CN109231965A - Firing process of glazed tile - Google Patents

Firing process of glazed tile Download PDF

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Publication number
CN109231965A
CN109231965A CN201811407577.9A CN201811407577A CN109231965A CN 109231965 A CN109231965 A CN 109231965A CN 201811407577 A CN201811407577 A CN 201811407577A CN 109231965 A CN109231965 A CN 109231965A
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Prior art keywords
firing
day
warming
glazed tiles
stove
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CN201811407577.9A
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Chinese (zh)
Inventor
夏云春
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Anhui Jianzhu University
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Anhui Jianzhu University
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Priority to CN201811407577.9A priority Critical patent/CN109231965A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/32Burning methods
    • C04B33/34Burning methods combined with glazing
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/86Glazes; Cold glazes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6562Heating rate
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6567Treatment time
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/66Specific sintering techniques, e.g. centrifugal sintering
    • C04B2235/661Multi-step sintering

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Furnace Details (AREA)

Abstract

The invention relates to the technical field of glazed tiles, in particular to a firing process of glazed tiles, which comprises the following steps: sequentially carrying out primary firing, flameout and water drainage and secondary firing on the primary glazed tile blank in a kiln. The invention can overcome the defects that the tile body is easy to deform and crack and more defective products are caused by the existing glazed tile sintering process.

