C/h, after being warming up to 1450 DEG C, be incubated 2 hours, Utilize glazed tiles prepared by Suzhou soil.
As preferably, the chemical composition of Suzhou soil is: SiO248wt%, Al2O339wt%, CaO 7%, other compositions 6wt%.
As preferably, the particle diameter of schmigel is less than 1 μm.
As preferably, this glazed tiles base substrate weight portion composition is as follows:
110 parts of Suzhou soil;Schmigel 25 parts;Albite 9 parts;5 parts of quartz;Fused magnesite 5 parts;Organic fiber 5 Part;5 parts of phenolic resin;Starch 5 parts;5 parts of rice husk.
As preferably, this glazed tiles glaze weight portion composition is as follows:
Iron oxide yellow 45 parts;Yttrium stable zirconium oxide 5 parts;Feldspar powder 5 parts;Nano zine oxide 5 parts;Carborundum 5 parts;Carbon Fiber 5 parts;Tin ash 5 parts;TEOS 5 parts;Politef 5 parts.
Beneficial effects of the present invention:
(1) generally speaking, by optimizing glazed tiles base substrate and the composition of glaze, improve the colouring effect of glazed tiles, resistance to compression, The performance of fire-resistant and acid and alkali-resistance and the physical and chemical performance such as water absorption rate and breathability;This glazed tiles smooth surface is clean and tidy, bright in colour bright Beautiful, there is excellent resistance to compression, the fire-resistant and performance of acid and alkali-resistance, and light weight, water absorption rate is low, good permeability, low cost.Should The water absorption rate of glazed tiles is less than 4.6%, and comprcssive strength is more than 70MPa.
(2) in base substrate dispensing, being the first primary raw material with Suzhou soil, schmigel is the second primary raw material, and assists sodium long Stone, quartz, fused magnesite, organic fiber, phenolic resin, starch and rice husk, and form by optimizing the weight portion of each component, The resistance to compression of customer service Suzhou soil is strong, the imperfect deficiency of stability, and optimizes water suction and the permeability of base substrate.And due to Suzhou soil has preferable viscosity, and preferable with the combination of glaze layer, therefore, glaze layer can be the thinnest, such that it is able to prevent glaze There is be full of cracks, collapses the defect of stripping in face.Meanwhile, Suzhou soil carries color (pure white), also can be bright to the color that glazed tiles are overall Degree produces material impact.
(3) by with the addition of yttrium stable zirconium oxide and carborundum in glaze, the toughness of surface layer can be improved, and nano oxygen Change zinc, the automatically cleaning effect of glazed tiles can be played;And feldspar powder can play the effect of sintering aid;And TEOS and poly-four The interpolation of fluorothene, can carry out effective surface protection for glazed tiles, improve the smooth degree on surface.Prepared by the application Glazed tiles smooth surface out is clean and tidy, bright in colour beautiful, and has preferable stability.
Detailed description of the invention
Below in conjunction with specific embodiment, and with reference to data, the present invention is described in further detail.Should be understood that these The embodiment present invention solely for the purpose of illustration, rather than limit the scope of the present invention by any way.
Embodiment 1:
A kind of glazed tiles utilizing Suzhou soil to prepare,
This glazed tiles base substrate weight portion composition is as follows:
110 parts of Suzhou soil;Schmigel 25 parts;Albite 9 parts;5 parts of quartz;Fused magnesite 5 parts; Organic fiber 5 parts;5 parts of phenolic resin;Starch 5 parts;5 parts of rice husk;
This glazed tiles glaze weight portion composition is as follows,
Iron oxide yellow 45 parts;Yttrium stable zirconium oxide 5 parts;Feldspar powder 5 parts;Nano zine oxide 5 parts;Carbonization Silicon 5 parts;5 parts of carbon fiber;Tin ash 5 parts;TEOS 5 parts;Politef 5 parts;
The chemical composition of Suzhou soil is: SiO248wt%, Al2O339wt%, CaO 7%, other compositions 6wt%.
The particle diameter of schmigel is less than 1 μm.
Its preparation method is as follows:
(1) batch mixing: glazed tiles blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 2 days;
(2) pressed compact molding, compressing under 50MPa pressure, it is incubated 2 hours, the demoulding;
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, and during kiln discharge, base substrate water content is less than 1.2wt %;
(4) glazing: added water by glaze raw material and prepare glaze, and glazing, glaze thickness is 0.2mm;Glazing Afterwards and dry 24 hours at 150 DEG C;
(5) burn till: in calcining kiln, heating rate 60 DEG C/h, after being warming up to 1450 DEG C, be incubated 2 Hour, utilize glazed tiles prepared by Suzhou soil.
Embodiment 2:
A kind of glazed tiles utilizing Suzhou soil to prepare,
This glazed tiles base substrate weight portion composition is as follows:
112 parts of Suzhou soil;Schmigel 26 parts;Albite 8 parts;5 parts of quartz;Fused magnesite 4 parts; Organic fiber 5 parts;4 parts of phenolic resin;Starch 5 parts;5 parts of rice husk;
This glazed tiles glaze weight portion composition is as follows,
Iron oxide yellow 46 parts;Yttrium stable zirconium oxide 5 parts;Feldspar powder 2 parts;Nano zine oxide 2 parts;Carbonization Silicon 5 parts;5 parts of carbon fiber;Tin ash 2 parts;TEOS 5 parts;Politef 5 parts;
The chemical composition of Suzhou soil is: SiO248wt%, Al2O339wt%, CaO 7%, other compositions 6wt%.
