CN104860646A - Glazed tile prepared from black soil - Google Patents
Glazed tile prepared from black soil Download PDFInfo
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- CN104860646A CN104860646A CN201510292856.5A CN201510292856A CN104860646A CN 104860646 A CN104860646 A CN 104860646A CN 201510292856 A CN201510292856 A CN 201510292856A CN 104860646 A CN104860646 A CN 104860646A
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- parts
- cotta
- terra
- black earth
- glaze
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- 239000002689 soil Substances 0.000 title abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 31
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910052596 spinel Inorganic materials 0.000 claims abstract description 18
- 239000011029 spinel Substances 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000010433 feldspar Substances 0.000 claims abstract description 12
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 11
- 229910052581 Si3N4 Inorganic materials 0.000 claims abstract description 11
- 229920002472 Starch Polymers 0.000 claims abstract description 11
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 11
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(II) oxide Inorganic materials [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000835 fiber Substances 0.000 claims abstract description 11
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims abstract description 11
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims abstract description 11
- 239000001095 magnesium carbonate Substances 0.000 claims abstract description 11
- 239000000843 powder Substances 0.000 claims abstract description 11
- 239000010453 quartz Substances 0.000 claims abstract description 11
- 235000009566 rice Nutrition 0.000 claims abstract description 11
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims abstract description 11
- 235000019698 starch Nutrition 0.000 claims abstract description 11
- 239000008107 starch Substances 0.000 claims abstract description 11
- 239000010959 steel Substances 0.000 claims abstract description 11
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 10
- 239000004917 carbon fiber Substances 0.000 claims abstract description 10
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 10
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000758 substrate Substances 0.000 claims description 27
- GANNOFFDYMSBSZ-UHFFFAOYSA-N [AlH3].[Mg] Chemical compound [AlH3].[Mg] GANNOFFDYMSBSZ-UHFFFAOYSA-N 0.000 claims description 17
- 239000002994 raw material Substances 0.000 claims description 16
- 238000002156 mixing Methods 0.000 claims description 14
- 241000209094 Oryza Species 0.000 claims description 10
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 10
- 229910000428 cobalt oxide Inorganic materials 0.000 claims description 10
- 239000010903 husk Substances 0.000 claims description 10
- 229960001708 magnesium carbonate Drugs 0.000 claims description 10
- 235000014380 magnesium carbonate Nutrition 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 229910052700 potassium Inorganic materials 0.000 claims description 10
- 239000011591 potassium Substances 0.000 claims description 10
- 229920003987 resole Polymers 0.000 claims description 10
- 239000004576 sand Substances 0.000 claims description 10
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 9
- 238000001354 calcination Methods 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- 238000007493 shaping process Methods 0.000 claims description 7
- 238000010792 warming Methods 0.000 claims description 7
- 239000002253 acid Substances 0.000 abstract description 5
- -1 magnesium aluminate Chemical class 0.000 abstract 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract 1
- 240000007594 Oryza sativa Species 0.000 abstract 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- IUYLTEAJCNAMJK-UHFFFAOYSA-N cobalt(2+);oxygen(2-) Chemical compound [O-2].[Co+2] IUYLTEAJCNAMJK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 229920001568 phenolic resin Polymers 0.000 abstract 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 abstract 1
- 239000004810 polytetrafluoroethylene Substances 0.000 abstract 1
- 229940072033 potash Drugs 0.000 abstract 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 abstract 1
- 235000015320 potassium carbonate Nutrition 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 description 14
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- 229910052681 coesite Inorganic materials 0.000 description 6
- 230000006835 compression Effects 0.000 description 6
- 238000007906 compression Methods 0.000 description 6
- 229910052593 corundum Inorganic materials 0.000 description 6
- 229910052906 cristobalite Inorganic materials 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 6
- 229910052682 stishovite Inorganic materials 0.000 description 6
- 229910052905 tridymite Inorganic materials 0.000 description 6
- 229910001845 yogo sapphire Inorganic materials 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- 230000009970 fire resistant effect Effects 0.000 description 4
- 239000003973 paint Substances 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 238000004040 coloring Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 238000009423 ventilation Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
Abstract
The invention relates to glazed tile prepared from black soil. The green body of the glazed tile comprises black soil, magnesium aluminate spinel, potash feldspar, quartz, magnesium carbonate, steel fiber, phenol formaldehyde resin, starch and rice hull; glaze of the glazed tile comprises iron oxide yellow, cobaltous oxide, feldspar powder, nano-zinc oxide, silicon nitride, carbon fiber, stannic oxide, TEOS and polytetrafluoroethylene. The glazed tile is smooth and clean in surface and bright in color, has good properties of crush resistance, fire resistance and acid and alkali resistance, and is light in mass, low in water absorption, good in breathability and low in cost.
Description
Technical field
The invention belongs to terra-cotta field, particularly a kind of terra-cotta utilizing black earth to prepare.
Background technology
Terra-cotta are ancient, the traditional stupaliths of one, China.Along with the development of tourism, people are also more and more for the demand of terra-cotta, are also more and more higher to its requirement.
Terra-cotta, material is firm, bright in luster, glaze colours is smooth, and always as the building object of Chinese tradition, it developed through the successive dynasties, the improvement of quality, owing to having multiple excellent function, and is widely used in modern architecture.
Existing terra-cotta are all adopt multiple pug mixed sintering to form usually, and its glaze layer is general thicker and produce stress, quality weight, easily cause product glaze paint to occur be full of cracks, collapse the defect of stripping.Smooth not, and pug easily produces pollution in process of production, cost and energy consumption high, the quality of product is stable not, and its glaze paint glossiness is inadequate, and colour generation is abundant not, stable, easily fades under solar radiation in climate variability area or for a long time.
The technical problem that the present invention mainly solves is: for the deficiencies in the prior art, a kind of terra-cotta utilizing black earth to prepare are provided, this terra-cotta smooth surface is clean and tidy, bright in colour beautiful, there is the performance of excellent resistance to compression, fire-resistant and acid and alkali-resistance, and quality is light, water-intake rate is low, good permeability, and cost is low.
Summary of the invention
The object of the invention is for the problems referred to above, develop a kind of terra-cotta utilizing black earth to prepare, by optimizing the composition of terra-cotta base substrate and glaze, improve the colouring effect of terra-cotta, resistance to compression, the performance of fire-resistant and acid and alkali-resistance and the physical and chemical performance such as water-intake rate and ventilation property.
Utilize terra-cotta prepared by black earth, this terra-cotta base substrate weight part is composed as follows:
Black earth 90-150 part; Magnesium-aluminium spinel 20-30 part; Potassium felspar sand 8-10 part; Quartz 1-7 part; Magnesiumcarbonate 1-7 part; Steel fiber 1-7 part; Resol 1-7 part; Starch 1-7 part; Rice husk 1-7 part;
This terra-cotta glaze weight part is composed as follows:
Iron oxide yellow 40-50 part; Cobalt oxide 1-5 part; Feldspar Powder 1-5 part; Nano zine oxide 1-5 part; Silicon nitride 1-5 part; Carbon fiber 1-5 part; Tindioxide 1-5 part; TEOS 1-5 part; Tetrafluoroethylene 1-5 part;
Its preparation method is as follows:
(1) batch mixing: terra-cotta blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 3 days;
(2) pressed compact is shaping, makes type at 60Mpa pressure, is incubated 2 hours, the demoulding;
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, during kiln discharge, base substrate water-content is less than 1.2wt%;
(4) glazing: glaze raw material is added water and prepares glaze, and glazing, glaze thickness is 0.2mm; Dry 24 hours after glazing and at 150 DEG C;
(5) burn till: in calcining kiln, temperature rise rate 80 DEG C/h, after being warming up to 1200 DEG C, be incubated 2 hours, utilize black earth to prepare terra-cotta.
As preferably, the chemical constitution of black earth is: SiO2 45wt%, Al2O3 35wt%, CaO 10wt%, other compositions 10wt%.
As preferably, the particle diameter of magnesium-aluminium spinel is less than 1 μm.
As preferably, this terra-cotta base substrate weight part is composed as follows:
110 parts, black earth; Magnesium-aluminium spinel 25 parts; Potassium felspar sand 9 parts; 4 parts, quartz; 4 parts, magnesiumcarbonate; Steel fiber 4 parts; 4 parts, resol; Starch 4 parts; 4 parts, rice husk.
As preferably, this terra-cotta glaze weight part is composed as follows:
Iron oxide yellow 45 parts; Cobalt oxide 4 parts; Feldspar Powder 4 parts; Nano zine oxide 4 parts; Silicon nitride 4 parts; 4 parts, carbon fiber; Tindioxide 4 parts; TEOS 4 parts; Tetrafluoroethylene 4 parts.
Beneficial effect of the present invention:
(1) generally speaking, by optimizing the composition of terra-cotta base substrate and glaze, the colouring effect of terra-cotta, resistance to compression, the performance of fire-resistant and acid and alkali-resistance and the physical and chemical performance such as water-intake rate and ventilation property is improved; This terra-cotta smooth surface is clean and tidy, bright in colour beautiful, and have the performance of excellent resistance to compression, fire-resistant and acid and alkali-resistance, and quality is light, water-intake rate is low, good permeability, and cost is low.The water-intake rate of these terra-cotta is less than 5.4%, and ultimate compression strength is greater than 56Mpa.
(2) in base substrate batching, be the first main raw material with black earth, magnesium-aluminium spinel is the second main raw material, and auxiliary potassium felspar sand, quartz, magnesiumcarbonate, steel fiber, resol, starch and rice husk, and the weight part composition by optimizing each component, the resistance to compression of customer service black earth is strong, the imperfect deficiency of stability, and optimizes water suction and the permeability of base substrate.And there is good viscosity due to black earth, better with the keying action of glaze layer, therefore, glaze layer can be very thin, thus can prevent glaze paint from occurring be full of cracks, collapse the defect of stripping.Meanwhile, black earth carries color, also can produce material impact to the colour brightness of terra-cotta entirety.
(3) by with the addition of cobalt oxide and silicon nitride in glaze, the toughness of upper layer can be improved, and nano zine oxide, the automatically cleaning effect of terra-cotta can be played; And Feldspar Powder can play the effect of sintering aid; And the interpolation of TEOS and tetrafluoroethylene, effective surface protection can be carried out for terra-cotta, improve the smooth degree on surface.Terra-cotta smooth surface out prepared by the application is clean and tidy, bright in colour beautiful, and has good stability.
Embodiment
Below in conjunction with specific embodiment, and comparable data describes in further detail the present invention.Should be understood that these embodiments just in order to demonstrate the invention, but not limit the scope of the invention by any way.
Embodiment 1:
Utilize terra-cotta prepared by black earth,
This terra-cotta base substrate weight part is composed as follows:
110 parts, black earth; Magnesium-aluminium spinel 25 parts; Potassium felspar sand 9 parts; 4 parts, quartz; 4 parts, magnesiumcarbonate; Steel fiber 4 parts; 4 parts, resol; Starch 4 parts; 4 parts, rice husk;
This terra-cotta glaze weight part is composed as follows,
Iron oxide yellow 45 parts; Cobalt oxide 4 parts; Feldspar Powder 4 parts; Nano zine oxide 4 parts; Silicon nitride 4 parts; 4 parts, carbon fiber; Tindioxide 4 parts; TEOS 4 parts; Tetrafluoroethylene 4 parts;
The chemical constitution of black earth is: SiO2 45wt%, Al2O3 35wt%, CaO 10wt%, other compositions 10wt%.
The particle diameter of magnesium-aluminium spinel is less than 1 μm.
Its preparation method is as follows:
(1) batch mixing: terra-cotta blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 3 days;
(2) pressed compact is shaping, makes type at 60Mpa pressure, is incubated 2 hours, the demoulding;
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, during kiln discharge, base substrate water-content is less than 1.2wt%;
(4) glazing: glaze raw material is added water and prepares glaze, and glazing, glaze thickness is 0.2mm; Dry 24 hours after glazing and at 150 DEG C;
(5) burn till: in calcining kiln, temperature rise rate 80 DEG C/h, after being warming up to 1200 DEG C, be incubated 2 hours, utilize black earth to prepare terra-cotta.
Embodiment 2:
Utilize terra-cotta prepared by black earth,
This terra-cotta base substrate weight part is composed as follows:
112 parts, black earth; Magnesium-aluminium spinel 26 parts; Potassium felspar sand 8 parts; 4 parts, quartz; 4 parts, magnesiumcarbonate; Steel fiber 4 parts; 4 parts, resol; Starch 4 parts; 4 parts, rice husk;
This terra-cotta glaze weight part is composed as follows,
Iron oxide yellow 46 parts; Cobalt oxide 4 parts; Feldspar Powder 2 parts; Nano zine oxide 2 parts; Silicon nitride 4 parts; 4 parts, carbon fiber; Tindioxide 2 parts; TEOS 4 parts; Tetrafluoroethylene 4 parts;
The chemical constitution of black earth is: SiO2 45wt%, Al2O3 35wt%, CaO 10wt%, other compositions 10wt%.
The particle diameter of magnesium-aluminium spinel is less than 1 μm.
Its preparation method is as follows:
(1) batch mixing: terra-cotta blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 3 days;
(2) pressed compact is shaping, makes type at 60Mpa pressure, is incubated 2 hours, the demoulding;
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, during kiln discharge, base substrate water-content is less than 1.2wt%;
(4) glazing: glaze raw material is added water and prepares glaze, and glazing, glaze thickness is 0.2mm; Dry 24 hours after glazing and at 150 DEG C;
(5) burn till: in calcining kiln, temperature rise rate 80 DEG C/h, after being warming up to 1200 DEG C, be incubated 2 hours, utilize black earth to prepare terra-cotta.
Embodiment 3:
Utilize terra-cotta prepared by black earth,
This terra-cotta base substrate weight part is composed as follows:
109 parts, black earth; Magnesium-aluminium spinel 22 parts; Potassium felspar sand 9 parts; 5 parts, quartz; 5 parts, magnesiumcarbonate; Steel fiber 5 parts; 5 parts, resol; Starch 5 parts; 5 parts, rice husk;
This terra-cotta glaze weight part is composed as follows,
Iron oxide yellow 42 parts; Cobalt oxide 4 parts; Feldspar Powder 2 parts; Nano zine oxide 2 parts; Silicon nitride 2 parts; 4 parts, carbon fiber; Tindioxide 4 parts; TEOS2 part; Tetrafluoroethylene 2 parts;
The chemical constitution of black earth is: SiO2 45wt%, Al2O3 35wt%, CaO 10wt%, other compositions 10wt%.
The particle diameter of magnesium-aluminium spinel is less than 1 μm.
Its preparation method is as follows:
(1) batch mixing: terra-cotta blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 3 days;
(2) pressed compact is shaping, makes type at 60Mpa pressure, is incubated 2 hours, the demoulding;
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, during kiln discharge, base substrate water-content is less than 1.2wt%;
(4) glazing: glaze raw material is added water and prepares glaze, and glazing, glaze thickness is 0.2mm; Dry 24 hours after glazing and at 150 DEG C;
(5) burn till: in calcining kiln, temperature rise rate 80 DEG C/h, after being warming up to 1200 DEG C, be incubated 2 hours, utilize black earth to prepare terra-cotta.
Embodiment 4:
Utilize terra-cotta prepared by black earth,
This terra-cotta base substrate weight part is composed as follows:
119 parts, black earth; Magnesium-aluminium spinel 27 parts; Potassium felspar sand 9 parts; 2 parts, quartz; 5 parts, magnesiumcarbonate; Steel fiber 2 parts; 2 parts, resol; Starch 2 parts; 5 parts, rice husk;
This terra-cotta glaze weight part is composed as follows,
Iron oxide yellow 47 parts; Cobalt oxide 4 parts; Feldspar Powder 2 parts; Nano zine oxide 2 parts; Silicon nitride 2 parts; 2 parts, carbon fiber; Tindioxide 2 parts; TEOS2 part; Tetrafluoroethylene 2 parts;
The chemical constitution of black earth is: SiO2 45wt%, Al2O3 35wt%, CaO 10wt%, other compositions 10wt%.
The particle diameter of magnesium-aluminium spinel is less than 1 μm.
Its preparation method is as follows:
(1) batch mixing: terra-cotta blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 3 days;
(2) pressed compact is shaping, makes type at 60Mpa pressure, is incubated 2 hours, the demoulding;
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, during kiln discharge, base substrate water-content is less than 1.2wt%;
(4) glazing: glaze raw material is added water and prepares glaze, and glazing, glaze thickness is 0.2mm; Dry 24 hours after glazing and at 150 DEG C;
(5) burn till: in calcining kiln, temperature rise rate 80 DEG C/h, after being warming up to 1200 DEG C, be incubated 2 hours, utilize black earth to prepare terra-cotta.
Embodiment 5:
Utilize terra-cotta prepared by black earth,
This terra-cotta base substrate weight part is composed as follows:
100 parts, black earth; Magnesium-aluminium spinel 20 parts; Potassium felspar sand 9 parts; 3 parts, quartz; 5 parts, magnesiumcarbonate; Steel fiber 4 parts; 5 parts, resol; Starch 4 parts; 5 parts, rice husk;
This terra-cotta glaze weight part is composed as follows,
Iron oxide yellow 50 parts; Cobalt oxide 4 parts; Feldspar Powder 2 parts; Nano zine oxide 2 parts; Silicon nitride 2 parts; 2 parts, carbon fiber; Tindioxide 4 parts; TEOS2 part; Tetrafluoroethylene 2 parts;
The chemical constitution of black earth is: SiO2 45wt%, Al2O3 35wt%, CaO 10wt%, other compositions 10wt%.
The particle diameter of magnesium-aluminium spinel is less than 1 μm.
Its preparation method is as follows:
(1) batch mixing: terra-cotta blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 3 days;
(2) pressed compact is shaping, makes type at 60Mpa pressure, is incubated 2 hours, the demoulding;
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, during kiln discharge, base substrate water-content is less than 1.2wt%;
(4) glazing: glaze raw material is added water and prepares glaze, and glazing, glaze thickness is 0.2mm; Dry 24 hours after glazing and at 150 DEG C;
(5) burn till: in calcining kiln, temperature rise rate 80 DEG C/h, after being warming up to 1200 DEG C, be incubated 2 hours, utilize black earth to prepare terra-cotta.
To those skilled in the art, obviously the invention is not restricted to the details of above-mentioned one exemplary embodiment, and when not deviating from spirit of the present invention or essential characteristic, the present invention can be realized in other specific forms.Therefore, no matter from which point, all should embodiment be regarded as exemplary, and be nonrestrictive, scope of the present invention is limited by claims instead of above-mentioned explanation, and all changes be therefore intended in the implication of the equivalency by dropping on claim and scope are included in the present invention.
In addition, be to be understood that, although this specification sheets is described according to embodiment, but not each embodiment only comprises an independently technical scheme, this narrating mode of specification sheets is only for clarity sake, those skilled in the art should by specification sheets integrally, and the technical scheme in each embodiment also through appropriately combined, can form other embodiments that it will be appreciated by those skilled in the art that.
Claims (5)
1. the terra-cotta utilizing black earth to prepare, is characterized in that:
This terra-cotta base substrate weight part is composed as follows:
Black earth 90-150 part; Magnesium-aluminium spinel 20-30 part; Potassium felspar sand 8-10 part; Quartz 1-7 part; Magnesiumcarbonate 1-7 part; Steel fiber 1-7 part; Resol 1-7 part; Starch 1-7 part; Rice husk 1-7 part;
This terra-cotta glaze weight part is composed as follows:
Iron oxide yellow 40-50 part; Cobalt oxide 1-5 part; Feldspar Powder 1-5 part; Nano zine oxide 1-5 part; Silicon nitride 1-5 part; Carbon fiber 1-5 part; Tindioxide 1-5 part; TEOS 1-5 part; Tetrafluoroethylene 1-5 part;
Its preparation method is as follows:
(1) batch mixing: terra-cotta blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 3 days;
(2) pressed compact is shaping, makes type at 60Mpa pressure, is incubated 2 hours, the demoulding;
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, during kiln discharge, base substrate water-content is less than 1.2wt%;
(4) glazing: glaze raw material is added water and prepares glaze, and glazing, glaze thickness is 0.2mm; Dry 24 hours after glazing and at 150 DEG C;
(5) burn till: in calcining kiln, temperature rise rate 80 DEG C/h, after being warming up to 1200 DEG C, be incubated 2 hours, utilize black earth to prepare terra-cotta.
2. the terra-cotta utilizing black earth to prepare as claimed in claim 1, is characterized in that, the chemical constitution of black earth is: SiO245wt%, Al2O335wt%, CaO 10wt%, other compositions 10wt%.
3. the terra-cotta utilizing black earth to prepare as claimed in claim 1 or 2, is characterized in that, the particle diameter of magnesium-aluminium spinel is less than 1 μm.
4. the terra-cotta utilizing black earth to prepare as claimed in claim 1, is characterized in that, this terra-cotta base substrate weight part is composed as follows:
110 parts, black earth; Magnesium-aluminium spinel 25 parts; Potassium felspar sand 9 parts; 4 parts, quartz; 4 parts, magnesiumcarbonate; Steel fiber 4 parts; 4 parts, resol; Starch 4 parts; 4 parts, rice husk.
5. the terra-cotta utilizing black earth to prepare as described in claim 1 or 5, is characterized in that, this terra-cotta glaze weight part is composed as follows:
Iron oxide yellow 45 parts; Cobalt oxide 4 parts; Feldspar Powder 4 parts; Nano zine oxide 4 parts; Silicon nitride 4 parts; 4 parts, carbon fiber; Tindioxide 4 parts; TEOS 4 parts; Tetrafluoroethylene 4 parts.
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| CN201510292856.5A CN104860646B (en) | 2015-06-01 | 2015-06-01 | A kind of glazed tiles utilizing black earth to prepare |
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Cited By (5)
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| CN106116467A (en) * | 2016-06-22 | 2016-11-16 | 徐晓 | A kind of method utilizing black earth to prepare low grade fever's glazed tiles |
| CN106116463A (en) * | 2016-06-22 | 2016-11-16 | 徐晓 | The preparation method of low grade fever's glazed tiles additive |
| CN106242275A (en) * | 2016-08-08 | 2016-12-21 | 太仓市科教新城琉璃艺术策划中心 | The preparation technology of colored drawing coloured glaze |
| CN107265851A (en) * | 2017-07-24 | 2017-10-20 | 太仓市科教新城琉璃艺术策划中心 | A kind of coloured glaze containing black earth composition |
| CN107417254A (en) * | 2017-06-28 | 2017-12-01 | 常州市沃兰特电子有限公司 | A kind of easy fired antique glazed tile and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103538141A (en) * | 2013-10-15 | 2014-01-29 | 常熟大象建陶有限公司 | Colored glaze ceramic tile, production method of colored glaze ceramic tile, and forming device using production method |
| CN103693993A (en) * | 2013-12-23 | 2014-04-02 | 宾阳县明翔新材料科技有限公司 | Ceramic tile with heat-preservation and heat-insulation functions and production method of same |
| CN103833325A (en) * | 2014-01-04 | 2014-06-04 | 安徽省含山瓷业股份有限公司 | Low-cost domestic ceramic containing laterite |
| CN104311152A (en) * | 2014-09-30 | 2015-01-28 | 句容金猴机械研究所有限公司 | Glazed tile glaze and preparation method and application thereof |
| CN104860644A (en) * | 2015-05-29 | 2015-08-26 | 苏州拓科仪器设备有限公司 | Underglaze blue and underglaze red glaze ceramic |
-
2015
- 2015-06-01 CN CN201510292856.5A patent/CN104860646B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103538141A (en) * | 2013-10-15 | 2014-01-29 | 常熟大象建陶有限公司 | Colored glaze ceramic tile, production method of colored glaze ceramic tile, and forming device using production method |
| CN103693993A (en) * | 2013-12-23 | 2014-04-02 | 宾阳县明翔新材料科技有限公司 | Ceramic tile with heat-preservation and heat-insulation functions and production method of same |
| CN103833325A (en) * | 2014-01-04 | 2014-06-04 | 安徽省含山瓷业股份有限公司 | Low-cost domestic ceramic containing laterite |
| CN104311152A (en) * | 2014-09-30 | 2015-01-28 | 句容金猴机械研究所有限公司 | Glazed tile glaze and preparation method and application thereof |
| CN104860644A (en) * | 2015-05-29 | 2015-08-26 | 苏州拓科仪器设备有限公司 | Underglaze blue and underglaze red glaze ceramic |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106116467A (en) * | 2016-06-22 | 2016-11-16 | 徐晓 | A kind of method utilizing black earth to prepare low grade fever's glazed tiles |
| CN106116463A (en) * | 2016-06-22 | 2016-11-16 | 徐晓 | The preparation method of low grade fever's glazed tiles additive |
| CN106242275A (en) * | 2016-08-08 | 2016-12-21 | 太仓市科教新城琉璃艺术策划中心 | The preparation technology of colored drawing coloured glaze |
| CN107417254A (en) * | 2017-06-28 | 2017-12-01 | 常州市沃兰特电子有限公司 | A kind of easy fired antique glazed tile and preparation method thereof |
| CN107265851A (en) * | 2017-07-24 | 2017-10-20 | 太仓市科教新城琉璃艺术策划中心 | A kind of coloured glaze containing black earth composition |
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| CN104860646B (en) | 2016-10-05 |
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