Description

A kind of firing process of glazed tiles
Technical field
The present invention relates to glazed tiles technical fields, and in particular to a kind of firing process of glazed tiles.
Background technique
In recent years, Chinese people occupies condition and is significantly improved, and people also start to pursue high-grade living conditions, many places People build the single villa formula building of oneself, and the roofing of these buildings mostly uses greatly glazed tiles.
Clay is mostly used to prepare greatly the solid glazed tiles making material sold currently on the market, firing speed is general At 11 days or so, and exist for the non-clay glazed tiles of hollow structure, internal structure and making material and clay glazed tiles Apparent difference will be due to sintering procedure if firing such glazed tiles using traditional glazed tiles process for calcining again Temperature rise is too fast and generates a large amount of substandard products, and some glazed tiles even can also torsional deformation or upper and lower unbaked tile junction generation cracking Deng.Therefore, it is necessary to the firing process to the non-clay glazed tiles with hollow structure to improve.
Summary of the invention
Technical problems based on background technology, the invention proposes a kind of firing process of glazed tiles, existing to overcome There is glazed tiles firing process bring watt body easily-deformable and cracking and the more defect of defect ware.
A kind of firing process of glazed tiles proposed by the present invention, the technique include the following steps:
S1, loading of kiln: it will be sent into stove by surface using the glazed tiles first product that glaze pour glaze completion, and by glazed tiles First product is layered stacked neat and opening down, and the spacing of every piece of glazed tiles first product is 10-15mm, staggeredly puts between every layer It sets, is separated above and below at interval of layer 2-3 with partition;
The glaze is preferably prepared by the raw material of following parts by weight: lead frit powder 84%, Lip river tin rouge and powder end 10%, When preparation, raw material is mixed in proportion for kaolin powder 6%, and it is mixed that water is added according to the ratio that mixture and water are 1:4-5 It closes, and stirs evenly, to pour glaze immediately after mixing evenly, and to scrape off extra glaze after pouring glaze;Remaining glaze is packed into envelope It closes in bucket, to pour glaze before use again after mixing evenly;
S2, envelope kiln: after loading of kiln, with brick by stove door termination, and clay mud 3-5mm is smeared by brick outside envelope kiln brick It seams and closes tightly;When stove door termination, the square kiln temperature that position reserves that side length is 100-150mm among main wicket is observed The closing brick in hole, peep hole lower edge stretches out 100-150mm, and it is vertical to be usually close to peep hole on the outside of peep hole using 2 pieces of bricks It places to block closing;
S4, firing: successively once being fired, flame-out to discharge water, secondary firing;
S5, flame-out cooling: after the completion of firing, closing all fuel valves, and stove stops working rear venting natural cooling;It closes When fuel valve, air compressor and air door are not closed, using burner to being aerated in stove, the air of ventilation Amount is maintained at air capacity when primary firing;
S7, finished product kiln discharge: 4-6 days opening stove doors after stove is flame-out fill the brownish red glazed tiles finished product of firing Vehicle kiln discharge, and it is in barnyard in heaps neatly packed;Kiln temperature must be checked before kiln discharge, when touching patch wicket non-scald on hand with the back of the hand Kiln discharge;When kiln discharge, the quality of finished product coloured glaze semicircular tile must be examined and reject underproof defect ware.
Preferably, in the primary firing, firing time 8-10d, highest firing temperature is 740-750 DEG C.
Preferably, the concrete operations once fired are as follows: be warming up to 110-120 DEG C for first day, fire 2d;Third day rises Temperature fires 2d to 250-300 DEG C;It is warming up within 5th day 450-500 DEG C, fires 1d;It is warming up within 6th day 600-620 DEG C, is fired 1-2d;It is finally warming up to 700-750 DEG C, fires 2-3d.
Preferably, in the primary firing, first day heating rate is 18-24 DEG C/h.
Preferably, the flame-out time to discharge water is 6-8h.
Preferably, the flame-out concrete operations to discharge water are as follows: after the completion of primary fire, all fuel valves are closed, After stove is flame-out, all air holes and Draw off valve at the top of stove are opened, discharged water to stove and are drained in stove all Steam.
Preferably, in the secondary firing, firing time 7-8d, highest firing temperature is 1050-1060 DEG C.
Preferably, the concrete operations of the secondary firing are as follows: be warming up to 780-800 DEG C for first day, fire 2d;Third day rises Temperature fires 2d to 880-900 DEG C;It is warming up within 5th day 980-1000 DEG C, fires 1d;It is warming up within 6th day 1050-1060 DEG C, is burnt 2-3d processed.
Preferably, in the secondary firing, first day heating rate is 156-266 DEG C/h.
A kind of firing process of glazed tiles provided by the invention, is divided into and firing twice, and in sintering procedure, in stove Temperature gradually rises and is kept for certain firing time in each temperature section, can effectively improve the yield rate of glazed tiles, make to burn The defect ware rate of glazed tiles after is greatly lowered, and quality of finished product good, intensity are high, clear, entire body no color differnece, surface It is highly polished without blackspot, it is unlikely to deform and cracks.The operation is simple and convenient for burning process of the invention.
Detailed description of the invention
Fig. 1 is the structural diagram of the present invention;Wherein, 1 is semicircular tile body, and 2 be intermediate gaps layer, and 3 be the hanging edge of a dripping tile.
Specific embodiment
In the following, technical solution of the present invention is described in detail by specific embodiment.
Embodiment 1
A kind of firing process of glazed tiles, the technique include the following steps:
S1, loading of kiln: it will be sent into stove by surface using the glazed tiles first product that glaze pour glaze completion, and by glazed tiles First product is layered stacked neat and opening down, and the spacing of every piece of glazed tiles first product is 13mm, is staggeredly placed between every layer, It is separated above and below at interval of 2 layers with partition;
The glaze is preferably prepared by the raw material of following parts by weight: lead frit powder 84%, Lip river tin rouge and powder end 10%, When preparation, raw material is mixed in proportion for kaolin powder 6%, and it is mixed that water is added according to the ratio that mixture and water are 1:4.5 It closes, and stirs evenly;
S2, envelope kiln: after loading of kiln, with brick by stove door termination, and clay mud 4mm is smeared by brickwork joint outside envelope kiln brick Closing is tight;When stove door termination, the square kiln temperature peep hole that side length is 120mm, observation are reserved in position among main wicket The closing brick of hole lower edge stretches out 120mm, is usually close to peep hole on the outside of peep hole using 2 pieces of bricks and is disposed vertically block and seal It closes;
S4, firing: successively once being fired, flame-out to discharge water, secondary firing;
S5, flame-out cooling: after the completion of firing, closing all fuel valves, and stove stops working rear venting natural cooling;
S7, finished product kiln discharge: 5 days opening stove doors after stove is flame-out, by the brownish red glazed tiles finished product of firing (such as Fig. 1 institute Show) entrucking kiln discharge is carried out, and it is in barnyard in heaps neatly packed;
Wherein, the concrete operations once fired are as follows: be warming up to 115 DEG C for first day, fire 2d;Third day is warming up to 270 DEG C, fire 2d;470 DEG C are warming up within 5th day, 1d is fired;610 DEG C are warming up within 6th day, 2d is fired;Finally it is warming up to 730 DEG C, fire 3d;
In the primary firing, first day heating rate is 20 DEG C/h;
The flame-out time to discharge water is 7h;
The flame-out concrete operations to discharge water are as follows: after the completion of primary fire, close all fuel valves, stove is flame-out Afterwards, all air holes and Draw off valve at the top of stove are opened, discharged water to stove and drain whole steam in stove;
The concrete operations of the secondary firing are as follows: be warming up to 790 DEG C for first day, fire 2d;Third day is warming up to 890 DEG C, Fire 2d;990 DEG C are warming up within 5th day, 1d is fired;1055 DEG C are warming up within 6th day, 3d is fired;
In the secondary firing, first day heating rate is 200 DEG C/h.
Embodiment 2
A kind of firing process of glazed tiles, the technique include the following steps:
S1, loading of kiln: it will be sent into stove by surface using the glazed tiles first product that glaze pour glaze completion, and by glazed tiles First product is layered stacked neat and opening down, and the spacing of every piece of glazed tiles first product is 10mm, is staggeredly placed between every layer, It is separated above and below at interval of 3 layers with partition;
The glaze is preferably prepared by the raw material of following parts by weight: lead frit powder 84%, Lip river tin rouge and powder end 10%, When preparation, raw material is mixed in proportion for kaolin powder 6%, and it is mixed that water is added according to the ratio that mixture and water are 1:4 It closes, and stirs evenly;
S2, envelope kiln: after loading of kiln, with brick by stove door termination, and clay mud 5mm is smeared by brickwork joint outside envelope kiln brick Closing is tight;When stove door termination, the square kiln temperature peep hole that side length is 100mm, observation are reserved in position among main wicket The closing brick of hole lower edge stretches out 150mm, is usually close to peep hole on the outside of peep hole using 2 pieces of bricks and is disposed vertically block and seal It closes;
S4, firing: successively once being fired, flame-out to discharge water, secondary firing;
S5, flame-out cooling: after the completion of firing, closing all fuel valves, and stove stops working rear venting natural cooling;
S7, finished product kiln discharge: 4 days opening stove doors after stove is flame-out, by the brownish red glazed tiles finished product of firing (such as Fig. 1 institute Show) entrucking kiln discharge is carried out, and it is in barnyard in heaps neatly packed;
Wherein, the concrete operations once fired are as follows: be warming up to 120 DEG C for first day, fire 2d;Third day is warming up to 250 DEG C, fire 2d;500 DEG C are warming up within 5th day, 1d is fired;600 DEG C are warming up within 6th day, 2d is fired;Finally it is warming up to 700 DEG C, fire 3d;
In the primary firing, first day heating rate is 18 DEG C/h;
The flame-out time to discharge water is 8h;
The flame-out concrete operations to discharge water are as follows: after the completion of primary fire, close all fuel valves, stove is flame-out Afterwards, all air holes and Draw off valve at the top of stove are opened, discharged water to stove and drain whole steam in stove;
The concrete operations of the secondary firing are as follows: be warming up to 780 DEG C for first day, fire 2d;Third day is warming up to 900 DEG C, Fire 2d;980 DEG C are warming up within 5th day, 1d is fired;1060 DEG C are warming up within 6th day, 2d is fired;
In the secondary firing, first day heating rate is 266 DEG C/h.
Embodiment 3
A kind of firing process of glazed tiles, the technique include the following steps:
S1, loading of kiln: it will be sent into stove by surface using the glazed tiles first product that glaze pour glaze completion, and by glazed tiles First product is layered stacked neat and opening down, and the spacing of every piece of glazed tiles first product is 15mm, is staggeredly placed between every layer, It is separated above and below at interval of 2 layers with partition;
The glaze is preferably prepared by the raw material of following parts by weight: lead frit powder 84%, Lip river tin rouge and powder end 10%, When preparation, raw material is mixed in proportion for kaolin powder 6%, and it is mixed that water is added according to the ratio that mixture and water are 1:5 It closes, and stirs evenly;
S2, envelope kiln: after loading of kiln, with brick by stove door termination, and clay mud 3mm is smeared by brickwork joint outside envelope kiln brick Closing is tight;When stove door termination, the square kiln temperature peep hole that side length is 150mm, observation are reserved in position among main wicket The closing brick of hole lower edge stretches out 100mm, is usually close to peep hole on the outside of peep hole using 2 pieces of bricks and is disposed vertically block and seal It closes;
S4, firing: successively once being fired, flame-out to discharge water, secondary firing;
S5, flame-out cooling: after the completion of firing, closing all fuel valves, and stove stops working rear venting natural cooling;
S7, finished product kiln discharge: 6 days opening stove doors after stove is flame-out, by the brownish red glazed tiles finished product of firing (such as Fig. 1 institute Show) entrucking kiln discharge is carried out, and it is in barnyard in heaps neatly packed;
Wherein, the concrete operations once fired are as follows: be warming up to 110 DEG C for first day, fire 2d;Third day is warming up to 300 DEG C, fire 2d;450 DEG C are warming up within 5th day, 1d is fired;620 DEG C are warming up within 6th day, 1d is fired;Finally it is warming up to 750 DEG C, fire 2d;
In the primary firing, first day heating rate is 24 DEG C/h;
The flame-out time to discharge water is 6h;
The flame-out concrete operations to discharge water are as follows: after the completion of primary fire, close all fuel valves, stove is flame-out Afterwards, all air holes and Draw off valve at the top of stove are opened, discharged water to stove and drain whole steam in stove;
The concrete operations of the secondary firing are as follows: be warming up to 800 DEG C for first day, fire 2d;Third day is warming up to 880 DEG C, Fire 2d;1000 DEG C are warming up within 5th day, 1d is fired;1050 DEG C are warming up within 6th day, 3d is fired;
In the secondary firing, first day heating rate is 156 DEG C/h.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (9)

