CN102276149A - Method for preparing fritted glaze for ancient glazed members - Google Patents

Method for preparing fritted glaze for ancient glazed members Download PDF

Info

Publication number
CN102276149A
CN102276149A CN2010101957731A CN201010195773A CN102276149A CN 102276149 A CN102276149 A CN 102276149A CN 2010101957731 A CN2010101957731 A CN 2010101957731A CN 201010195773 A CN201010195773 A CN 201010195773A CN 102276149 A CN102276149 A CN 102276149A
Authority
CN
China
Prior art keywords
glaze
shrend
mixed grinding
orders
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2010101957731A
Other languages
Chinese (zh)
Inventor
苗建民
王时伟
段鸿莺
李合
康葆强
丁银忠
赵兰
侯佳钰
李媛
窦一村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PALACE MUSEUM
Original Assignee
PALACE MUSEUM
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by PALACE MUSEUM filed Critical PALACE MUSEUM
Priority to CN2010101957731A priority Critical patent/CN102276149A/en
Publication of CN102276149A publication Critical patent/CN102276149A/en
Pending legal-status Critical Current

Links

Abstract

The invention relates to a method for preparing fritted glaze for ancient glazed articles, in particular to a method for preparing glaze for glazing resintering of glaze-striped ancient glazed members and for ancient glazed members, ancient three color glazed ware, common glazed members, art ceramics and other low-temperature glazed and sintered ceramics. The glaze prepared by the method has the characteristics of high glossiness, a serial coefficient of thermal expansion, environment friendliness, low cost, easy implementation n and the like.

