CN1121496A - Baking-free imitation of ancient art and craft glazed tile and making method - Google Patents
Baking-free imitation of ancient art and craft glazed tile and making method Download PDFInfo
- Publication number
- CN1121496A CN1121496A CN94113619A CN94113619A CN1121496A CN 1121496 A CN1121496 A CN 1121496A CN 94113619 A CN94113619 A CN 94113619A CN 94113619 A CN94113619 A CN 94113619A CN 1121496 A CN1121496 A CN 1121496A
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- China
- Prior art keywords
- baking
- cotta
- terra
- cement
- ancient art
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00612—Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Toys (AREA)
Abstract
The face material is composed of cement or magnesium oxide, sand stone, fine sand, powdered quartz, talc powder and pigment, the face material is mixed with acids, gums, ammonium salts, alcoholic, diffuser and coating agent then filled into mould, then cement or magnesium oxide, sand stone, slag, wood dust and fibre are mixed into base material and filled into mould, then the invented product is made up after drying. The face material also may be resin, cyclohexanone peroxide or benzoyl peroxide, cobalt naphthenate or dimethyl aniline and pigment and is filled in mould, then the base material is made from said face material adding stone powder and rubble, then the product is made up by filling said base material on face material.
Description
The invention belongs to building materials and decoration material field.
Existing terra-cotta manufacturing mainly is to have two kinds, a kind of modern waveform chloro-magnesium cement terra-cotta, and main drawback is anti-alkali, and not mildew-resistant is not corrosion-resistant, and UV resistant not easily tarnishes and can grow white hair.Another kind is the terra-cotta by ancient times, traditional technology was produced, by traditional technology is the roof clay tile of firing with 900-1500 ℃ of degree pyritous earth kiln or modernized shaft furnace, and it is produced all its and reaches 40-80 days, and investment is big, ten thousand yuan of 5-400, complex process (tens-tens procedures) energy consumption height, three-waste pollution is serious, and contaminated area is big, the color potlery tile of the glazing of producing can only be list-color or one or two kind of look, the cost height, frangible, be unfavorable for transportation.
Purpose of the present invention just to produce a kind of three-waste free pollution, not anti-alkali becomes mildewed, cost is low, and is non-friable, energy consumption is low, less investment, rich color, technology is simple, baking-free imitation of ancient art terra-cotta with short production cycle.
Summary of the invention of the present invention is such, first kind of baking-free imitation of ancient art terra-cotta, it is characterized in that, A) by natural water 75--90%, acids and salt 3--16%, glue class 2--10%, about the about 3mm of ammonium class thickness, vibrate about 3--5 minute, the cement bed material is added water furnishing cement slurry to going into Mo Nei and dried in the shade 1--3 days again, the maintenance of demoulding water got final product in 5 days.The third baking-free imitation of ancient art terra-cotta, it is characterized in that, A) by resin 80--98%, cyclohexanone peroxide or benzoyl peroxide 0.4--10%, cobalt naphthenate or xylidine 0.5--10%, colorant 0.5--4% forms lining, B) by resin 80--98%, cyclohexanone peroxide or benzoyl peroxide 0.4--10%, cobalt naphthenate or xylidine 0.5--10%, C) at 100% above-mentioned B) in the resin bed material, add 5% stone flour and 5% stone chippings and form bed material.Its manufacture method is such, it is characterized in that A) described lining furnishing pasty state is to going in the mould, the about 3mm of thickness vibrates 3--5 minute, leaves standstill and dries in the shade about 25 minutes, with C) described bed material furnishing pasty state is topped on lining, dry in the shade got final product in 2--3 days.Above-described resin is No. 191 or No. 195.More than the colorant described in three kinds of baking-free imitation of ancient art terra-cotta be the ferric oxide colorant.As red iron oxide, iron oxide black, barba hispanica and oily colorant etc.