1. a kind of firing process of glazed tiles, which is characterized in that the technique includes the following steps: base at the beginning of glazed tiles in stove It is inside successively once fired, flame-out to discharge water, secondary firing.
2. the firing process of glazed tiles according to claim 1, which is characterized in that in the primary firing, the firing time is 8-10d, highest firing temperature are 740-750 DEG C.
3. the firing process of glazed tiles according to claim 1 or claim 2, which is characterized in that the concrete operations once fired Are as follows: it is warming up within first day 110-120 DEG C, fires 2d;Third day is warming up to 250-300 DEG C, fires 2d;It is warming up to 450- within 5th day 500 DEG C, fire 1d;It is warming up within 6th day 600-620 DEG C, fires 1-2d;It is finally warming up to 700-750 DEG C, fires 2-3d.
4. the firing process of glazed tiles according to claim 3, which is characterized in that in the primary firing, first day liter Warm rate is 18-24 DEG C/h.
5. the firing process of glazed tiles according to claim 1 or claim 2, which is characterized in that the flame-out time to discharge water is 6- 8h。
6. according to claim 1 or the firing process of 5 glazed tiles, which is characterized in that the flame-out concrete operations to discharge water Are as follows: after the completion of primary fire, successively stop working to stove, discharge water, discharges steam.
7. the firing process of glazed tiles according to claim 1 or claim 2, which is characterized in that in the secondary firing, the firing time For 7-8d, highest firing temperature is 1050-1060 DEG C.
8. according to claim 1 or the firing process of 7 glazed tiles, which is characterized in that the concrete operations of the secondary firing Are as follows: it is warming up within first day 780-800 DEG C, fires 2d;Third day is warming up to 880-900 DEG C, fires 2d;It is warming up to 980- within 5th day 1000 DEG C, fire 1d;It is warming up within 6th day 1050-1060 DEG C, fires 2-3d.
9. the firing process of glazed tiles according to claim 8, which is characterized in that in the secondary firing, first day liter Warm rate is 156-266 DEG C/h.
CN201811407577.9A 2018-11-23 2018-11-23 Firing process of glazed tile Pending CN109231965A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1052651A (en) * 1990-12-31 1991-07-03 崔永福 Low-loss water-saving fast made method for clays burnt product
CN1121496A (en) * 1994-10-26 1996-05-01 佘爱华 Baking-free imitation of ancient art and craft glazed tile and making method
CN104860650A (en) * 2015-06-01 2015-08-26 嘉善星窑新型建材有限公司 Preparation method of acid-resistant and freeze-resistant coal ash glazed tile
KR20180072048A (en) * 2016-12-21 2018-06-29 한국세라믹기술원 Manufacturing method of ceramic tile
CN108503337A (en) * 2018-05-16 2018-09-07 安徽建筑大学 Brown red coal gangue glazed tile and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1052651A (en) * 1990-12-31 1991-07-03 崔永福 Low-loss water-saving fast made method for clays burnt product
CN1121496A (en) * 1994-10-26 1996-05-01 佘爱华 Baking-free imitation of ancient art and craft glazed tile and making method
CN104860650A (en) * 2015-06-01 2015-08-26 嘉善星窑新型建材有限公司 Preparation method of acid-resistant and freeze-resistant coal ash glazed tile
KR20180072048A (en) * 2016-12-21 2018-06-29 한국세라믹기술원 Manufacturing method of ceramic tile
CN108503337A (en) * 2018-05-16 2018-09-07 安徽建筑大学 Brown red coal gangue glazed tile and preparation method thereof

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