Description

A kind of preparation method of coloured glaze fritted glaze modelled after an antique
Technical field
The present invention relates to a kind of preparation method of coloured glaze fritted glaze modelled after an antique, the preparation method who be specifically related to a kind ofly to can be used for shelling that the glazing of glaze coloured glaze in ancient times member is heavily burnt, coloured glaze member modelled after an antique, imitative tri-coloured glazed pottery, common coloured glaze member, the art pottery and other low temperature glaze burns glaze such as pottery.
Background technology
Gluzed enamel is one of low temperature color glaze.Because plumbous oxide has lower fusing point, plays strong fusing assistant effect in glaze, traditional gluzed enamel is as fusing assistant, and red lead content is up to 60~70% more than in the glaze.Because of plumbous oxide has higher specific refractory power, make traditional gluzed enamel can obtain special gloss again, and obtain smooth and bright like a mirror glaze and gorgeous color.But this lead glaze also has its fatal shortcoming, because of lead glaze thermal expansivity height, is difficult to carry out suitable coupling with its base substrate, and because of its poor chemical stability, easily in use gloss dies down, and occurs glaze cracking easily and phenomenon such as come off.Make behind the resintering ancient times the coloured glaze member and coloured glaze member modelled after an antique be difficult to permanent use, the coloured glaze member that uses on the ancient architecture faces the gloss variation and peels off problem such as frequent replacing because of glaze.Simultaneously, plumbous oxide not only costs an arm and a leg but also has toxicity, and its health of firing personnel is worked the mischief, its environment is polluted.In view of the foregoing, the development of lead-free gluzed enamel or low lead frit gluzed enamel is its developing direction.
Summary of the invention:
For the preparation method of the quite similar gluzed enamel of the high plumbous gluzed enamel color of a kind of and ancient times tradition, gloss, texture is provided, and be pollution-free, low-cost, easily enforcement, the coefficient of expansion of glaze is 5.0~9.0 * 10 -6Scope, firing temperature are between 900~1060 ℃, and (coefficient of expansion is 4.5~9.0 * 10 can be applicable to the different material composition -6Between), the coloured glaze base substrate of different firing temperature (between 950~1200 ℃).
For achieving the above object, the technological method that the present invention adopts is: 1) adopt multiple basic metal and alkaline earth metal oxide or its solubility salt material batching to be prepared into frit, and introduce that oxide compounds such as bismuth oxide, Lithium Oxide 98min reach low lead or the coefficient of expansion of leadless glaze under different firing temperatures is low, gloss is high and requirement such as beautiful in colour; 2) adopt the method for founding frit, make plumbous oxide and quartzy congruent melting generate lead silicate, introduce plumbous oxide on a small quantity in frit, guaranteed planeness, slickness and color and luster and the texture effect of easy fired glaze; 3) in special frit, introduce preparation glaze such as coloring oxide and suspension agent, water reducer, use for glazing through grinding to form glaze slip.
Below in conjunction with embodiment the present invention is described in further detail.
Embodiment 1
At first by mass percentage with 15.0% feldspar, 16.0% quartz, 20.2% red lead powder, 20.0% lithionite, 4.0% borax, 3.3% boric acid, 1.5% CaCO 3, 1.5% MgCO 3, 11.0% BaCO 3, 1.5% TiO 2, 2.0% Al (OH) 3Carry out mixed grinding with 4.0% ZnO, after with compound shrend after 1200 ℃ of fusings in High Temperature Furnaces Heating Apparatus, it is standby again the piece material after the shrend to be finely ground to 200 orders;
According to mass percent with 90% frit powder, 5% Suzhou soil, 5% painted ferric oxide and the water that accounts for raw material total amount 60%, 0.3% water reducer and 0.4% suspension agent mixed grinding are to expecting all that 250 orders made glaze slip, then glaze slip is coated in equably on the base after the biscuiting, can makes coloured glaze (glaze) goods 900~920 ℃ of glaze firing.
The physical and chemical performance of this prescription glaze is:
Firing range Glossiness The coefficient of expansion
900~920℃ 90 9.0×10 -6About
Embodiment 2
At first by mass percentage with 24.0% feldspar, 28.0% quartz, 8.5% red lead powder, 10.0% lithionite, 6.0% borax, 5.0% boric acid, 2.5% CaCO 3, 2.0% MgCO 3, 7.5% BaCO 3, 1.0% TiO 2, 2.0% Al (OH) 3Carry out mixed grinding with 3.5% ZnO, after with compound shrend after 1250 ℃ of fusings in High Temperature Furnaces Heating Apparatus, it is standby again the piece material after the shrend to be finely ground to 200 orders;
According to mass percent with 90% frit powder, 5% Suzhou soil, 5% painted ferric oxide and the water that accounts for raw material total amount 60%, 0.3% water reducer and 0.4% suspension agent mixed grinding are to expecting all that 250 orders made glaze slip, then glaze slip is coated in equably on the base after the biscuiting, can makes the gluzed enamel goods 930-960 ℃ of glaze firing.
The physical and chemical performance of this prescription glaze is:
Firing range Glossiness The coefficient of expansion
930~960℃ 90 8.0×10 -6About
Embodiment 3
At first by mass percentage with 26.0% feldspar, 23.0% quartz, 6.5% red lead powder, 11.0% lithionite, 10.0% borax, 9.0% boric acid, 1.0% CaCO 3, 2.0% MgCO 3, 8.0% BaCO 3, 0.5% TiO 2, 0.5% Al (OH) 3Carry out mixed grinding with 2.5% ZnO, after with compound shrend after 1280 ℃ of fusings in High Temperature Furnaces Heating Apparatus, it is standby again the piece material after the shrend to be finely ground to 200 orders;
According to mass percent with 90% frit, 5% Suzhou soil, 5% painted ferric oxide and the water that accounts for raw material total amount 60%, 0.3% water reducer and 0.4% suspension agent mixed grinding are to expecting all that 250 orders made glaze slip, then glaze slip is coated in equably on the base after the biscuiting, can makes the gluzed enamel goods 970~1000 ℃ of glaze firing.
The physical and chemical performance of this prescription glaze is:
Firing range Glossiness The coefficient of expansion
970~1000℃ 83 7.0×10 -6About
Embodiment 4
At first by mass percentage with 29.0% feldspar, 24.0% quartz, 4.0% red lead powder, 9.0% lithionite, 11.0% borax, 11.0% boric acid, 1.5% CaCO 3, 2.0% MgCO 3, 7.0% BaCO 3Carry out mixed grinding with 2.0% ZnO, after with compound shrend after 1300 ℃ of fusings in High Temperature Furnaces Heating Apparatus, it is standby again the piece material after the shrend to be finely ground to 200 orders;
According to mass percent with 93% frit powder, 2% Suzhou soil, 5% painted ferric oxide and account for the water, 0.2% water reducer of raw material total amount 60% and 0.5% suspension agent mixed grinding to expecting all that 250 orders made glaze slip, then glaze slip is coated in equably on the base after the biscuiting, can makes the gluzed enamel goods 1000~1030 ℃ of glaze firing.
The physical and chemical performance of this prescription glaze is:
Firing range Glossiness The coefficient of expansion
1000~1030℃ 78 6.0×10 -6About
Embodiment 5
At first by mass percentage with 31.0% feldspar, 25.0% quartz, 5.5% lithionite, 12.0% borax, 11.0% boric acid, 0.5% CaCO 3, 1.0% MgCO 3, 7.0% BaCO3,5.0% Bi 2O 3Carry out mixed grinding with 2.0% ZnO, after with compound shrend after 1350 ℃ of fusings in High Temperature Furnaces Heating Apparatus, it is standby again the piece material after the shrend to be finely ground to 200 orders:
According to mass percent with 93% frit, 2% Suzhou soil, 5% painted ferric oxide and the water that accounts for raw material total amount 60%, 0.2% water reducer and 0.6% suspension agent mixed grinding are to expecting all that 250 orders made glaze slip, then glaze slip is coated in equably on the base after the biscuiting, can makes coloured glaze (glaze) goods 1030~1060 ℃ of glaze firing.
The physical and chemical performance of this prescription glaze is:
Firing range Glossiness The coefficient of expansion
1030~1060℃ 71 5.0?x?10 -6About
In sum; the preparation method of this coloured glaze fritted glaze modelled after an antique; in the protection work of stripping glaze coloured glaze in ancient times member, in the firing of coloured glaze member modelled after an antique, fire in the work at imitative tri-coloured glazed pottery, common coloured glaze member, the art pottery and low temperature glaze firing pottery etc.; be with a wide range of applications, particularly have great importance and far-reaching influence in the protection of coloured glaze building and the repair in ancient times.

Claims (6)

1. the preparation method of a coloured glaze fritted glaze modelled after an antique is characterized in that utilizing mixed alkali effect to replace plumbous fluxing action.
2. the preparation method of a kind of fritted glaze modelled after an antique according to claim 1 is characterized in that at first by mass percentage with 15.0% feldspar 16.0% quartz, 20.2% red lead powder, 20.0% lithionite, 4.0% borax, 3.3% boric acid, 1.5% CaCO 3, 1.5% MgCO 3, 11.0% BaCO 3, 1.5% TiO 2, 2.0% Al (OH) 3Carry out mixed grinding with 4.0% ZnO, after with compound shrend after 1200 ℃ of fusings in High Temperature Furnaces Heating Apparatus, it is standby again the piece material after the shrend to be finely ground to 200 orders; According to mass percent with 90% frit powder, 5% Suzhou soil, 5% painted ferric oxide and the water that accounts for raw material total amount 60%, 0.3% water reducer and 0.4% suspension agent mixed grinding are to expecting all that 250 orders made glaze slip.
3. the preparation method of a kind of fritted glaze modelled after an antique according to claim 1 is characterized in that at first by mass percentage with 24.0% feldspar 28.0% quartz, 8.5% red lead powder, 10.0% lithionite, 6.0% borax, 5.0% boric acid, 2.5% CaCO 3, 2.0% MgCO 3, 7.5% BaCO 3, 1.0% TiO 2, 2.0% Al (OH) 3Carry out mixed grinding with 3.5% ZnO, after with compound shrend after 1250 ℃ of fusings in High Temperature Furnaces Heating Apparatus, it is standby again the piece material after the shrend to be finely ground to 200 orders; According to mass percent with 90% frit powder, 5% Suzhou soil, 5% painted ferric oxide and the water that accounts for raw material total amount 60%, 0.3% water reducer and 0.4% suspension agent mixed grinding are to expecting all that 250 orders made glaze slip.
4. the preparation method of a kind of fritted glaze modelled after an antique according to claim 1 is characterized in that at first by mass percentage with 26.0% feldspar 23.0% quartz, 6.5% red lead powder, 11.0% lithionite, 10.0% borax, 9.0% boric acid, 1.0% CaCO 3, 2.0% MgCO 3, 8.0% BaCO 3, 0.5% TiO 2, 0.5% Al (OH) 3Carry out mixed grinding with 2.5% ZnO, after with compound shrend after 1280 ℃ of fusings in High Temperature Furnaces Heating Apparatus, it is standby again the piece material after the shrend to be finely ground to 200 orders; According to mass percent with 90% frit, 5% Suzhou soil, 5% painted ferric oxide and the water that accounts for raw material total amount 60%, 0.3% water reducer and 0.4% suspension agent mixed grinding are to expecting all that 250 orders made glaze slip.
5. the preparation method of a kind of fritted glaze modelled after an antique according to claim 1 is characterized in that at first by mass percentage with 29.0% feldspar 24.0% quartz, 4.0% red lead powder, 9.0% lithionite, 11.0% borax, 11.0% boric acid, 1.5% CaCO 3, 2.0% MgCO 3, 7.0% BaCO 3Carry out mixed grinding with 2.0% ZnO, after with compound shrend after 1300 ℃ of fusings in High Temperature Furnaces Heating Apparatus, it is standby again the piece material after the shrend to be finely ground to 200 orders; According to mass percent with 93% frit powder, 2% Suzhou soil, 5% painted ferric oxide and the water that accounts for raw material total amount 60%, 0.2% water reducer and 0.5% suspension agent mixed grinding are to expecting all that 250 orders made glaze slip.
6. the preparation method of a kind of fritted glaze modelled after an antique according to claim 1 is characterized in that at first by mass percentage with 31.0% feldspar 25.0% quartz, 5.5% lithionite, 12.0% borax, 11.0% boric acid, 0.5% CaCO 3, 1.0% MgCO 3, 7.0% BaCO 3, 5.0% Bi 2O 3Carry out mixed grinding with 2.0% ZnO, after with compound shrend after 1350 ℃ of fusings in High Temperature Furnaces Heating Apparatus, it is standby again the piece material after the shrend to be finely ground to 200 orders; According to mass percent with 93% frit, 2% Suzhou soil, 5% painted ferric oxide and the water that accounts for raw material total amount 60%, 0.2% water reducer and 0.6% suspension agent mixed grinding are to expecting all that 250 orders made glaze slip.
CN2010101957731A 2010-06-09 2010-06-09 Method for preparing fritted glaze for ancient glazed members Pending CN102276149A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2010101957731A CN102276149A (en) 2010-06-09 2010-06-09 Method for preparing fritted glaze for ancient glazed members

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2010101957731A CN102276149A (en) 2010-06-09 2010-06-09 Method for preparing fritted glaze for ancient glazed members

Publications (1)

Publication Number Publication Date
CN102276149A true CN102276149A (en) 2011-12-14

Family

ID=45101947

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2010101957731A Pending CN102276149A (en) 2010-06-09 2010-06-09 Method for preparing fritted glaze for ancient glazed members

Country Status (1)

Country Link
CN (1) CN102276149A (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102731147A (en) * 2012-06-14 2012-10-17 卡罗比亚釉料(昆山)有限公司 Frit with good formability
CN103183527A (en) * 2011-12-29 2013-07-03 湖南省明丰达陶瓷琉璃瓦业有限公司 Blue gray glaze for glazed tiles and its firing method
CN103224414A (en) * 2013-04-27 2013-07-31 广东道氏技术股份有限公司 One-time sintered chrome green frit dry particles and preparation method thereof
CN103224415A (en) * 2013-04-27 2013-07-31 广东道氏技术股份有限公司 One-time sintered cobalt blue frit dry particles and preparation method thereof
CN103224329A (en) * 2013-04-27 2013-07-31 广东道氏技术股份有限公司 One-time sintered beige frit dry particles and preparation method thereof
CN103723922A (en) * 2013-12-09 2014-04-16 常熟市永达化工设备厂 Wear-resistant corrosion-resistant enamel glaze with good adhesive force
CN104496557A (en) * 2014-12-04 2015-04-08 谢梓潼 Olive green transparent glaze
CN104944907A (en) * 2015-06-01 2015-09-30 苏州拓科仪器设备有限公司 Glazed tile produced from Suzhou clay
CN104944908A (en) * 2015-06-01 2015-09-30 苏州拓科仪器设备有限公司 Glazed tile produced from purple sandy clay
CN106082961A (en) * 2016-06-22 2016-11-09 徐晓 A kind of method utilizing Suzhou soil to prepare low grade fever's glazed tiles
CN110171985A (en) * 2019-05-09 2019-08-27 潮州市潮安区派陶瓷业有限公司 A kind of low temperature sinter ceramic and preparation method thereof