Invention effect of the present invention is such, and it is non-friable that baking-free imitation of ancient art of the present invention watt has, and is convenient to carrying, chemical resistance is good, not anti-alkali, fast in colour or amine salt class 2--4%, alcohols 0--5%, light-shielding agent 0--5% forms luminous agent, and pH value is 2--8, B) by cement 50%, silica powder 30%, talcum powder 10%, colorant 10% is formed lining, C) by cement 60%, and sandstone 10%, slag 10%, glass fibre or wood chip 20% are formed the cement bed material.Second kind of baking-free imitation of ancient art terra-cotta, it is characterized in that, A) by 22--28 degree magnesium chloride brine 70--75%, alum or acids and salt 3--16%, glue class 2--10%, diffusant (NNO) 2--5%, alcohols 0--5%, light-shielding agent 0--5%, form luminous agent, B) by magnesium oxide 50%, stone flour 15%, fine sand 15%, talcum powder 10%, colorant 10% is formed lining, C) by 22--28 degree magnesium chloride brine 50%, sand 10%, stone 10%, slag 10%, wood chip 10%, glass fibre 10% is formed bed material.More than acids and the salt described in two kinds of technology watt be oxalic acid or phosphoric acid, amine or amine salt class are aniline or trolamine, alcohols is ethanol or glycerol.The above two kinds of its manufacture method of baking-free imitation of ancient art terra-cotta is such, it is characterized in that with luminous water of A gained and B gained cement lining furnishing pasty state, to going in the mould, property is better than modern waveform chloro-magnesium cement watt, does not ftracture because of temperature Change, and technology is simple, less investment need not take large stretch of factory building or soil, and cost is low, not electricity consumption, three-waste free pollution, light weight is three/two-fold of terra-cotta in ancient times, impact resistance can easily be produced antique imitation process terra-cotta that there emerged a kind of complicated appearance.
Below be several embodiments of the present invention,
Embodiment 1, a kind of baking-free imitation of ancient art terra-cotta is characterized in that, A) by natural water 85%, acids and salt 6%, glue class 4%, ammonium class or amine salt class 3%, alcohols 1%, light-shielding agent 1% is formed luminous agent, and pH value is 2--8, B) by cement 50%, silica powder 30%, talcum powder 10%, colorant 10% is formed lining, C) by cement 60%, and sandstone 10%, slag 10%, glass fibre or wood chip 20% are formed the cement bed material.Acids or salt described in the above technology watt are sulfuric acid, and amine or amine salt class are aniline, and alcohols is an ethanol.Colorant is oily colorant.The above its manufacture method of baking-free imitation of ancient art terra-cotta is such, it is characterized in that luminous water of A gained and B gained cement lining furnishing pasty state, to going in the mould, about the about 3mm of thickness, vibrate about 3 minutes, the cement bed material is added water furnishing cement slurry to going into Mo Nei and dried in the shade 2 days, the maintenance of demoulding water got final product in 5 days again.
Embodiment 2, a kind of baking-free imitation of ancient art terra-cotta is characterized in that, A) by 22--28 degree magnesium chloride brine 73%, and alum or acids and salt 14%, glue class 7%, diffusant (NNO) 3%, alcohols 2%, light-shielding agent 1%, form luminous agent, B) by magnesium oxide 50%, stone flour 15%, fine sand 15%, talcum powder 10%, colorant 10% is formed lining, C) by 22--28 degree magnesium chloride brine 50%, sand 10%, stone 10%, slag 10%, wood chip 10%, glass 10% is formed bed material.Acids and salt described in the above technology watt are phosphoric acid, and amine or amine salt class are trolamine, and alcohols is a glycerol.The above its manufacture method of baking-free imitation of ancient art terra-cotta is such, it is characterized in that luminous water of A gained and B gained cement lining furnishing pasty state, to going in the mould, about the about 3mm of thickness, vibrate about 4 minutes, the cement bed material is added water furnishing cement slurry to going into Mo Nei and dried in the shade 3 days, the maintenance of demoulding water got final product in 5 days again.Used colorant is a red iron oxide.
Embodiment 3, a kind of baking-free imitation of ancient art terra-cotta, it is characterized in that, A) by resin 90%, cyclohexanone peroxide or benzoyl peroxide 4%, cobalt naphthenate or xylidine 3%, colorant 3% is formed lining, B) by resin 90%, cyclohexanone peroxide or benzoyl peroxide 6%, cobalt naphthenate or xylidine 4%, C) at 100% above-mentioned B) add 5% stone flour in the resin bed material, 5% stone chippings is formed bed material.Its manufacture method is such, it is characterized in that A) described lining furnishing pasty state is to going in the mould, the about 3mm of thickness vibrates 3--5 minute, leaves standstill and dries in the shade about 25 minutes, with C) described bed material furnishing pasty state is topped on lining, dry in the shade got final product in 2--3 days.Above-described resin is 191.More than the colorant described in three kinds of baking-free imitation of ancient art terra-cotta be oily colorant or ferric oxide colorant, as iron oxide black, barba hispanica etc.
Claims (10)
1. baking-free imitation of ancient art terra-cotta is characterized in that
A, by natural water 75--90%, acids and salt 3--16%, glue class 2--10%, ammonium class or amine salt class 2--4%, alcohols 0--5%, light-shielding agent 0--5% forms luminous agent, and pH value is 2--8,
B, by cement 50%, silica powder 30%, talcum powder 10%, colorant 10% is formed lining,
C, by cement 60%, sandstone 10%, slag 10%, glass fibre or wood chip 20% are formed the cement bed material.