The particle diameter of schmigel is less than 1 μm.
Its preparation method is as follows:
(1) batch mixing: glazed tiles blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 2 days;
(2) pressed compact molding, compressing under 50MPa pressure, it is incubated 2 hours, the demoulding;
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, and during kiln discharge, base substrate water content is less than 1.2wt %;
(4) glazing: added water by glaze raw material and prepare glaze, and glazing, glaze thickness is 0.2mm;Glazing Afterwards and dry 24 hours at 150 DEG C;
(5) burn till: in calcining kiln, heating rate 60 DEG C/h, after being warming up to 1450 DEG C, be incubated 2 Hour, utilize glazed tiles prepared by Suzhou soil.
Embodiment 3:
A kind of glazed tiles utilizing Suzhou soil to prepare,
This glazed tiles base substrate weight portion composition is as follows:
109 parts of Suzhou soil;Schmigel 22 parts;Albite 9 parts;5 parts of quartz;Fused magnesite 5 parts; Organic fiber 5 parts;5 parts of phenolic resin;Starch 5 parts;5 parts of rice husk;
This glazed tiles glaze weight portion composition is as follows,
Iron oxide yellow 42 parts;Yttrium stable zirconium oxide 5 parts;Feldspar powder 2 parts;Nano zine oxide 2 parts;Carbonization Silicon 2 parts;5 parts of carbon fiber;Tin ash 5 parts;TEOS2 part;Politef 2 parts;
The chemical composition of Suzhou soil is: SiO248wt%, Al2O339wt%, CaO 7%, other compositions 6wt%.
The particle diameter of schmigel is less than 1 μm.
Its preparation method is as follows:
(1) batch mixing: glazed tiles blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 2 days;
(2) pressed compact molding, compressing under 50MPa pressure, it is incubated 2 hours, the demoulding;
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, and during kiln discharge, base substrate water content is less than 1.2wt %;
(4) glazing: added water by glaze raw material and prepare glaze, and glazing, glaze thickness is 0.2mm;Glazing Afterwards and dry 24 hours at 150 DEG C;
(5) burn till: in calcining kiln, heating rate 60 DEG C/h, after being warming up to 1450 DEG C, be incubated 2 Hour, utilize glazed tiles prepared by Suzhou soil.
Embodiment 4:
A kind of glazed tiles utilizing Suzhou soil to prepare,
This glazed tiles base substrate weight portion composition is as follows:
119 parts of Suzhou soil;Schmigel 27 parts;Albite 9 parts;2 parts of quartz;Fused magnesite 5 parts; Organic fiber 2 parts;2 parts of phenolic resin;Starch 2 parts;5 parts of rice husk;
This glazed tiles glaze weight portion composition is as follows,
Iron oxide yellow 47 parts;Yttrium stable zirconium oxide 5 parts;Feldspar powder 2 parts;Nano zine oxide 2 parts;Carbonization Silicon 2 parts;2 parts of carbon fiber;Tin ash 2 parts;TEOS2 part;Politef 2 parts;
The chemical composition of Suzhou soil is: SiO248wt%, Al2O339wt%, CaO 7%, other compositions 6wt%.
The particle diameter of schmigel is less than 1 μm.
Its preparation method is as follows:
(1) batch mixing: glazed tiles blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 2 days;
(2) pressed compact molding, compressing under 50MPa pressure, it is incubated 2 hours, the demoulding;
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, and during kiln discharge, base substrate water content is less than 1.2wt %;
(4) glazing: added water by glaze raw material and prepare glaze, and glazing, glaze thickness is 0.2mm;Glazing Afterwards and dry 24 hours at 150 DEG C;
(5) burn till: in calcining kiln, heating rate 60 DEG C/h, after being warming up to 1450 DEG C, be incubated 2 Hour, utilize glazed tiles prepared by Suzhou soil.
Embodiment 5:
A kind of glazed tiles utilizing Suzhou soil to prepare,
This glazed tiles base substrate weight portion composition is as follows:
100 parts of Suzhou soil;Schmigel 20 parts;Albite 9 parts;4 parts of quartz;Fused magnesite 5 parts; Organic fiber 4 parts;5 parts of phenolic resin;Starch 4 parts;5 parts of rice husk;
This glazed tiles glaze weight portion composition is as follows,
Iron oxide yellow 50 parts;Yttrium stable zirconium oxide 5 parts;Feldspar powder 2 parts;Nano zine oxide 2 parts;Carbonization Silicon 2 parts;2 parts of carbon fiber;Tin ash 5 parts;TEOS2 part;Politef 2 parts;
The chemical composition of Suzhou soil is: SiO248wt%, Al2O339wt%, CaO 7%, other compositions 6wt%.
The particle diameter of schmigel is less than 1 μm.
Its preparation method is as follows:
(1) batch mixing: glazed tiles blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 2 days;
(2) pressed compact molding, compressing under 50MPa pressure, it is incubated 2 hours, the demoulding;
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, and during kiln discharge, base substrate water content is less than 1.2wt %;
(4) glazing: added water by glaze raw material and prepare glaze, and glazing, glaze thickness is 0.2mm;Glazing Afterwards and dry 24 hours at 150 DEG C;
(5) burn till: in calcining kiln, heating rate 60 DEG C/h, after being warming up to 1450 DEG C, be incubated 2 Hour, utilize glazed tiles prepared by Suzhou soil.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and And without departing from the spirit or essential characteristics of the present invention, it is possible to realize this in other specific forms Bright.Therefore, no matter from the point of view of which point, embodiment all should be regarded as exemplary, and be non-limiting , the scope of the present invention is limited by claims rather than described above, wants it is intended that will fall in right All changes in the implication of the equivalency asked and scope are included in the present invention.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, but the most each embodiment party Formula only comprises an independent technical scheme, and this narrating mode of description is only for clarity sake, ability Field technique personnel should be using description as an entirety, and the technical scheme in each embodiment can also be through suitable group Close, form other embodiments that it will be appreciated by those skilled in the art that.

Claims (5)

1. one kind utilizes glazed tiles prepared by Suzhou soil, it is characterised in that:
This glazed tiles base substrate weight portion composition is as follows:
Suzhou soil 90-140 part;Schmigel 20-30 part;Albite 8-10 part;Quartz 1-6 part;Fused magnesite 1-6 Part;Organic fiber 1-6 part;Phenolic resin 1-6 part;Starch 1-6 part;Rice husk 1-6 part;
This glazed tiles glaze weight portion composition is as follows:
Iron oxide yellow 40-50 part;Yttrium stable zirconium oxide 1-6 part;Feldspar powder 1-6 part;Nano zine oxide 1-6 part; Carborundum 1-6 part;Carbon fiber 1-6 part;Tin ash 1-6 part;TEOS 1-6 part;Politef 1-6 Part;
Its preparation method is as follows:
(1) batch mixing: glazed tiles blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 2 days;
(2) pressed compact molding, compressing under 50MPa pressure, it is incubated 2 hours, the demoulding;
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, and during kiln discharge, base substrate water content is less than 1.2wt %;
(4) glazing: added water by glaze raw material and prepare glaze, and glazing, glaze thickness is 0.2mm;After glazing also Dry 24 hours at 150 DEG C;
(5) burn till: in calcining kiln, heating rate 60 DEG C/h, after being warming up to 1450 DEG C, be incubated 2 hours, Utilize glazed tiles prepared by Suzhou soil.
2. one kind utilizes glazed tiles prepared by Suzhou soil as claimed in claim 1, it is characterised in that Suzhou soil Chemical composition is: SiO248wt%, Al2O339wt%, CaO 7%, other compositions 6wt%.
3. one kind utilizes glazed tiles prepared by Suzhou soil as claimed in claim 1 or 2, it is characterised in that corundum The particle diameter of powder is less than 1 μm.
4. one kind utilizes glazed tiles prepared by Suzhou soil as claimed in claim 1, it is characterised in that these glazed tiles Base substrate weight portion composition is as follows:
110 parts of Suzhou soil;Schmigel 25 parts;Albite 9 parts;5 parts of quartz;Fused magnesite 5 parts;Organic Fiber 5 parts;5 parts of phenolic resin;Starch 5 parts;5 parts of rice husk.
5. one kind utilizes glazed tiles prepared by Suzhou soil as claimed in claim 1, it is characterised in that these glazed tiles Glaze weight portion composition is as follows:
Iron oxide yellow 45 parts;Yttrium stable zirconium oxide 5 parts;Feldspar powder 5 parts;Nano zine oxide 5 parts;Carborundum 5 Part;5 parts of carbon fiber;Tin ash 5 parts;TEOS 5 parts;Politef 5 parts.
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106082961B (en) * 2016-06-22 2018-11-13 嵊州市森汇知识产权运营有限公司 A method of preparing low fever's glazed tiles using Suzhou soil
CN106219974A (en) * 2016-08-08 2016-12-14 太仓市科教新城琉璃艺术策划中心 High-cleanness, high coloured glaze

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* Cited by examiner, † Cited by third party
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CN1101025A (en) * 1993-03-01 1995-04-05 成江 Glazed porcelain
CN1121496A (en) * 1994-10-26 1996-05-01 佘爱华 Baking-free imitation of ancient art and craft glazed tile and making method
CN1143058A (en) * 1996-07-01 1997-02-19 张成华 Preparing method for new type glass tile
CN101851119A (en) * 2009-04-02 2010-10-06 故宫博物院 Glazing resintering technology of unglazed ancient colored glaze components
CN102276149A (en) * 2010-06-09 2011-12-14 故宫博物院 Method for preparing fritted glaze for ancient glazed members
CN104418585B (en) * 2013-08-29 2017-06-16 孙即杰 Ceramics and coloured glaze high temperature molding processes

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