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103183527A (en) * 2011-12-29 2013-07-03 湖南省明丰达陶瓷琉璃瓦业有限公司 Blue gray glaze for glazed tiles and its firing method
CN102731147A (en) * 2012-06-14 2012-10-17 卡罗比亚釉料(昆山)有限公司 Frit with good formability
CN103224414B (en) * 2013-04-27 2014-09-10 广东道氏技术股份有限公司 One-time sintered chrome green frit dry particles and preparation method thereof
CN103224415A (en) * 2013-04-27 2013-07-31 广东道氏技术股份有限公司 One-time sintered cobalt blue frit dry particles and preparation method thereof
CN103224329A (en) * 2013-04-27 2013-07-31 广东道氏技术股份有限公司 One-time sintered beige frit dry particles and preparation method thereof
CN103224414A (en) * 2013-04-27 2013-07-31 广东道氏技术股份有限公司 One-time sintered chrome green frit dry particles and preparation method thereof
CN103224415B (en) * 2013-04-27 2014-09-10 广东道氏技术股份有限公司 One-time sintered cobalt blue frit dry particles and preparation method thereof
CN103723922A (en) * 2013-12-09 2014-04-16 常熟市永达化工设备厂 Wear-resistant corrosion-resistant enamel glaze with good adhesive force
CN104496557A (en) * 2014-12-04 2015-04-08 谢梓潼 Olive green transparent glaze
CN104496557B (en) * 2014-12-04 2016-10-12 江苏永银化纤有限公司 A kind of olive green clear frit
CN104944907A (en) * 2015-06-01 2015-09-30 苏州拓科仪器设备有限公司 Glazed tile produced from Suzhou clay
CN104944908A (en) * 2015-06-01 2015-09-30 苏州拓科仪器设备有限公司 Glazed tile produced from purple sandy clay
CN106082961A (en) * 2016-06-22 2016-11-09 徐晓 A kind of method utilizing Suzhou soil to prepare low grade fever's glazed tiles
CN106082961B (en) * 2016-06-22 2018-11-13 嵊州市森汇知识产权运营有限公司 A method of preparing low fever's glazed tiles using Suzhou soil
CN110171985A (en) * 2019-05-09 2019-08-27 潮州市潮安区派陶瓷业有限公司 A kind of low temperature sinter ceramic and preparation method thereof

Similar Documents

Publication Publication Date Title
CN102276149A (en) Method for preparing fritted glaze for ancient glazed members
CN101759441B (en) Ceramic glaze and preparation process thereof
CN102249739B (en) Preparation method of carbon-golden metallic luster crystalline glaze
CN105330158A (en) Glaze of brunet ceramic and preparation method of glaze
CN102173875B (en) Preparation method of B2O3-TiO2 series fambe ceramic crystalline glaze
CN106977098B (en) A kind of low-temperature lead-free colored glaze
CN102432342A (en) Preparation method of vanadium-titanium-iron system golden crystal glaze
CN104478217A (en) Environment-friendly copper ruby glass glaze, preparation method of environment-friendly copper ruby glass glaze and method for preparing copper ruby glass glaze surface from environment-friendly copper ruby glass glaze
CN104496554A (en) Jun red glaze and preparation method thereof
CN102603365A (en) Green glaze for ceramic wine bottle and preparation method thereof
CN103044083A (en) Transparent glaze and manufacturing method thereof
CN103193515B (en) One-process fast-fired transparent microcrystalline brick and production process thereof
CN107352800B (en) A kind of unleaded enamel brightness base glaze and its application method
JP2014201477A (en) Low melting point leadless glass composition for ceramics
CN103332965B (en) Golden yellow crystallized dry-granular glaze and using method thereof
CN104891808A (en) Brown crystal glaze composition
CN105152684B (en) Lightweight porcelain low temperature transmutation erythema glaze, method of preparation and use
CN107663022B (en) Celeste jun porcelain glaze and preparation method thereof
CN101508597A (en) Ceramic veneer glaze of electromagnetic furnace and method of producing the same
CN103011905B (en) Lead-free open-flame fast-firing full-frit bone-china glaze and preparation method for same
CN110713345B (en) Enamel color material, preparation method and application in repairing enamel cultural relics painted on porcelain body
CN104591793A (en) Colored high-class daily delicate porcelain and preparation method thereof
CN105236742B (en) Without ground-coat enamel low temperature transmutation zirconium white glaze, method of preparation and use
CN105130191B (en) Lightweight porcelain low temperature transmutation covellite colour glaze, method of preparation and use
CN102010232A (en) Building ceramic aventurine glaze and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20111214