2. baking-free imitation of ancient art terra-cotta is characterized in that,
A, by 22--28 degree magnesium chloride brine 70--75%, alum or acids and salt 3--16%, glue class 2--10%, diffusant (NNO) 2--5%, alcohols 0--5%, light-shielding agent 0--5% forms luminous agent,
B, by magnesium oxide 50%, stone flour 15%, fine sand 15%, talcum powder 10%, colorant 10% is formed lining,
C, by 20--28 degree magnesium chloride brine 50%, sand 10%, stone 10%, slag 10%, wood chip 10%, glass fibre 10% is formed bed material.
3. as claim 1,2 described baking-free imitation of ancient art terra-cotta is characterized in that described acids is a sulfuric acid.
4. as claim 1,2 described baking-free imitation of ancient art terra-cotta is characterized in that described amine is a trolamine.
5. as claim 1,2 described baking-free imitation of ancient art terra-cotta is characterized in that described alcohols is a glycerol.
6. as claim 1,2 described its manufacture method of baking-free imitation of ancient art terra-cotta, it is characterized in that luminous water of A gained and B gained cement lining furnishing pasty state, to going in the mould, about the about 3mm of thickness, vibrate about 3--5 minute, the cement bed material is added water furnishing cement slurry to going into Mo Nei and dried in the shade 1--3 days again, the maintenance of demoulding water got final product in 5 days.
7. baking-free imitation of ancient art terra-cotta is characterized in that,
A, by resin 80--98%, cyclohexanone peroxide or benzoyl peroxide 0.4--10%, cobalt naphthenate or xylidine 0.5--10%, colorant 0.5--4% forms lining,
B, by resin 80--98%, cyclohexanone peroxide or benzoyl peroxide 0.4--10%, cobalt naphthenate or xylidine 0.5--10%,
C in 100% above-mentioned B item resin bed material, adds 5% stone flour and 5% stone chippings and forms bed material.
8. its manufacture method of baking-free imitation of ancient terra-cotta as claimed in claim 7 is characterized in that the described lining furnishing of A pasty state to going in the mould the about 3mm of thickness, vibrate 3--5 minute, leave standstill and dry in the shade about 25 minutes, the described bed material furnishing of C pasty state is topped on lining, and dry in the shade got final product in 2--3 days.
9. baking-free imitation of ancient art terra-cotta as claimed in claim 7 is characterized in that described resin is No. 191.
10. as claim 1,2,7 described baking-free imitation of ancient art terra-cotta is characterized in that described colorant is oily colorant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN94113619A CN1121496A (en) | 1994-10-26 | 1994-10-26 | Baking-free imitation of ancient art and craft glazed tile and making method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN94113619A CN1121496A (en) | 1994-10-26 | 1994-10-26 | Baking-free imitation of ancient art and craft glazed tile and making method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1121496A true CN1121496A (en) | 1996-05-01 |
Family
ID=5036766
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN94113619A Pending CN1121496A (en) | 1994-10-26 | 1994-10-26 | Baking-free imitation of ancient art and craft glazed tile and making method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1121496A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010076097A1 (en) * | 2008-12-17 | 2010-07-08 | Construction Research & Technology Gmbh | Sealing paste |
| CN104944908A (en) * | 2015-06-01 | 2015-09-30 | 苏州拓科仪器设备有限公司 | Glazed tile produced from purple sandy clay |
| CN104944907A (en) * | 2015-06-01 | 2015-09-30 | 苏州拓科仪器设备有限公司 | Glazed tile produced from Suzhou clay |
| CN107200546A (en) * | 2017-06-12 | 2017-09-26 | 何新桥 | Non-sintered inorganic ceramic brick plate and preparation method thereof |
| CN109231965A (en) * | 2018-11-23 | 2019-01-18 | 安徽建筑大学 | Firing process of glazed tile |
-
1994
- 1994-10-26 CN CN94113619A patent/CN1121496A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010076097A1 (en) * | 2008-12-17 | 2010-07-08 | Construction Research & Technology Gmbh | Sealing paste |
| CN104944908A (en) * | 2015-06-01 | 2015-09-30 | 苏州拓科仪器设备有限公司 | Glazed tile produced from purple sandy clay |
| CN104944907A (en) * | 2015-06-01 | 2015-09-30 | 苏州拓科仪器设备有限公司 | Glazed tile produced from Suzhou clay |
| CN107200546A (en) * | 2017-06-12 | 2017-09-26 | 何新桥 | Non-sintered inorganic ceramic brick plate and preparation method thereof |
| CN109231965A (en) * | 2018-11-23 | 2019-01-18 | 安徽建筑大学 | Firing process of glazed tile |
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| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |